tls_ctx_load_ca: Improve certificate error messages

If a CA certificate file includes intermediate certificates, and any
of them fail to verify, the current code will file with "Cannot load
CA certificate file".  Instead, generate a more specific error message
identifying the specific sub-certificate(s) which did not validate.

I make no claim that I really understand the OpenVPN code, but here's the scenario that led to this patch:

I was using the "pile of certificates" handed to me by StartSSL, and one of them was expired, but unnecessary to the verification chain.  So when I tried to verify using openssl, it worked fine, but OpenVPN complained with a not-very-helpful "Cannot load CA certificate file."  The following patch was what I ended up doing to figure out what was going wrong.

I have the suspicion that there are more complex procedures for submitting a patch that I don't know about, but I figured I'd start like this to see if the change was interesting enough to you for me to pursue it further.