Honor REQUESTS_CA_BUNDLE env var in Endpoint class

This allows users to set the path to a cert bundle.
The logic is:

* Any explicit value passed to `get_endpoint()` is used
* Otherwise use `REQUESTS_CA_BUNDLE` if the var exists in the env
* Otherwise, default to true.

I'll also have to update the CLI to use this new value.

Fixes: https://github.com/boto/botocore/issues/200