氟磺酸盐

氟磺酸盐是氟磺酸的盐，含有SO3F−离子。氟磺酸根可以看作是硫酸氢根的一个羟基被氟取代而成的离子。氟磺酸根离子与金属阳离子形成配合物的倾向较低。由于氟的大小和氧相似，氟磺酸根基本是四面体形的，类似于高氯酸根。它和硫酸氢根 HSO− 4是等电子体。 如果氟磺酸的氢原子被替换成有机基团，就会形成氟磺酸酯（英语：Fluorosulfonate）。 在溶液中，氟磺酸根会完全电离。这个离子的体积为 47.8 cm3/mol。大部分金属和季铵盐都可以形成氟磺酸盐。氟磺酸盐可以由金属氯化物和无水氟磺酸反应而成，并放出氯化氢。复分解反应制备法包括金属硫酸盐和氟磺酸钡的反应，或是金属氯化物和氟磺酸银的反应，会留下沉淀。 氟磺酸根的配位性很弱，且难以氧化。它在历史上作为很重要的非配位阴离子模型。然而，到了21世纪，氟硫酸盐在这种用途中被BARF（英语：Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate）取代了。 很多二元氟磺酸盐是已知的。非金属氟磺酸盐包括卤素和氙的氟磺酸盐。一些三元氟磺酸盐也是已知的，包括 Cs[Sb(SO3F)6]、Cs[Au(SO3F)4]和 Cs2[Pt(SO3F)6]。 相关的离子化合物有氟代硒酸盐 SeO3F− 和氟代亚硫酸盐 SO2F−。氟化硫酸盐（英语：sulfate fluorides）则是另外一类化合物，它们的氟离子没有和硫酸根连接。 reederite-(Y)（英语：reederite-(Y)）是一种含有氟磺酸根的天然矿物。它是一种混合阴离子化合物（英语：mixed anion compound），其中也存在着碳酸根和氯离子。 Michałowski, Tomasz; Leszczyński, Piotr J.; Cyrański, Michał; Dobrzycki, Łukasz; Budzianowski, Armand; Grochala, Wojciech. The missing crystal structures of fluorosulfates of monovalent cations: M(I)SO3F, M=Na, Rb and Tl. Journal of Fluorine Chemistry. August 2012, 140: 116–120. doi:10.1016/j.jfluchem.2012.05.004.  Michałowski, Tomasz; Malinowski, Przemysław J.; Grochala, Wojciech. Synthesis, crystal structures, and selected properties of metal fluorosulfates(VI). Journal of Fluorine Chemistry. September 2016, 189: 102–118. doi:10.1016/j.jfluchem.2016.07.024.  Lawrance, Geoffrey A. Coordinated trifluoromethanesulfonate and fluorosulfate. Chemical Reviews. February 1986, 86 (1): 17–33. doi:10.1021/cr00071a002.  Simons, J. H. Fluorine Chemistry volume 5. Elsevier. 1964: 71–72 [2021-11-30]. ISBN 9780323147248. （原始内容存档于2021-11-30） （英语）.  Grice, Joel D.; Gault, Robert A.; Chao, George Y. Reederite-(Y), a new sodium rare-earth carbonate mineral with a unique fluorosulfate anion. American Mineralogist. 1 October 1995, 80 (9–10): 1059–1064. Bibcode:1995AmMin..80.1059G. S2CID 100079211. doi:10.2138/am-1995-9-1023.  Jache, Albert W., Fluorosulfuric Acid, Its Salts, and Derivatives, Advances in Inorganic Chemistry and Radiochemistry 16, Elsevier: 177–200, 1974, ISBN 978-0-12-023616-9, doi:10.1016/s0065-2792(08)60292-7 （英语）  Roberts, John E.; Cady, George H. The Preparation of Mercury(II), Nitrosyl and Nitronium Fluorosulfonates from Peroxydisulfuryl Difluoride. Journal of the American Chemical Society. January 1960, 82 (2): 353–354. ISSN 0002-7863. doi:10.1021/ja01487a024 （英语）.  Hayek, E.; Czaloun, A.; Krismer, B. Bildung und Zersetzung von Fluorsulfonaten. Monatshefte für Chemie. 1956, 87 (6): 741–748. ISSN 0026-9247. doi:10.1007/BF00899586 （德语）.  Singh, Sukhjinder; Verma, Rajendar D. Aluminium tris(fluorosulphate). Polyhedron. January 1983, 2 (11): 1209–1210. doi:10.1016/S0277-5387(00)84360-0.  Sharpe, H.J. Emeléus, A.G. Advances in inorganic chemistry and radiochemistry Volume 18. [S.l.]: Academic Press. 1976: 357–358. ISBN 0-12-023618-4.  Ben Altabef, A.; Brandán, S.A. A new vibrational study of chromyl fluorosulfate, CrO2(SO3F)2 by DFT calculations. Journal of Molecular Structure. September 2010, 981 (1–3): 146–152. Bibcode:2010JMoSt.981..146B. doi:10.1016/j.molstruc.2010.07.045.  Mallela, S. P.; Aubke, F. Fluorosulfate derivatives of manganese and rhenium. Inorganic Chemistry. September 1985, 24 (19): 2969–2975. ISSN 0020-1669. doi:10.1021/ic00213a020 （英语）.  Goubeau, J.; Milne, J. B. Preparation and characterization of Zn(II), Cu(II), and Fe(III) fluorosulfates. Canadian Journal of Chemistry. 15 October 1967, 45 (20): 2321–2326. doi:10.1139/v67-378 .  Alleyne, Carl S.; Thompson, Robert C. Coordinating Properties of the Fluorosulfate Ion. Tetrakis(pyridine) Complexes of Zinc(II), Copper(II), and Nickel(II) Fluorosulfates. Canadian Journal of Chemistry. 1974-09-15, 52 (18): 3218–3228. ISSN 0008-4042. doi:10.1139/v74-474  （英语）.  Storr, A.; Yeats, P. A.; Aubke, F. Gallium(III)-trisfluorosulfate. Canadian Journal of Chemistry. 1972-02-01, 50 (3): 452–454. ISSN 0008-4042. doi:10.1139/v72-068  （英语）.  Storr, A.; Yeats, P. A.; Aubke, F. Gallium(III)-trisfluorosulfate. Canadian Journal of Chemistry. February 1972, 50 (3): 452–454. doi:10.1139/v72-068 .  Emme, Larry. Synthesis of Uranium Fluorosulfates and the Group VI B Difluorophosphates. Dissertations and Theses. 2000-01-01. doi:10.15760/etd.1593  （英语）.  Cicha, Walter Vladimir. Fluorosulfate Derivatives of Niobium and Tanatalum and their behavior as Components of Novel Super Acid Systems (学位论文). University of British Columbia: 107,138. 1984 [2021-11-30]. （原始内容存档于2021-11-30）.  Leung, Patrick C.; Aubke, Friedhelm. Fluorosulfates of the noble metals. Part 6. Synthesis and magnetic properties of fluorosulfato compounds of ruthenium. Canadian Journal of Chemistry. 1984-12-01, 62 (12): 2892–2897. ISSN 0008-4042. doi:10.1139/v84-489 （英语）.  Leung, P.C.; Wong, G.B.; Aubke, F. Fluorosulfates of the noble metals, Part 7: The tris fluorosulfates of osmium and rhodium. Journal of Fluorine Chemistry. May 1987, 35 (4): 607–620. doi:10.1016/S0022-1139(00)81959-4 （英语）.  Lee, K. C.; Aubke, F. Fluorosulfates of palladium. Canadian Journal of Chemistry. 1977-07-01, 55 (13): 2473–2477. ISSN 0008-4042. doi:10.1139/v77-338 （英语）.  Hwang, G.; Wang, C.; Bodenbinder, M.; Willner, H.; Aubke, F. The syntheses and vibrational spectra of bis(carbonyl)platinum(II) fluorosulfate, Pt(CO)2(SO3F)2, and bis(carbonyl)palladium(II) fluorosulfate, Pd(CO)2(SO3F)2. Journal of Fluorine Chemistry. February 1994, 66 (2): 159–166. doi:10.1016/0022-1139(93)03013-C （英语）.  Wang, Changqing; Bodenbinder, Matthias; Willner, Helge; Rettig, Steven; Trotter, James; Aubke, Friedhelm. Synthesis, Molecular Structure, and Vibrational Spectra of cyclo-Bis(.mu.-carbonyl)dipalladium(I) Fluorosulfate, [c-Pd2(.mu.-CO)2](SO3F)2. Inorganic Chemistry. February 1994, 33 (4): 779–786. ISSN 0020-1669. doi:10.1021/ic00082a026 （英语）.  Malinowski, Przemysław J.; Derzsi, Mariana; Mazej, Zoran; Jagličić, Zvonko; Leszczyński, Piotr J.; Michałowski, Tomasz; Grochala, Wojciech. Silver(II) Fluorosulfate: A Thermally Fragile Ferromagnetic Derivative of Divalent Silver in an Oxa-Ligand Environment. European Journal of Inorganic Chemistry. June 2011, 2011 (16): 2499–2507. doi:10.1002/ejic.201100077.  Michałowski, T.; Mazej, Z.; Budzianowski, A.; Jagličić, Z.; Leszczyński, P. J.; Grochala, W. Unexpectedly Complex Crystalline Phases in the MSO 3 F-Ag(SO 3 F) 2 Phase Diagram (M = Na, K, Rb, Cs): Complex Crystalline Phases. European Journal of Inorganic Chemistry. January 2015, 2015 (2): 324–332. doi:10.1002/ejic.201402948 （英语）.  Paul, R. C., Sharma, R. D., Singh, S., & Verma, R. D. Indium and thalium fluorosulphates. Journal of Inorganic and Nuclear Chemistry. 1981, 43 (8): 1919–1920. doi:10.1016/0022-1902(81)80409-5.  Zhang, Dingliang; Rettig, Steven J.; Trotter, James; Aubke, Friedhelm. Superacid Anions: Crystal and Molecular Structures of Oxonium Undecafluorodiantimonate(V), [H 3 O][Sb 2 F 11 ], Cesium Fluorosulfate, CsSO 3 F, Cesium Hydrogen Bis(fluorosulfate), Cs[H(SO 3 F) 2 ], Cesium Tetrakis(fluorosulfato)aurate(III), Cs[Au(SO 3 F) 4 ], Cesium Hexakis(fluorosulfato)platinate(IV), Cs 2 [Pt(SO 3 F) 6 ], and Cesium Hexakis(fluorosulfato)antimonate(V), Cs[Sb(SO 3 F) 6 ]. Inorganic Chemistry. January 1996, 35 (21): 6113–6130. ISSN 0020-1669. doi:10.1021/ic960525l （英语）.  Yeats, P.A; Wilson, W.W; Aubke, F. Dibromoiodine(III)-and dichloroiodine(III)-fluorosulfate. Inorganic and Nuclear Chemistry Letters. February 1973, 9 (2): 209–214. doi:10.1016/0020-1650(73)80057-1 （英语）.  Aubke, Friedhelm; Cady, George H.; Kennard, C. H. L. Iodyl Fluorosulfate. Inorganic Chemistry. December 1964, 3 (12): 1799–1800. ISSN 0020-1669. doi:10.1021/ic50022a041 （英语）.  Johnson, Wesley M.; Macklin, John W. Vibration spectra and structure of lanthanide fluorosulfate compounds. Inorganic Chemistry. May 1976, 15 (5): 1216–1220. ISSN 0020-1669. doi:10.1021/ic50159a049 （英语）.  Dev, Rajendar.; Cady, George H. Synthesis and characterization of oxotetrakis(fluorosulfato)tungsten(VI). Inorganic Chemistry. May 1972, 11 (5): 1134–1135. ISSN 0020-1669. doi:10.1021/ic50111a046 （英语）.  Wang, Changqing; Lewis, Andrew R.; Batchelor, Raymond J.; Einstein, Frederick W. B.; Willner, Helge; Aubke, Friedhelm. Synthesis, Molecular Structure, and Vibrational Spectra of mer -Tris(carbonyl)iridium(III) Fluorosulfate, mer -Ir(CO) 3 (SO 3 F) 3. Inorganic Chemistry. January 1996, 35 (5): 1279–1285. ISSN 0020-1669. PMID 11666319. doi:10.1021/ic9506769 （英语）.  Lee, Keith C.; Aubke, Friedhelm. Fluorosulfates of the noble metals, part 4 fluorosulfates of iridium. Journal of Fluorine Chemistry. January 1982, 19 (3–6): 501–516. doi:10.1016/S0022-1139(00)83149-8 （英语）.  Willner, H.; Mistry, F.; Hwang, G.; Herring, F.G.; Cader, M.S.R.; Aubke, F. Fluorosulfate derivatives of divalent gold. Journal of Fluorine Chemistry. April 1991, 52 (1): 13–27. doi:10.1016/S0022-1139(00)80318-8.  Carter, Henry A., Charles A. Milne, and F. Aubke. Lead (IV) fluorosulphate. Journal of Inorganic and Nuclear Chemistry. 1975, 37 (1): 282–283. doi:10.1016/0022-1902(75)80170-9. (not consulted) Paul, R. C.; Singh, S.; Kumar, R. C.; Sharma, R. D.; Verma, R. D. NATURE OF TRIS (FLUOROSULPHATO) BISMUTH (III) AND CHLOROBIS (FLUOROSULPHATO) BISMUTH (III). Indian Journal of Chemistry, Section A. 1979, 17 (3): 273–275. (not consulted) Paul, R.C.; Singh, Sukhijinder; Verma, Rajendar D. Dioxouranium(VI) and oxouranium(IV) fluorosulphates and double fluorosulphates of uranium(IV). Journal of Fluorine Chemistry. August 1980, 16 (2): 153–160. doi:10.1016/S0022-1139(00)82390-8.