Oblast Saporischschja
Along with a number of other villages in northwestern Azerbaijan, Slavyanka was settled in 1844 by the Doukhobors, members of a Pacifist dissenter Christian group resettled to Transcaucasia by Nicholas I from the Molochna River settlements in today's Zaporizhia Oblast of the Ukraine. The village is said to have been named after the town of Slavyansk (in today's Donetsk Oblast), where many of the ancestors of the Molochna Doukhobors had originated.