handle do_not_email user profile property change in a more generic way

* removed the assumption that unsubscription request always come from the MailChimp webhook. this will allow go-mailchimp to unsubscribe user as a result of setting the do_not_email user profile to `TRUE`
* also allow a user to be resubscribed if the `do_not_email` flag is set back to FALSE

related to https://github.com/GigaOM/legacy-pro/issues/3858