硝酸钛

硝酸钛是一种化学性质活泼的无机化合物，化学式为Ti(NO3)4。 与原本的制备方法类似，硝酸钛可以由五氧化二氮或硝酸氯和四氯化钛反应制得。 水合硝酸钛 [Ti(H2O)6](NO3)3则可以由钛化合物溶于硝酸中而成。 硝酸钛的对称群是D2d，有四个二齿的硝酸根配体，其中的N-O键长为1.29 Å（配位）和1.185 Å（非配位）。 硝酸钛可溶于非极性溶剂四氯化硅和四氯化碳。 硝酸钛具有吸湿性，会转化为不明确的水合物。无水硝酸钛的反应性很高，甚至会和碳氢化合物反应。它也会和正十二烷、对二氯苯、苯甲醚和联苯反应。 硝酸钛受热分解成二氧化钛。 Garner, C. D.; Wallwork, S. C. The crystal structures of anhydrous nitrates and their complexes. Part III. Titanium(IV) nitrate. J. Chem. Soc. A. 1966: 1496–1500. doi:10.1039/J19660001496.  ICSD 26639 : ICSD Structure : N4 O12 Ti. Cambridge Structural Database: Access Structures. Cambridge Crystallographic Data Centre. [2021-05-08]. （原始内容存档于2021-05-09）.  Titanium(iv) nitrate (Ti(NO3)4). [27 September 2014]. （原始内容存档于2021-12-01）.  Chemistry of the Elements (Second Edition). N. N. Greenwood and A. Earnshaw. P966. 21.3.4 Compounds with oxoanions Nathaniel Howell Furman; R. J. Mundy; G. H. Morrison. The Distribution of Uranyl Nitrate from Aqueous Solutions to Diethyl Ether. the University of Michigan: U.S. Atomic Energy Commission. Technical Information Service. 1955: 51 （英语）.  Garner, C. David; Ian H. Hillier; Martyn F. Guest. Ab initio self-consistent field molecular-orbital calculation of the ground state of tetranitratotitanium(IV); comments on the reactivity of anhydrous metal nitrates. Journal of the Chemical Society, Dalton Transactions. 1975, (19): 1934. ISSN 0300-9246. doi:10.1039/DT9750001934.  Reihlen, Hans; Andreas Hake. Über die Konstitution des N2O4 und N2O3 und die Additionsverbindungen von Nitro- und Nitrosokörpern an Zinn- und Titantetrachlorid. Justus Liebig's Annalen der Chemie. 1927, 452 (1): 47–67. ISSN 0075-4617. doi:10.1002/jlac.19274520104 （德语）.  Schmeisser, Martin. Die Chemie der anorganischen Acylnitrate (ein Problem des Nitrylchlorids) und Acylperchlorate (ein Problem des Dichlorhexoxyds). Angewandte Chemie. 1955, 67 (17–18): 493–501. Bibcode:1955AngCh..67..493S. ISSN 0044-8249. doi:10.1002/ange.19550671708 （德语）.  P. Ehrlich "Titanium Tetranitrate" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1237. Schmeisser, M.; Brandle, K. Acyl nitrates and perchlorates. IV. ClNO3 as starting material for acyl nitrates. Angewandte Chemie, 1957. 69: 781. ISSN: 0044-8249. Wiberg, Egon; Wiberg, Nils. Inorganic Chemistry. Academic Press. 2001: 1331 [28 September 2014]. ISBN 9780123526519. （原始内容存档于2021-12-01）.  Amos, D.W.; G.W. Flewett. Raman spectra of titanium (IV) and tin (IV) nitrates. Spectrochimica Acta Part A: Molecular Spectroscopy. 1974, 30 (2): 453–461. Bibcode:1974AcSpA..30..453A. ISSN 0584-8539. doi:10.1016/0584-8539(74)80085-1.  Amos, D.W.; D.A. Baines, G.W. Flewett. Nitration by titanium (IV) nitrate. Tetrahedron Letters. 1973, 14 (34): 3191–3194. ISSN 0040-4039. doi:10.1016/S0040-4039(00)79808-X.  Coombes, Robert G.; Leslie W. Russell. Nitration of aromatic compounds by tetranitratotitanium(IV) in carbon tetrachloride solution. Journal of the Chemical Society, Perkin Transactions 2. 1974, (7): 830. ISSN 0300-9580. doi:10.1039/P29740000830.  Schofield, Kenneth. Aromatic Nitration. CUP Archive. 1980: 97–98 [27 September 2014]. ISBN 9780521233620. （原始内容存档于2020-08-06）.  Allendorf, Mark Donald. Titanium Oxide CVD from Titanium (IV) Nitrate .... Proceedings of the Symposium on Fundamental Gas-Phase and Surface Chemistry of Vapor-Phase Materials Synthesis. The Electrochemical Society. 1999-01-01: 395–397 [27 September 2014]. ISBN 9781566772174. （原始内容存档于2021-12-01）.  Partington, J. R.; A. L. Whynes. 660. Reactions of nitrosyl chloride. Part II. Journal of the Chemical Society (Resumed). 1949: 3135. ISSN 0368-1769. doi:10.1039/JR9490003135.  Dauerman, L.; G.E. Salser. Mass spectra of covalent inorganic nitrates: copper(II) nitrate and titanium(IV) nitrate. Journal of Inorganic and Nuclear Chemistry. 1973, 35 (1): 304–306. ISSN 0022-1902. doi:10.1016/0022-1902(73)80643-8.