ペレコープ地峡
The first missions over the battle zone in front of Perekop and over the Crimea were flown on 17 October 1941, either flying Ju 87 escort missions or combat air patrols. On two separate missions that day, Gollob claimed two I-61s and one I-16 shot down. On 18 October 1941, the 11the Army began its attack on the Isthmus of Perekop and Ishun. II. "Gruppe" flew several combat air patrols that day and reported 16 aerial victories for the loss of two Bf 109s damaged in combat. Gollob alone accounted for nine of these 16 claimed victories. This was the third time he had become an "ace-in-a-day" and was the most successful day of his combat career. During the course of three combat missions, he increased his personal score to 70. That day he filed a claim for nine I-61s shot down, two at 07:18 and 07:20, five more at 10:05, 10:07, 10:19, 10:20 and 10:29 and two more at 14:46 and 14:48. On 19 October, Gollob again achieved "ace-in-a-day" for the fourth time, claiming a I-61 at 08:55, three P-2s at 12:36, 12:37 and 12:42, and another I-61 at 15:35. The next day, he was credited with one further I-61, taking his total to 76 victories. Two days later, on 22 October, Gollob made "ace-in-a-day" for the fifth time and surpassed eighty victories. That day he claimed three I-16s, one Pe-2 and one I-61. One day later, he claimed three aerial victories, all I-61s, and on 24 October, he was credited with his 85th victory after he shot down a I-153. Following this streak of 37 aerial victories in October 1941, he was awarded the Knight's Cross of the Iron Cross with Oak Leaves () after reaching 85 victories. He was the 38th member of the German armed forces to be so honored. Gollob, together with "Oberleutnant" Erbo Graf von Kageneck, received the Oak Leaves from Adolf Hitler personally at the Wolf's Lair, Hitler's headquarters in Rastenburg, present-day Kętrzyn in Poland, on 5 November 1941.