价层电子对互斥理论
VSEPR theory predicts a bent-T-shaped molecular geometry for the group 17 trifluorides. All known halogen trifluorides have this molecular geometry and have a structure of AX3E2—a central atom, denoted A, surrounded by three ligands, X, and two unshared electron pairs, E. If relativistic effects are ignored, TsF3 should follow its lighter congeners in having a bent-T-shaped molecular geometry. More sophisticated predictions show that this molecular geometry would not be energetically favored for TsF3, predicting instead a trigonal planar molecular geometry (AX3E0). This shows that VSEPR theory may not be consistent for the superheavy elements. The TsF3 molecule is predicted to be significantly stabilized by spin–orbit interactions; a possible rationale may be the large difference in electronegativity between tennessine and fluorine, giving the bond a partially ionic character.