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Water in Earth's atmosphere is not merely below its boiling point (100 °C), but at altitude it goes below its freezing point (0 °C), due to water's highly polar attraction. When combined with its quantity, water vapor then has a relevant dew point and frost point, unlike e. g., carbon dioxide and methane. Water vapor thus has a scale height a fraction of that of the bulk atmosphere, as the water condenses and exits, primarily in the troposphere, the lowest layer of the atmosphere. Carbon dioxide () and methane, being non-polar, rise above water vapor. The absorption and emission of both compounds contribute to Earth's emission to space, and thus the planetary greenhouse effect. This greenhouse forcing is directly observable, via distinct spectral features versus water vapor, and observed to be rising with rising levels. Conversely, adding water vapor at high altitudes has a disproportionate impact, which is why methane (rising, then oxidizing to and two water molecules) and jet traffic have disproportionately high warming effects.