Move io::file to io::fs and fns out of File

This renames the `file` module to `fs` because that more accurately describes
its current purpose (manipulating the filesystem, not just files).

Additionally, this adds an UnstableFileStat structure as a nested structure of
FileStat to signify that the fields should not be depended on. The structure is
currently flagged with #[unstable], but it's unlikely that it has much meaning.