Patent ID: 11674084

Abstract:
Some variations provide an anisotropic thermally conductive polymer composition comprising a plurality of polarizable, thermotropic main-chain liquid-crystal polymer molecules with crystalline domains. The liquid-crystal polymer molecules are in a nematic phase or a smectic phase, and at least 80% of the crystalline domains are aligned along a crystal axis. A method of making an anisotropic thermally conductive polymer composition comprises: synthesizing or obtaining a polymer containing polarizable domains; heating the polymer to form a polymer melt; cooling the polymer melt to form a thermotropic liquid-crystal polymer; exposing the thermotropic liquid-crystal polymer to an electrical field, thereby aligning the polarizable domains along a crystal axis; and recovering the thermotropic liquid-crystal polymer as an anisotropic thermally conductive polymer composition. The polymer composition may be formed into an object characterized by thermal conductivity along the minimum dimension that is at least three times greater than thermal conductivity along the maximum dimension.