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Stier was born at Fraustadt (Wschowa) in South Prussia and studied at the University of Halle and Humboldt University, Berlin, first law and afterwards theology; he continued his theological studies later at the pastoral seminary of Wittenberg. In 1824 he was made professor at the Missionary Institute in Basel. Afterwards he held pastorates at Frankleben near Merseburg (1829) and at Wichlinghausen (now part of Wuppertal) (1838). In 1850 he was appointed superintendent at Schkeuditz, and in 1859 at Eisleben.