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Baker and her husband James A. Baker, IV, who serves as a senior partner at the law firm Baker Botts as of 2009, married in Ravello, Italy, in 2006. James is the son of attorney and statesman James Baker, III, who served as White House Chief of Staff and United States Secretary of the Treasury under President Ronald Reagan, and as United States Secretary of State and White House Chief of Staff under President George H. W. Bush.