Duke of Arcos
He married again in 1672, aged 47, 19 years old Ana Antonia Francisca, (Milán, 14 April 1653 - Madrid, 4 December 1707, aged 50), 4th Marchioness of Caracena, a daughter of Luis de Benavides Carrillo, Marquis of Caracena, 6th marquis of Frómista, Governor of the Duchy of Milan, Governor of the Habsburg Netherlands. Her mother was Catalina Ponce de León, third daughter of Rodrigo Ponce de León, 4th Duke of Arcos and of María Francica Córdoba de Aragón, a daughter of the 5th Dukes of Segorbe.