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Scott began his performance career as a singer at age seven, and by the age of eleven began performing at the Apollo Theater as the featured vocalist for musicians such as Earl "Fatha" Hines. Other notable accomplishments include dancing as a member of the Alvin Ailey company in 1959, rising to the starring role of The Wiz in the Broadway company from 1975 to 1979, scoring a hit with the song "Bolinas" as featured vocalist with Billy Cobham in 1978, and appearances with the Boston Pops under John Williams. In his later career, Scott began exploring and teaching the art of Bel canto singing, including a recital at Merkin Hall at Lincoln Center in October 2004. Scott was on faculty as a vocal instructor at the Mannes College of Music and the New School for Jazz and Contemporary Music, also Morgan State University as Artist in Residence since August 28, 2012. He became a member of Phi Mu Alpha Sinfonia fraternity, Pi Eta chapter, on April 6, 2013.