Hydrogen fluoride
Hydrogen fluoride and sulfur dioxide emissions from U.S. Steel's Donora Zinc Works and its American Steel &amp; Wire plant were frequent occurrences in Donora. What made the 1948 event more severe was a temperature inversion, a situation in which warmer air aloft traps pollution in a layer of colder air near the surface. The pollutants in the air mixed with fog to form a thick, yellowish, acrid smog that hung over Donora for five days. The sulfuric acid, nitrogen dioxide, fluorine, and other poisonous gases that usually dispersed into the atmosphere were caught in the inversion and accumulated until rain ended the weather pattern.