Zona Fantasma
In the 1978 series "Super Friends" there is an episode entitled "Terror from the Phantom Zone" in which a comet's collision causes the Phantom Zone to release three Kryptonian villains Hul, Rom-Lok and Logar. The villains go on a crime spree and banish the Superfriends to the Phantom Zone but keep Superman on Earth...exposing him to red kryptonite which causes him to age quickly. The villains get great enjoyment showing off "old Superman" to the world...Superman then manages to figure out with help from the Justice League computer that blue kryptonite may reverse the aging process because blue kryptonite is harmful to backwards "Bizarro" and therefore should be helpful to Superman. Superman finds the blue kryptonite and is aged back to normal and then goes on his quest to rescue the other Super Friends from the Phantom Zone and ultimately send the three villains back into the Phantom Zone. This episode can be found on the DVD collection ""Super Friends: Volume Two", which features 16 "Super Friends" cartoons from 1978.