DigiShot® Plus.4G Electronic Initiation System — SDS
Document type: SDS
Categories: Electronic Initiation

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier
Product name ELECTRONIC DETONATORS
Synonyms DIGISHOT ELECTRONIC DETONATOR ● DIGISHOT PLUS ELECTRONIC DETONATOR ● DIGISHOT
 PLUS XR ● DIGISHOT PLUS XRS ● DIGISHOT PLUS.4G ELECTRONIC DETONATOR ● DRIFTSHOT
 ELECTRONIC DETONATOR ● DRIFTSHOT STARTER ● GEOSHOT ELECTRONIC DETONATOR ●
 HOTSHOT ELECTRONIC DETONATOR ● QUICKSHOT ELECTRONIC DETONATOR ● SMARTSHOT
 ELECTRONIC DETONATOR

1.2 Uses and uses advised against
Uses DETONATOR ● INITIATING EXPLOSIVE CHARGE ● MINING EXPLOSIVE ● MINING INDUSTRY

1.3 Details of the supplier of the product
Supplier name DYNO NOBEL ASIA PACIFIC LIMITED
Address Level 12, 515 St Pauls Terrace, Fortitude Valley, QLD, 4006, AUSTRALIA
Telephone +61 7 2143 8730
Email dnap.marketing@ap.dynonobel.com
Website http://www.dynonobel.com

1.4 Emergency telephone numbers
Emergency 1800 098 836

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
Physical Hazards
Explosives: Division 1.4

Health Hazards
Not classified as a Health Hazard

Environmental Hazards
Not classified as an Environmental Hazard

2.2 GHS Label elements
Signal word WARNING
Pictograms

Hazard statements
None allocated.

Prevention statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P240 Ground and bond container and receiving equipment.
P250 Do not subject to grinding/shock/friction/rough handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

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Response statements
P370 + P372 + P380 + In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives.
P373
Storage statements
P401 Store in accordance with relevant site and storage provisions.
Disposal statements
P503 Refer to manufacturer/supplier for information on disposal/recovery/recycling.

2.3 Other hazards
This is a packaged product that will not result in exposure to the explosive material under normal conditions of use. Exposure
concerns are primarily with post-detonation reaction products. If released, contents of package will be hazardous.

3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures
 Ingredient CAS Number EC Number Content
 6-DIAZO-2,4-DINITROCYCLOHEXA-2,4-DIEN-1-ONE 4682-03-5 225-134-9 Not Available
 LEAD AZIDE 13424-46-9 236-542-1 Not Available
 NITROCELLULOSE 9004-70-0 682-719-5 Not Available
 PENTAERYTHRITOL TETRANITRATE (PETN) 78-11-5 201-084-3 Not Available
 NON HAZARDOUS INGREDIENTS Not Available Not Available Remainder

4. FIRST AID MEASURES
4.1 Description of first aid measures
Eye Exposure is considered unlikely unless casing is damaged. Flush gently with running water. Seek medical
 attention if irritation develops.
Inhalation Due to product form / nature of use, an inhalation hazard is not anticipated.
Skin Exposure is considered unlikely unless casing is damaged. Gently flush affected areas with water. Seek
 medical attention if irritation develops.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to
 product form and application, ingestion is considered unlikely.
First aid facilities Eye wash facilities and normal washroom facilities should be available.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Immediate medical attention and special treatment needed
Treat symptomatically.

5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
DO NOT attempt to extinguish burning explosives. Evacuate area immediately. Notify trained emergency response personnel.

5.2 Special hazards arising from the substance or mixture
EXPLOSIVE. Will explode under specific conditions. May evolve toxic gases (carbon/ nitrogen/ lead oxides) when heated to
decomposition or detonated. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters,
naked lights, pilot lights, etc when handling. CAUTION: Will explode if exposed to heat or with heavy impact.

5.3 Advice for firefighters
Evacuate area and contact emergency services. Exposure to heat may result in detonation, however effects are expected to be limited
to the package. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full
protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Do not attempt to fight fire if other
explosives are present. Use waterfog to cool unexploded cartridges.

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5.4 Hazchem code
1YE
1 Coarse Water Spray.
Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.
E Evacuation of people in and around the immediate vicinity of the incident should be considered.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Clear area of all unprotected personnel. Contact emergency services where appropriate. CAUTION: May detonate if exposed to heat,
friction or shock.

6.2 Environmental precautions
Prevent product from entering drains and waterways.

6.3 Methods of cleaning up
If spilt/ containers damaged (bulk), contact emergency services where appropriate. Clear area of all unprotected personnel. Eliminate
all sources of ignition. Only trained personnel should undertake clean up.

6.4 Reference to other sections
See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities
Store in a clean, dry magazine licensed for detonators. Detonators should not be stored with explosives. Store removed from
incompatible materials and heat or ignition sources. Ensure the magazine is adequately placarded. Large storage areas should have
appropriate ventilation and fire protection systems.

7.3 Specific end uses
No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
 TWA STEL
 Ingredient Reference
 ppm mg/m³ ppm mg/m³
 Lead, inorganic dusts & fumes (as Pb) SWA [AUS] -- 0.05 -- --

Biological limits

Ingredient Reference Determinant Sampling Time BEI
 PENTAERYTHRITOL ACGIH BEI Methemoglobin in blood During or end of 1.5% of
 TETRANITRATE (PETN) shift hemoglobin

8.2 Exposure controls
Engineering controls Avoid inhalation. Use in well ventilated areas. When testing detonators, explosion proof mechanical
 extraction ventilation may be required in poorly ventilated areas.

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PPE
 Eye / Face Wear safety glasses.
 Hands Wear PVC or rubber gloves.
 Body Wear coveralls.
 Respiratory Not required under normal conditions of use.

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
 Appearance COPPER TUBE WITH A COLOURED WIRING HARNESS
 Odour ODOURLESS
 Flammability EXPLOSIVE
 Flash point NOT AVAILABLE
 Boiling point NOT AVAILABLE
 Melting point NOT AVAILABLE
 Evaporation rate NOT AVAILABLE
 pH NOT AVAILABLE
 Vapour density NOT AVAILABLE
 Relative density NOT AVAILABLE
 Solubility (water) INSOLUBLE
 Vapour pressure NOT AVAILABLE
 Upper explosion limit NOT AVAILABLE
 Lower explosion limit NOT AVAILABLE
 Partition coefficient NOT AVAILABLE
 Autoignition temperature 100°C
 Decomposition temperature 100°C
 Viscosity NOT AVAILABLE
 Explosive properties EXPLOSIVE
 Oxidising properties NOT AVAILABLE
 Odour threshold NOT AVAILABLE

10. STABILITY AND REACTIVITY
10.1 Reactivity
Reacts with incompatible materials.

10.2 Chemical stability
Explosive material. Detonation may occur from impact, friction, or excessive heating.

10.3 Possibility of hazardous reactions
Polymerization will not occur.

10.4 Conditions to avoid
Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials
May detonate if heated strongly or exposed to severe shock. Due to enclosed form, reaction with other materials is unlikely, however
avoid contact with acids (e.g. nitric acid), metal powders, combustibles and oxidisers.

10.6 Hazardous decomposition products
May evolve toxic gases (carbon/ nitrogen/ lead oxides) when heated to decomposition or detonated.

11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects

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Acute toxicity Due to the product encapsulation, acute toxicity associated with the contents is not anticipated with normal
 use. Use safe work practices to avoid dust/fume inhalation after detonation. WARNING: May explode with
 shock, heat, friction or static charge. Serious damage may result from explosive fragments.
 Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50
 Ingredient

NITROCELLULOSE > 5 g/kg (rat) -- --
 PENTAERYTHRITOL TETRANITRATE (PETN) 1660 mg/kg (rat) -- --
Skin Contact with contents/fumes may result in irritation, redness, pain, rash and dermatitis. Due to product form
 (enclosed), the potential for exposure to contents is not anticipated. Serious damage may result from
 explosive fragments. Eye Contact with contents/fumes may cause discomfort, lacrimation and redness. Due to product form
 (enclosed), the potential for exposure to contents is not anticipated. Serious damage may result from
 explosive fragments. Sensitisation Not classified as causing skin or respiratory sensitisation. Mutagenicity Lead azide is suspected of causing genetic defects. Due to product form (enclosed), the potential for
 exposure to contents is not anticipated. Carcinogenicity Lead compounds (inorganic) are classified as probably carcinogenic to humans (IARC Group 2A). Due to
 product form (enclosed), the potential for exposure to contents is not anticipated. Reproductive There is sufficient data to indicate that lead compounds may damage fertility or the unborn child. STOT - single Not classified as causing organ damage from single exposure. However, serious damage may result from
exposure explosive fragments. STOT - repeated Lead is a cumulative poison, and symptoms are often delayed. Repeated exposure may result in lead
exposure poisoning.

ever, serious damage may result from
exposure explosive fragments. STOT - repeated Lead is a cumulative poison, and symptoms are often delayed. Repeated exposure may result in lead
exposure poisoning. Symptoms may include blood, kidney and central nervous system/brain damage. Due to product
 form (enclosed), the potential for exposure to contents is not anticipated. Aspiration This product does not present an aspiration hazard.

12. ECOLOGICAL INFORMATION
12.1 Toxicity
The contents of this product may be hazardous to the environment.

12.2 Persistence and degradability
This product is not readily biodegradable.

12.3 Bioaccumulative potential
No information provided.

12.4 Mobility in soil
No information provided.

12.5 Other adverse effects
Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Waste disposal Waste must be disposed of in accordance with AS2187.2 as well as state regulatory and environmental
 legislation. Small quantities of damaged or deteriorated material may be destroyed by inclusion in a blast
 hole containing good explosives (by licensed personnel). Detonators should not be inserted into defective
 explosives. For large quantities, contact the manufacturer/supplier for additional information.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

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LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 0512 0512 0512
14.2 Proper DETONATORS, ELECTRONIC DETONATORS, ELECTRONIC DETONATORS, ELECTRONIC
Shipping Name programmable for blasting programmable for blasting programmable for blasting

14.3 Transport 1.4B 1.4B 1.4B
hazard class
14.4 Packing Group None allocated. None allocated. None allocated.
14.5 Environmental hazards
Not a Marine Pollutant.
14.6 Special precautions for user
 Hazchem code 1YE
 EmS F-B, S-X

15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the
 Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
 Labelling of Chemicals (GHS Revision 7).
Inventory listings AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)
 Some components are listed on AIIC, or are exempt.

16. OTHER INFORMATION
Additional information DISCLAIMER: The information provided herein concern explosive products which should only be
 handled by persons having the appropriate technical expertise, training, and licence(s). The result is
 largely dependent upon the conditions of storage, transportation and use.

Whilst Dyno Nobel Asia Pacific make every effort to ensure the information contained within this SDS
 is as accurate and up-to-date as possible, the conditions under which its products are used are not
 within Dyno Nobel Asia Pacific's control. Each user has the responsibility to ensure awareness of the
 details contained within this SDS, the product applications, and the specific context of the intended
 usage. Buyers and users assume all risk, responsibility and liability arising from the use of this
 product and the information within this SDS. Dyno Nobel Asia Pacific is not responsible for damages
 of any nature resulting from the use of its products or reliance upon the information. Dyno Nobel Asia
 Pacific makes no express or implied warranties other than those implied mandatory by the
 Commonwealth, State or Territory Legislation.

® DYNO, DIGISHOT,DRIFTSHOT, GEOSHOT,HOTSHOT, QUICKSHOT ,SMARTSHOT are
 registered trademarks of the Dyno Nobel/Incitec Pivot Group.

EXPLOSIVES & BLASTING AGENTS: Refer to Local State and Federal legislation that specifically
 relates to the use of Explosives. Users of products described in this ChemAlert Report are advised to
 ensure familiarity and compliance with the appropriate legal requirements (e.g. Regulations) prior to
 the use of this product. Where any further information is required, users may contact their local
 authority in Explosives and Dangerous Goods.

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PRODUCT NAME ELECTRONIC DETONATORS
 EXPLOSIONS: Fires involving explosives or explosive mixtures may undergo further explosions and
 rapid propagation. Police and emergency personnel should be notified immediately. Evacuate
 individuals to a safe sheltered area at least 800 metres away. If possible remove vehicles and further
 heat and ignition sources from the area. Do not return to areas until at least one hour after fire and
 explosions have ceased. EXPLOSIONS: Fires involving explosives or explosive mixtures may
 undergo further explosions and rapid propagation. Police and emergency personnel should be
 notified immediately. Evacuate individuals to a safe sheltered area. If possible remove vehicles and
 further heat and ignition sources from the area. Do not return to areas until at least one hour after fire
 and explosions have ceased.

EXPLOSIONS: For further information please refer to Australian Standard 1216, for classification of
 explosives and Local and Federal Explosive and Dangerous Goods legislation (Act and Regulations).

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
 The recommendation for protective equipment contained within this report is provided as a guide
 only. Factors such as form of product, method of application, working environment, quantity used,
 product concentration and the availability of engineering controls should be considered before final
 selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:
 It should be noted that the effects from exposure to this product will depend on several factors
 including: form of product; frequency and duration of use; quantity used; effectiveness of control
 measures; protective equipment used and method of application. Given that it is impractical to
 prepare a report which would encompass all possible scenarios, it is anticipated that users will
 assess the risks and apply control methods where appropriate.

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists
 CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
 CNS Central Nervous System
 EC No. EC No - European Community Number
 EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
 Goods)
 GHS Globally Harmonized System
 GTEPG Group Text Emergency Procedure Guide
 IARC International Agency for Research on Cancer
 LC50 Lethal Concentration, 50% / Median Lethal Concentration
 LD50 Lethal Dose, 50% / Median Lethal Dose
 mg/m³ Milligrams per Cubic Metre
 OEL Occupational Exposure Limit
 pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
 alkaline).
 ppm Parts Per Million
 STEL Short-Term Exposure Limit
 STOT-RE Specific target organ toxicity (repeated exposure)
 STOT-SE Specific target organ toxicity (single exposure)
 SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
 SWA Safe Work Australia
 TLV Threshold Limit Value
 TWA Time Weighted Average

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
 product and serves as their Safety Data Sheet ('SDS').
 It is based on information concerning the product which has been provided to RMT by the
 manufacturer, importer or supplier or obtained from third party sources and is believed to represent
 the current state of knowledge as to the appropriate safety and handling precautions for the product
 at the time of issue. Further clarification regarding any aspect of the product should be obtained
 directly from the manufacturer, importer or supplier.
 While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
 not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
 no liability for any loss, injury or damage (including consequential loss) which may be suffered or
 incurred by any person as a consequence of their reliance on the information contained in this SDS.

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PRODUCT NAME ELECTRONIC DETONATORS

Prepared by Risk Management Technologies
 5 Ventnor Ave, West Perth
 Western Australia 6005
 Phone: +61 8 9322 1711
 Fax: +61 8 9322 1794
 Email: info@rmtglobal.com
 Web: www.rmtglobal.com

 [ End of SDS ]

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