Claim: Brad Pitt appeared in a movie.

Mr. & Mrs. Smith is a 2005 American action comedy film directed by Doug Liman and written by Simon Kinberg . The film stars Brad Pitt and Angelina Jolie as a bored upper-middle class married couple surprised to learn that they are assassins belonging to competing agencies , and that they have been assigned to kill each other .   Besides being a box office hit , it is also notable for establishing Jolie and Pitt 's relationship .