Patent ID: 11629431

Abstract:
The present disclosure relates to P-type SnSe crystal capable of being used as thermoelectric refrigeration material and a preparation method thereof. The material is a Na-doped and Pb-alloyed SnSe crystal. A molar ratio of Sn, Se, Pb and Na is (1-x-y):1:y:x, where 0.015≤x≤0.025 and 0.05≤y≤0.11. The P-type SnSe crystal provided by the present disclosure is capable of being used as the thermoelectric refrigeration material. A power factor PF of the P-type SnSe crystal at a room temperature is ≥70 μWcm−1K−2, and ZT at the room temperature is ≥1.2. A single-leg temperature difference measurement platform built on the basis of the obtained SnSe crystal may realize a refrigeration temperature difference of 17.6 K at a current of 2 A. The present disclosure adopts a modified directional solidification method and uses a continuous temperature region for slow cooling to grow a crystal to obtain the large-sized high-quality SnSe crystal.