TROJAN® NB UNIVERSAL — SDS
Document type: SDS
Categories: Cast Boosters

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier
Product name TROJAN® CAST BOOSTERS
Synonyms TROJAN® NB UNIVERSAL ● TROJAN® RINGPRIME® ● TROJAN® SHIELD™ ● TROJAN® SPARTAN™ ●
 TROJAN® SPARTAN™ SR ● TROJAN® STINGER ● TROJAN® TWINPLEX® ● TROJAN® TWINPLEX® B
 ● TROJAN® WB

1.2 Uses and uses advised against
Uses BLASTING APPLICATIONS ● BOOSTER CHARGE

1.3 Details of the supplier of the product
Supplier name DYNO NOBEL ASIA PACIFIC LIMITED
Address Level 12, 515 St Pauls Terrace, Fortitude Valley, QLD, 4006, AUSTRALIA
Telephone +61 7 2143 8730
Email dnap.marketing@ap.dynonobel.com
Website http://www.dynonobel.com

1.4 Emergency telephone numbers
Emergency 1800 098 836

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
Physical Hazards
Explosives: Division 1.1

Health Hazards
Acute Toxicity: Oral: Category 3
Acute Toxicity: Skin: Category 3
Acute Toxicity: Inhalation: Category 3
Specific Target Organ Toxicity (Repeated Exposure): Category 2

Environmental Hazards
Aquatic Toxicity (Chronic): Category 2

2.2 GHS Label elements
Signal word DANGER
Pictograms

Hazard statements
H201 Explosive; mass explosion hazard.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

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Prevention statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P234 Keep only in original packaging. P240 Ground and bond container and receiving equipment. P250 Do not subject to grinding/shock/friction/rough handling. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response statements
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P311 Call a POISON CENTRE or doctor/physician. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment is advised - see first aid instructions. P330 Rinse mouth. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P370 + P372 + P380 + In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives. P373
P391 Collect spillage. Storage statements
P401 Store in accordance with relevant site and storage provisions.

fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives. P373
P391 Collect spillage. Storage statements
P401 Store in accordance with relevant site and storage provisions. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal statements
P501 Dispose of contents/container in accordance with relevant regulations. P503 Refer to manufacturer/supplier for information on disposal/recovery/recycling.

2.3 Other hazards
No information provided.

3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures
 Ingredient CAS Number EC Number Content
 PENTAERYTHRITOL TETRANITRATE (PETN) 78-11-5 201-084-3 <70%
 CYCLOTRIMETHYLENE TRINITRAMINE (RDX) 121-82-4 204-500-1 <60%
 TRINITROTOLUENE (TNT) 118-96-7 204-289-6 30 to 60%
 ALUMINIUM POWDER (PYROPHORIC) 7429-90-5 640-421-2 <15%
 CYCLOTETRAMETHYLENE TETRANITRAMINE (HMX) 2691-41-0 220-260-0 <10%

4. FIRST AID MEASURES
4.1 Description of first aid measures
Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to
 stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator where an inhalation
 risk exists. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
 Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Rinse
 mouth out with water and give plenty of water to drink.
First aid facilities Eye wash facilities should be available.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

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4.3 Immediate medical attention and special treatment needed
Treat symptomatically. Explosive material. Shrapnel from detonation may cause burns, wounds and bruises - treat symptomatically.
PETN is a vasodilator. Maintain blood pressure by fluid administration. May cause methemoglobinemia. Treat as for exposure to
nitrates. Clinical findings: The smooth muscle relaxant effect of nitrate salts may lead to headache, dizziness and marked
hypotension. Cyanosis is clinically detectable when approximately 15% of the haemoglobin has been converted to methaemoglobin
(ie. ferric iron). Symptoms such as headache, dizziness, weakness and dyspnoea occur when methaemoglobin concentrations are
30% to 40%; at levels of about 60%, stupor, convulsions, coma and respiratory paralysis occur and the blood is a chocolate brown
colour. At higher levels death may result. Spectrophotometric analysis can determine the presence and concentration of
methaemoglobin in blood.

5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
DO NOT attempt to extinguish burning explosives. Evacuate area immediately. Notify trained emergency response personnel.

5.2 Special hazards arising from the substance or mixture
EXPLOSIVE. Will explode under specific conditions. May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to
decomposition. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters, naked lights,
pilot lights, etc when handling. CAUTION: Will explode if exposed to heat or with heavy impact.

5.3 Advice for firefighters
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those
downwind of hazard. Do not attempt to fight fire. Use waterfog to cool intact containers and nearby storage areas. May explode from
heat, pressure, friction or shock.

5.4 Hazchem code
E Evacuation of people in and around the immediate vicinity of the incident should be considered.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel.

6.2 Environmental precautions
Prevent product from entering drains and waterways.

6.3 Methods of cleaning up
Contain spillage, then collect and place in suitable containers for disposal. Eliminate all sources of ignition.

6.4 Reference to other sections
See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities
Store in clean, well ventilated and dry magazine licensed for Class 1.1 Explosives. Segregate from incompatible substances and
foodstuffs. Ensure magazines are adequately labelled and protected from physical damage/shock or friction.

7.3 Specific end uses
No information provided.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
 TWA STEL
 Ingredient Reference
 ppm mg/m³ ppm mg/m³
 2,4,6-Trinitrotoluene SWA [Proposed] -- 0.1 -- --
 2,4,6-Trinitrotoluene (TNT) SWA [AUS] -- 0.5 -- --
 Aluminium (metal dust) SWA [AUS] -- 10 -- --
 Aluminium (metal dust) SWA [Proposed] -- 10 -- --
 Aluminium (welding fumes) (as Al) SWA [AUS] -- 1 -- --
 Aluminium (welding fumes) (as Al) SWA [Proposed] -- 1 -- --
 Aluminium, alkyls (NOC) (as Al) SWA [Proposed] -- 2 -- --
 Aluminium, alkyls (NOC+) (as Al) SWA [AUS] -- 2 -- --
 Aluminium, pyro powders (as Al) SWA [AUS] -- 5 -- --
 Aluminium, pyro powders (as Al) SWA [Proposed] -- 5 -- --
 Aluminium, soluble salts (as Al) SWA [AUS] -- 2 -- --
 Aluminium, soluble salts (as Al) SWA [Proposed] -- 2 -- --
 Cyclonite SWA [AUS] -- 1.5 -- --
 Cyclonite SWA [Proposed] -- 0.1 -- --

Biological limits

Ingredient Reference Determinant Sampling Time BEI
 PENTAERYTHRITOL ACGIH BEI Methemoglobin in blood During or end of 1.5% of
 TETRANITRATE (PETN) shift hemoglobin
 TRINITROTOLUENE (TNT) ACGIH BEI Methemoglobin in blood During or end of 1.5% of
 shift hemoglobin

8.2 Exposure controls
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proof
 extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.

PPE
 Eye / Face Wear safety glasses.
 Hands Wear PVC or rubber gloves.
 Body Wear coveralls.
 Respiratory Where an inhalation risk exists, wear a Class P1 (particulate) / N95 respirator.

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
 Appearance TAN TO BROWN SOLID
 Odour ODOURLESS
 Flammability EXPLOSIVE
 Flash point NOT AVAILABLE
 Boiling point NOT AVAILABLE
 Melting point 80°C (TNT)
 Evaporation rate NOT AVAILABLE
 pH NOT AVAILABLE
 Vapour density NOT AVAILABLE
 Relative density NOT AVAILABLE
 Solubility (water) INSOLUBLE
 Vapour pressure 0.042 mm Hg @ 80°C (TNT)

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9.1 Information on basic physical and chemical properties
 Upper explosion limit NOT AVAILABLE
 Lower explosion limit NOT AVAILABLE
 Partition coefficient NOT AVAILABLE
 Autoignition temperature NOT AVAILABLE
 Decomposition temperature NOT AVAILABLE
 Viscosity NOT AVAILABLE
 Explosive properties NOT AVAILABLE
 Oxidising properties NOT AVAILABLE
 Odour threshold NOT AVAILABLE
9.2 Other information
 Density 1.55 to 1.65 g/cc

10. STABILITY AND REACTIVITY
10.1 Reactivity
Carefully review all information provided in sections 10.2 to 10.6.

10.2 Chemical stability
Stable under recommended conditions of storage.

10.3 Possibility of hazardous reactions
Polymerization will not occur.

10.4 Conditions to avoid
Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials
May detonate if heated strongly or exposed to severe shock. Incompatible (explosively) with acids (e.g. nitric acid), metal powders,
combustible materials, alkalis (e.g. sodium hydroxide), oxidising agents (e.g. hypochlorites), chloride salts, sulphur, urea, nitrites and
reducing agents.

10.6 Hazardous decomposition products
May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to decomposition.

11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity Toxic if swallowed, in contact with skin, or if inhaled.
 Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50
 Ingredient

PENTAERYTHRITOL TETRANITRATE (PETN) 1660 mg/kg (rat) -- --
 CYCLOTRIMETHYLENE TRINITRAMINE (RDX) 59 mg/kg (mouse) -- --
 TRINITROTOLUENE (TNT) 660 mg/kg (mouse) -- --
 CYCLOTETRAMETHYLENE TETRANITRAMINE 50 mg/kg (rabbit) 630 mg/kg (rabbit) --
 (HMX)
Skin Not classified as a skin irritant. Adverse health effects via skin contact are not anticipated. However, serious
 damage may result from explosive fragments.
Eye Not classified as an eye irritant. Due to product form, exposure can only occur during detonation. Serious
 damage may result from explosive fragments.
Sensitisation Not classified as causing skin or respiratory sensitisation.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen.
Reproductive Not classified as a reproductive toxin.
STOT - single Due to the product encapsulation, exposure to contents is not anticipated with normal use. Use safe work
exposure practices to avoid dust/fume inhalation after detonation. Toxic fumes evolved. PETN is not absorbed
 appreciably through the skin, but is absorbed slowly through the lungs and gastrointestinal tract, causing
 dilation of the blood vessels and a reduction in blood pressure. Exposure to high doses may cause breathing
 difficulties and methaemoglobinaemia. WARNING: May explode with shock, heat, friction or static charge.
 Serious damage may result from explosive fragments.

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STOT - repeated Contains Trinitrotoluene (TNT) which may cause damage to organs (liver, blood, bone marrow, eye, kidney
exposure and nervous system) through prolonged or repeated exposure. However, exposure to contents is unlikely.
Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION
12.1 Toxicity
Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability
Expected to be persistent in the environment.

12.3 Bioaccumulative potential
TNT has moderate bioaccumulation potential; PETN is likely low.

12.4 Mobility in soil
High mobility in water and soil/sediments.

12.5 Other adverse effects
Avoid contamination of drains and waterways.

13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Waste disposal Waste must be disposed of in accordance with AS2187.2 as well as state regulatory and environmental
 legislation. Small quantities of damaged or deteriorated material may be destroyed by inclusion in a blast
 hole containing good explosives (by licensed personnel). Detonators should not be inserted into defective
 explosives. For large quantities, contact the manufacturer/supplier for additional information.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 0042 0042 None allocated.
14.2 Proper BOOSTERS without detonator BOOSTERS without detonator None allocated.
Shipping Name

14.3 Transport 1.1D 1.1D None allocated.
hazard class
14.4 Packing Group II II None allocated.
14.5 Environmental hazards
Marine Pollutant.
14.6 Special precautions for user
 Hazchem code E
 GTEPG EXP1
 EmS F-B, S-X
Other information The environmentally hazardous substance mark is not required when transported in packages of less
 than 5 kg/L (UN Model Regulations: Special Provision 375; IATA: Special Provision A197; IMDG:
 Special Provision 969) or less than 500 kg/L by Australian Road and Rail.

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15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the
 Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
 Labelling of Chemicals (GHS Revision 7).
Inventory listings AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)
 All components are listed on AIIC, or are exempt.

16. OTHER INFORMATION
Additional information DISCLAIMER: The information provided herein concern explosive products which should only be
 handled by persons having the appropriate technical expertise, training, and licence(s). The result is
 largely dependent upon the conditions of storage, transportation and use.

Whilst Dyno Nobel Asia Pacific make every effort to ensure the information contained within this SDS
 is as accurate and up-to-date as possible, the conditions under which its products are used are not
 within Dyno Nobel Asia Pacific's control. Each user has the responsibility to ensure awareness of the
 details contained within this SDS, the product applications, and the specific context of the intended
 usage. Buyers and users assume all risk, responsibility and liability arising from the use of this
 product and the information within this SDS. Dyno Nobel Asia Pacific is not responsible for damages
 of any nature resulting from the use of its products or reliance upon the information. Dyno Nobel Asia
 Pacific makes no express or implied warranties other than those implied mandatory by the
 Commonwealth, State or Territory Legislation.

® DYNO, TROJAN are registered trademarks of the Dyno Nobel/Incitec Pivot Group.

EXPLOSIONS: Fires involving explosives or explosive mixtures may undergo further explosions and
 rapid propagation. Police and emergency personnel should be notified immediately. Evacuate
 individuals to a safe sheltered area and if possible remove vehicles and further heat and ignition
 sources from the area. Consult with emergency services to determine evacuation distance and
 suitable re-entry time.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
 The recommendation for protective equipment contained within this report is provided as a guide
 only. Factors such as form of product, method of application, working environment, quantity used,
 product concentration and the availability of engineering controls should be considered before final
 selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:
 It should be noted that the effects from exposure to this product will depend on several factors
 including: form of product; frequency and duration of use; quantity used; effectiveness of control
 measures; protective equipment used and method of application. Given that it is impractical to
 prepare a report which would encompass all possible scenarios, it is anticipated that users will
 assess the risks and apply control methods where appropriate.

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Abbreviations ACGIH American Conference of Governmental Industrial Hygienists
 CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
 CNS Central Nervous System
 EC No. EC No - European Community Number
 EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
 Goods)
 GHS Globally Harmonized System
 GTEPG Group Text Emergency Procedure Guide
 IARC International Agency for Research on Cancer
 LC50 Lethal Concentration, 50% / Median Lethal Concentration
 LD50 Lethal Dose, 50% / Median Lethal Dose
 mg/m³ Milligrams per Cubic Metre
 OEL Occupational Exposure Limit
 pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
 alkaline).
 ppm Parts Per Million
 STEL Short-Term Exposure Limit
 STOT-RE Specific target organ toxicity (repeated exposure)
 STOT-SE Specific target organ toxicity (single exposure)
 SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
 SWA Safe Work Australia
 TLV Threshold Limit Value
 TWA Time Weighted Average

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
 product and serves as their Safety Data Sheet ('SDS').
 It is based on information concerning the product which has been provided to RMT by the
 manufacturer, importer or supplier or obtained from third party sources and is believed to represent
 the current state of knowledge as to the appropriate safety and handling precautions for the product
 at the time of issue. Further clarification regarding any aspect of the product should be obtained
 directly from the manufacturer, importer or supplier.
 While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
 not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
 no liability for any loss, injury or damage (including consequential loss) which may be suffered or
 incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies
 5 Ventnor Ave, West Perth
 Western Australia 6005
 Phone: +61 8 9322 1711
 Fax: +61 8 9322 1794
 Email: info@rmtglobal.com
 Web: www.rmtglobal.com

[ End of SDS ]

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