MAINT: lmfit.minimize, deprecating lmfit.minimize.Minimize.lbfgs.

scipy.optimize.minimize was added in scipy v0.11.  The minimum scipy version for lmfit is now 0.13.  This PR used a numpy deprecation warning to say that the minimize.Minimize.lbfgs and fmin method will be removed in the future.  This was originally discussed in #65.
Before merging the version number needs to be checked.