History of Jin
The "History of Jin" 《金史》 (compiled by 1345) states that in 1232, as the Mongol general Subutai (1176–1248) descended on the Jin stronghold of Kaifeng, the defenders had a "thunder crash bomb" which "consisted of gunpowder put into an iron container ... then when the fuse was lit (and the projectile shot off) there was a great explosion the noise whereof was like thunder, audible for more than thirty miles, and the vegetation was scorched and blasted by the heat over an area of more than half a "mou". When hit, even iron armour was quite pierced through."