Radicaux indépendants
In Serbian politics, he was a devoted democrat, Senator in 1901 and the member of the People's Radical Party of Nikola Pašić. After 1905, Žujović joined the Independent Radical Party of Ljubomir Stojanović. In the government of Independent Radicals, Žujović was a Minister of Foreign Affairs from 12 August to 15 December 1905. Also, Žujović held the post of Minister of Education and Religious Affairs on two occasions, from 16 May to 30 July 1905, and from 11 October 1909 to 12 September 1910.