NONEL® STARTER™ — SDS
Document type: SDS
Categories: Nonelectric Initiation

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier
Product name NONEL® NON-ELECTRIC DETONATORS
Synonyms NONEL® EZTL ● NONEL® LP ● NONEL® MS ● NONEL® MS CONNECTOR ● NONEL® MS HD ●
 NONEL® MS HT ● NONEL® PRIMAFIRE ● NONEL® STARTER

1.2 Uses and uses advised against
Uses DELAY IN DETONATOR ASSEMBLIES ● DETONATORS

1.3 Details of the supplier of the product
Supplier name DYNO NOBEL ASIA PACIFIC LIMITED
Address Level 12, 515 St Pauls Terrace, Fortitude Valley, QLD, 4006, AUSTRALIA
Telephone +61 7 2143 8730
Email dnap.marketing@ap.dynonobel.com
Website http://www.dynonobel.com

1.4 Emergency telephone numbers
Emergency 1800 098 836

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
Physical Hazards
Explosives: Division 1.1

Health Hazards
Acute Toxicity: Oral: Category 4
Skin Sensitisation: Category 1
Acute Toxicity: Inhalation: Category 4
Germ Cell Mutagenicity: Category 2
Carcinogenicity: Category 1
Toxic to Reproduction: Category 1A
Specific Target Organ Toxicity (Repeated Exposure): Category 2

Environmental Hazards
Aquatic Toxicity (Acute): Category 2
Aquatic Toxicity (Chronic): Category 2

2.2 GHS Label elements
Signal word DANGER
Pictograms

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Hazard statements
H201 Explosive; mass explosion hazard. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. Prevention statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P230 Keep wetted. P234 Keep only in original packaging. P240 Ground and bond container and receiving equipment. P250 Do not subject to grinding/shock/friction/rough handling. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response statements
P302 + P352 IF ON SKIN: Wash with plenty of water.

id release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response statements
P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment is advised - see first aid instructions. P330 Rinse mouth. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P372 + P380 + In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives. P373
P391 Collect spillage. Storage statements
P401 Store in accordance with relevant site and storage provisions. P405 Store locked up. Disposal statements
P501 Dispose of contents/container in accordance with relevant regulations. P503 Refer to manufacturer/supplier for information on disposal/recovery/recycling.

2.3 Other hazards
The components contained within the unit will not represent a safety hazard under normal operating conditions. Exposure to
components may only result if the integrity of the unit is compromised. Exposure concerns are primarily with post-detonation reaction
products, particularly heavy metal compounds.

3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures
 Ingredient CAS Number EC Number Content
 CYCLOTETRAMETHYLENE TETRANITRAMINE (HMX) 2691-41-0 220-260-0 1 to 95%
 PENTAERYTHRITOL TETRANITRATE (PETN) 78-11-5 201-084-3 1 to 95%
 ALUMINIUM POWDER (PYROPHORIC) 7429-90-5 640-421-2 <10%
 ANTIMONY 7440-36-0 695-029-4 <10%
 BARIUM CHROMATE 10294-40-3 233-660-5 <10%
 BARIUM SULPHATE 7727-43-7 231-784-4 <10%
 DIATOMACEOUS EARTH 61790-53-2 807-338-5 <10%
 LEAD 7439-92-1 231-100-4 <10%
 LEAD (II) CHROMATE 7758-97-6 231-846-0 <10%

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LEAD AZIDE 13424-46-9 236-542-1 <10%
 LEAD TETROXIDE 1314-41-6 215-235-6 <10%
 MOLYBDENUM 7439-98-7 231-107-2 <10%
 POTASSIUM PERCHLORATE 7778-74-7 231-912-9 <10%
 SELENIUM 7782-49-2 231-957-4 <10%
 SILICON 7440-21-3 680-457-6 <10%
 TUNGSTEN 7440-33-7 231-143-9 <10%
 TITANIUM DIOXIDE 13463-67-7 643-044-1 <10%

4. FIRST AID MEASURES
4.1 Description of first aid measures
Eye Exposure is considered unlikely unless casing is damaged. Flush gently with running water. Seek medical
 attention if irritation develops.
Inhalation Due to product form / nature of use, an inhalation hazard is not anticipated.
Skin Exposure is considered unlikely unless casing is damaged. Gently flush affected areas with water. Seek
 medical attention if irritation develops.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to
 product form and application, ingestion is considered unlikely.
First aid facilities Eye wash facilities and safety shower should be available.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Immediate medical attention and special treatment needed
Treat symptomatically.

5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
DO NOT attempt to extinguish burning explosives. Evacuate area immediately. Notify trained emergency response personnel.

5.2 Special hazards arising from the substance or mixture
EXPLOSIVE. Will explode under specific conditions. May evolve toxic gases (carbon/ nitrogen/ lead oxides) when heated to
decomposition or detonated. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters,
naked lights, pilot lights, etc when handling. CAUTION: Will explode if exposed to heat or with heavy impact. May evolve sulphides,
chromates, antimony and various oxides and complex oxides of metals when heated to decomposition or detonated.

5.3 Advice for firefighters
Evacuate area and contact emergency services. Exposure to heat may result in detonation, however effects are expected to be limited
to the package. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full
protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Do not attempt to fight fire if other
explosives are present. Use waterfog to cool unexploded cartridges.

5.4 Hazchem code
E Evacuation of people in and around the immediate vicinity of the incident should be considered.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Clear area of all unprotected personnel. Contact emergency services where appropriate. CAUTION: Heating, impact or static charge
may cause explosion.

6.2 Environmental precautions
Prevent product from entering drains and waterways.

6.3 Methods of cleaning up
If cartridges are spilt or containers damaged, contain spillage, then collect and place in suitable containers for disposal. Eliminate all
sources of ignition.

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6.4 Reference to other sections
See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities
Store in a clean, dry magazine licensed for detonators. Detonators should not be stored with explosives. Store removed from
incompatible materials and heat or ignition sources. Ensure the magazine is adequately placarded. Large storage areas should have
appropriate ventilation and fire protection systems.

7.3 Specific end uses
No information provided.

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8.

EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
 TWA STEL
 Ingredient Reference
 ppm mg/m³ ppm mg/m³
 Aluminium (metal dust) SWA [AUS] -- 10 -- --
 Aluminium (metal dust) SWA [Proposed] -- 10 -- --
 Aluminium (welding fumes) (as Al) SWA [AUS] -- 1 -- --
 Aluminium (welding fumes) (as Al) SWA [Proposed] -- 1 -- --
 Aluminium, alkyls (NOC) (as Al) SWA [Proposed] -- 2 -- --
 Aluminium, alkyls (NOC+) (as Al) SWA [AUS] -- 2 -- --
 Aluminium, pyro powders (as Al) SWA [AUS] -- 5 -- --
 Aluminium, pyro powders (as Al) SWA [Proposed] -- 5 -- --
 Aluminium, soluble salts (as Al) SWA [AUS] -- 2 -- --
 Aluminium, soluble salts (as Al) SWA [Proposed] -- 2 -- --
 Antimony & compounds (as Sb) SWA [AUS] -- 0.5 -- --
 Antimony and compounds (excluding antimony SWA [Proposed] -- 0.5 -- --
 trioxide)
 Barium and soluble compounds SWA [Proposed] -- 0.5 -- --
 Barium sulfate (inhalable) SWA [Proposed] -- 4 -- --
 Barium sulfate (respirable) SWA [Proposed] -- 1.35 -- --
 Barium sulphate SWA [AUS] -- 10 -- --
 Chromium (VI) compounds (as Cr) SWA [AUS] -- 0.05 -- --
 Diatomaceous earth (uncalcined) SWA [Proposed] -- 10 -- --
 Diatomaceous earth (uncalcined) (a) SWA [AUS] -- 10 -- --
 Lead chromate (as Cr) SWA [AUS] -- 0.05 -- --
 Lead, inorganic dusts & fumes (as Pb) SWA [AUS] -- 0.05 -- --
 Lead, inorganic dusts and fumes (as Pb) SWA [Proposed] -- 0.05 -- --
 Molybdenum, insoluble compounds (as Mo) SWA [AUS] -- 10 -- --
 Molybdenum, insoluble compounds (as Mo) SWA [Proposed] -- 10 -- --
 (inhalable)
 Molybdenum, insoluble compounds (as Mo) SWA [Proposed] -- 3 -- 

PRODUCT NAME NONEL® NON-ELECTRIC DETONATORS

Biological limits

Ingredient Reference Determinant Sampling Time BEI
 BARIUM CHROMATE ACGIH BEI Total chromium in urine End of shift at 25 µg/L
 end of workweek
 ACGIH BEI Total chromium in urine Increase during 10 µg/L
 shift
 LEAD ACGIH BEI Lead in blood Not critical 200 µg/L
 ACGIH BEI Lead in blood (women of child Not critical 10 µg/100ml
 bearing potential)
 SWA [AUS] Lead in blood (women of child Not critical 10 µg/dL
 bearing potential)
 SWA [AUS] Lead in blood Not critical 30 µg/dL
 LEAD (II) CHROMATE ACGIH BEI Total chromium in urine End of shift at 25 µg/L
 end of workweek
 ACGIH BEI Total chromium in urine Increase during 10 µg/L
 shift
 WEL [UK] Total chromium in urine Post shift 10 μmol
 chromium/mo
 l creatinine in
 urine
 WES [NZ] Total chromium in urine End of shift at 30 µg/L
 end of workweek
 WES [Proposed] Total chromium in urine End of shift at 25 µg/L
 end of workweek
 PENTAERYTHRITOL ACGIH BEI Methemoglobin in blood During or end of 1.5% of
 TETRANITRATE (PETN) shift hemoglobin

8.2 Exposure controls
Engineering controls Avoid inhalation. Use in well ventilated areas. When testing detonators, explosion proof mechanical
 extraction ventilation may be required in poorly ventilated areas. Maintain dust levels below the
 recommended exposure standard.

PPE
 Eye / Face Wear safety glasses.
 Hands Wear PVC or rubber gloves.
 Body Wear coveralls.
 Respiratory Not required under normal conditions of use.

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
 Appearance CYLINDRICAL SOLID
 Odour ODOURLESS
 Flammability EXPLOSIVE
 Flash point NOT RELEVANT
 Boiling point NOT AVAILABLE
 Melting point NOT AVAILABLE
 Evaporation rate NOT AVAILABLE
 pH NOT AVAILABLE
 Vapour density NOT AVAILABLE
 Relative density NOT AVAILABLE
 Solubility (water) INSOLUBLE
 Vapour pressure NOT RELEVANT
 Upper explosion limit NOT RELEVANT
 Lower explosion limit NOT RELEVANT
 Partition coefficient NOT AVAILABLE

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9.1 Information on basic physical and chemical properties
 Autoignition temperature NOT AVAILABLE
 Decomposition temperature NOT AVAILABLE
 Viscosity NOT AVAILABLE
 Explosive properties EXPLOSIVE
 Oxidising properties NOT AVAILABLE
 Odour threshold NOT AVAILABLE

10. STABILITY AND REACTIVITY
10.1 Reactivity
Carefully review all information provided in sections 10.2 to 10.6.

10.2 Chemical stability
No information provided.

10.3 Possibility of hazardous reactions
No information provided.

10.4 Conditions to avoid
No information provided.

10.5 Incompatible materials
May detonate if heated strongly or exposed to severe shock. Due to enclosed form, reaction with other materials is unlikely, however
avoid contact with acids (e.g. nitric acid), metal powders, combustibles and oxidisers.

10.6 Hazardous decomposition products
May evolve toxic gases (carbon/ nitrogen/ lead oxides) when heated to decomposition or detonated.

11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity Harmful if swallowed and if inhaled. WARNING: May explode with shock, heat, friction or static charge.
 Serious damage may result from explosive fragments.
 Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50
 Ingredient

CYCLOTETRAMETHYLENE TETRANITRAMINE 50 mg/kg (rabbit) 630 mg/kg (rabbit) --
 (HMX)
 PENTAERYTHRITOL TETRANITRATE (PETN) 1660 mg/kg (rat) -- --
 BARIUM SULPHATE > 5000 mg/kg (rat) > 2000 mg/kg (rat) --
 DIATOMACEOUS EARTH > 5000 mg/kg (rat) > 5000 mg/kg (rabbit) --
 LEAD 50 mg/kg to 600 mg/kg -- --
 (calf)
 LEAD (II) CHROMATE 12 g/kg (mouse) -- --
 SELENIUM 6700 mg/kg (rat) -- --
 SILICON 3,160 mg/kg (rat) > 5,000 mg/kg (rabbit) --
 TUNGSTEN > 2,000 mg/kg (rat) > 2,000 mg/kg (rat) > 5.4 mg/l/4hrs (rat)
 TITANIUM DIOXIDE 5000 mg/kg (rat) -- 3.43 - 6.82 mg/L air (rat)
Skin Not classified as a skin irritant. Due to product form, exposure can only occur during detonation. Serious
 damage may result from explosive fragments. Eye Not classified as an eye irritant. Due to product form, exposure can only occur during detonation. Serious
 damage may result from explosive fragments. Sensitisation Exposure to contents may cause skin sensitisation. This product is not classified as a respiratory sensitiser. Mutagenicity Suspected of causing genetic defects. Due to product form (enclosed), the potential for exposure to contents
 is not anticipated. Carcinogenicity Chromium (VI) compounds are classified as carcinogenic to humans (Group 1). Lead compounds (inorganic)
 are classified as probably carcinogenic to humans (IARC Group 2A).

anticipated. Carcinogenicity Chromium (VI) compounds are classified as carcinogenic to humans (Group 1). Lead compounds (inorganic)
 are classified as probably carcinogenic to humans (IARC Group 2A). Selenium and Selenium compounds
 are not classifiable as to their carcinogenicity (IARC Group 3). Due to product form (enclosed), the potential
 for exposure to contents is not anticipated.

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Reproductive Lead and lead compounds are classified as damaging fertility or the unborn child. Due to product form
 (enclosed), the potential for exposure to contents is not anticipated.
STOT - single Not classified as causing organ damage from single exposure. However, serious damage may result from
exposure explosive fragments.
STOT - repeated Lead is a cumulative poison, and symptoms are often delayed. Repeated exposure may result in lead
exposure poisoning. Symptoms may include blood, kidney and central nervous system/brain damage. Due to product
 form (enclosed), the potential for exposure to contents is not anticipated.
Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION
12.1 Toxicity
Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability
No information provided.

12.3 Bioaccumulative potential
No information provided.

12.4 Mobility in soil
No information provided.

12.5 Other adverse effects
Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Waste disposal Waste must be disposed of in accordance with AS2187.2 as well as state regulatory and environmental
 legislation. Small quantities of damaged or deteriorated material may be destroyed by inclusion in a blast
 hole containing good explosives (by licensed personnel). Detonators should not be inserted into defective
 explosives. For large quantities, contact the manufacturer/supplier for additional information.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 0360 0360 PROH
14.2 Proper DETONATOR ASSEMBLIES, DETONATOR ASSEMBLIES, Air transport PROHIBITED under
Shipping Name NON-ELECTRIC for blasting NON-ELECTRIC for blasting the International Air Transport
 Association (IATA) Dangerous
 Goods Regulations for transport by
 air in passenger and cargo aircraft.
14.3 Transport 1.1B 1.1B None allocated.
hazard class
14.4 Packing Group None allocated. None allocated. None allocated.
14.5 Environmental hazards
Marine Pollutant.
14.6 Special precautions for user
 Hazchem code E
 EmS F-B, S-X

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15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
 Labelling of Chemicals (GHS Revision 7).
Inventory listings AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)
 All components are listed on AIIC, or are exempt.

16. OTHER INFORMATION
Additional information DISCLAIMER: The information provided herein concern explosive products which should only be
 handled by persons having the appropriate technical expertise, training, and licence(s). The result is
 largely dependent upon the conditions of storage, transportation and use.

Whilst Dyno Nobel Asia Pacific make every effort to ensure the information contained within this SDS
 is as accurate and up-to-date as possible, the conditions under which its products are used are not
 within Dyno Nobel Asia Pacific's control. Each user has the responsibility to ensure awareness of the
 details contained within this SDS, the product applications, and the specific context of the intended
 usage. Buyers and users assume all risk, responsibility and liability arising from the use of this
 product and the information within this SDS. Dyno Nobel Asia Pacific is not responsible for damages
 of any nature resulting from the use of its products or reliance upon the information. Dyno Nobel Asia
 Pacific makes no express or implied warranties other than those implied mandatory by the
 Commonwealth, State or Territory Legislation.

® DYNO, NONEL are registered trademarks of the Dyno Nobel/Incitec Pivot Group.

EXPLOSIVES & BLASTING AGENTS: Refer to Local State and Federal legislation that specifically
 relates to the use of Explosives. Users of products described in this ChemAlert Report are advised to
 ensure familiarity and compliance with the appropriate legal requirements (e.g. Regulations) prior to
 the use of this product. Where any further information is required, users may contact their local
 authority in Explosives and Dangerous Goods.

EXPLOSIONS: Fires involving explosives or explosive mixtures may undergo further explosions and
 rapid propagation. Police and emergency personnel should be notified immediately. Evacuate
 individuals to a safe sheltered area. If possible remove vehicles and further heat and ignition sources
 from the area. Do not return to areas until at least one hour after fire and explosions have ceased.

EXPLOSIONS: For further information please refer to Australian Standard 1216, for classification of
 explosives and Local and Federal Explosive and Dangerous Goods legislation (Act and Regulations).

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
 The recommendation for protective equipment contained within this report is provided as a guide
 only. Factors such as form of product, method of application, working environment, quantity used,
 product concentration and the availability of engineering controls should be considered before final
 selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:
 It should be noted that the effects from exposure to this product will depend on several factors
 including: form of product; frequency and duration of use; quantity used; effectiveness of control
 measures; protective equipment used and method of application. Given that it is impractical to
 prepare a report which would encompass all possible scenarios, it is anticipated that users will
 assess the risks and apply control methods where appropriate.

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Abbreviations ACGIH American Conference of Governmental Industrial Hygienists
 CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
 CNS Central Nervous System
 EC No. EC No - European Community Number
 EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
 Goods)
 GHS Globally Harmonized System
 GTEPG Group Text Emergency Procedure Guide
 IARC International Agency for Research on Cancer
 LC50 Lethal Concentration, 50% / Median Lethal Concentration
 LD50 Lethal Dose, 50% / Median Lethal Dose
 mg/m³ Milligrams per Cubic Metre
 OEL Occupational Exposure Limit
 pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
 alkaline).
 ppm Parts Per Million
 STEL Short-Term Exposure Limit
 STOT-RE Specific target organ toxicity (repeated exposure)
 STOT-SE Specific target organ toxicity (single exposure)
 SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
 SWA Safe Work Australia
 TLV Threshold Limit Value
 TWA Time Weighted Average

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
 product and serves as their Safety Data Sheet ('SDS').
 It is based on information concerning the product which has been provided to RMT by the
 manufacturer, importer or supplier or obtained from third party sources and is believed to represent
 the current state of knowledge as to the appropriate safety and handling precautions for the product
 at the time of issue. Further clarification regarding any aspect of the product should be obtained
 directly from the manufacturer, importer or supplier.
 While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
 not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
 no liability for any loss, injury or damage (including consequential loss) which may be suffered or
 incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies
 5 Ventnor Ave, West Perth
 Western Australia 6005
 Phone: +61 8 9322 1711
 Fax: +61 8 9322 1794
 Email: info@rmtglobal.com
 Web: www.rmtglobal.com

[ End of SDS ]

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