Hydrochloric acid
Hydrochloric acid as the binary (two-component) mixture of HCl and H2O has a constant-boiling azeotrope at 20.2% HCl and 108.6 °C (227 °F). There are four constant-crystallization eutectic points for hydrochloric acid, between the crystal form of [H3O]Cl (68% HCl), [H5O2]Cl (51% HCl), [H7O3]Cl (41% HCl), [H3O]Cl·5H2O (25% HCl), and ice (0% HCl). There is also a metastable eutectic point at 24.8% between ice and the [H7O3]Cl crystallization. They are all Hydronium salts.