Surface tension
Surface tension is the physical property which rules interface processes involving liquids. For a liquid film on flat surfaces, the liquid-vapor interface keeps flat to minimize interfacial area and system free energy. For a liquid film on rough surfaces, the surface tension tends to keep the meniscus flat, while the disjoining pressure makes the film conformal to the substrate. The equilibrium meniscus shape is a result of the competition between the capillary pressure and disjoining pressure.