superenv: find Homebrew's gcc-4.2

If we're using a homebrewed gcc-4.2, xcrun may fail to find it (or,
worse, find superenv's shim instead). Explicitly add it to the PATH and
search all path elements for the requested tool.

Also make sure to specify 'gcc-4.2' as the compiler name, not plain
'gcc'. That can resolve to llvm-gcc and to gcc-4.0 on various Xcodes.