Synthesis of nanostructured materials in near and or supercritical fluids : methods fundamentals and modeling Intro Synthesis of Nanostructured Materials in Near and or Supercritical Fluids: Methods Fundamentals and Modeling Copyright Contents Foreword Preface Chapter 1: Introduction 1.1. Some conventions 1.2. Motivation 1.2.1. Metallic materials 1.2.2. Metal oxide materials 1.3. Scope of the book References Chapter 2: Compounds of interest 2.1. Introduction 2.2. Types of coordination compounds 2.3. Structures and bonding in coordination compounds 2.4. Reactions of organometallic compounds on surfaces Chapter 3: Support materials 3.1. Different support materials 3.1.1. Silicas 3.1.2. Mesoporous silicas 3.1.3. Aluminas 3.1.4. Zeolites 3.1.5. Silica aluminas 3.1.6. Metal organic frameworks 3.1.7. Aerogels 3.1.8. Silica aerogel 3.1.9. Alumina aerogel 3.1.10. Carbonaceous supports 3.1.11. Carbon aerogels 3.1.12. Graphene aerogels 3.2. Characterization of porous materials 3.2.1. Nitrogen physisorption 3.2.2. X ray diffraction References Chapter 4: Fundamental aspects of pure supercritical fluids 4.1. Introduction 4.2. Thermal and caloric properties 4.3. Transport properties 4.4. Applications of supercritical fluids References Chapter 5: Thermodynamics and transport properties of mixtures composed of metal complexes and supercritical fluids 5.1. Introduction 5.2. Phase behavior 5.3. Solubility and binary diffusion coefficients of metal complexes in SCF 5.4. Determination of high pressure phase behavior data 5.5. Experimental procedure 5.6. Modeling solubility of metal complexes in SCFs 5.7. Experimental determination and modeling of the solubility of salts in sub and supercritical H2O References Chapter 6: Thermodynamics and kinetics of adsorption of metal complexes on surfaces from supercritical solutions.