PRIMALINE® SMS
Document type: SDS
Categories: Detonating Cord, Metal

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

SECTION 1 – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Name, Address, and Telephone of the Responsible Party
Dyno Nobel LTD SDS #: 1123
6440 S. Millrock Drive, Suite 150 Date: 05/01/2025
Salt Lake City, Utah 84121 Supersedes: 07/20/2020
Phone: 801-364-4800
E-Mail: dna.healthsafety@am.dynonobel.com
www.dynonobel.com
1.1 Product Identifier
Trade Name: Detonator with Detonating Cord
Article Number: 1123
Other Product Identifiers:
 PRIMALINE® SMS Salt Mine Series

1.2 Relevant Identified uses of the Substance or Mixture and uses Advised Against
No further relevant information available.
Application of the Substance / the Mixture
Explosive product.
Commercial blasting applications.
1.3. Emergency Telephone Number
CHEMTREC 1-800-424-9300 (US/Canada)
 +01 703-527-3887 (International)

SECTION 2 – HAZARD(S) IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification According to Regulation (EC) No 1272/2008
Classifications listed also are applicable to the OSHA GHS Hazard Communication Standard (29CFR1910.1200).

exploding bomb

Expl. 1.1 H201 Explosive; mass explosion hazard.
Additional information: There are no other hazards not otherwise classified that have been identified.
0 percent of the mixture consists of component(s) of unknown toxicity
2.2 Label Elements
Labelling According to Regulation (EC) No 1272/2008
The product is additionally classified and labelled according to the Globally Harmonized System within the
United States (GHS).
The product is classified and labelled according to the CLP regulation.
Hazard Pictograms

SDS# 1123 Date: 05/01/2025 Page 1 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

GHS01
Signal Word : Danger
Hazard Statements : H201 Explosive; mass explosion hazard. Precautionary Statements : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P230 - Keep wetted. P250 - Do not subject to grinding/shock/friction. P280 - Wear protective gloves/protective clothing/eye
 protection/face protection. P240 - Ground/bond container and receiving equipment. P373 - DO NOT fight fire when fire reaches explosives. P370+P380 - In case of fire: Evacuate area. P372 - Explosion risk in case of fire. P401 - Store in accordance with local/regional/national/international
 regulations. P501 - Dispose of contents/container in accordance with
 local/regional/national/international regulations. Hazard Description
WHMIS-Symbols : Explosive products are not classified under WHMIS. NFPA Ratings (scale 0 - 4) : Not available. HMIS-Ratings (scale 0 - 4) : Not available. HMIS Long Term Health Hazard Substances
7778-74-7 potassium perchlorate
2.3 Other Hazards
Results of PBT and vPvB Assessment
PBT : Not applicable. vPvB : Not applicable. Explosive Product Notice: PREVENTION OF ACCIDENTS IN THE USE OF EXPLOSIVES - The prevention of
accidents in the use of explosives is a result of careful planning and observance of the best known practices.

sive Product Notice: PREVENTION OF ACCIDENTS IN THE USE OF EXPLOSIVES - The prevention of
accidents in the use of explosives is a result of careful planning and observance of the best known practices. The
explosives user must remember that he is dealing with a powerful force and that various devices and methods have been
developed to assist him in directing this force. He should realize that this force, if misdirected, may either kill or injure both
him and his fellow workers. WARNING - All explosives are dangerous and must be carefully handled and used following approved safety procedures
either by or under the direction of competent, experienced persons in accordance with all applicable federal, state, and
local laws, regulations, or ordinances. If you have any questions or doubts as to how to use any explosive product, DO
NOT USE IT before consulting with your supervisor, or the manufacturer, if you do not have a supervisor. If your
supervisor has any questions or doubts, he should consult the manufacturer before use.

SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Some delay periods may contain potassium perchlorate. Those that do contain between from about 4 to a maximum of
approximately 60 mg perchlorate per detonator.

SDS# 1123 Date: 05/01/2025 Page 2 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

 Dangerous components:
 CAS: 78-11-5 pentaerythritol tetranitrate (PETN)
 EINECS: 201-084-3
 Index number: 603-035-00-5 Unst. Expl., H200
 CAS: 7778-74-7 potassium perchlorate
 EINECS: 231-912-9
 Ox. Sol. 1, H271
 Index number: 017-008-00-5
 Acute Tox. 4, H302
Additional Information: For the listed ingredients, the identity and exact percentages are being withheld as a trade secret.
For the wording of the listed risk phrases refer to section 16.

SDS# 1123 Date: 05/01/2025 Page 3 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

SECTION 4 – FIRST AID MEASURES
4.1 Description of First Aid Measures
General Information: Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the
accident.
After Inhalation: Unlikely route of exposure.
Supply fresh air; consult doctor in case of complaints.
After Skin Contact: Generally the product does not irritate the skin.
Wash with soap and water.
If skin irritation is experienced, consult a doctor.
After Eye Contact: Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After Swallowing: Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Blast injury if mishandled.
Hazards
Danger of blast or crush-type injuries.
Harmful if swallowed.
Danger of disturbed cardiac rhythm.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Medical supervision for at least 48 hours.
Product may produce physical injury if mishandled. Treatment of these injuries should be based on the blast and
compression effects.

SECTION 5 – FIRE-FIGHTING MEASURES
5.1 Extinguishing Media
Suitable Extinguishing Agents: DO NOT FIGHT FIRE WHEN FIRE REACHES EXPLOSIVES.
For Safety Reasons Unsuitable Extinguishing Agents: None.
5.2 Special Hazards Arising from the Substance or Mixture
DO NOT ATTEMPT TO FIGHT FIRES INVOLVING EXPLOSIVE MATERIALS. Evacuate all personnel to a predetermined
safe location, no less than 2,500 feet in all directions. Can explode or detonate under fire conditions. Burning material
may produce toxic vapors. It is recommended that users of explosives material be familiar with the Institute of Makers of
Explosives Safety Library publications.
Explosive; mass explosion hazard.
5.3 Advice for Firefighters
Protective Equipment: Wear self-contained respiratory protective device.
Wear fully protective suit.
Additional Information
Flammability Classification: (defined by 29 CFR 1910.1200) Explosive. Can explode under fire conditions. Individual
devices will randomly explode. Mass explosion of multiple devices is possible under certain conditions. Burning material
may produce toxic and irritating vapors. In unusual cases, shrapnel may be thrown from exploding devices under
containment. See 2012 Emergency response Guidebook for further information.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

SDS# 1123 Date: 05/01/2025 Page 4 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

6.1 Personal Precautions, Protective Equipment and Emergency Procedures
Remove persons from danger area.
Ensure adequate ventilation
Wear protective clothing.
Protect from heat.
Evacuate area.
Isolate area and prevent access.
6.2 Environmental Precautions
No special measures required.
6.3 Methods and Material for Containment and Cleaning Up
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
Dispose unusable material as waste according to item 13.
6.4 Reference to Other Sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7 – HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Open and handle receptacle with care.
Handle with care. Avoid jolting, friction and impact.
Use only in well ventilated areas.
Do not subject to grinding/shock/friction.
Information About Fire - and Explosion Protection: Protect from heat. Prevent impact and friction. Emergency cooling
must be available in case of nearby fire.
7.2 Conditions for Safe Storage, Including Any Incompatibilities
Storage:
Requirements to be Met by Storerooms and Receptacles: Store in a cool location.
Avoid storage near extreme heat, ignition sources or open flame.
Information About Storage in One Common Storage Facility: Store away from foodstuffs.
Further Information About Storage Conditions: Store under lock and key and with access restricted to technical
experts or their assistants only. Keep away from heat.
7.3 Specific End Use(s): No further relevant information available.

SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional Information About Design of Technical Facilities: No further data; see item 7.
8.1 Control Parameters
Ingredients with Limit Values that Require Monitoring at the Workplace: The product does not contain any relevant
quantities of materials with critical values that have to be monitored at the workplace.
DNELs: No further relevant information available.
PNECs: No further relevant information available.
Additional Information: The lists valid during the making were used as basis.

SDS# 1123 Date: 05/01/2025 Page 5 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

8.2 Exposure Controls
Personal Protective Equipment:
General Protective and Hygienic Measures: The usual precautionary measures are to be adhered to when handling
chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory Protection: Not required under normal conditions of use.
Respiratory protection may be required after product use.
Protection of Hands: Wear gloves for the protection against mechanical hazards according to NIOSH or EN 388.
Material of Gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.
Penetration Time of Glove Material: The exact break through time has to be found out by the manufacturer of the
protective gloves and has to be observed.
Eye Protection:

Safety glasses

Face protection
Body Protection: Impervious protective clothing
Limitation and Supervision of Exposure into the Environment: No further relevant information available.
Risk Management Measures: Organizational measures should be in place for all activities involving this product.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical and Chemical Properties
General Information
Appearance
Form : Solid material
Colour : According to product specification
Odour : Characteristic
Odour Threshold : Not determined.
pH- Value : Not applicable.
Change in Condition
Melting point/Melting range : Not Determined.
Boiling point/Boiling range : Undetermined.
Flash Point : Not applicable.
Flammability (solid, gaseous) : Explosive; mass explosion hazard.
Auto/Self-ignition temperature : Not determined.
Decomposition temperature : Not determined.
Self-igniting : Product is not self-igniting.

SDS# 1123 Date: 05/01/2025 Page 6 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

Danger of explosion : Risk of explosion by shock, friction, fire or other sources of ignition.
Explosion limits
Lower : Not determined.
Upper : Not determined.
Vapour pressure : Not applicable.
Density : Not determined.
Relative density : Not determined.
Vapour density : Not applicable.
Evaporation rate : Not applicable.
Solubility in / Miscibility with water : Variable, dependent upon product composition and packaging.
Partition coefficient (n-octanol/water) : Not determined.
Viscosity
Dynamic : Not applicable.
Kinematic : Not applicable.
9.2 Other Information : No further relevant information available.

SDS# 1123 Date: 05/01/2025 Page 7 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

SECTION 10 – STABILITY AND REACTIVITY
10.1 Reactivity:
10.2 Chemical Stability:
Thermal Decomposition / Conditions to be Avoided: Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
10.3 Possibility of Hazardous Reactions: Danger of explosion.
Toxic fumes may be released if heated above the decomposition point.
10.4 Conditions to Avoid: No further relevant information available.
10.5 Incompatible Materials: No further relevant information available.
10.6 Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Nitrogen oxides. Chlorine
compounds.

SECTION 12 – ECOLOGICAL INFORMATION
12.1 Toxicity
Aquatic Toxicity: No further relevant information available.
12.2 Persistence and Degradability: No further relevant information available.
12.3 Bioaccumulative Potential: No further relevant information available.
12.4 Mobility in Soil: No further relevant information available.
Additional Ecological Information
General Notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow
undiluted product or large quantities of it to reach ground water, water course or sewage system.
12.5 Results of PBT and vPvB Assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other Adverse Effects: No further relevant information available.
SDS# 1123 Date: 05/01/2025 Page 8 of 10

SECTION 11 – TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects
Acute Toxicity:
LD/LC50 Values Relevant for Classification: None.
Primary irritant effect:
On the Skin: Not a skin irritant in unused form. Vapors/particles from used product are possibly irritating to skin.
On the Eye: Not an eye irritant in unused form. Vapors/particles from used product are possibly irritating to eyes.
Sensitisation: No sensitising effects known.
Subacute to Chronic Toxicity: No further relevant information available.
Additional toxicological information: The product shows the following dangers according to the calculation method of
the General EU
Classification Guidelines for Preparations as issued in the latest version: Harmful
Acute Effects (Acute toxicity, Irritation and Corrosivity): Danger of blast or crush-type injuries.
Harmful if swallowed.
Repeated dose toxicity: No further relevant information available.

SECTION 14 – TRANSPORT INFORMATION
14.1 UN-Number
DOT, ADR, IMDG : UN0360
IATA : FORBIDDEN
14.2 UN Proper Shipping Name
DOT, IMDG : DETONATOR ASSEMBLIES, NON-ELECTRIC
ADR : 0360 DETONATOR ASSEMBLIES, NON-ELECTRIC
IATA : FORBIDDEN
14.3 Transport Hazard Class(es)
DOT
Class : 1.1
Label : 1.1
ADR, IMDG
Class : 1.1
Label : 1.1B
IATA
Class : FORBIDDEN
14.4 Packing Group
DOT, ADR, IMDG : II
IATA FORBIDDEN
14.5 Environmental Hazards
Marine Pollutant : No
Special marking (IATA) : FORBIDDEN BY AIR.
14.6 Special Precautions for User: Not applicable.
EMS Number : F-B, S-X
Segregation groups : Perchlorates

SDS# 1123 Date: 05/01/2025 Page 9 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

SECTION 13 – DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods:
Recommendation: Must not be disposed together with household garbage. Do not allow product to reach sewage
system. Damaged materials pose a danger to anyone in the immediate area; consult experts for disposal of damaged
products.
The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with
all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and
nonhazardous wastes. Residual materials should be treated as hazardous.
Uncleaned Packaging:
Recommendation: Disposal must be made according to official regulations.

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

SECTION 15 – REGULATORY INFORMATION

SDS# 1123 Date: 05/01/2025 Page 10 of 10

)
 All ingredients are listed. Canadian Ingredient Disclosure list (limit 0.1%)
 None of the ingredients are listed. Canadian Ingredient Disclosure list (limit 1%)
 None of the ingredients are listed. Other regulations, limitations and prohibitive regulations
 This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
 SDS contains all the information required by the Controlled Products Regulations. Substances of very high concern (SVHC) according to REACH, Article 57
 None of the ingredients are listed.

15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SDS# 1123 Date: 05/01/2025 Page 11 of 10

15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture
United States (USA)
 SARA
 Section 355 (Extremely Hazardous Substances)
 None of the ingredients are listed. Section 313 (Specific Toxic Chemical Listings)
 None of the ingredients are listed. TSCA (Toxic Substances Control Act)
 All ingredients are listed. Proposition 65 (California)
 Chemicals known to cause cancer
 None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females
 None of the ingredients are listed. Chemicals known to cause reproductive toxicity for males
 None of the ingredients are listed. Chemicals known to cause developmental toxicity
 None of the ingredients are listed. Carcinogenic Categories
 EPA (Environmental Protection Agency)
 7778-74-7 potassium perchlorate NL
 IARC (International Agency for Research on Cancer)
 None of the ingredients are listed. TLV (Threshold Limit Value established by ACGIH)
 None of the ingredients are listed. NIOSH-Ca (National Institute for Occupational Safety and Health)
 None of the ingredients are listed. Canada
 Canadian Domestic Substances List (DSL)
 All ingredients are listed. Canadian Ingredient Disclosure list (limit 0.1%)
 None of the ingredients are listed. Canadian Ingredient Disclosure list (limit 1%)
 None of the ingredients are listed.

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

SECTION 16 – OTHER INFORMATION
Revision Date : 05/01/2025
Other Information : This information is based on our present knowledge. However, this shall not
 constitute a guarantee for any specific product features and shall not establish a
 legally valid contractual relationship.
Relevant Phrases
  H200 Unstable explosives.
  H271 May cause fire or explosion; strong oxidiser.
  H302 Harmful if swallowed.

Abbreviations and acronyms:
  ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
 concerning the International Carriage of Dangerous Goods by Road)
  IMDG: International Maritime Code for Dangerous Goods
  DOT: US Department of Transportation
  IATA: International Air Transport Association
  GHS: Globally Harmonised System of Classification and Labelling of Chemicals
  ACGIH: American Conference of Governmental Industrial Hygienists
  EINECS: European Inventory of Existing Commercial Chemical Substances
  ELINCS: European List of Notified Chemical Substances
  CAS: Chemical Abstracts Service (division of the American Chemical Society)
  NFPA: National Fire Protection Association (USA)
  HMIS: Hazardous Materials Identification System (USA)
  WHMIS: Workplace Hazardous Materials Information System (Canada)
  DNEL: Derived No-Effect Level (REACH)
  PNEC: Predicted No-Effect Concentration (REACH)
  LC50: Lethal concentration, 50 percent
  LD50: Lethal dose, 50 percent
  Expl. 1.1: Explosives, Division 1.1
  Unst. Expl.: Explosives, Unstable explosives
  Ox. Sol. 1: Oxidising Solids, Hazard Category 1
  Acute Tox. 4: Acute toxicity, Hazard Category 4

SDS# 1123 Date: 05/01/2025 Page 12 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com

Party Responsible for the Preparation of this Document
Dyno Nobel LTD
6440 S. Millrock Drive, Suite 150
Salt Lake City, Utah 84121
Phone: 801-364-4800

SDS# 1123 Date: 05/01/2025 Page 13 of 10

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonator with Detonating Cord

Disclaimer
Dyno Nobel LTD and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, the information contained
herein, or the results to be obtained, whether express or implied, INCLUDING WITHOUT LIMITATION, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. The information contained herein is provided for
reference purposes only and is intended only for persons having relevant technical skills. Because conditions and manner of use are outside of our
control, the user is responsible for determining the conditions of safe use of the product. Buyers and users assume all risk, responsibility and liability
whatsoever from any and all injuries (including death), losses, or damages to persons or property arising from the use of this product or information.
Under no circumstances shall either Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or incidental damages or for
anticipated loss of profits.

Dyno Nobel SDS

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