pp_tms should use a local struct tms, instead of PL_timesbuf.

PL_timesbuf is effectively a vestige of Perl 1, and doesn't actually need to
be an interpreter variable. It will be removed early in v5.21.x, but it's a
good idea to refactor the code not to use it before then. A local struct tms
will be on the C stack, which will be in the CPU's L1 cache, whereas the
relevant part of the interpreter struct may well not be in the CPU cache at
all. Therefore this change might reduce cache pressure fractionally. A local
variable access should also be simpler machine code on most CPU architectures.