دينو زوف
Anzolin was also part of the Italian squad in the 1966 FIFA World Cup as a substitute behind starting keeper Albertosi, as well as Pizzaballa. He made his only appearance for the "Azzurri" in a friendly pre-World Cup match against Mexico on 29 June 1966, which ended in a 5–0 victory for Italy, as he was later kept out of the squad by Dino Zoff.