Thermal expansion
When selecting materials for thermoelectric generation, a number of other factors need to be considered. During operation, ideally, the thermoelectric generator has a large temperature gradient across it. Thermal expansion will then introduce stress in the device which may cause fracture of the thermoelectric legs or separation from the coupling material. The mechanical properties of the materials must be considered and the coefficient of thermal expansion of the n and p-type material must be matched reasonably well. In segmented thermoelectric generators, the material's compatibility must also be considered.