電子移動反応
Arylation of nitrile anions is also possible and can take place through different mechanisms depending on the substrates and reaction conditions. Aryl halides lacking electron-withdrawing groups react through an elimination-addition mechanism involving benzyne intermediates. Aryl phosphates and ammoniums react through the SRN1 pathway, which involves the generation of an aryl radical anion, fragmentation, and bond formation with a nucleophile. Electron transfer to a second molecule of arene carries on the radical chain.