Electron and phonon spectrometrics Part I. Electron Emission: Quantum Entrapment and Polarization Introduction Theory: Bond Electron Energy Correlation Probing Strategies: STM S PES APECS XAS ZPS Solid and Liquid Skins: Quantum Entrapment and Polarization Adatoms Defects and Kink Edges Atomic Chain Ends Clusters and Nanocrystals Carbon Allotropes Hetero Coordinated Interfaces Tetrahedrally Coordinated Bond Formation Hetero and Under Coordination Coupling Liquid Phase Concluding Remarks Part II. Electron Diffraction: Bond band Barrier Forming Dynamics Principles: Bond band barrier Correlation Methodology: Parameterization and Justification VLEED Capability and Sensitivity Bond Geometry Valence Band Potential Barrier and Work Function Four Stage Cu3O2 Bonding Dynamics Conclusion Part 3. Multifield Phonon Dynamics Wonders of Multifield Lattice Oscillation Theory: Multifield Oscillation Dynamics Phonons of the Layered Structures Phonons of the Sized Crystals Water and Aqueous Solutions Concluding Remarks. This book presents the latest advances and future trends in electron and phonon spectrometrics focusing on combined techniques using electron emissions electron diffraction and phonon absorption and reflection spectrometrics from a substance under various perturbations to obtain new information on bond electron phonon dynamics. Discussing the principles of the bond order length strength (BOLS) correlation nonbonding electron polarization (NEP) local bond average (LBA) and multi field lattice oscillation dynamics for systems under perturbation the book covers topics like differential photoelectron phonon spectrometrics (DPS) which distils transition of the length energy stiffness and the fraction of bonds upon chemical or physical conditioning; and the derived performance of electrons in various bands in terms of quantum entrapment and polarization. This book appeals to researchers scientists and engineers in the fields of chemistry physics surface and interface science and materials science and engineering who are interested in electron and phonon spectrometrics. .