Add tab-completion for \unset and valid setting values of psql variables.

This commit also changes tab-completion for \set so that it displays
all the special variables like COMP_KEYWORD_CASE. Previously it displayed
only variables having the set values. Which was not user-friendly for
those who want to set the unset variables.

This commit also changes tab-completion for :variable so that only the
variables having the set values are displayed. Previously even unset
variables were displayed.

Pavel Stehule, modified by me.