jimnoneill/paper-to-field-training huggingface dataset:
Monsignor Van Hee, Congo, ca.1920-1940

"Mgr. Van Hee, Vicaire-apostolique du Kwango." A portrait of a Catholic missionary father shows the monsignor in his clerical vestments.; The back of the postcard is closely covered in handwriting and is stamped and postmarked. Printed in the correspondence section is "Mission des RR. PP. Jesuites au Kwango (Congo Belge)

Topic: Diphtheria, Corynebacterium, and Tetanus
Subfield: Endocrinology
Field: Biochemistry, Genetics and Molecular Biology
Domain: Life Sciences
Ruthenium Complexes of Stibino Derivatives of Carboxylic Amides: Synthesis and Characterization of Bidentate Sb,E, Tridentate Sb,E<sub>2</sub>, and Tetradentate Sb,E<sub>3</sub> (E = N and O) Ligands and Their Reactivity Toward [RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>]

Neutral bi-, tri-, and tetradentate ligands of the type Ph<sub>3-<i>x</i></sub>Sb(<b>L</b>)<sub><i>x</i></sub> [<i>x</i> = 1 (<b>1</b>), 2 (<b>2</b>), and 3 (<b>3</b>). <b>L</b> = <b>La</b> = phthalimidinyl (<b>1a</b>, <b>2a</b>, and <b>3a</b>), <b>Lb</b> = 2-pyridyloxy (<b>1b</b>, <b>2b</b>, and <b>3b</b>)] have been synthesized and characterized. Reaction of the Sb,E and Sb,E<sub>2</sub> ligands with [RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>] proceeded under anion scrambling with formation of complexes of type [Ph<sub>2</sub>Sb(μ-<b>L</b>)<sub>2</sub>Ru(PPh<sub>3</sub>)(μ-Cl)]<sub>2</sub> (<b>5</b>) or [PhSb(μ-<b>L</b>)<sub>3</sub>RuCl(PPh<sub>3</sub>)] (<b>8</b>) in addition to various byproducts. Reactions of the Sb,E<sub>3</sub> ligands and [RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>] afforded highly diverse product mixtures. Deliberate syntheses of complexes of types <b>5</b> and <b>8</b> were successful by supplementing the reaction mixture with the required stoichiometric amount of either H<b>La</b> or H<b>Lb</b> and a supporting base. The Sb-Ru bonds, which are bridged by two (type <b>5</b>) or three (type <b>8</b>) phthalimidinyl or 2-pyridyloxy ligands, have been investigated using quantum chemical calculations at the DFT level (NBO/NLMO and AIM). Treatment of complexes of type <b>8</b> with fluoride ions resulted in the formation of compounds of type [PhFSb(μ-<b>La</b>)<sub>3</sub>Ru<b>L'</b>(PPh<sub>3</sub>)] (<b>L'</b> = O<sub>2</sub> (<b>9a-O</b><sub><b>2</b></sub>), NCMe (<b>9a-NCMe</b>), or [PhFSb(μ-<b>Lb</b>)<sub>2</sub>Ru(κ<sup>2</sup>-<b>Lb</b>)(PPh<sub>3</sub>)] (<b>10b</b>)). In contrast to other similar bimetallic Sb-TM complexes (TM = transition metal), which may switch the rather dative intermetallic bond from Sb→TM to Sb←TM upon replacing TM bound chloride by Sb-bound fluoride, the character of the Sb→Ru bond is essentially retained upon going from chloro complex <b>5</b> or <b>8</b> to fluoro complex <b>9</b> or <b>10</b>. Charge discrepancies caused by anion transfer from Ru to Sb are mainly compensated for by charge flow along the ligand backbone. All isolated complexes were characterized with multinuclear NMR spectroscopy, single-crystal X-ray diffraction, elemental analysis, and quantum chemical calculations.

Topic: Metal complexes synthesis and properties
Subfield: Oncology
Field: Medicine
Domain: Health Sciences
Apple Harvest and Problems in Turkey

Modern Concepts & Developments in Agronomy Apple Harvest and Problems in Turkey Yasemin Vurarak1*, Mehmet Emin Bilgili1, Ahmet İnce2 and Ali Uzdil1 1Eastern Mediterranean Agricultural Research Institute Directorate, Turkey 2Department of Agricultural Machinery and Technologies Engineering, Turkey *Corresponding author: Yasemin Vurarak, Eastern Mediterranean Agricultural Research Institute Directorate, 01375 Adana, Turkey Submission: January 27, 2023;Published: February 06, 2023 DOI: 10.31031/MCDA.2023.12.000785 ISSN 2637-7659Volume12 Issue 2

Topic: Plant Physiology and Cultivation Studies
Subfield: Plant Science
Field: Agricultural and Biological Sciences
Domain: Life Sciences
Dysmicoccus boninsis Kuwana 1909

Dysmicoccus boninsis (Kuwana, 1909) Hosts. Polyphagous, known to feed on 39 species belonging to ten plant families (García Morales et al. 2016). In Colombia, D. boninsis has been previously recorded feeding on stems of sugarcane. In this study, this species was found for the first time feeding on the roots of sugarcane. Diagnosis. Dorsum: numerous oral collar tubular ducts present; with only 8 or 9 pairs of cerarii, each containing 2 enlarged setae. Venter: multilocular disc pores present on the fifth and posterior abdominal segments; translucent pores present on hind coxa and a few on the hind tibia; circulus normally notched at each side and divided by an intersegmental line, but sometimes small and oval (Williams & Granara de Willink 1992). Distribution. Cosmopolitan. In Colombia, it has been previously recorded from the departments of Antioquia, Caldas, Cauca, Nariño, Norte de Santander, Quindío, Santander, Tolima and Valle del Cauca (Kondo et al. 2008). Here it is recorded for the first time from the department of Caquetá. Economic importance and control. The gray sugarcane mealybug has been recorded from a wide range of grasses, as well as host plants from other families. On sugarcane, this species has been generally recorded as a minor pest but, when attended by ants, it may kill young shoots (Bartlett 1978). Kondo et al. (2008) recorded eight ant species associated with D. boninsis in Colombia: Brachymyrmex sp., Crematogaster sp., Ectatoma ruidum Roger, Linepithema sp., Neilanderia sp., Solenopsis sp., Pheidole sp. and Wasmania auropunctata Roger. Dysmicoccus boninsis is not considered a pest of sugarcane in Colombia (Lastra & Gómez 2000, Bustillo 2013). Material studied. COLOMBIA: Antioquia, Medellín, 1560 m a.s.l., 25.iii.2010, 5 ♀, UNAB voucher N° 843; Boyacá: Togui, Vda. Garibal, Fca El Milagro, 1664 m a.s.l., 05°55′00″N, 73°30′54″W, 23.iii.2012, coll. H. Matheus, 9 ♀, UNAB voucher N° 843; Caquetá: Florencia, Vda. La Carbona, 674 m a.s.l., 01°42′01″N, 75°02′26″W, 12.x.2013, coll. J. Silva, tended by Crematogaster sp. (Formicidae) and Wasmannia auropunctata (Formicidae), 1 ♀, UNAB voucher N° 843; Florencia, Vda. Avenida Sebastopol, 826 m a.s.l., 01°44′57″N, 75°39′13″W, 13.x.2013, coll. J. Silva, tended by Pheidole biconstricta Mayr (Formicidae), 6 ♀, UNAB voucher N° 843; Florencia, Vda. San Luis, 388 m a.s.l., 01°41′01″N, 75°37′42″W, 11.x.2013, coll. E. Rojas, tended by Pheidole sp. (Formicidae), 4 ♀, UNAB voucher N° 843; Chocó: Acandí, Sapzurro, 8.i.2005, coll. F. Serna & E. Vergara, 19 ♀, UNAB voucher N° 843; Tolima, Coello, Ibagué, San Francisco, 1158 m a.s.l., 04°23′56″N, 75°17′18″W, 13.xii.2005, coll. A. Ramos, 6 ♀, UNAB voucher N° 843. Note. All material collected off stems of S. officinarum, except for those from Boyacá, which were collected from roots. Observations. This is the first record of D. boninsis being associated with Pheidole biconstricta in Colombia.

Topic: Research on scale insects
Subfield: Insect Science
Field: Agricultural and Biological Sciences
Domain: Life Sciences
USBIPS Framework: Protecting Hosts from Malicious USB Peripherals

Universal Serial Bus (USB)-based attacks have increased in complexity in recent years. Modern attacks incorporate a wide range of attack vectors, from social engineering to signal injection. The security community is addressing these challenges using a growing set of fragmented defenses. Regardless of the vector of a USB-based attack, the most important risks concerning most people and enterprises are service crashes and data loss. The host OS manages USB peripherals, and malicious USB peripherals, such as those infected with BadUSB, can crash a service or steal data from the OS. Although USB firewalls have been proposed to thwart malicious USB peripherals, such as USBFilter and USBGuard, their effect is limited for preventing real-world intrusions. This paper focuses on building a security framework called USBIPS within Windows OSs to defend against malicious USB peripherals. This includes major efforts to explore the nature of malicious behavior and achieve persistent protection from USB-based intrusions. Herein, we first introduce an allowlisting-based method for USB access control. We then present a behavior-based detection mechanism focusing on attacks integrated into USB peripherals. Finally, we propose a novel approach that combines cross-layer methods to build the first generic security framework that thwarts USB-based intrusions. Within a centralized threat analysis framework, the approach provides persistent protection and may detect unknown malicious behavior. By addressing key security and performance challenges, these efforts help modern OSs against attacks from untrusted USB peripherals.

Topic: Advanced Malware Detection Techniques
Subfield: Signal Processing
Field: Computer Science
Domain: Physical Sciences
Understanding direct and indirect effects of Payment for Ecosystem Services on resource use and wildlife

Payments for ecosystem services (PES) programs have been implemented worldwide to balance human needs and ecosystem conservation. However, the effects of PES programs on economic activities and the associated effects on wildlife remain unclear. China's Grain-to-Green program (GTGP) that aims to convert cropland to forest or grassland represents one of the largest PES programs in the world. We combine household surveys with wildlife camera data to ask whether GTGP is associated with direct or indirect effects on economic activities, wildlife occupancy and wildlife species richness. We also consider how resource use and extraction, wildlife occupancy, and species richness differ between GTGP and natural forest sites. We found that farming and the amount of fuelwood extracted from forests have declined, while the collection of other forest resources remained largely unchanged. While residents engaged less in cattle grazing after GTGP implementation, goat grazing and pig forage collection remained unchanged. Paired camera trap and household survey data analyses suggest that presence of humans and dogs was positively related to resource collection, and negatively related to wildlife occupancy, which likely contributed to the lower wildlife species richness detected at GTGP forest relative to natural forest. The results suggest that while PES programs, like GTGP, may reduce some human impacts on forest ecosystems (i.e. reduced firewood collection and cattle grazing) and provide habitat for wildlife through afforestation, the persistence of other types of resource use may limit the positive benefits of PES to wildlife diversity. Our results suggest there may be opportunities for PES programs to extend the multi-benefit approach of balancing human needs and ecosystem services to increase potential benefits to wildlife and biodiversity.

Topic: Conservation, Biodiversity, and Resource Management
Subfield: Global and Planetary Change
Field: Environmental Science
Domain: Physical Sciences
The Contribution of Simone Weil to the Enrichment of the Ethics of Care

This theoretical paper aims at providing a contribution to the Care Approach of organizations by proposing a discussion that is based on the philosophy of Simone Weil (1909–1943). More precisely, we discuss the contribution of two specific aspects of the Philosophy of Simone Weil ("thinking one's own work" and "Spirituality") to the Ethics of Care. We argue that, despite many aspects that oppose both philosophies, Weil enriches the notion of dialogue and the object of the dialogue.

Topic: Philosophy and Literary Analysis
Subfield: Philosophy
Field: Arts and Humanities
Domain: Social Sciences
War and Peace: The 34th Annual Donald C. Brace Lecture

This paper is a near-verbatim text of lecture delivered in April 2005 to the members of the Copyright Society of the USA and published in the Journal of the Copyright Society in October 2005. In the lecture I talk about what has been called a copyright war, comparing it to actual military wars, and I offer some suggestions about what it would take to make a workable peace.

Topic: Copyright and Intellectual Property
Subfield: Marketing
Field: Business, Management and Accounting
Domain: Social Sciences
THE PRODUCTION FACTORS OF CASSAVA CRACKER BUSINESS IN SUNGAI SAHURAI VILLAGE

The research problem comes from the production factors of cassava crackers. This research aims to describe the production factors of the cracker business. The research used a qualitative method to describe the production factors of the cassava cracker business in Sungai Sahurai Village. Data were collected through observation, interviews, and documentation. Data analysis with data reduction refers to the research objectives, presentation of data obtained in the field, and conclusion. Testing data validity through triangulation and member check. Based on the results of the study, it was found that the production activities of the cassava crackers business have several factors in the form of raw materials, capital, labour, and entrepreneurial skills. The primary raw material is cassava, capital whose source comes from its own and borrowed capital, labour, namely the business actors themselves, and additional labour and entrepreneurial skills that are passed down from generation to generation. This study concludes that in Sungai Sahurai Village, most of the residents have a cassava cracker business; these business activities can take place and still exist today because there are production factors that support each other.

Topic: Cassava research and cyanide
Subfield: Plant Science
Field: Agricultural and Biological Sciences
Domain: Life Sciences
Virtual reality-based eye tracking throughout typical concussion recovery

<b>Objective:</b> The purpose of this study was to determine the effects of concussion on visual and oculomotor function using a virtual reality-based eye tracking system throughout recovery. <b>Design:</b> A prospective, longitudinal cohort design assessed at the subacute, return-to-activity, and 6-month timepoints was used. <b>Methods:</b> Recently concussed (<i>n</i> = 21; age = 30 ± 14) and healthy control participants (<i>n</i> = 20; age = 29 ± 11) completed visual and oculomotor testing at three timepoints (subacute, return-to-activity, and 6-months) using a virtual reality-based head mounted display eye tracking system sampled at 100 Hz. Symptoms and clinical assessments were collected using the Sport Concussion Assessment Tool-5<sup>th</sup> Edition (SCAT-5). <b>Results:</b> No statistically significant visual and oculomotor group differences were observed (<i>p</i> > 0.01), although individuals within the concussion group demonstrated highly variable outcomes at the subacute timepoint. <b>Conclusions:</b> While our findings did not reveal significant group-wide differences in visual and oculomotor function, the high inter-individual variability within the concussion group underscores the need for individualized assessment approaches. The ability of eye-tracking technology to detect subtle, yet potentially clinically relevant impairments at the individual level suggests its potential as a valuable adjunct to symptom-based concussion assessments. Future studies should explore the integration of symptom-based tools, clinical oculomotor assessments, and objective eye-tracking metrics to improve our understanding of concussion-related impairments.

Topic: Traumatic Brain Injury Research
Subfield: Epidemiology
Field: Medicine
Domain: Health Sciences
A Facile Synthesis of Fragment D of Antibiotic, Nosiheptide

A facile synthesis of the N,O-diprotected fragment of D of Nosiheptide, 2-[(1’S,3’S)-1’-amino-3’-carboxy-3’-hydroxypropyl]thiazole-4-carboxylic acid, from (S)-2,2-dimethyl-1,3-dioxalane-4-acetaldehyde in 10 steps and 10.6% overall yield, is described.

Topic: Carbohydrate Chemistry and Synthesis
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Petrology of autoliths in granitic rocks

Abstract Homeogenie inclusions - autoliths - widely distributed in granitic rocks, are restricted to hypabyssal and mesabyasal massifs of the gabbro-granite, tonalite-granodiorite, and adamellite-granite composition. Several geological and petrological characteristics of autoliths (independence of their composition from that of the Intruded rocks, close similarity between their composition and the composition of granitic rocks in which they occur, isofacial relation between autolilhs and the enclosing granites, etc.) distinguish them from other kinds of inclusions and indicate that they are regular members of the granitic series. From detailed chemical and mineraloglcal studies of autoliths from different massifs of the USSR and from analysis of data in the literature, we conclude thai autoliths form in the process of differentiation of granitic magmas. —Authors.

Topic: Geological Studies and Exploration
Subfield: Geology
Field: Earth and Planetary Sciences
Domain: Physical Sciences
Prognosis of Acute Leukemia (Continued)

I would like to communicate to Drs. Stein, et al.1,2 the experience of the Pediatric Department of Roswell Park Memorial Institute in order to illustrate the continued improvement in remission and survival rates that has occurred during tue last 7 years. I wish to avoid speculation3,4 as to future survival rates, but to establish firmly the facts that with the accumulation of data through cooperative studies, we have been able to improve upon survival figures. During the years 1963-1965, in the Department of Pediatrics at Roswell Park Memorial Institute, we entered 13 children with acute lymphobiastic leukemia on Acute Leukemia Group B protocol 6307.

Topic: Hematological disorders and diagnostics
Subfield: Emergency Medicine
Field: Medicine
Domain: Health Sciences
Psychopathology in individuals with sexual dysfunction

The literature contains contradictory reports on the psychiatric status of individuals with sexual dysfunction. As a step toward resolving the controversy the authors administered the SCL-90-R to a large series of patients who sought treatment for sexual disorders (N = 325). Psychiatric evaluations were also done for each patient. Results showed disproportionate levels of psychological distress, reflected in SCL-90-R symptom profiles; approximately one-third of the 199 men and one-half of the 126 women in the series were also assigned psychiatric diagnoses. Findings provided evidence suggesting that the various sexual dysfunctions have characteristic symptom profiles; however, interpretation should be cautious because the cause-and-effect relationship between psychological distress and sexual dysfunctions remains complex and uncharted.

Topic: Sexual function and dysfunction studies
Subfield: Psychiatry and Mental health
Field: Medicine
Domain: Health Sciences
Comparative analysis of bone grafting materials for jaw defect reconstruction

BACKGROUND: Autogenous bone remains the gold standard for grafting because of its osteogenic properties; however, its use is limited. Allogeneic and xenogeneic grafts are more convenient but require meticulous preparation. Combined approaches, including the use of growth factors, represent a promising direction. Optimal material selection should be tailored to individual patient factors and the clinical context. The article compares Russian-manufactured bone grafting materials with imported counterparts and reports a histological examination of the newly formed bone tissue. AIM: To analyze newly formed bone tissue in patients following the use of contemporary bone graft materials. METHODS: A total of 79 bone-augmentation procedures were performed using xenogeneic materials—both imported and Russian-manufactured grafts; 39 of these cases were selected for histological assessment of the newly formed bone. Patients were allocated into 3 groups according to the bone-graft combinations placed at implantation: group 1, Osteomatrix, Bioimplant GAP, and Biomatrix (Konektbiopharm, Russia); group 2, Bio-Oss and Bio-Gide (Geistlich Pharma AG, Switzerland); and group 3, bioOST and bioPLATE (Cardioplant, Russia). Biopsy specimens of newly formed bone were obtained 5 months postoperatively for subsequent histological assessment of tissue and cellular architecture. RESULTS: Group 1 demonstrated predominance of mature lamellar bone with active osteoblasts and preosteoblasts. Application of the group 2 and group 3 grafts yielded high bone density and active osteogenesis, with trabecular bone formation. CONCLUSION: Clinical, radiographic, and histological data suggest that Osteomatrix, Bioimplant GAP, Biomatrix, bioOST, and bioPLATE grafting materials support uniform bone regeneration. Their regenerative potential is comparable to that of imported counterparts, indicating their viability as alternative grafting materials.

Topic: Dental Implant Techniques and Outcomes
Subfield: Oral Surgery
Field: Dentistry
Domain: Health Sciences
Cultural diversity: an exercise in elaboration

This paper explores how I used personal construct theory (PCT) to underpin an intervention I designed and delivered to improve organizational effectiveness. The aim was to help improve the poor relationship between one of the teams in the organization I work for and representatives of their American customer which was adversely affected by cultural misunderstanding. I used a variety of tools and techniques to help individuals explore their understanding of each other's beliefs, values and language and its impact on the relationship. Delegates embarked on a journey that took them from the generic macro level of cultural stereotypes and perceptions to the micro-level of what these actually meant in their individual relationships. PCT provides a strong, robust framework for understanding one another's world from within. Because it is based on a strong theoretical base it provides guidelines within which the practitioner can, effectively and efficiently, work.

Topic: Cognitive and psychological constructs research
Subfield: Social Psychology
Field: Psychology
Domain: Social Sciences
Aerodynamics-based forward-swept wing structure optimization

This paper reviews and evaluates the most recent studies on forward-swept wing technology. A number of experimental plans and applications for forward-swept wing aircraft have been produced as a result of the study of forward-swept wings, the investigation of aerodynamic circumstances, and the creation of related designs. The related theories and exposed problems of the forward-swept wing aircraft, such as the problem of aeroelastic divergence, structural strength, and the descent of transonic flight state, are gradually solved. It will be demonstrated that forward-swept wing aircraft have outstanding aerodynamic performance in subsonic flight. In comparison to current aircraft, it may gain more controllability advantages, enhance low-speed controllability, increase aerodynamic efficiency in a variety of flying scenarios, decrease stall speed, making the aircraft less likely to enter the spiral state, and increase safety and dependability. The research in the field of forward swept wing will increase the possibility of successful development and practical use of forward swept wing aircraft.

Topic: Computational Fluid Dynamics and Aerodynamics
Subfield: Computational Mechanics
Field: Engineering
Domain: Physical Sciences