new subscribe/unsubscribe event

make changes according to weixin 4.5 api changes (20130327) 
http://mp.weixin.qq.com/wiki/index.php?title=%E6%B6%88%E6%81%AF%E6%8E%A5%E5%8F%A3%E6%8C%87%E5%8D%97#.E4.BA.8B.E4.BB.B6.E6.8E.A8.E9.80.81