kcherry497/dyno-blast-4b-rag huggingface dataset:
FIRELINE 10/50 HMX LS RIBBON (SDS), page 10 of 16

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonating Cord, Specialty (Oil Field) (Class 1.1D)

11.1 Information on Toxicological Effects
Acute Toxicity:
LD/LC50 Values Relevant for Classification
126-73-8 Tributyl Phosphate
Oral LD50 3000 mg/kg (rat)
Primary Irritant Effect:
On the Skin: Not a skin irritant in unused form. Vapors/particles from used product are possibly irritating to skin.
On the Eye: Not an eye irritant in unused form. Vapors/particles from used product are possibly irritating to eyes.
Sensitisation: No sensitising effects known.
Subacute to Chronic toxicity: No further relevant information available.
Acute Effects (Acute Toxicity, Irritation and Corrosivity): Danger of blast or crush-type injuries.
Repeated Dose Toxicity: No further relevant information available.
DIFFERENTIAL ENERGY (Brochure), page 3 of 3

DIFFERENTIAL ENERGY breaks new ground in...

Coal Metal Quarry
Mining Mining Blasting

DIFFERENTIAL ENERGY™
How does DIFFERENTIAL ENERGY improve safety, productivity, and
the environment?
 99 Product is not sensitized until it is delivered to the blasthole
SAFETY

99 Reduces potential for flyrock by placing low density gassed emulsion near the collar and/or areas of low burden
 99 Improves highwall stability, a result of accurate control of energy at the crest
 99 Thickened emulsion resists flowing into cracks and voids
 99 Emulsion densities can be tailored to the hardness of the rock
 99 Single product for both wet and dry conditions
 99 Reduces explosives inventory costs and simplifies budgeting
 99 Eliminates need to ship and store blasting agents at the site
PRODUCTIVITY
Always and Nevers (Guide), page 6 of 8

el cartucho a un lado del primer cartouche. ALWAYS follow manufacturer’s recommendations for using detonating cord with agujero, inserte el detonador en este nuevo orificio, luego estire los alambres. NE JAMAIS tirer les fils trop serrés, car ils pourraient se rompre ou abîmer
cast or manufactured boosters. CAST BOOSTERS – Figura 3 l’isolation. MISCELLANEOUS TYPES OF PRIMERS SIEMPRE siga las recomendaciones del fabricante acerca de cómo sujetar y
ALWAYS follow manufacturer’s recommendations for preparation of primers not utilizar detonadores con cast boosters. CARTOUCHES DE GRAND DIAMETRE
covered elsewhere in these recommendations. (plus de 2 po – 5,08 cm – de diamètre) – Figure 2
 CARTUCHOS EN ENVOLTURA PLÁSTICA – Figura 4. 1o: Percer un trou de biais en allant du centre de l’une des extremités de Ia
 PREPARANDO CARGAS INICIADORAS (PRIMERS) CON MECHAS O
 USING EXPLOSIVE MATERIALS: cartouche vers l’un des côtés, sur une hauteur de 2 po (5,08 cm) ou plus à partir
 DETONADORES NO-ELÉCTRICOS
 GENERAL PRECAUTIONS de l’extrémité. PROTECTING YOURSELF MÉTODO DE CARGAS INICIADORAS (PRIMERS) LATERALES – Figura 5. 2o: Replier les fils à environ 12 po (30,48 cm) du détonateur de manière à former
ALWAYS keep explosive materials away from food, eyes or skin. Flush areas Paso 1: Perfore un orificio en el costado del cartucho. Haga el agujero más un coude bien défini.
AMMONIA (SDS), page 6 of 10

Safety Data Sheet
Respiratory Protection: Use a NIOSH-approved self-contained breathing apparatus whenever exposure may exceed
established Occupational Exposure Limits.
Thermal Hazard Protection: Wear suitable protective clothing.
Other Information: When using, do not eat, drink or smoke.
Collaboration with DroneDeploy Leads to Mine Mapping (EEG Guide), page 1 of 1

Dyno Nobel’s experimental use of UAV’s (Unmanned Aerial Vehicles) combined with a partnership involving DroneDeploy, LLC is developing methodology and software to allow for rapid mapping of large areas of mines and quarries. Data collection that used to take entire days can be accomplished much more efficiently, sometimes in less than 30 minutes.

Collaboration with DroneDeploy Leads to Mine Mapping
FIRELINE 13/60 HMX LS (Tech Info), page 1 of 2

Temp. Deg. C (F)
 • Shrinkage is defined as the overall decrease in length. (325) (325)
 • Velocity was tested unconfined, at ambient pressure, and after 121 (250)
 “cool down.” 90 (200)
 Hazardous Shipping Description 66 (150)
 Cord, Detonating, 1.1D, UN 0065 II EX 1992020035
 Alternative packaging: FIREPAK® 1.4D air cargo shipping containers 38 (100)
 Product Code A574015 10 (50)
 Cord, Detonating, 1.4D UN 0289 EX 2007060067
 0
 1Hr 24 Hr 48 Hr 100 Hr 200 Hr 300 Hr 400 Hr

ADDITIONAL INFORMATION – Visit dynonobel.com for Brochures and Case Studies related to this product.

Product Disclaimer: Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, or the results to be obtained, whether express or implied, INCLUDING WITHOUT
LIMITATION, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. Buyers and users assume all risk, responsibility and liability whatsoever from any and
all injuries (including death), losses, or damages to persons or property arising from the use of this product. Under no circumstances shall Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or
incidental damages or for anticipated loss of profits.
Use of Electronic Detonators to reduce boulders and fines (Case Study), page 1 of 1

Use of Electronic Detonators to Reduce
 Boulders and Fines

Background

BOULDERS AND FINES BECOMING AN ISSUE

This recently opened limestone quarry in Ontario, Canada
is in the process of opening up a pit for a future operation.
A number of blasts were done using NONEL® detonators.
All blasts were considered pioneering as a thick layer of
overburden was stripped, exposing fractured rock, an
uneven surface, and bedding planes of various thicknesses.
The customer raised concerns that the large amount
of boulders generated by the blasts were becoming an
issue. At the same time, fines recuperated throughout the
crushing process keep piling up and cannot be recycled or
sold. Dyno Nobel was invited to investigate and propose
solutions at a competitive cost.
Dyno42 and SignaShot: Proprietary Signature Hole Analysis Software and Technical Expertise Control Coal Mine Cast Shot Vibration (Case Study), page 2 of 4

his goal with
Due to this, the mine anticipated higher operation costs
 provided timings that allowed the mine to keep its cast
and lower efficiency as hole size would be reduced,
 blast design as-is. SignaShot performed so well in its
which would result in more holes and shot length being
 predicted PPV the mine ceased decking in mid-pit after
decreased. This would result in more blast delays and
 the simulations of the selected Dyno42 timing showed
lower cast performance, and other blasting parameters
 vibrations would not exceed the 2 IPS limit. would potentially need to be adjusted to ensure the 2 IPS
limit was not exceeded. The two guiding determinations
 The postponement of detrimental changes to the cast
to the mine for when to deck and change hole size were
 program contributed to the pipeline owners resuming
their site-specific scaled distance equation and trends in
 negotiations and reaching an agreement on the future of
the vibration results. An example of this is the mine had
 the pipeline
observed higher than expected peak particle velocities
(PPV) when blasting in the middle of the pit and therefore
 During the project Dyno42 was used to generate a range
had started to deck for this section of the pit. of timings for each additional signature hole, and these
 results were analyzed through SignaShot.
BLASTLITE® — Tech Info (Tech Info), page 2 of 2

BlastLite® Technical
 Information
Low Density Explosive
Recommendations Safe handling, transportation and storage
Priming Requirements - BlastLite is booster sensitive and should be primed with First Aid – You can find detailed first aid information on the relevant Dyno Nobel
a minimum 400g cast booster. Smaller booster types may reduce the performance Safety Data Sheet. Refer to www.dynonobel.com for more information if required. of the explosive. Additional boosters should be used when the column height
exceeds 10 metres or where there is risk of column disruption. For specific Safety – All explosives are classified as dangerous goods and can cause
priming requirements please contact your Dyno Nobel representative. personal injury and damage to property if used incorrectly. Sleep Time - Under normal conditions in dry, stemmed blastholes, BlastLite may
 Shelf Life – BlastLite has a maximum shelf life of six (6) months dependent on
be slept for a period of up to two (2) weeks. The sleep time may be limited to the
 temperature and humidity conditions. Storage in a high humidity and high
recommended sleep time of the initiating system. For applications where unusual
 temperature environment will accelerate product breakdown and should be
or specific conditions exist please consult your local Dyno Nobel representative. avoided.
Waste Oil fuel blends deliver cost reduction (Case Study), page 1 of 2

Waste Oil Fuel Blends Deliver a Fuel Oil
 Cost Reduction for Bulk Explosive

traffic and the potential for environmental damage due to
 Project Summary spillage during transport and handling.
 While the onsite processing of waste oil is not new technology,
WASTE OIL FUEL BLENDS DELIVER UP TO A 25%
 the rapid development of satellite communications and rugged
FUEL OIL COST REDUCTION FOR BULK processing platforms has enabled the most recent development
EXPLOSIVES of remote processing plants.
Dyno Nobel have worked collaboratively with CREATENERGYe Robust emulsion technology
to bring new technology to the processing of site-based waste
oil and blending with diesel fuel oil for the onsite manufacture of The robust formulation of Dyno Nobel’s TITAN range of
bulk explosive products. The result has been a reduction in bulk emulsions enables the partial replacement of fuel oil with
explosive fuel oil cost of up to 25% for customers adopting this processed waste oil without affecting performance for emulsion
new technology. based products.
ELECTRIC SUPER STARTER™ — SDS (SDS), page 2 of 8

Hazard statements
H201 Explosive; mass explosion hazard. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Prevention statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P230 Keep wetted. P234 Keep only in original packaging. P240 Ground and bond container and receiving equipment. P250 Do not subject to grinding/shock/friction/rough handling. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response statements
P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
UREA ULTRA LOW BIURET (ULBU) (SDS), page 4 of 8

Safety Data Sheet
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store
away from direct sunlight, extremely high or low temperatures and incompatible materials.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Aldehydes.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
No Occupational Exposure Limits (OELs) have been established for this product or its chemical components.
Exposure Controls
Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash
fountains and safety showers should be available but not required.

Personal Protective Equipment: Safety glasses, gloves and general work clothing are recommended. Where ventilation
is insufficient, wear respiratory protection. Wearing of appropriate protective clothing and gloves is suggested if
epidermal sensitivity develops.
Redesigning Stopes for Improved Recovery of Ore (Case Study), page 1 of 1

n and practices was carried out with the mine Next Steps
engineers. In addition, an underground tour of the mine
gave DynoConsult a first-hand account of the situation and
current results experienced. EVOLVING BLAST DESIGNS
Although the customer had initially assumed the issues Refinements on the stope blast designs continue to evolve
they were experiencing could be resolved with different through discussions with the mining engineers at this
delay times, the investigation on site quickly revealed that operation and will lead to continued improvements in the
the issue was related to lack of relief for the stope blasts. blasting program at this operation. The void into which the rock from the stopes was designed
to expand was far too little to allow for proper rock
 20%
breakage. DynoConsult’s representative informed the increased
 recovery

Disclaimer This case study is provided for informational purposes only. No representation or warranty is made
 or intended by DYNO NOBEL INC. / DYNO NOBEL ASIA PACIFIC PTY LIMITED or its affiliates as to the
 applicability of any procedures to any particular situation or circumstance or as to the completeness or accuracy
 of any information contained herein. User assumes sole responsibility for all results and consequences.
 ©2017 Dyno Nobel
AQUA AMMONIA (SDS), page 8 of 10

Safety Data Sheet
In Accordance with IATA
Proper Shipping Name : AMMONIA SOLUTION
Packing Group : III
Identification Number : UN2672
Hazard Class : 8
Label Codes : 8
ERG Code (IATA) : 8L
In Accordance with TDG
Proper Shipping Name : AMMONIA SOLUTION
Packing Group : III
Hazard Class : 8
Identification Number : UN2672
Label Codes : 8
Controlling fume generation with TITAN® 9000xero® (Case Study), page 2 of 2

r blasthole VoD, with a standard operating environment for the mine site, no
average measurements of between 4,400 – 5,000 m/s modifications to blast design with respect to confinement
being recorded. and timing were implemented and, in addition, standard
 site based loading procedures and sleep times were
Blast chamber testing was conducted at our R&D test
 utilised. The product verification process tracked and
facility in the US to verify the gas components generated
 delivered 35 consecutive NOx free blasts in eastern
by the explosive product. In addition, during field testing
 Australian coal mines. in-field gas monitors were used to collect data. Video
recording was employed to enhance post blast analysis of The testing has confirmed that Dyno Nobel’s TITAN
blast cloud generation. 9000xero is a reliable bulk product solution for soft, wet
 and fractured ground conditions when NOx emissions
 must be controlled.

For more information contact your Dyno Nobel
 representative, visit www.dynonobel.com or call
 1800 251 872.

TITAN 9000xero can be delivered through a standard MPU
into the blasthole via auger or pump
 ®
TITAN® 2000 Matrix Blends — SDS (SDS), page 3 of 8

4.3 Immediate medical attention and special treatment needed
Treat as for nitrate overexposure (methaemoglobinemia). Treatment:
1. Give 100% oxygen. 2. In cases of (a) ingestion: use gastric lavage, (b) contamination of skin (unburnt or burnt): continue washing to remove salts. 3. Observe blood pressure and treat hypotension if necessary. 4. When methaemoglobin concentrations exceed 40% or when symptoms are present, give methylene blue 1 to 2 mg/kg body weight
in a 1% solution by slow intravenous injection. If cyanosis has not resolved within one hour a second dose of 2 mg/kg body weight
may be given. The total dose should not exceed 7 mg/kg body weight as unwanted effects such as dyspnoea, chest pain, vomiting,
diarrhoea, mental confusion and cyanosis may occur. Without treatment methaemoglobin levels of 20-30% revert to normal within 3
days. 5. Bed rest is required for methaemoglobin levels in excess of 40%. 6. Continue to monitor and give oxygen for at least two hours after treatment with methylene blue. 7. Consider transfer to centre where haemoperfusion can be performed to remove the nitrates from the blood if the condition of the
patient is unstable. 8. Following inhalation of oxides of nitrogen the patient should be observed in hospital for 24 hours for delayed onset of pulmonary
oedema.
FIRELINE 17/80 RDX (Tech Info), page 2 of 2

Product Disclaimer: Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, or the results to be obtained, whether express or implied, INCLUDING WITHOUT
 LIMITATION, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. Buyers and users assume all risk, responsibility and liability whatsoever from any and
 all injuries (including death), losses, or damages to persons or property arising from the use of this product. Under no circumstances shall Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or
 incidental damages or for anticipated loss of profits.
DynoConsult® Assists in Permit Change (EEG Guide), page 1 of 1

This northeast US limestone operation was facing production constraints due to limitations in blast size imposed by the original state mining permit. The operator was seeking to petition the state to remove the limitations based on size due to the ability to provide minimum community impact while dramatically increasing shot size to meet production demands with the use of technical blasting applications.

DynoConsult Assists in Permit Change
Recovering revenue through coal loss protection (Case Study), page 2 of 2

ations were R13N GLS strip. The improved drill and blast solutions
implemented for each site to minimize coal loss during during the validation phase have virtually eliminated the
overburden blasting. edge loss, increasing the coal yield from this strip by
The following tools were used to monitor and quantify 22,500 tonnes per annum. the coal losses: The value of the recovered coal is estimated at more
  Laser profiling to measure front row burden than one million dollars per annum. At Rix’s Creek, the
 distances coal loss in Arties 25 seam was reduced by 42 per cent
  Application of SiroVision technology for pre/post compared to the benchmark trials. blast surveying and survey of targets used for Based on the production rates for Arties 25 seam, a coal
 burden movement monitoring recovery of this magnitude would increase production by
  Digital still photography for highwall mosaic some 42,000 tonnes per annum, yielding additional
 development revenue of around two million dollars per annum.  High speed digital photography to determine
 movement velocity profiles
  Mine survey techniques to develop coal models
 for recovery calculations
NONEL® STARTER™ — SDS (SDS), page 2 of 10

Hazard statements
H201 Explosive; mass explosion hazard. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. Prevention statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P230 Keep wetted. P234 Keep only in original packaging. P240 Ground and bond container and receiving equipment. P250 Do not subject to grinding/shock/friction/rough handling. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response statements
P302 + P352 IF ON SKIN: Wash with plenty of water.
TITAN® 9000 Matrix Blends — Tech Info (Tech Info), page 1 of 6

TECHNICAL DATA SHEET

TITAN® 9000
Heavy and Gassed Emulsion Blends
NONEL® & Primacord® Product Manual (Guide), page 18 of 85

. . . attempt to initiate detonating cord with a
 . . . cut or trim shock tube, and never remove or surface delay connector designed for the initia-
 crimp a cap on shock tube. When tube is cut, tion of shock tube only. moisture can enter and cause misfires. If you
 do not have the length or delay you want, DO . . . put explosives materials in pockets of your
 NOT try to manufacture it. Special procedures clothing. pertain to Starter units. . . . use NONEL products in fireworks or pyro-
 . . . attach the primary initiator to the round or technic displays. shot until after all the connections have been
 . . . use explosive materials that appear to be
 made and the blasting area has been cleared. damaged or deteriorated. Before using con-
 . . . load NONEL detonators or detonating cord sult your supervisor or the manufacturer. into a hot hole, or expose them to tempera-
 . . . burn explosive materials packaging in a
 tures above 66° C (150°F). confined space. . . . leave loaded blast holes out of the main
 . . . leave an un-hooked surface delay connec-
 blast pattern tie-in. Loaded blast holes that are
 tor in close proximity to the shock tube of a
 not tied in to the main pattern (shot break prac-
 loaded blasthole. tice) may be initiated from the shock energy of
 an adjacent blast hole(s). This practice may . . . drive any vehicle over shock tube.
Redesigning Stopes for Improved Recovery of Ore (Case Study), page 1 of 1

Project Summary
$1 MILLION OF UNRECOVERABLE ORE
This underground nickel mine in the Midwest United States
is relatively young with only a few years of production
blasting. The operation is employing a sublevel stope
mining technique. The operator purchases Dyno TITAN®
RU emulsion and electronic detonators for blasting. The customer was experiencing poor blast results over
a substantial period of time. When the customer first
contacted DynoConsult® for assistance, the concern was
the under-breaking of the ore which left valuable material
along the ribs. At that time the mine engineers were looking
for guidance on the delay times they should be using to
improve the recovery of ore mining engineers at that time that most, if not all, of their
During the site visit by DynoConsult, it was also discovered blasting issues could be resolved by redesigning their
that there were a few instances of benches and bridges stope panels to incorporate a greater void for relief. being left in the stope after mucking. In one stope it
was estimated that over $1 million worth of ore was left Results
unrecoverable in the stope. It was also revealed during the site visit that there were PROPER VOID FOR PROPER ROCK
issues related to tight digging of the muckpile even though EXPANSION
the fragmentation was adequate.
DIGISHOT® ELECTRONIC INITIATION SYSTEM 1.4B (Tech Info), page 1 of 2

Detonator Shell Copper
 Cable Color Red
 Tensile Strength >500 N / 112 lbs
 System Operating Temperature (range) -40° to +80°C / -40° to +176°F
 Detonator Strength #12
 Net Explosive Quantity (per 100 units) 0.10 kg / 0.22 lbs
 Maximum Delay 20,000 ms
 Maximum Detonators per Blaster 600
 Maximum Surface Wire Length 2.5 km / 8,202 ft APPLICATION RECOMMENDATIONS
 • Due to the system’s flexibility, contact your local Dyno Nobel representative for
 Application Recommendations.