Stefan Nemanja
Sometime before 1163, Stefan Nemanja, then only a Prince, was baptized in the church. In 1166, Stefan Nemanja acquired the throne of Serbia with the title of Grand Prince. He was married in the church (to Ana); their two sons, Rastko (later known as Saint Sava; l. 1175-1235), and Stefan Nemanjić, were baptized in the church. Stefan Nemanja held the council that outlawed the Bogumils at the church.