jablonkagroup/rise_ai_scientists huggingface dataset:
Authors: Xuan Zhang | Yiyi Xu | Cristian Valenzuela | Xinfang Zhang | Ling Wang | Wei Feng | Quan Li
Source: Light Science & Applications (review, 2022-07-14)
Field: Materials Science — Electronic, Optical and Magnetic Materials

Liquid crystal-templated chiral nanomaterials: from chiral plasmonics to circularly polarized luminescence Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond. Nanomaterials ; Nanotechnology ; Chirality (physics) ; Materials science ; Circular dichroism ; Luminescence ; Plasmon ; Chemistry ; Physics ; Optoelectronics ; Chiral symmetry Metamaterials and Metasurfaces Applications ; Liquid Crystal Research Advancements ; Synthesis and Properties of Aromatic Compounds
Authors: Zhichao Yu | Hexiang Gong | Mei‐Jin Li | Dianping Tang
Source: Biosensors and Bioelectronics (article, 2022-09-27)
Field: Materials Science — Materials Chemistry

Hollow prussian blue nanozyme-richened liposome for artificial neural network-assisted multimodal colorimetric-photothermal immunoassay on smartphone Prussian blue ; Biosensor ; Absorbance ; Detection limit ; Immunoassay ; Materials science ; Photothermal therapy ; SIGNAL (programming language) ; Cascade ; Chemistry ; Nanotechnology ; Computer science ; Chromatography ; Electrochemistry ; Electrode Advanced Nanomaterials in Catalysis ; Advanced biosensing and bioanalysis techniques ; Nanoplatforms for cancer theranostics
Authors: Liangying Li | Lidong Guo | David H. Olson | Shikai Xian | Zhiguo Zhang | Qiwei Yang | Kaiyi Wu | Yiwen Yang | Zongbi Bao | Qilong Ren | Jing Li
Source: Science (article, 2022-07-14)
Field: Chemistry — Inorganic Chemistry

Discrimination of xylene isomers in a stacked coordination polymer The separation and purification of xylene isomers is an industrially important but challenging process. Developing highly efficient adsorbents is crucial for the implementation of simulated moving bed technology for industrial separation of these isomers. Herein, we report a stacked one-dimensional coordination polymer {[Mn(dhbq)(H<sub>2</sub>O)<sub>2</sub>], H<sub>2</sub>dhbq = 2,5-dihydroxy-1,4-benzoquinone} that exhibits an ideal molecular recognition and sieving of xylene isomers. Its distinct temperature-adsorbate-dependent adsorption behavior enables full separation of <i>p</i>-, <i>m</i>-, and <i>o</i>-xylene isomers in both vapor and liquid phases. The delicate stimuli-responsive swelling of the structure imparts this porous material with exceptionally high flexibility and stability, well-balanced adsorption capacity, high selectivity, and fast kinetics at conditions mimicking industrial settings. This study may offer an alternative approach for energy-efficient and adsorption-based industrial xylene separation and purification processes. Adsorption ; Structural isomer ; Xylene ; Chemistry ; Selectivity ; Polymer ; p-Xylene ; Chemical engineering ; Separation process ; o-Xylene ; Flexibility (engineering) ; Materials science ; Catalysis ; Organic chemistry ; Chromatography ; Toluene Metal-Organic Frameworks: Synthesis and Applications ; Covalent Organic Framework Applications ; Membrane Separation and Gas Transport
Authors: Salem S. Salem | Eman Hammad | Asem A. Mohamed | Wagdi I.A. El-Dougdoug | Z Farooqi | A Qadeer | M Hussain | N Zeeshan | P Ilic | S Salem | A Fouda | R Varghese | S Parani | S Thomas | O Oluwafemi | J Wu | T Barik | G Maity | P Gupta | L Mohan | T Santra | B Singh | S Lee | K Na | M Fouda | M Awad | E Al-Olayan | A Allam | T Shaheen | S Khan | S Mansoor | Z Rafi | B Kumari | A Shoaib | M Saeed | S Alshehri | M Ghoneim | M Rahamathulla | U Hani | H Prez-Hernndez | A Prez-Moreno | C Sarabia-Castillo | S Garca-Mayagoitia | G Medina-Prez | F Lpez-Valdez | R Campos-Montiel | P Jayanta-Kumar | F Fernndez-Luqueo | R Singh | S Singh | K Pathakoti | L Goodla | M Manubolu | H.-M Hwang | M Elkodous | H El-Husseiny | G El-Sayyad | A Hashem | A Doghish | D Elfadil | Y Radwan | H El-Zeiny | H Bedair | O Ikhdair | S Bayda | M Adeel | T Tuccinardi | M Cordani | F Rizzolio | L Qiu | N Zhu | Y Feng | E Michaelides | G ya | D Jing | X Zhang | P Norris | C Markides | O Mahian | V Chivere | P Kondiah | Y Choonara | V Pillay | M El-Naggar | M Hasanin | N Alvandi | M Rajabnejad | Z Taghvaei | N Esfandiari | A El-Rashedy | S Kamel
Source: Biointerface Research in Applied Chemistry (review, 2022-01-24)
Field: Materials Science — Materials Chemistry

A Comprehensive Review of Nanomaterials: Types, Synthesis, Characterization, and Applications Nanotechnology has infiltrated all sectors due to its unique and evident impacts, which give the scientific community numerous breakthroughs in the medical, agricultural, and other domains. Nanomaterials (NMs) have risen to prominence in technological breakthroughs due to their adjustable physical, chemical, and biological characteristics and superior performance over bulk equivalents. NMs are divided into many categories based on size, composition, capping agents, form, and origin. The capacity to forecast NMs' unique features raises the value of each categorization. As the manufacturing of NMs and industrial uses grow, so does their demand. The purpose of this review is to compare synthetic and naturally occurring nanoparticles and nanostructured materials to determine their nanoscale characteristics and to identify particular knowledge gaps related to the environmental application of nanoparticles and nanostructured materials. The paper review includes an overview of NMs' history and classifications and the many nanoparticles and nanostructured materials sources, both natural and manufactured. Furthermore, the many applications for nanoparticles and nanostructured materials. Nanotechnology ; Nanomaterials ; Characterization (materials science) ; Nanoparticle ; Materials science Nanoparticles: synthesis and applications ; Nanotechnology research and applications
Authors: M. Ramesh | L. Rajeshkumar | N. Srinivasan | D. Vasanth Kumar | D. Balaji
Source: e-Polymers (review, 2022-01-01)
Field: Materials Science — Polymers and Plastics

Influence of filler material on properties of fiber-reinforced polymer composites: A review Abstract The current day target for material scientists and researchers is developing a wholesome material to satisfy the parameters such as durability, manufacturability, low cost, and lightweight. Extensive research studies are ongoing on the possible application of polymer matrix composites in engineering and technology, since these materials have an edge over conventional materials in terms of performance. Hybridization of reinforcements is considered to be a better option to enhance the efficiency and performance of composite materials. Accordingly, research studies focus on the surface treatment of natural fibers and the addition of nanofillers (natural or synthetic) by industry and academia to take the properties and application of composites to the next level. This review purely focuses on the influence of fillers on the properties of composites along with the probable application of filler-based polymer composites. Composite material ; Materials science ; Filler (materials) ; Design for manufacturability ; Durability ; Natural fiber ; Polymer ; Fiber ; Synthetic fiber ; Natural materials ; Advanced composite materials ; Enhanced Data Rates for GSM Evolution ; Fiber-reinforced composite ; Composite number ; Mechanical engineering ; Computer science ; Polymer science ; Engineering Natural Fiber Reinforced Composites ; Tribology and Wear Analysis ; Polymer Nanocomposites and Properties
Authors: Jae‐Kyung Kim | Junhwa Seong | Younghwan Yang | Seong‐Won Moon | Trevon Badloe | Junsuk Rho
Source: Advanced Photonics (review, 2022-03-07)
Field: Materials Science — Electronic, Optical and Magnetic Materials

Tunable metasurfaces towards versatile metalenses and metaholograms: a review Metasurfaces have attracted great attention due to their ability to manipulate the phase, amplitude, and polarization of light in a compact form. Tunable metasurfaces have been investigated recently through the integration with mechanically moving components and electrically tunable elements. Two interesting applications, in particular, are to vary the focal point of metalenses and to switch between holographic images. We present the recent progress on tunable metasurfaces focused on metalenses and metaholograms, including the basic working principles, advantages, and disadvantages of each working mechanism. We classify the tunable stimuli based on the light source and electrical bias, as well as others such as thermal and mechanical modulation. We conclude by summarizing the recent progress of metalenses and metaholograms, and providing our perspectives for the further development of tunable metasurfaces. Holography ; Polarization (electrochemistry) ; Optoelectronics ; Materials science ; Optics ; Focal point ; Modulation (music) ; Physics ; Cardinal point ; Acoustics ; Chemistry Metamaterials and Metasurfaces Applications ; Advanced Antenna and Metasurface Technologies ; Advanced Materials and Mechanics
Authors: Sirong Li | Zijun Zhou | Zuoxiu Tie | Bing Wang | Meng Ye | Lei Du | Ran Cui | Wei Liu | Cuihong Wan | Quanyi Liu | Sheng Zhao | Quan Wang | Yihong Zhang | Shuo Zhang | Huigang Zhang | Yan Du | Hui Wei
Source: Nature Communications (article, 2022-02-11)
Field: Materials Science — Materials Chemistry

Data-informed discovery of hydrolytic nanozymes Nanozyme is a collection of nanomaterials with enzyme-like activity but higher environmental tolerance and long-term stability than their natural counterparts. Improving the catalytic activity and expanding the category of nanozymes are prerequisites to complement or even supersede enzymes. However, the development of hydrolytic nanozymes is still challenged by diverse hydrolytic substrates and following complicated mechanisms. Here, two strategies are informed by data to screen and predict catalytic active sites of MOF (metal-organic framework) based hydrolytic nanozymes: (1) to increase the intrinsic activity by finely tuned Lewis acidity of the metal clusters; (2) to improve the density of active sites by shortening the length of ligands. Finally, as-obtained Ce-FMA-MOF-based hydrolytic nanozyme is capable of cleaving phosphate bonds, amide bonds, glycosidic bonds, and even their mixture, biofilms. This work provides a rational methodology to design hydrolytic nanozyme, enriches the diversity of nanozymes, and potentially sheds light on future evolution of enzyme engineering. Chemistry ; Hydrolysis ; Catalysis ; Glycosidic bond ; Combinatorial chemistry ; Peptide bond ; Rational design ; Nanotechnology ; Enzyme ; Organic chemistry ; Materials science Advanced Nanomaterials in Catalysis ; Nanocluster Synthesis and Applications ; Carbon and Quantum Dots Applications
Authors: Andreas Mund | Andreas‐David Brunner | Matthias Mann
Source: Molecular Cell (review, 2022-06-01)
Field: Chemistry — Spectroscopy

Unbiased spatial proteomics with single-cell resolution in tissues Proteomics ; Biology ; Proteome ; Laser capture microdissection ; Computational biology ; Transcriptome ; Single-cell analysis ; Cell ; Quantitative proteomics ; Bioinformatics ; Cell biology ; Genetics ; Gene expression ; Gene Advanced Proteomics Techniques and Applications ; Single-cell and spatial transcriptomics ; Mass Spectrometry Techniques and Applications
Authors: Aanchna Sharma | T. Mukhopadhyay | Sanjay Mavinkere Rangappa | Suchart Siengchin | Vinod Kushvaha
Source: Archives of Computational Methods in Engineering (article, 2022-01-30)
Field: Materials Science — Materials Chemistry

Advances in Computational Intelligence of Polymer Composite Materials: Machine Learning Assisted Modeling, Analysis and Design Overfitting ; Aerospace ; Computer science ; Curse of dimensionality ; Reliability (semiconductor) ; Machine learning ; Interpretability ; Artificial intelligence ; Aerospace engineering ; Engineering ; Artificial neural network Machine Learning in Materials Science ; Probabilistic and Robust Engineering Design ; Industrial Vision Systems and Defect Detection
Authors: Sheron Tavares | Kesong Yang | Marc A. Meyers
Source: Progress in Materials Science (article, 2022-09-21)
Field: Materials Science — Electronic, Optical and Magnetic Materials

Heusler alloys: Past, properties, new alloys, and prospects Materials science ; Ferromagnetism ; Spintronics ; Superlattice ; Condensed matter physics ; Nanotechnology ; Engineering physics ; Optoelectronics ; Physics Heusler alloys: electronic and magnetic properties ; Advanced Thermoelectric Materials and Devices ; Machine Learning in Materials Science
Authors: Shuo Zhai | Heping Xie | Peng Cui | Daqin Guan | Jian Wang | Siyuan Zhao | Bin Chen | Yufei Song | Zongping Shao | Meng Ni
Source: Nature Energy (article, 2022-09-05)
Field: Materials Science — Materials Chemistry

A combined ionic Lewis acid descriptor and machine-learning approach to prediction of efficient oxygen reduction electrodes for ceramic fuel cells Materials science ; Cathode ; Oxide ; Perovskite (structure) ; Polarization (electrochemistry) ; Ceramic ; Characterization (materials science) ; Oxygen ; Ionic bonding ; Lewis acids and bases ; Electrode ; Solid oxide fuel cell ; Chemical engineering ; Nanotechnology ; Catalysis ; Composite material ; Chemistry ; Ion ; Anode ; Physical chemistry ; Metallurgy Advancements in Solid Oxide Fuel Cells ; Electrocatalysts for Energy Conversion ; Perovskite Materials and Applications
Authors: Guglielmo A. Coppola | Serena Pillitteri | Erik V. Van der Eycken | Shu‐Li You | Upendra K. Sharma
Source: Chemical Society Reviews (review, 2022-01-01)
Field: Chemistry — Organic Chemistry

Multicomponent reactions and photo/electrochemistry join forces: atom economy meets energy efficiency Visible-light photoredox catalysis has been regarded as an extremely powerful tool in organic chemistry, bringing the spotlight back to radical processes. The versatility of photocatalyzed reactions has already been demonstrated to be effective in providing alternative routes for cross-coupling as well as multicomponent reactions. The photocatalyst allows the generation of high-energy intermediates through light irradiation rather than using highly reactive reagents or harsh reaction conditions. In a similar vein, organic electrochemistry has experienced a fruitful renaissance as a tool for generating reactive intermediates without the need for any catalyst. Such milder approaches pose the basis toward higher selectivity and broader applicability. In photocatalyzed and electrochemical multicomponent reactions, the generation of the radical species acts as a starter of the cascade of events. This allows for diverse reactivity and the use of reagents is usually not covered by classical methods. Owing to the availability of cheaper and more standardized photo- and electrochemical reactors, as well as easily scalable flow-setups, it is not surprising that these two fields have become areas of increased research interest. Keeping these in view, this review is aimed at providing an overview of the synthetic approaches in the design of MCRs involving photoredox catalysis and/or electrochemical activation as a crucial step with particular focus on the choice of the difunctionalized reagent. Reagent ; Chemistry ; Catalysis ; Organic synthesis ; Light energy ; Combinatorial chemistry ; Electrochemistry ; Photoredox catalysis ; Atom economy ; Photochemistry ; Reactivity (psychology) ; Photocatalysis ; Nanotechnology ; Biochemical engineering ; Organic chemistry ; Materials science ; Physical chemistry Radical Photochemical Reactions ; Sulfur-Based Synthesis Techniques ; Advanced Photocatalysis Techniques
Authors: M. H. Abobeih | Yang Wang | J. Randall | S. J. H. Loenen | C. E. Bradley | Matthew Markham | Daniel J. Twitchen | Barbara M. Terhal | T. H. Taminiau
Source: Nature (article, 2022-05-05)
Field: Materials Science — Materials Chemistry

Fault-tolerant operation of a logical qubit in a diamond quantum processor Solid-state spin qubits is a promising platform for quantum computation and quantum networks<sup>1,2</sup>. Recent experiments have demonstrated high-quality control over multi-qubit systems<sup>3-8</sup>, elementary quantum algorithms<sup>8-11</sup> and non-fault-tolerant error correction<sup>12-14</sup>. Large-scale systems will require using error-corrected logical qubits that are operated fault tolerantly, so that reliable computation becomes possible despite noisy operations<sup>15-18</sup>. Overcoming imperfections in this way remains an important outstanding challenge for quantum science<sup>15,19-27</sup>. Here, we demonstrate fault-tolerant operations on a logical qubit using spin qubits in diamond. Our approach is based on the five-qubit code with a recently discovered flag protocol that enables fault tolerance using a total of seven qubits<sup>28-30</sup>. We encode the logical qubit using a new protocol based on repeated multi-qubit measurements and show that it outperforms non-fault-tolerant encoding schemes. We then fault-tolerantly manipulate the logical qubit through a complete set of single-qubit Clifford gates. Finally, we demonstrate flagged stabilizer measurements with real-time processing of the outcomes. Such measurements are a primitive for fault-tolerant quantum error correction. Although future improvements in fidelity and the number of qubits will be required to suppress logical error rates below the physical error rates, our realization of fault-tolerant protocols on the logical-qubit level is a key step towards quantum information processing based on solid-state spins. Qubit ; Quantum computer ; Computer science ; Quantum error correction ; Fault tolerance ; Error detection and correction ; Topology (electrical circuits) ; Algorithm ; Quantum ; Theoretical computer science ; Quantum mechanics ; Physics ; Mathematics ; Distributed computing Diamond and Carbon-based Materials Research ; Quantum Computing Algorithms and Architecture ; Quantum Information and Cryptography
Authors: Omar A. M. Abdelraouf | Ziyu Wang | Hailong Liu | Zhaogang Dong | Qian Wang | Ming Ye | Xiao Renshaw Wang | Qi Jie Wang | Hong Liu
Source: ACS Nano (review, 2022-08-17)
Field: Materials Science — Electronic, Optical and Magnetic Materials

Recent Advances in Tunable Metasurfaces: Materials, Design, and Applications Metasurfaces, a two-dimensional (2D) form of metamaterials constituted by planar meta-atoms, exhibit exotic abilities to tailor electromagnetic (EM) waves freely. Over the past decade, tremendous efforts have been made to develop various active materials and incorporate them into functional devices for practical applications, pushing the research of tunable metasurfaces to the forefront of nanophotonics. Those active materials include phase change materials (PCMs), semiconductors, transparent conducting oxides (TCOs), ferroelectrics, liquid crystals (LCs), atomically thin material, <i>etc.</i>, and enable intriguing performances such as fast switching speed, large modulation depth, ultracompactness, and significant contrast of optical properties under external stimuli. Integration of such materials offers substantial tunability to the conventional passive nanophotonic platforms. Tunable metasurfaces with multifunctionalities triggered by various external stimuli bring in rich degrees of freedom in terms of material choices and device designs to dynamically manipulate and control EM waves on demand. This field has recently flourished with the burgeoning development of physics and design methodologies, particularly those assisted by the emerging machine learning (ML) algorithms. This review outlines recent advances in tunable metasurfaces in terms of the active materials and tuning mechanisms, design methodologies, and practical applications. We conclude this review paper by providing future perspectives in this vibrant and fast-growing research field. Metamaterial ; Nanophotonics ; Nanotechnology ; Materials science ; Field (mathematics) ; Computer science ; Engineering physics ; Optical materials ; Optoelectronics ; Physics Metamaterials and Metasurfaces Applications ; Advanced Antenna and Metasurface Technologies ; Antenna Design and Analysis
Authors: Shreya Mahajan | Manu Lahtinen
Source: Journal of environmental chemical engineering (article, 2022-11-05)
Field: Chemistry — Inorganic Chemistry

Recent progress in metal-organic frameworks (MOFs) for CO2 capture at different pressures Global climate change ensued by the rise in atmospheric CO2 levels is one of the greatest challenges our planet is facing today. This worldwide distress demands technologies that can contribute to our society toward “negative carbon emissions”. Carbon capture and storage (CCS) technologies are in important role for capturing CO2 from existing emission sources, such as industrial and energy production point sources, before new more prominent modifications to the energy infrastructure can be implemented. Recently, alongside point source capture, direct air capture (DAC) processes have emerged as highly sought-after technologies that are able to capture CO2 from the ambient air. Alongside the traditional inorganic adsorbents, a new class of solid porous adsorbents, called as metal-organic frameworks (MOFs) have emerged in recent years also, as a group of potentially very efficient materials to capture CO2. The promising results of MOF-based adsorbents have already achieved great interest and have contributed to their ever-accelerating research to develop new and even better adsorbents for both point source and DAC recovery technologies. This review highlights the research that has been focused on utilizing MOFs in the carbon capture processes, particularly targeting materials applicable to low CO2 partial pressures but also capturing processes in pure CO2 (1 bar) will be reviewed, because it is a widely used test condition for characterizing sorption properties of MOF adsorbents. Herein, we outline four major approaches, through which the CO2 adsorption capacity and selectivity can be boosted, including targeted modifications of the metal centers, pore size control, proper selection and substitution of linker units, and functionalization of MOFs by amines. The mechanisms of the sorption event are also reviewed from the perspective of both physisorption and chemisorption phenomena. At the end of the review, we briefly examine the variables related to the coordination of technical-economical, process-technical, and physicochemical properties of adsorbents, which both researchers and engineers should consider when developing new adsorbents and recovery processes, with emphasis on material processing, capture capacity, selectivity, regeneration cyclicity, and cost. Metal-organic framework ; Environmental science ; Process engineering ; Waste management ; Chemistry ; Engineering ; Adsorption ; Organic chemistry Metal-Organic Frameworks: Synthesis and Applications ; Carbon Dioxide Capture Technologies ; Inorganic Fluorides and Related Compounds