単結晶
Sc3.67–xB41.4–y–zC0.67+zSi0.33–w (x = 0.52, y = 1.42, z = 1.17 and w = 0.02) has a hexagonal crystal structure with space group "Pm2" (No. 187) and lattice constants "a" = "b" = 1.43055(8) and "c" = 2.37477(13) nm. Single crystals of this compound were obtained as an intergrowth phase in a float-zoned single crystal of Sc0.83–xB10.0–yC0.17+ySi0.083–z. This phase is not described in the phase diagram of figure 17 because it is a quaternary compound. Its hexagonal structure is rare and has 79 atomic positions in the unit cell: eight partially occupied Sc sites, 62 B sites, two C sites, two Si sites and six B/C sites. Six B sites and one of the two Si sites have partial occupancies. The associated atomic coordinates, site occupancies and isotropic displacement factors are listed in table X.