Unsubscribes via members_controller are queued.

Unsubscribes coming from the CMS (i.e. via the members_controller) are
queued. Increase error checking in the controller and return more useful
results on error.

Refactor event handling code to share code between SendGrid events and
the unsubs described above. Only unsubscribe, not permanently
unsubscribe, on an unsubscribe event.