氟化氢
Alternatively, ethylene can be oligomerized (partially polymerized) to produce linear alkenes. The resulting linear mono-olefins react with benzene in the presence of a catalyst to produce the LABs. Hydrogen fluoride (HF) and aluminium chloride (AlCl3) are the two major catalysts for the alkylation of benzene with linear mono-olefins. The HF-based process is commercially dominant; however, the risk of releasing HF (a poisonous substance) into the environment became a concern particularly after the Clean Air Act Amendment. In 1995, a solid catalyst system (the DETAL process) became available. The process eliminates catalyst neutralization and HF disposal. Consequently, most LAB plants built since then have utilized this process.