kcherry497/dyno-blast-4b-rag huggingface dataset:
POWERMITE® THERMO® — SDS (SDS), page 7 of 7

PRODUCT NAME POWERMITE THERMO®
 EXPLOSIONS: Fires involving explosives or explosive mixtures may undergo further explosions and
 rapid propagation. Police and emergency personnel should be notified immediately. Evacuate
 individuals to a safe sheltered area and if possible remove vehicles and further heat and ignition
 sources from the area. Consult with emergency services to determine evacuation distance and
 suitable re-entry time.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
 The recommendation for protective equipment contained within this report is provided as a guide
 only. Factors such as form of product, method of application, working environment, quantity used,
 product concentration and the availability of engineering controls should be considered before final
 selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:
 It should be noted that the effects from exposure to this product will depend on several factors
 including: form of product; frequency and duration of use; quantity used; effectiveness of control
 measures; protective equipment used and method of application. Given that it is impractical to
 prepare a report which would encompass all possible scenarios, it is anticipated that users will
 assess the risks and apply control methods where appropriate.
DIFFERENTIAL ENERGY Yields Excellent Results (Case Study), page 1 of 1

CASE STUDY

DIFFERENTIAL ENERGY® YIELDS EXCELLENT
RESULTS

BACKGROUND
TRAINING AND EQUIPMENT RELIABILITY ARE
A BIG CHALLENGE FOR THIS QUARRY
Quarries in this Western U.S. area have been utilizing
the TITAN® XL1000 technology with end of hose gassing
for several years but have never tried the capabilities of
DIFFERENTIAL ENERGY loading.
Training and equipment reliability have been the biggest
challenges for this distribution channel. Customers
are unaware of technology because of the lack of
understanding and confidence of blasters and operators.

TECHNOLOGY APPLIED 3. Much to their surprise, blasters have noticed:
TITAN DIFFERENTIAL ENERGY GASSING • A 10% reduction in powder was accomplished while
TECHNOLOGY MAY BE THE SOLUTION achieving an equivalent or better blasting result.

DIFFERENTIAL ENERGY was introduced to a single • Holes were loaded based on pounds, not bobbing
customer in this market area. Training of the blaster the hole as in the past. This proved to be much
 more accurate and holes were never stemmed prior
and the operator, in conjunction with a new and more
 to gassing completion as they often were before.
reliable operating system, has provided a basis of
moving forward. • Explosive column height actually grew 8 to 9 feet.
INERT STEMMING SL (SDS), page 3 of 13

Revision date: 07/20/2020 Supersedes date:02/26/2018

4.2. Most important symptoms and effects, both acute and
delayed
General information See Section 11 for additional information on health hazards. The severity
 of the symptoms described will vary dependent on the concentration and
 the length of exposure.

Inhalation Prolonged inhalation of high concentrations may damage respiratory
 system.

Ingestion Gastrointestinal symptoms, including upset stomach. Fumes from the
 stomach contents maybe inhaled, resulting in the same symptoms as
 inhalation.

Skin contact Prolonged contact may cause dryness of the skin.
Eye contact Irritating to eyes.

4.3. Indication of immediate medical attention and special treatment
needed
Notes for the doctor Treat symptomatically.
SECTION 5. Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media: Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or
water fog. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture
Specific hazards Containers can burst violently or explode when heated, due to excessive
 pressure build-up.
NITRIC ACID 67% (SDS), page 4 of 10

Safety Data Sheet
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Evacuate unnecessary personnel. Eliminate ignition sources. Stop leak if safe to do so.
Ventilate area.
Environmental Precautions
Prevent entry to sewers and public waters.
Methods and Material for Containment and Cleaning Up
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Cautiously neutralize spilled liquid.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Cautiously neutralize spilled liquid.
Use water spray to disperse vapors. Do not spray water into acid. Take up large spills with pump or vacuum. Absorb
and/or contain small spills with inert material, then place in suitable container. Do not absorb with combustible material
such as saw dust or cellulosic material. Contact competent authorities after a spill.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection
NONEL® and PRIMACORD® Product Manual (Guide), page 79 of 87

NONEL MS Connector - Cord Not in Groove

 • Detonator suspected not to have had detonating cord in groove of the
 connector. After the detonating cord functioned, a gap was created between
 the shock tube and the detonator. The delay was initiated - not the base
 charge - and functioned the detonator after this gap was created.

 A lways place the detonating
 cord in the groove of the con-
 nector block.

 Figure 117 - Gap between detonator and Figure 118 - Gap between detonator and
 shock tube. shock tube.

 Figure 119 - Detonator after functioning with Figure 120 - Detonator after functioning
 detonating cord NOT in groove of the with detonating cord in groove of the con-
 connector. nector.

 ®

70
 Product Application Manual: NONEL® & PRIMACORD® March 2011
 ™
Always and Nevers (Guide), page 1 of 8

“ALWAYS AND NEVERS” “SIEMPRES Y NUNCAS” “TOUJOURS ET NE JAMAIS”
 WARNINGS AND INSTRUCTIONS ADVERTENCIA E INSTRUCCIONES AVERTISSEMENTS ET INSTRUCTIONS
 ADOPTADO POR EL INSTITUTO DE FABRICANTES DE EXPLOSIVOS, Adopté par L’institut des Fabricants D’explosifs, Juin 1997
 ADOPTED BY THE INSTITUTE OF JUNIO 1997 Tous les explosifs sont dangereux et doivent être manutentionnés et employés
 MAKERS OF EXPLOSIVES, JUNE, 1997 Todos los explosivos son peligrosos y deben manejarse con cuidado. Deben avec précaution par un personnel compétent et expérimenté ou sous sa direction,
All explosives are dangerous and must be carefully handled and used following usarse siguiendo procedimientos de seguridad aprobados y deben ser selon les consignes de sécurité admises ainsi qu’en conformité avec toutes
approved safety procedures either by or under the direction of competent, manejados por o bajo la dirección de personas capacitadas y experimentadas. les lois, tous les règlements et tous les arrêtés en viguer dans le pays, l’état,
experienced persons in accordance with all applicable federal, state, and local Deben utilizarse de conformidad con las leyes, reglamentos y ordenanzas la province ou la municipalité. Si, aprés avoir lu ce document attentivement et
laws, regulations and ordinances. If, after carefully reading this entire leaflet, you federales, estatales y locales aplicables.
Trench Blasting Guide (Guide), page 8 of 20

UNIMAX
 ®
 TECHNICAL
Best All Around
EXTRA GELATIN NITROGLYCERIN DYNAMITE
MSDS #1019

 2 x 16 Convolute Shell Tamptite

 Properties

 Density (g/cc) 1.51

 Energy (cal/g) 1,055
 (cal/cc) 1,510

 Relative Weight Strength 1.20

 Relative Bulk Strength 2.10

 Velocity (ft/sec) 19,700
 (m/sec) 6,000

 Detonation Pressure (Kbars) 136

 Gas Volume (moles/kg) 32

 Water Resistance Excellent

 Fume Class IME1 & NRCan1

 Unimax is susceptible to sympathetic deto-
 nation when used in very wet conditions.
DIGISHOT® ELECTRONIC INITIATION SYSTEM 1.1B (SDS), page 8 of 16

Safety Data Sheet
According to: 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS
Trade Name: Detonators, Electronic (Class 1.1B)

Personal Protective Equipment:
General Protective And Hygienic Measures: The usual precautionary measures are to be adhered to when handling
chemicals.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Respiratory Protection: Not required under normal conditions of use.
Respiratory protection may be required after product use.
Protection of Hands: Wear gloves for the protection against mechanical hazards according to NIOSH or EN 388.
Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the
protective gloves and has to be observed.
Eye Protection:

Safety glasses

Face protection
Body Protection: Impervious protective clothing
Limitation and Supervision of Exposure into the Environment: No further relevant information available.
Risk Management Measures: Organizational measures should be in place for all activities involving this product.

SDS# 1152 Date: 05/01/2025 Page 8 of 12
Ammonium Nitrate — SDS (SDS), page 7 of 7

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists
 CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
 CNS Central Nervous System
 EC No. EC No - European Community Number
 EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
 Goods)
 GHS Globally Harmonized System
 GTEPG Group Text Emergency Procedure Guide
 IARC International Agency for Research on Cancer
 LC50 Lethal Concentration, 50% / Median Lethal Concentration
 LD50 Lethal Dose, 50% / Median Lethal Dose
 mg/m³ Milligrams per Cubic Metre
 OEL Occupational Exposure Limit
 pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
 alkaline).
 ppm Parts Per Million
 STEL Short-Term Exposure Limit
 STOT-RE Specific target organ toxicity (repeated exposure)
 STOT-SE Specific target organ toxicity (single exposure)
 SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
 SWA Safe Work Australia
 TLV Threshold Limit Value
 TWA Time Weighted Average
AMMONIUM NITRATE UN1942 (SDS), page 6 of 9

SECTION 11 - TOXICOLOGICAL INFORMATION
Information on Toxicological Effects – Product
Acute Toxicity: Not classified
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Not classified
Serious Eye Damage/Irritation: Causes serious eye irritation.
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not available
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: May cause respiratory irritation.
Symptoms/Injuries After Skin Contact: May cause skin irritation.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: None known.
Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
Ammonium nitrate (6484-52-2)
LD50 Oral Rat 2217 mg/kg
LC50 Inhalation Rat > 88.8 mg/l/4h
ATE CLP (oral) 2217.000 mg/kg body weight

SECTION 12: ECOLOGICAL INFORMATION
Toxicity Not classified
Persistence and Degradability
Superprill
Persistence and Degradability Not established.

SDS# 1020 Date: 05/01/2025 Page 6 of 9
NONEL® and PRIMACORD® Product Manual (Guide), page 1 of 87

Product Manual

NONEL® and PRIMACORD®
DigiShot® Detonator Precision Improves Cast and Lowers Overburden Removal for Large Scale Mining Operations (EEG Guide), page 1 of 1

DigiShot electronic detonators were used to confirm that accurate delay timing provided by precision electronic detonators correlates to improved explosive performance and an associated increase in effective overburden cast.

The benefit of increased cast volumes is substantial cost savings from reduced re-handling, reduced dozer and dragline time and quicker exposure of coal for extraction. Results of cast blasts in large western U.S. coal mines have shown a significant increase in effective cast, resulting in cost savings that more than compensated for the cost of using a value-added electronic initiation system.

DigiShot-Detonator-Precision-Improves-Cast-and-Lowers-Overburden-Removal-Costs-for-Large-Scale-Mining-Operations
BlastHi-T™ — SDS (SDS), page 4 of 7

PRODUCT NAME BlastHi-T®

PPE
 Eye / Face Wear safety glasses.
 Hands Wear PVC or rubber gloves.
 Body Wear coveralls.
 Respiratory Not required under normal conditions of use.

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
 Appearance COLOURED SOLID
 Odour SLIGHT ODOUR
 Flammability EXPLOSIVE
 Flash point NOT RELEVANT
 Boiling point NOT AVAILABLE
 Melting point NOT AVAILABLE
 Evaporation rate NOT AVAILABLE
 pH NOT AVAILABLE
 Vapour density NOT AVAILABLE
 Relative density 0.80 to 0.85 (Poured) 0.85 to 0.95 (Pneumatically loaded)
 Solubility (water) SOLUBLE
 Vapour pressure NOT AVAILABLE
 Upper explosion limit NOT RELEVANT
 Lower explosion limit NOT RELEVANT
 Partition coefficient NOT AVAILABLE
 Autoignition temperature NOT AVAILABLE
 Decomposition temperature NOT AVAILABLE
 Viscosity NOT AVAILABLE
 Explosive properties EXPLOSIVE
 Oxidising properties NOT AVAILABLE
 Odour threshold NOT AVAILABLE

10. STABILITY AND REACTIVITY
10.1 Reactivity
Explosive material. Detonation may occur from heavy impact or excessive heating, particularly under confinement.

10.2 Chemical stability
Potential for exothermic hazard.

10.3 Possibility of hazardous reactions
Polymerization will not occur.

10.4 Conditions to avoid
Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.
BLASTGEL® 1000 (SDS), page 5 of 10

Safety Data Sheet
USA ACGIH ACGIH TWA (mg/m³) 100 mg/m³
Alberta OEL TWA (mg/m³) 100 mg/m³
British Columbia OEL TWA (mg/m³) 100 mg/m³
Manitoba OEL TWA (mg/m³) 100 mg/m³
Newfoundland & OEL TWA (mg/m³) 100 mg/m³
Labrador
Nova Scotia OEL TWA (mg/m³) 100 mg/m³
Ontario OEL TWA (mg/m³) 100 mg/m³
Prince Edward Island OEL TWA (mg/m³) 100 mg/m³
Saskatchewan OEL STEL (mg/m³) 150 mg/m³
Saskatchewan OEL TWA (mg/m³) 100 mg/m³
Exposure Controls
Appropriate Engineering Controls: Ensure all national/local regulations are observed. Ensure adequate ventilation,
especially in confined areas.
Personal Protective Equipment: Protective goggles. Gloves. Insufficient ventilation: wear respiratory protection.
Protective clothing.

Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or face shield.
Skin and Body Protection: Not available
Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of
vapor or mist are expected to exceed exposure limits.
Other Information: When using, do not eat, drink or smoke.
Differential GPS brochure (Brochure), page 1 of 4

THE FIRST EVER TAGGING
 & HOLE IDENTIFICATION
 METHOD USING
 DIFFERENTIAL GLOBAL
 POSITIONING SYSTEM

dynonobel.com
SANFOLD® — SDS (SDS), page 5 of 7

PRODUCT NAME SANFOLD®

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met. WARNING: May explode with shock, heat,
 friction or static charge. Serious damage may result from explosive fragments.
 Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50
 Ingredient

AMMONIUM NITRATE 2217 mg/kg (rat) > 5000 mg/kg (rat) --
Skin Contact may result in irritation, redness, rash and dermatitis.
Eye Contact may result in irritation, lacrimation, pain, blurred vision and redness.
Sensitisation Not classified as causing skin or respiratory sensitisation.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen.
Reproductive Not classified as a reproductive toxin.
STOT - single Over exposure may result in irritation of the nose and throat, coughing, nausea and headache. High level
exposure exposure may result in drowsiness, breathing difficulties and methaemoglobinemia (blood's oxygen-carrying
 capacity is reduced).
STOT - repeated Not classified as causing organ damage from repeated exposure.
exposure
Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION
12.1 Toxicity
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

12.2 Persistence and degradability
No information provided.
Z-BAR® — SDS (SDS), page 3 of 8

PRODUCT NAME Z-BAR®

5.2 Special hazards arising from the substance or mixture
EXPLOSIVE. Will explode under specific conditions. May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to
decomposition. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters, naked lights,
pilot lights, etc when handling. CAUTION: Will explode if exposed to heat or with heavy impact.

5.3 Advice for firefighters
Evacuate area and contact emergency services. Exposure to heat may result in detonation. Toxic gases may be evolved in a fire
situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing
Apparatus (SCBA) when combating fire. Do not attempt to fight fire if other explosives are present. Use waterfog to cool unexploded
cartridges.

5.4 Hazchem code
E Evacuation of people in and around the immediate vicinity of the incident should be considered.

6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel.

6.2 Environmental precautions
Prevent product from entering drains and waterways.
TITAN® 1000 LD (SDS), page 5 of 10

Safety Data Sheet
Appropriate Engineering Controls: Ensure all national/local regulations are observed. Ensure adequate ventilation,
especially in confined areas.
Personal Protective Equipment: Protective goggles. Gloves. Insufficient ventilation: wear respiratory protection.
Protective clothing.

Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or face shield.
Skin and Body Protection: Not available
Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of
vapor or mist are expected to exceed exposure limits.
Other Information: When using, do not eat, drink or smoke.
Electronic Detonator Re-closure Letter (Guide), page 1 of 2

The DOT regulates hazardous materials (explosives) for safe transportation over public roads. To ensure
these hazardous materials in their original packages can be safely transported, the DOT requires that
anyone that performs a “function-specific” task associated with erecting a package, packaging product into
a container, closing and sealing a container of hazardous materials, and offing a package of hazardous
materials for shipment be Trained, Tested, and Certified that each one of these people know exactly what is
to be done correctly.

This Function-Specific training must be done within 90 days of employment and every three years after.
Records must be kept inclusive of the preceding three years, for as long as that employee is employed as a
hazmat employee and for 90 days thereafter.

Electronic Detonator Re-Closure Packaging Instructions:

To Close Box with Flaps: Boxes with flaps require the minor (inner) flaps to be closed first and the major

Page 1 of 2
 PKS-DNNA-DNIS-TRON.0013
AMMONIUM NITRATE UN2067 (SDS), page 1 of 9

Safety Data Sheet
SECTION 1 – IDENTIFICATION
Name, Address, and Telephone of the Responsible Party
Dyno Nobel LTD SDS #: 1022
6440 S. Millrock Drive, Suite 150 Date: 05/01/2025
Salt Lake City, Utah 84121 Supersedes: 01/01/2025
Phone: 801-364-4800
E-Mail: dna.healthsafety@am.dynonobel.com
www.dynonobel.com
Product Identifier
Product Name: Ammonium Nitrate

Other Means of Identification
Synonyms: Superprill™, Prilled Ammonium Nitrate, Industrial Grade LoDAN, Ammonium Nitrate, Industrial Grade
HiDAN, Ammonium Nitrate, Agricultural Grade
Intended Use of the Product
Industrial applications
Emergency Telephone Number
FOR 24 HOUR EMERGENCY, CALL CHEMTREC (USA) 800-424-9300
 CANUTEC (CANADA) 613-996-6666

SECTION 2 – HAZARD(S) IDENTIFICATION
Classification of the Substance or Mixture
Classification (GHS-US)
Ox. Sol. 3 H272
Eye Irrit. 2A H319
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :

GHS03 GHS07
NONEL® & Primacord® Product Manual (Guide), page 41 of 85

Non Self-to-Self Reliable Downlines
 1. Place a pigtail of 3.6 g/m (18 gr/ft) detonating cord in the Bunch Block par-
 allel to the detonator.
 2. Tie the detonating cord downlines to the pigtail with a clove hitch knot.
 Make sure the knots are at least 15 cm (6 in) from the Bunch Block, and
 that there is at least 5 to 7.5 cm (2 to 3 in) between knots.
 3. Attach the J-hook(s) of the outgoing shock tube lead to the pigtail 5 to 7.5
 cm (2 to 3 inches) from any knot and
 at least 15 cm (6 in) from the Bunch
 Block. Make sure all your connections
 are at right angles, and that the shock
 tube leads do not come in contact with
 the detonating cord after the J-hook
 connection.
 4. Make sure the J-hook(s) are at least
 15 cm (6 in) from the Bunch Block and
 5 to 7.5 cm (2 to 3 in) from any knots.
 5. Trim any excessive detonating cord
 Figure 52 - Proper use of TD detonator
 tails. Extraneous contact of detonat- Bunch Block with non self-to-self reliable
 ing cord and shock tube connections detonating cord downline(s).
 may result in cut-offs.
 6. Once all the blastholes are connected, make a visual inspection of all
 hook-ups for proper connections. After verifying proper hook-up, turn each
 Bunch Block connection upside down and cover with drill cuttings, stem-
 ming, or other similar material to help prevent cut-offs and control noise.
DYNO® AP (Tech Info), page 2 of 2

wide variety of sizes. Custom
 sizes are subject to surcharge and may require longer than usual lead times. Case Dimensions
 • Check with your Dyno Nobel representative should you have any questions. 44 x 35 x 20 cm 17.25 x 13.875 x 7.875 in
 *Add two pounds for Gross Case Weight

ADDITIONAL INFORMATION – Visit dynonobel.com for Brochures and Case Studies related to this product.

Product Disclaimer: Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, or the results to be obtained, whether express or implied, INCLUDING WITHOUT
LIMITATION, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. Buyers and users assume all risk, responsibility and liability whatsoever from any and
all injuries (including death), losses, or damages to persons or property arising from the use of this product. Under no circumstances shall Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or
incidental damages or for anticipated loss of profits.