Patent ID: 10772330

Abstract:
Polymers containing nitrogen-halogen covalent bonds, i.e., N-halamine polymers, are provided for use in water treatment by reducing or removing microbes and toxic chemicals. Polymers containing one or more amide groups, guanidino groups, or groups derived from urethane or urea, are directly halogenated. The hydrolysis of N-halamine bonds is closely monitored by the presence of different electron-donating or electron-withdrawing groups adjacent to the nitrogen(s) of the N-halamine groups, and the resultant polymer can be facilely reloaded with halogen. Released halogen is in the form of an oxidative halogen or a hypohalous acid, in an effective amount and in an extended period of time, to significantly reduce the amount of a wide range of microbes including Escherichia coli and bacteriophage MS2 in contaminated water. Sponges, beads, resins, gel, and membranes made from these polymers are used in water treatment.