Patent ID: 11952333

Abstract:
Systems and methods for producing 1,3-butadiene from a C4 hydrocarbon mixture are disclosed. The C4 hydrocarbon mixture comprising 1,3-butadiene, C4 acetylenes, and other C4 hydrocarbons is processed in an extractive distillation column to produce a crude 1,3-butadiene stream that comprises 1,3-butadiene, and C4 acetylenes including vinyl acetylene and ethyl acetylene. The crude 1,3-butadiene stream is subsequently distilled in the first distillation column, and the bottom stream of the first distillation column is further distilled in a second distillation column to produce an overhead stream comprising primarily 1,3-butadiene. A side stream comprising primarily C4 acetylenes is withdrawn from the second distillation column and processed in a selective hydrogenation unit to produce additional 1,3-butadiene.