Radial velocity
Radial velocity measurements taken by Henri-Alexandre Deslandres in 1900 at Paris Observatory showed that Mintaka had a variable radial velocity and therefore was a spectroscopic binary. His preliminary orbital period estimate of 1.92 days was shown to be incorrect in 1904 when Johannes Franz Hartmann using photographic plates taken at Potsdam Observatory showed that the orbital period was 5.7 days. Hartmann also noticed that the calcium K line at 393.4 nanometres in the stellar spectrum did not share in the periodic displacements of the lines due to orbital motion of the star and theorized that there was a cloud in the line of sight to Mintaka that contained calcium. This was the first detection of the interstellar medium.