Союз освобождения
Golovin was born in Moscow into a noble family on December 21, 1867. In 1891 he began studying law at Moscow University. Following his law studies, he began political activities. In 1899 he became a member of the group "Conversation"; in 1903 of the Union of Liberation; in 1904 of the Union of Zemstvo-Constitutionalists; and in the autumn of 1905 he was one of the organizers of the Constitutional Democratic Party. He was an active freemason.