add Headers.set_raw, remove unsafe from .get_raw

Internal representation was changed from an enum back to a Struct again.
The raw representation *has* to stick around, even if parsed as a proper
typed header. The reason is that internally, hyper will access some
headers to know which parts of the http protocol to follow (such as if
the response has a length or is chunked). The raw value may still be
needed afterwards, such as for a DOM binding of
.getAllResponseHeaders().

Since the raw is kept around, the unsafety of get_raw is no longer true,
and so that is removed.

It's still more ergonomic to access the types, and safer as well, so
that is recommended when possible.