Карло I Токко
Centurione was the son of Andronikos Asen Zaccaria and grandson of Centurione I Zaccaria. He succeeded his father in the barony of Arkadia (modern Kyparissia) in 1402. Though young, he was ambitious and he overthrew his aunt, Maria II Zaccaria, in Achaea in 1404; a move which was approved by his overlord, the king of Naples. Immediately, he reinforced his power on a local basis by marrying Creusa, the daughter of Leonardo II Tocco, lord of Zante and niece of Carlo I Tocco whose dominions covered Cephalonia and Lefkada and extended to Epirus and the western Peloponnese. Centurione then made his brother Stephen the Latin Archbishop of Patras.