Fix emote usability check. Ref #3

Previously, checking usability when API call was done. As emote sets
weren't always populated at the time the API finished, sub/turbo emotes
weren't always shown.

API call will now push to `rawEmotes` and `emotes` will be the usable
ones. `checkEmotesUsable` will run every time `populateEmotes` is run.
Although it may take some time to get the proper emotes, it is now in
line with the way Twitch handles it.