Mie scattering
At sunrise and sunset, when the path through the atmosphere is longer, the blue and green components are removed almost completely leaving the longer wavelength orange and red hues seen at those times. The remaining reddened sunlight can then be scattered by cloud droplets and other relatively large particles to light up the horizon red and orange. The removal of the shorter wavelengths of light is due to Rayleigh scattering by air molecules and particles much smaller than the wavelength of visible light (less than 50 nm in diameter). The scattering by cloud droplets and other particles with diameters comparable to or larger than the sunlight's wavelengths (more than 600 nm) is due to Mie scattering and is not strongly wavelength-dependent. Mie scattering is responsible for the light scattered by clouds, and also for the daytime halo of white light around the Sun (forward scattering of white light).