jimnoneill/paper-to-field-training huggingface dataset:
(CAAC)CuCl: A Competent Precatalyst for Carbonyl and Ester Hydrosilylation

Field: Chemistry (Physical Sciences)

Cu-catalyzed carbonyl hydrosilylation involves a ligated "[(L)CuH]" as the active catalyst, where the ligand L has a crucial role toward the stability, stereoselectivity, and enhancement of the hydridicity. Strongly σ-donating N-heterocyclic carbenes (NHCs), their ring-expanded form, and an abnormal NHC as ligands have yielded robust and efficient Cu catalysts. However, cyclic(alkyl)(amino)carbenes (CAACs), despite being stronger σ-donors than NHCs and already having a salient Cu(I) chemistry, are yet to be reported as a similar ligand platform for this purpose. We establish here the familiar [(Me2CAAC)CuCl] as a powerful precatalyst in this regard. Additionally, it also catalyzes the more challenging ester hydrosilylation, which is a rare feat for a Cu catalyst. Apart from the stronger σ-donating ability, the more steric "openness" of CAACs than bulky NHCs also seems to be advantageous. To corroborate, three new (CAAC)CuCl complexes [(ArCH2,MeCAAC)CuCl] (Ar = Ph, 1-naphthyl, and 1-prenyl) are devised, where the effective steric around the copper is practically unaltered from the case of [(Me2CAAC)CuCl]. All three are equally active in carbonyl and ester hydrosilylation as [(Me2CAAC)CuCl]. Computation suggests the carbonyl insertion into a "(CAAC)Cu-H" as the rate-limiting step. To elucidate the involvement of a "(CAAC)CuH", "(PhCH2,MeCAAC)CuH" is generated in situ and is trapped as its BH3 adduct (PhCH2,MeCAAC)CuBH4.
AB047. Quebec database of clinical data and biological material for research on uveal melanoma

Field: Medicine (Health Sciences)

Background: Sharing biological material and clinical data from patients with uveal melanoma. Methods: Uveal melanoma is the most common intraocular malignancy in the adult population. Because uveal melanoma is primarily a sporadic cancer and familial cases are rare, it is difficult to prevent or detect it. Despite effective treatment of ocular tumors, more than 50% of patients develop incurable liver metastases mainly in the 5–10 years following the detection of the primary tumor. This cancer is relatively rare and the obtained biopsies are very small. About 20 samples are taken each year in Quebec. This provincial infrastructure is made of biological material from donors with uveal melanoma and a large clinical database. Collected tumor biopsies are used for culturing cell lines and the creation of a DNA/RNA library used for genomic and genetic studies. Results: This infrastructure plays an important role in the achievement of various research programs for a better understanding of genetic and environmental factors involved in the development of melanoma and the spread of metastasis. It allows collaboration with other researchers at a provincial, national and international level in order to make progress in basic and clinical research on uveal melanoma. Conclusions: The biological material and clinical data of this infrastructure are available upon request to VHRN members whose research project was approved by the ethics committee of the institution.
THE DIAGNOSIS AND TREATMENT OF EPERYTHROZOONOSIS IN HOHHOT KAITONG PIGGERY

Field: Veterinary (Health Sciences)

The pigs suspected infected eperythrozoonosis were surveyed in kaitong piggery of hohhot from march to june in 2010.The synthesize diagnosis was developed including epidemiology,clinical symptom,pathology changes and hematology.The pigs were diagnosed eperythrozoonosis.There were 1674 pigs in the piggery comprised of sow,piglets and fattening pigs.Infected and suspected pigs were 478 and account for 28.6%.After treatment,the cure rate was 94.8%(454),the death rate was 5.02%(24).
The Development of Husserl's Analysis of Physical Pain1

Field: Arts and Humanities (Social Sciences)

This is an Accepted Manuscript of a book chapter published by Routledge in \nThe New Yearbook for Phenomenology and Phenomenological Philosophy on 2022, available online: http://www.routledge.com/books/edit/10.4324/b23070/new-yearbook-phenomenology-phenomenological-philosophy-burt-hopkins-john-drummond?refId=7f94dece-00ca-429b-b597-23518383d79a&context=ubx
ERIC ED464451: Assistive Technology in the Schools: A Guide for Idaho Educators.

Field: Health Professions (Health Sciences)

This manual is designed to provide Idaho educators, parents, students with disabilities, and related service providers with assistance in identifying, selecting, and acquiring assistive technology (AT) devices and services. The consideration of AT devices and services is required during the development of every Individualized Family Service Plan and every Individualized Education Program (IEP). The first section of the manual begins by explaining the importance of assistive technology in education and the challenge of delivering AT devices and services. Part 2 discusses assistive technology in special education law and includes an extensive list of case law related to adaptive equipment. Part 3 introduces a model of service delivery for AT, describes a series of quality indicators for AT services, and outlines how to include AT in the IEP. The suggested forms to use are included in this section. The final part discuses funding options for AT. Appendices provide a list of acronyms used in the manual, examples of AT for computer access and communication, examples of switches, examples of writing AT into the IEP, and a list of state and national resources for AT. (Contains 16 references.) (Author/CR)
Accidental Loss of Plastic Tube into Venous System

Field: Medicine (Health Sciences)

in muscle, while leaving the constrictor (alpha) actions unopposed.We would suggest on this limited experience the following pre-operative regime: phenoxybenzamine 1 mg./kg./day orally, plus pronethalol 300-400 mg./day (in three or four doses), for an adult, both drugs for three days before surgery.If, during operation, undue tachycardia or abnormal rhythms occur, intravenous pronethalol might be necessary -say, 25 mg.at first.We are grateful to the clinicians in charge of these cases for leave to refer to them here.
Isoflurane induced eNOS signaling and cardioprotection: Preconditioning mechanisms under normal and hyperglycemic conditions

Field: Pharmacology, Toxicology and Pharmaceutics (Life Sciences)

The main goal of the thesis was to evaluate the mechanisms conferring cardioprotection offered by anesthetic preconditioning (APC), i.e. the administration of inhalation anesthetics producing resistance to subsequent cessation of blood and oxygen supply, and to evaluate why this technique fails in diabetic conditions. We found that APC with isoflurane protected rat hearts by modulating nitric oxide (NO) synthesis through time-dependent changes in the expression of key NO regulatory proteins, including endothelial NO synthase (eNOS) and guanosine triphosphate cyclohydrolase (GTPCH)-1, the rate-limiting enzyme of tetrahydrobiopterin biosynthesis. Involvement of endothelial NO in APC was confirmed in co-cultures of endothelial and cardiac cells, which is dependent on maintenance of eNOS phosphorylation, partly via induction of hypoxia-inducible factor (HIF1α). APC is thought critically dependent on mitochondria. Given that diabetes alters mitochondrial bioenergetics and disrupts APC protection, contribution of proteins encoded by mitochondrial DNA was studied by using two strains of diabetic rats with the same nuclear but distinct mitochondrial genome. As APC protected hearts of only one of both strains from ischemia, with antioxidants having opposite effects, mitochondria and mitochondrial oxygen radical production seem critical in APC induced cardioprotection. Further mitochondrial adaptations that may abrogate APC induced cardioprotection in hyperglycemia and diabetes are reviewed in depth. Finally, we demonstrate that the ApoA1 mimetic, D-4F, restores APC evoked cardioprotection in hyperglycemia by maintaining a proper cellular localization of eNOS and limiting oxygen radical production. Collectively, this thesis discloses important signal transduction pathways involved in APC affected by diabetic conditions, and identifies a therapeutic strategy to counteract such loss for further clinical investigation.
FIGURE 3. Eucosma aurilineana genitalia. a in A new species of Eucosma Hübner from the Western United States (Lepidoptera: Tortricidae: Eucosmini).

Field: Agricultural and Biological Sciences (Life Sciences)

FIGURE 3. Eucosma aurilineana genitalia. a, male; female (b–e), b, corpus bursae; bb, ductus seminalis and bursa seminalis; c, ovipositor lobes and apophyses; d, lamella postvaginalis and ostium bursae; e, signa.
Spherical TiO2 /Cr2O3 Composites Synthesized Using Ion-Exchange Resins as a Template

Field: Chemistry (Physical Sciences)

Two samples of TiO 2 /Cr 2 O 3 composites were synthesized as spherical grains by stepwise thermal treatment of ion-exchange resins, which were preliminarily saturated with chromium cations Cr 3+ and dichromate anions Cr2O 7 2– and covered with a film-forming solution of titania. The modes of calcination were based on thermal analysis and determined by the type of ion-exchange resin chosen as a template. The obtained composites consist mostly of the α-Cr 2 O 3 phase, while the content of the TiO 2 phase does not exceed 4 %. The composites retain the spherical grain shape of the initial ion-exchange resins with the size from 370 to 660 μm. Grains of the sample based on cationite, which adsorbs Cr 3+ ions, have a pore structure with swells and voids. Grains of the sample based on anionite have fractures and cracks over the entire surface due to nonuniform distribution of adsorbed Cr 2 O 7 2– anions in the initial anionite. The composites exhibit the catalytic activity in the complete oxidation of p-xylene. The sample based on cationite is more active. This may be related to a smaller accessible specific surface area of titania in the anionite-based sample due to formation of the Ti 3+ solid solution in α-Cr 2 O 3 .
A fluorescence microscopy method for determining the viability of entomophthoralean fungal spores

Field: Agricultural and Biological Sciences (Life Sciences)

Conidial viability of two species of entomophthoralean fungi was assessed using parallel vital fluorochrome staining and germination studies. Fluorescein diacetate (FDA) indicates viability when cells fluoresce yellow-green while propidium iodide (PI) indicates nonviability when cells fluoresce red. Various methods were used to induce Entomophaga maimaiga and Zoophthora radicans conidial mortality, including exposure to electromagnetic radiation, ethanol, or high temperatures. Following each treatment, half of the conidia were either stained with FDA and PI or held at ideal conditions for assessment of germination. In separate experiments, resting spores of Entomophaga grylli and E. maimaiga were treated either by autoclaving or with ethanol. Vital staining was used to assess the viability of the resting spores. FDA and PI were found to assess the viability of E. maimaiga and Z. radicans conidia accurately and precisely when compared to standard germination tests. No differences in comparative test results were found whether conidia were killed with ethanol, electromagnetic radiation, or high temperatures. When assessing resting spore viability, however, FDA and PI were not effective due to limited penetration of these stains through the thick walls of the spores and also due to the autofluorescence of E. maimaiga and E. grylli resting spores.
Biomedical Optical Imaging

Field: Medicine (Health Sciences)

Abstract Biomedical optical imaging is a rapidly emerging research area with widespread fundamental research and clinical applications. This book gives an overview of biomedical optical imaging with contributions from leading international research groups who have pioneered many of these techniques and applications. A unique research field spanning the microscopic to the macroscopic, biomedical optical imaging allows both structural and functional imaging. Techniques such as confocal and multiphoton microscopy provide cellular level resolution imaging in biological systems. The integration of this technology with exogenous chromophores can selectively enhance contrast for molecular targets as well as supply functional information on processes such as nerve transduction. Novel techniques integrate microscopy with state-of-the-art optics technology, and these include spectral imaging, two photon fluorescence correlation, nonlinear nanoscopy; optical coherence tomography techniques allow functional, dynamic, nanoscale, and cross-sectional visualization. Moving to the macroscopic scale, spectroscopic assessment and imaging methods such as fluorescence and light scattering can provide diagnostics of tissue pathology including neoplastic changes. Techniques using light diffusion and photon migration are a means to explore processes which occur deep inside biological tissues and organs. The integration of these techniques with exogenous probes enables molecular specific sensitivity.
1041 Changes in Information Seeking Patterns of Medical Students in the Social Media and Artificial Intelligence Age: Preliminary Findings

Field: Health Professions (Health Sciences)

Abstract Aim Non-traditional and novel online sources of medical information such as social media, large language models (LLMs) and video sharing platforms are providing medical students with opportunities for innovative learning. This cross-sectional study assesses current trends in use of these resources among medical students. Method A prospective, cross-sectional, observational, and descriptive study using an online questionnaire was utilised. Data collected included platform used, frequency of use, preferences, perceived benefits, and challenges associated with the use of these tools in the learning experiences of medical students. Results 273 medical students consented and completed the survey. 217 (79.1%) of students used social media or online video sharing platforms for educational purposes, mainly to supplement or replace course materials. The three reported benefits of using social media for educational purposes were: (I) accessing medical knowledge quickly and easily (87.7%), (II) accessing short duration compressed videos (70.8%), and (III) accessing infographics and visually appealing resources (67.5%). 143 (52.2%) of students have used Chat GPT or other LLMs. Of these, 54.7% have used LLMs for educational purposes (33% weekly and 44.3% monthly), and report using them mainly as resource when completing assignments, homework, or essays. 73.2% expressed concerns regarding unreliable medical information on social media, whereas only 54.8% expressed concerns with LLMs. Conclusions The survey results demonstrate that medical students are frequently seeking medical knowledge outside of core course materials. Medical educators must become aware of these changing trends. Guidance should be provided to medical students regarding the relative risks and benefits of these resources.
Multivariate time series prediction for CO2 concentration and flowrate of flue gas from biomass-fired power plants

Field: Energy (Physical Sciences)

Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method to achieve negative emissions. However, the use of versatile biomass, including waste, and the dynamic operation of bio-CHP plants leads to large fluctuations in the flowrate and CO2 concentration of the flue gas (FG), which further affect the operation of post-combustion CO2 capture. To optimize the dynamic operation of CO2 capture, a reliable model to predict the FG flowrate and CO2 concentration in real time is essential. In this paper, a data-driven model based on the Transformer architecture is developed. The model validation shows that the root mean squared error (RMSE), mean absolute percentage error (MAPE), and Pearson correlation coefficient (PPMCC) of Transformer are 0.3553, 0.0189, and 0.8099 respectively for the prediction of FG flowrate; and 13.137, 0.0318, and 0.8336 respectively for the prediction of CO2 concentration. The potential impact of various meteorological parameters on model accuracy is also assessed by analyzing the Shapley value. It is found that temperature and direct horizontal irradiance (DHI) are the most important factors, which should be selected as input features. In addition, using the near-infrared (NIR) spectral data as input features is also found to be an effective way to improve the prediction accuracy. It can reduce RMSE and MAPE for CO2 concentration from 0.2982 to 0.2887 and 0.0158 to 0.0157 respectively, and RMSE and MAPE for FG flowrate from 4.9854 to 4.7537 and 0.0141 to 0.0121 respectively. The Transformer model is also compared to other models, including long short-term memory network (LSTM) and artificial neural network (ANN), which results show that the Transformer model is superior in predicting complex dynamic patterns and nonlinear relationships.
Systematics and biogeography of pygmy possums (Burramyidae : Cercartetus )

Field: Agricultural and Biological Sciences (Life Sciences)

Mitochondrial DNA sequences from the ND2 gene were used to investigate the systematic relationships within pygmy possums ( Cercartetus ) at the subspecies and species level. The phylogenetic relationships identified between Cercartetus species using partitioned ND2 sequences are in agreement with published morphological characters. C. caudatus was identified as the basal member of this assemblage, whilst C. nanus and C. concinnus are linked to the exclusion of C. lepidus . Molecular data identifies some inconsistencies in the assignment of subspecies within Cercartetus , suggesting that revision may be warranted.
LPViT: A Transformer Based Model for PCB Image Classification and Defect Detection

Field: Computer Science (Physical Sciences)

PCB (printed circuit board) is an extremely important component of all electronic products, which has greatly facilitated human life. Meanwhile, tons of PCBs in the waste streams become a waste of resources, which puts the recycling and reuse of PCBs in urgent need. In the manufacturing and recycling of electronic products, the classification of PCBs, recognition of sub-components, and defect detection have been the key technology. Traditional manual detection and classification are subjective and rely on individuals’ experience. With the development of artificial intelligence, lots of research efforts have been dedicated to the automated detection and recognition of PCBs. In this paper, we propose a transformer-based model, LPViT, for defect detection and classification of PCBs. We conduct the defect detection task on the dataset DeepPCB, which consists of six different types of PCB defects. Defect detection benefits both manufacturing and recycling of PCBs. Among many electronic products, a group of affordable, general-purpose, and small-size PCBs is very popular, which are referred to as micro-PCBs. The classification and recognition of those PCBs will greatly facilitate the recycling and reuse process. We conduct the classification task on a dataset called micro-PCB, which includes 12 types of popular, general-purpose, affordable, and small PCBs. Through comparative experiments, our system demonstrates its advantage in both classification and defect detection tasks.
Preparation and identification of recombinant vaccinia virus harboring Hantaan virus S gene

Field: Biochemistry, Genetics and Molecular Biology (Life Sciences)

Objective:Preparing and identifing recombinant vaccinia virus with Hantaan virus S gene, to lay the foundation for the establishment of specific cytotoxic T lymphocytes (CTL) target cells expressing nucleocapsid protein of Hantaan virus. Methods: Vero cells were infected by wild vaccinia virus and recombinant vaccinia virus with Hantaan virus S gene, respectively. Viruses were multiplied and tittered. Hantaan virus S gene in recombinant vaccinia virus genome was identified using PCR and dot hybridization. Expression of nucleocapsid protein was detected using indirect immunofluorescent assay (IFA) and Western blot. Resusts:Recombinant vaccinia viruses with Hantaan virus S gene have been prepared. Virus titer is 4.02×10 7 . It can effectively express nucleocapsid protein in Vero cells. Conclusion:Recombinant vaccinia viruses with higher titer were prepared successfully and it can effectively expressed nucleocapsid protein of Hantaan virus.
Penyelesaian Sengketa Pemilihan Umum di Indonesia

Field: Social Sciences (Social Sciences)

The realization of democracy in Indonesia is one of which is carried out by general elections, this is a political contestation which often present disputes.There is a general understanding that effective electoral dispute resolution mechanisms and processes are a “sine qua non” for fair and fair elections.As well as the implementation of the general election system is designed in there is alwayas a possibility of violations that can reduce the quality of general elections, for that as well as the implementation of the general election system, within it is always available a trusted istitutional mechanism to resolve various types of general election objections and disputes.Disputes or disputes can be divided into two, that is (1) disputes in the electoral process (especially those that occur between participants in the general election or between candidates) which have been handled by the election supervisory committee and election results disputes or disputes. This paper aims to find out and analyze the dispute resolution of elections in Indonesia.The type of research used is normative juridical research, using conceptual approach, legislation approach, and historical approach
Efficacy and safety of a modified- ‘modified Ponticelli’ regimen for treatment of primary membranous nephropathy

Field: Medicine (Health Sciences)

Background: Modified Ponticelli regimen (mPR), consisting of cyclical steroids and cyclophosphamide, is the most established therapy for primary membranous nephropathy (MN). Yet, the potential toxicity of this treatment regimen poses a significant concern. Objectives: The aim of this study was to assess the efficacy and safety of a modified version of the conventional mPR for primary MN using lower-than-standard dose pulse steroids. Patients and Methods: This was a retrospective single-center analysis of patients admitted between January 2008 to December 2017. All treatment-naive patients with biopsy-proven primary MN treated with a lower-than-standard dose pulse steroid-based modification of the conventional mPR (intravenous pulse of 500 mg methyl-prednisolone, instead of 1000 mg) were included. We report the remission rates at the end of 6 months (both complete and partial), relapses and adverse effects of treatment at the end of follow-up. Results: A total of 41 individuals were included. Of 31 individuals who completed six months of treatment (six were lost to follow-up, while four discontinued immunosuppression due to infections), 71% (n=22) responded to treatment [complete remission in 25.8% (n=8), partial remission in 45.2% (n=14)]. Most common complications detected throughout the treatment were steroid induced diabetes mellitus in 40% (n=14/35), infections in 25.7% (of which immunosuppression was discontinued for four participants), and leucopenia in 8.5% (n=3/35). Relapses were seen in 29% (n=9) during follow-up (mean follow-up period: 36 months). Conclusions: The modified- ‘modified Ponticelli’ regimen with lower-than-standard dose intravenous steroids and cyclophosphamide was efficient in attaining remission in primary MN.