TITAN® 2000 Matrix Blends — SDS
Document type: SDS
Categories: Bulk Explosives

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier
Product name TITAN® MATRIX SERIES
Synonyms DX5030 ● TITAN® 2000 EMULSION ● TITAN® 2000 MATRIX ● TITAN® 3000 MATRIX ● TITAN® 5000
 EMULSION MATRIX ● TITAN® 5000 MATRIX ● TITAN® 7000 EMULSION MATRIX ● TITAN® 7000 MATRIX
 ● TITAN® 7000I EMULSION MATRIX ● TITAN® 7000I MATRIX ● TITAN® 7000SI EMULSION MATRIX ●
 TITAN® 7000SX MATRIX ● TITAN® 7100I MATRIX ● TITAN® 9000 MATRIX ● TITAN®1000 EMULSION
 MATRIX ● TITAN®1000XL MATRIX ● TITAN®1000ΔE MATRIX ● TITAN®1500 EMULSION MATRIX ●
 TITAN®1500XL MATRIX ● TITAN®1500ΔE MATRIX

1.2 Uses and uses advised against
Uses EXPLOSIVES

1.3 Details of the supplier of the product
Supplier name DYNO NOBEL ASIA PACIFIC LIMITED
Address Level 12, 515 St Pauls Terrace, Fortitude Valley, QLD, 4006, AUSTRALIA
Telephone +61 7 2143 8730
Email dnap.marketing@ap.dynonobel.com
Website http://www.dynonobel.com

1.4 Emergency telephone numbers
Emergency 1800 098 836

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
Physical Hazards
Oxidizing Liquids: Category 2

Health Hazards
Skin Corrosion / Irritation: Category 2
Serious Eye Damage / Eye Irritation: Category 2A
Specific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)
Carcinogenicity: Category 2

Environmental Hazards
Not classified as an Environmental Hazard

2.2 GHS Label elements
Signal word DANGER
Pictograms

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Hazard statements
H272 May intensify fire; oxidiser. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. Prevention statements
P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep away from clothing and other combustible materials. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response statements
P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
 do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment is advised - see first aid instructions. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use appropriate media to extinguish. Storage statements
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

it before reuse. P370 + P378 In case of fire: Use appropriate media to extinguish. Storage statements
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal statements
P501 Dispose of contents/container in accordance with relevant regulations.

2.3 Other hazards
No information provided.

3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures
 Ingredient CAS Number EC Number Content
 AMMONIUM NITRATE 6484-52-2 629-213-2 >60%
 SODIUM NITRATE 7631-99-4 231-554-3 <15%
 OIL(S) - - <10%
 NON HAZARDOUS INGREDIENTS Not Available Not Available 10 to 30%
 INORGANIC OXIDISER(S) - - <15%
 EMULSIFIER(S) - - <10%
 OXYGEN NEGATIVE MATERIALS - - <10%

4. FIRST AID MEASURES
4.1 Description of first aid measures
Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to
 stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs wash with water and soaps that are not a hazardous substance, do not have a
 pH greater than 7 and are compatible with oxidising agents. An example of compatible soap is Septone
 Nature Clean. If unsure, contact the company representative. Remove all contaminated clothing
 immediately. Wash affected area thoroughly with a compatible soap. Wash contaminated clothing before
 reuse or discard. Seek medical attention.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If
 swallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.

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4.2 Most important symptoms and effects, both acute and delayed
Over exposure may result in methaemoglobinemia, where the blood's oxygen-carrying capacity is reduced.

4.3 Immediate medical attention and special treatment needed
Treat as for nitrate overexposure (methaemoglobinemia). Treatment:
1. Give 100% oxygen. 2. In cases of (a) ingestion: use gastric lavage, (b) contamination of skin (unburnt or burnt): continue washing to remove salts. 3. Observe blood pressure and treat hypotension if necessary. 4. When methaemoglobin concentrations exceed 40% or when symptoms are present, give methylene blue 1 to 2 mg/kg body weight
in a 1% solution by slow intravenous injection. If cyanosis has not resolved within one hour a second dose of 2 mg/kg body weight
may be given. The total dose should not exceed 7 mg/kg body weight as unwanted effects such as dyspnoea, chest pain, vomiting,
diarrhoea, mental confusion and cyanosis may occur. Without treatment methaemoglobin levels of 20-30% revert to normal within 3
days. 5. Bed rest is required for methaemoglobin levels in excess of 40%. 6. Continue to monitor and give oxygen for at least two hours after treatment with methylene blue. 7. Consider transfer to centre where haemoperfusion can be performed to remove the nitrates from the blood if the condition of the
patient is unstable. 8. Following inhalation of oxides of nitrogen the patient should be observed in hospital for 24 hours for delayed onset of pulmonary
oedema.

from the blood if the condition of the
patient is unstable. 8. Following inhalation of oxides of nitrogen the patient should be observed in hospital for 24 hours for delayed onset of pulmonary
oedema. Further observation for 2-3 weeks may be required to detect the onset of the inflammatory changes of bronchiolitis fibrosa obliterans.

5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
Use an extinguishing agent suitable for the surrounding fire.

5.2 Special hazards arising from the substance or mixture
Oxidising agent. Explosive. In fire situation, water will evaporate & there is some potential for explosion (at high temperature and
pressure). May evolve toxic gases (ammonium nitrate, nitrogen oxides) when heated to decomposition.

5.3 Advice for firefighters
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those
downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use
waterfog to cool intact containers and nearby storage areas.

5.4 Hazchem code
1Y
1 Coarse Water Spray.
Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.

6.2 Environmental precautions
Prevent product from entering drains and waterways.

6.3 Methods of cleaning up
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in
suitable containers for disposal.

6.4 Reference to other sections
See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Use in a well ventilated area. DO NOT use in confined spaces. Build up of mists or vapours in the atmosphere must be prevented.
Avoid breathing in spray or mists or vapours. Do not use near welding or other ignition sources and avoid sparks. Do not smoke.
When dealing with large quantities, repeated or prolonged skin exposure without protection should be prevented in order to lessen the
possibility of skin disorders. It is essential that all who come into contact with this material maintain high standards of personal hygiene
ie. Washing hands prior to eating, drinking, smoking or using toilet facilities.

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7.2 Conditions for safe storage, including any incompatibilities
Store according to recommendations outlined in the AEISG Code of Practice for Ammonium Nitrate Emulsions, Suspensions or Gels -
ANE's (UN3375). Store in suitable, labelled containers away from incompatible materials. Inspect periodically for deficiencies such as
damage or leaks. Have appropriate fire extinguishers available in and near the storage area.

7.3 Specific end uses
No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.

Biological limits

Ingredient Reference Determinant Sampling Time BEI
 AMMONIUM NITRATE ACGIH BEI Methemoglobin in blood During or end of 1.5% of
 shift hemoglobin

8.2 Exposure controls
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction
 ventilation is recommended.

PPE
 Eye / Face Wear splash-proof goggles.
 Hands Wear PVC or butyl or nitrile gloves.
 Body Wear coveralls.
 Respiratory Where an inhalation risk exists, wear a Class P2 (particulate) / N95 respirator. At high vapour levels, wear
 an Air-line / Full Facepiece Supplied-Air Respirator (SAR).

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
 Appearance CLEAR GOLD LIQUID
 Odour SLIGHT ODOUR
 Flammability EXPLOSIVE
 Flash point NOT AVAILABLE
 Boiling point NOT AVAILABLE
 Melting point NOT AVAILABLE
 Evaporation rate NOT AVAILABLE
 pH NOT AVAILABLE
 Vapour density NOT AVAILABLE
 Relative density 1.29 to 1.42
 Solubility (water) INSOLUBLE
 Vapour pressure NOT AVAILABLE
 Upper explosion limit NOT AVAILABLE
 Lower explosion limit NOT AVAILABLE
 Partition coefficient NOT AVAILABLE
 Autoignition temperature NOT AVAILABLE
 Decomposition temperature NOT AVAILABLE
 Viscosity NOT AVAILABLE
 Explosive properties NOT AVAILABLE
 Oxidising properties OXIDISING LIQUID
 Odour threshold NOT AVAILABLE

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10. STABILITY AND REACTIVITY
10.1 Reactivity
Powerful oxidising agent.

10.2 Chemical stability
Powerful oxidising agent. Stable under recommended conditions of storage.

10.3 Possibility of hazardous reactions
Polymerization will not occur.

10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials
Oxidising agent. Incompatible with combustible materials, reducing agents (e.g. sulphites), acids (e.g. nitric acid), alkalis (e.g. sodium
hydroxide), metals, heat and ignition sources.

10.6 Hazardous decomposition products
May evolve nitrogen oxides (nitrous oxide) and ammonium nitrate when heated to decomposition.

11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity Acute exposure to mist or fumes may lead to coughing, headache, and shortness of breath. Although less
 toxic than pure ammonium nitrate, emulsions may still pose a risk of methemoglobinemia at high doses,
 interfering with oxygen transport in the blood. May explode with shock, heat, friction or static charge. Serious
 damage may result from explosive fragments.
 Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50
 Ingredient

AMMONIUM NITRATE 2217 mg/kg (rat) > 5000 mg/kg (rat) --
 SODIUM NITRATE 3430 mg/kg (rat) > 5000 mg/kg (rat) --
Skin Contact may result in irritation, redness, rash and dermatitis.
Eye Contact may result in irritation, lacrimation and redness.
Sensitisation Not classified as causing skin or respiratory sensitisation.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen. Diesel fuels, distillate (light) is not classifiable as to its carcinogenicity to
 humans (IARC Group 3).
Reproductive Not classified as a reproductive toxin.
STOT - single Over exposure to mists/vapours may result in irritation of the nose and throat, coughing, nausea and
exposure headache. High level exposure may result in drowsiness, breathing difficulties and methaemoglobinemia
 (blood's oxygen-carrying capacity is reduced).
STOT - repeated Not classified as causing organ damage from repeated exposure.
exposure
Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION
12.1 Toxicity
Ammonium nitrate itself has low acute toxicity to aquatic organisms, but in high concentrations, it can cause eutrophication, leading to
algal blooms and oxygen depletion in water bodies.

12.2 Persistence and degradability
Ammonium nitrate is readily soluble and does not persist in the environment.

12.3 Bioaccumulative potential
Does not bioaccumulate.

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12.4 Mobility in soil
Very high mobility due to its high water solubility.

12.5 Other adverse effects
Avoid contamination of drains and waterways.

13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For
 large quantities, contact the manufacturer/supplier for additional information. Prevent contamination of drains
 and waterways as aquatic life may be threatened and environmental damage may result.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 3375 3375 3375
14.2 Proper AMMONIUM NITRATE EMULSION AMMONIUM NITRATE EMULSION AMMONIUM NITRATE EMULSION
Shipping Name

14.3 Transport 5.1 5.1 5.1
hazard class
14.4 Packing Group II II II
14.5 Environmental hazards
Not a Marine Pollutant.
14.6 Special precautions for user
 Hazchem code 1Y
 GTEPG 5D1
 EmS F-H, S-Q

15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the
 Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
 Labelling of Chemicals (GHS Revision 7).
Inventory listings AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)
 All components are listed on AIIC, or are exempt.

16. OTHER INFORMATION
Additional information

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PRODUCT NAME TITAN® MATRIX SERIES
 DISCLAIMER The information provided herein concern explosive products which should only be
 handled by persons having the appropriate technical expertise, training, and licence(s). The result is
 largely dependent upon the conditions of storage, transportation and use.

Whilst Dyno Nobel Asia Pacific make every effort to ensure the information contained within this SDS
 is as accurate and up-to-date as possible, the conditions under which its products are used are not
 within Dyno Nobel Asia Pacific's control. Each user has the responsibility to ensure awareness of the
 details contained within this SDS, the product applications, and the specific context of the intended
 usage. Buyers and users assume all risk, responsibility and liability arising from the use of this
 product and the information within this SDS. Dyno Nobel Asia Pacific is not responsible for damages
 of any nature resulting from the use of its products or reliance upon the information. Dyno Nobel Asia
 Pacific makes no express or implied warranties other than those implied mandatory by the
 Commonwealth, State or Territory Legislation.

DYNO®, TITAN®, are registered trademarks of the Dyno Nobel/Incitec Pivot Group.

EXPLOSIONS: Fires involving explosives or explosive mixtures may undergo further explosions and
 rapid propagation. Police and emergency personnel should be notified immediately. Evacuate
 individuals to a safe sheltered area at least 800 metres away. If possible remove vehicles and further
 heat and ignition sources from the area. Do not return to areas until at least one hour after fire and
 explosions have ceased.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
 The recommendation for protective equipment contained within this report is provided as a guide
 only. Factors such as form of product, method of application, working environment, quantity used,
 product concentration and the availability of engineering controls should be considered before final
 selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:
 It should be noted that the effects from exposure to this product will depend on several factors
 including: form of product; frequency and duration of use; quantity used; effectiveness of control
 measures; protective equipment used and method of application. Given that it is impractical to
 prepare a report which would encompass all possible scenarios, it is anticipated that users will
 assess the risks and apply control methods where appropriate.

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists
 CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
 CNS Central Nervous System
 EC No. EC No - European Community Number
 EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
 Goods)
 GHS Globally Harmonized System
 GTEPG Group Text Emergency Procedure Guide
 IARC International Agency for Research on Cancer
 LC50 Lethal Concentration, 50% / Median Lethal Concentration
 LD50 Lethal Dose, 50% / Median Lethal Dose
 mg/m³ Milligrams per Cubic Metre
 OEL Occupational Exposure Limit
 pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
 alkaline).
 ppm Parts Per Million
 STEL Short-Term Exposure Limit
 STOT-RE Specific target organ toxicity (repeated exposure)
 STOT-SE Specific target organ toxicity (single exposure)
 SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
 SWA Safe Work Australia
 TLV Threshold Limit Value
 TWA Time Weighted Average

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PRODUCT NAME TITAN® MATRIX SERIES

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
 product and serves as their Safety Data Sheet ('SDS').
 It is based on information concerning the product which has been provided to RMT by the
 manufacturer, importer or supplier or obtained from third party sources and is believed to represent
 the current state of knowledge as to the appropriate safety and handling precautions for the product
 at the time of issue. Further clarification regarding any aspect of the product should be obtained
 directly from the manufacturer, importer or supplier.
 While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
 not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
 no liability for any loss, injury or damage (including consequential loss) which may be suffered or
 incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies
 5 Ventnor Ave, West Perth
 Western Australia 6005
 Phone: +61 8 9322 1711
 Fax: +61 8 9322 1794
 Email: info@rmtglobal.com
 Web: www.rmtglobal.com

 [ End of SDS ]

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