Ackermann function
Kleene et al. (cf §55 General recursive functions p. 270 in Kleene 1952) had to add a sixth recursion operator called the minimization-operator (written as μ-operator or mu-operator) because Ackermann (1925) produced a hugely growing function—the Ackermann function—and Rózsa Péter (1935) produced a general method of creating recursive functions using Cantor's diagonal argument, neither of which could be described by the 5 primitive-recursive-function operators. With respect to the Ackermann function: