Authors: Tyser Allami | Ahmed A. Al‐Amiery | M. H. Nassir | Amir H. Kadhum
Source: Polymers (review, 2021-07-27)
Field: Materials Science — Polymers and Plastics

Investigating Physio-Thermo-Mechanical Properties of Polyurethane and Thermoplastics Nanocomposite in Various Applications The effect of the soft and hard polyurethane (PU) segments caused by the hydrogen link in phase-separation kinetics was studied to investigate the morphological annealing of PU and thermoplastic polyurethane (TPU). The significance of the segmented PUs is to achieve enough stability for further applications in biomedical and environmental fields. In addition, other research focuses on widening the plastic features and adjusting the PU-polyimide ratio to create elastomer of the poly(urethane-imide). Regarding TPU- and PU-nanocomposite, numerous studies investigated the incorporation of inorganic nanofillers such as carbon or clay to incorporating TPU-nanocomposite in several applications. Additionally, the complete exfoliation was observed up to 5% and 3% of TPU-clay modified with 12 amino lauric acid and benzidine, respectively. PU-nanocomposite of 5 wt.% Cloisite<sup>®</sup>30B showed an increase in modulus and tensile strength by 110% and 160%, respectively. However, the nanocomposite PU-0.5 wt.% Carbone Nanotubes (CNTs) show an increase in the tensile modulus by 30% to 90% for blown and flat films, respectively. Coating PU influences stress-strain behavior because of the interaction between the soft segment and physical crosslinkers. The thermophysical properties of the TPU matrix have shown two glass transition temperatures (<i>T<sub>g</sub></i>'s) corresponding to the soft and the hard segment. Adding a small amount of tethered clay shifts <i>T<sub>g</sub></i> for both segments by 44 °C and 13 °C, respectively, while adding clay from 1 to 5 wt.% results in increasing the thermal stability of TPU composite from 12 to 34 °C, respectively. The differential scanning calorimetry (DSC) was used to investigate the phase structure of PU dispersion, showing an increase in thermal stability, solubility, and flexibility. Regarding the electrical properties, the maximum piezoresistivity (10 S/m) of 7.4 wt.% MWCNT was enhanced by 92.92%. The chemical structure of the PU-CNT composite has shown a degree of agglomeration under disruption of the sp2 carbon structure. However, with extended graphene loading to 5.7 wt.%, piezoresistivity could hit 10<sup>-1</sup> S/m, less than 100 times that of PU. In addition to electrical properties, the acoustic behavior of MWCNT (0.35 wt.%)/SiO<sub>2</sub> (0.2 wt.%)/PU has shown sound absorption of 80 dB compared to the PU foam sample. Other nanofillers, such as SiO<sub>2</sub>, TiO<sub>2</sub>, ZnO, Al<sub>2</sub>O<sub>3</sub>, were studied showing an improvement in the thermal stability of the polymer and enhancing scratch and abrasion resistance. Thermoplastic polyurethane ; Materials science ; Nanocomposite ; Differential scanning calorimetry ; Ultimate tensile strength ; Composite material ; Glass transition ; Polyurethane ; Dynamic mechanical analysis ; Thermal stability ; Young's modulus ; Elastomer ; Polymer ; Chemical engineering Polymer composites and self-healing ; Polymer Nanocomposites and Properties ; Synthesis and properties of polymers