アンギャン公
At the age of fifteen, she was engaged to Henri Jules, Duke of Enghien, the only surviving child of the famous military commander the "Grand Condé". The Grand Condé was the most senior "Prince du Sang" at the French court ("First Prince of the Blood"). Henri Jules was his heir and prior to his succession to the purely honorary title of Prince of Condé, was styled the Duke of Enghien and was addressed "Monsieur le Duc". The marriage ceremony took place at the Palais du Louvre on 11 December 1663 with Louis XIV of France and the rest of the royal family in attendance. At this time, Anne became "Madame la Duchesse", as Duchess of Enghien. At the death of her father-in-law in 1684, Anne took on the style of "Madame la Princesse". She was also known as "Anne, princesse Palatine".