jablonkagroup/rise_ai_scientists huggingface dataset:
Authors: Haiyan Li | Xin Wang | Yafei Chen | Han Leng | Junjie Bai | Yi Lü | Nan Wang | Du Cheng | Jianhua Wang | Mingli Chen
Source: Analytical Chemistry (article, 2025-01-13)
Field: Materials Science — Materials Chemistry

Lanthanide-Assisted Function Tailoring of the HOF-Based Logic Gate Sensor Array for Biothiol Detection and Disease Discrimination The advancement of lanthanide fingerprint sensors characterized by targeted emission responses and low self-fluorescence interference for the detection of biothiols is of considerable importance for the early diagnosis and treatment of cancer. Herein, the lanthanide "personality function tailoring" HOF composite sensor array is designed for the specific discrimination of biothiols (GSH, Cys, and Hcy) based on the activation of various luminescent molecules, such as r-AuNCs/luminol via HOF surface proximity. Lumi-HOF@Ce serves as a versatile platform for catalyzing the oxidation of <i>o</i>-phenylenediamine (OPD) to generate yellow fluorescent oligomers, accompanied by the fluorescence attenuation of luminol. HOF@Tb functions as a confinement interface that gathers gold nanoclusters (r-AuNCs) with red fluorescence, facilitating an aggregation-induced emission enhancement (AIEE). The fluorescence properties of AuNCs are subsequently impacted to varying degrees by the Au(I)-thiolate motifs from biothiol rooted in an enhanced ligand-metal charge transfer (LMCT) process. Additionally, the catalytic activity of Lumi-HOF@Ce, which exhibits oxidase-like properties, can be inhibited by different biothiols to varying extents. The five-channel fluorescent array demonstrates exceptional discrimination of biothiol fingerprints, aided by machine learning algorithms. Feature-tailored lanthanide HOF sensor arrays achieve sensitive identification with nearly 100% accuracy in classifying clinical liver cancer samples versus normal samples, using a logic gate strategy. The current strategy of lanthanide function tailoring boosts the suitability of biosensing applications. Lanthanide ; Chemistry ; Fluorescence ; Nanoclusters ; Biosensor ; Analyte ; Luminescence ; Chemiluminescence ; Photochemistry ; Combinatorial chemistry ; Nanotechnology ; Biochemistry ; Optoelectronics ; Chromatography ; Organic chemistry ; Materials science Nanocluster Synthesis and Applications ; Advanced Nanomaterials in Catalysis ; Advanced biosensing and bioanalysis techniques
Authors: Mugil Neelakandan | Preethi Dhandapani | Senthilkumar Ramasamy | Ramesh Duraisamy | Seung Jun Lee | Subramania Angaiah
Source: RSC Advances (review, 2025-01-01)
Field: Materials Science — Electronic, Optical and Magnetic Materials

A review on perovskite oxides and their composites as electrode materials for supercapacitors In energy storage applications, supercapacitors serve as an alternative to electrochemical batteries due to their large power density and exceptionally long cycle life. Redox-active supercapacitors are favoured for their durability and power density arising from the carbon-dominated field. However, their commercialization is questioned due to their slow reaction kinetics and low energy density limitations. Electrode materials with superior electrochemical behaviour must be developed to overcome these obstacles. The oxygen anion-intercalation mechanism leads to an interest in perovskite oxide materials with intrinsic oxygen vacancies and flexible structural characteristics. The primary objective of this review is to present an overview of the fundamental characteristics of perovskite oxides, their charge storage mechanism, and the key factors governing the electrochemical behaviour of the active material. This review was also compiled by reviewing previous research on perovskite materials for supercapacitors. This study examines the anion-intercalation mechanism and the variables affecting the electrochemical performance of electrodes. Furthermore, this review addresses the challenges and significance of previous research. Moreover, it presents the design guidelines for perovskite materials for supercapacitors, which appear beneficial for future studies on these materials. Supercapacitor ; Perovskite (structure) ; Materials science ; Capacitance ; Electrode ; Composite material ; Redox ; Chemical engineering ; Chemistry ; Metallurgy Supercapacitor Materials and Fabrication ; Advanced battery technologies research ; Electrocatalysts for Energy Conversion
Authors: Suvendu Panda | Tanmoy Maity | Susmita Sarkar | Arun K. Manna | Jagannath Mondal | Ritesh Haldar
Source: Nature Communications (article, 2025-02-03)
Field: Chemistry — Inorganic Chemistry

Diffusion-programmed catalysis in nanoporous material In the realm of heterogeneous catalysis, the diffusion of reactants into catalytically active sites stands as a pivotal determinant influencing both turnover frequency and geometric selectivity in product formation. While accelerated diffusion of reactants can elevate reaction rates, it often entails a compromise in geometric selectivity. Porous catalysts, including metal-organic and covalent organic frameworks, confront formidable obstacles in regulating reactant diffusion rates. Consequently, the chemical functionality of the catalysts typically governs turnover frequency and geometric selectivity. This study presents an approach harnessing diffusion length to achieve improved selectivity and manipulation of reactant-active site residence time at active sites to augment reaction kinetics. Through the deployment of a thin film composed of a porous metal-organic framework catalyst, we illustrate how programming reactant diffusion within a cross-flow microfluidic catalytic reactor can concurrently amplify turnover frequency (exceeding 1000-fold) and enhance geometric selectivity ( ~ 2-fold) relative to conventional nano/microcrystals of catalyst in one-pot reactor. This diffusion-programed strategy represents a robust solution to surmount the constraints imposed by bulk nano/microcrystals of catalysts, marking advancement in the design of porous catalyst-driven organic reactions. Catalysis ; Selectivity ; Nanoporous ; Diffusion ; Materials science ; Metal-organic framework ; Chemical engineering ; Chemistry ; Nanotechnology ; Reaction rate ; Porosity ; Organic chemistry ; Adsorption ; Thermodynamics ; Physics Metal-Organic Frameworks: Synthesis and Applications ; Covalent Organic Framework Applications ; Nanomaterials for catalytic reactions
Authors: Daniel Schwalbe‐Koda | Sébastien Hamel | Babak Sadigh | Fei Zhou | Vincenzo Lordi
Source: Nature Communications (article, 2025-04-29)
Field: Materials Science — Materials Chemistry

Model-free estimation of completeness, uncertainties, and outliers in atomistic machine learning using information theory An accurate description of information is relevant for a range of problems in atomistic machine learning (ML), such as crafting training sets, performing uncertainty quantification (UQ), or extracting physical insights from large datasets. However, atomistic ML often relies on unsupervised learning or model predictions to analyze information contents from simulation or training data. Here, we introduce a theoretical framework that provides a rigorous, model-free tool to quantify information contents in atomistic simulations. We demonstrate that the information entropy of a distribution of atom-centered environments explains known heuristics in ML potential developments, from training set sizes to dataset optimality. Using this tool, we propose a model-free UQ method that reliably predicts epistemic uncertainty and detects out-of-distribution samples, including rare events in systems such as nucleation. This method provides a general tool for data-driven atomistic modeling and combines efforts in ML, simulations, and physical explainability. Computer science ; Heuristics ; Outlier ; Uncertainty quantification ; Completeness (order theory) ; Entropy (arrow of time) ; Range (aeronautics) ; Machine learning ; Set (abstract data type) ; Artificial intelligence ; Data mining ; Mathematics ; Physics Machine Learning in Materials Science ; Protein Structure and Dynamics ; Ferroelectric and Negative Capacitance Devices
Authors: Weiwei Li | Yingzhe Li | Manzhang Xu | Yilin Zhou | Ruoyan Miao | Kexin Wang | Yunqiang Cao | Yan Song | Siying Dang | Lu Zheng | Xuewen Wang | Wei Huang
Source: Nature Communications (article, 2025-08-09)
Field: Materials Science — Polymers and Plastics

Highly customizable, ultrawide-temperature free-form flexible sensing electronic systems based on medium-entropy alloy paintings High-performance flexible sensing electronics on complex surfaces operating across broad temperatures are critical for aerospace and industrial applications. However, existing flexible sensors and materials face limitations in sensitivity and thermal stability. Here, we report an ink-engineering strategy to directly print single-face MoWNb medium entropy alloy paints on arbitrary surfaces without complicated post-processing. These sensors exhibit exceptional strain sensitivity (gauge factor up to -752.7 at 300 °C), a low detection limit (0.57 με), and superior thermal stability from -150 to 1100 °C. Through a cyclic dispersing/re-printing process, the fully recyclable sensors retain electrical properties and sensing performance. Furthermore, by integrating with a long-range radio module, we demonstrate a wireless sensing system for in-situ and real-time monitoring of a morphing aircraft under various extreme environments. Our findings provide a convenient and efficient approach for the direct fabrication of flexible sensors and the seamless integration into sensing systems that work reliably in harsh environmental conditions. Electronics ; Computer science ; Materials science ; Fabrication ; Gauge factor ; Aerospace ; Morphing ; Flexible electronics ; Inkwell ; Nanotechnology ; Aerospace engineering ; Electrical engineering ; Engineering Transition Metal Oxide Nanomaterials ; High Entropy Alloys Studies ; Advanced Thermoelectric Materials and Devices
Authors: Shimaa Hosny | Ghalia A. Gaber | Mona S. Ragab | Mohamed A. Ragheb | Mena Anter | Lamiaa Z. Mohamed
Source: Arabian Journal for Science and Engineering (article, 2025-09-13)
Field: Materials Science — Materials Chemistry

A Comprehensive Review of Silver Nanoparticles (AgNPs): Synthesis Strategies, Toxicity Concerns, Biomedical Applications, AI-Driven Advancements, Challenges, and Future Perspectives Abstract Silver nanoparticles (AgNPs) have garnered considerable attention due to their remarkable antimicrobial and biomedical properties. This review offers a comprehensive overview of AgNP synthesis methods, stability factors, toxicity concerns, and future research directions, including advancements driven by artificial intelligence (AI). Various synthesis approaches, including physical, chemical, electrochemical, photochemical, and biological methods, are explored, with particular emphasis on sustainable alternatives such as plant-based synthesis, as well as bacterial, fungal, and algal-mediated methods. Key factors influencing AgNP stability, such as size, shape, and surface modifications, are examined to assess their impact on functionality and overall performance. The biomedical applications of AgNPs, including their roles in antimicrobial treatments, wound healing, drug delivery, and cancer therapy, are reviewed alongside concerns about cytotoxicity and environmental implications. Nonetheless, we still have gaps in our understanding of the long-term biological impacts and our capacity to build consistent synthesis procedures. Challenges in AgNP synthesis, such as scalability, reproducibility, and controlled functionalization, are also discussed. Additionally, the integration of AI in AgNP research is highlighted, showcasing its potential in optimizing synthesis parameters, predicting stability, and enhancing material performance. This review aims to provide a thorough understanding of AgNP synthesis, stability, and biomedical applications while addressing toxicity issues and emphasizing the AI role in advancing nanoparticle research. This integration is a unique feature of the current article, as it has rarely been explored in previous studies. Finally, future perspectives and research directions are outlined to address existing challenges and drive further innovation in AgNP development with an emphasis on applying AI technology to overcome existing synthesis restrictions, improve repeatability, and promote intelligent AgNP-based medicinal platform design. Silver nanoparticle ; Human health ; Mechanism (biology) ; Biocompatible material Nanoparticles: synthesis and applications ; Graphene and Nanomaterials Applications ; Quantum Dots Synthesis And Properties
Authors: Juan Carlos Bravo | Gema Paniagua González | Rosa Marı́a Garcinuño Martı́nez | Asunción García-Mayor | Pilar Fernández Hernando
Source: Chemosensors (review, 2025-05-04)
Field: Materials Science — Materials Chemistry

Colorimetric Molecularly Imprinted Polymer-Based Sensors for Rapid Detection of Organic Compounds: A Review This review offers a comprehensive examination of the development and current state of the art in the field of molecularly imprinted polymer (MIP)-based colorimetric sensors, focusing on their potential for the rapid detection of organic compounds. These MIP-sensors are gaining considerable attention due to their distinctive capacity to modify sensor surfaces by creating recognition cavities within the polymer matrix, providing a versatile and highly selective platform for detecting a broad spectrum of analytes. This review systematically examines different types of MIP-based colorimetric sensors, attending to the target analyte, highlighting their applications in on-site sample detection, drug monitoring, environmental analysis, and food safety detection. The integration of novel technologies, such as nanozymes and smartphone-based detection, which enhance the capabilities of colorimetric MIP sensors, is also addressed. The sensors are particularly valuable due to their low cost, rapid response times, portability, and ease of use. Finally, the review outlines the future challenges for the development of MIP-based colorimetric sensors, focusing on overcoming existing limitations, improving sensor performance, and expanding their applications across various fields. Molecularly imprinted polymer ; Molecular imprinting ; Chemistry ; Chromatography ; Materials science ; Organic chemistry ; Selectivity Advanced Nanomaterials in Catalysis ; Analytical chemistry methods development ; Electrochemical sensors and biosensors
Authors: A. Madan | Adel Hussein | Syed Sohail Akhtar
Source: Corrosion Reviews (review, 2025-04-01)
Field: Materials Science — Materials Chemistry

A review on internal corrosion of pipelines in the oil and gas industry due to hydrogen sulfide and the role of coatings as a solution Abstract This review paper explores the ongoing challenge of internal corrosion in oil and gas pipelines, specifically focusing on the damage caused by hydrogen sulfide (H 2 S). It highlights the superior performance of coating technologies such as chemical resistance, long-term durability, and resistance to high temperatures, including epoxy and other nonmetallic coatings, which effectively protect pipelines against H 2 S-induced corrosion. The review covers the practical application of coating technologies to improve pipeline durability and operational efficiency, beginning with an examination of the corrosive impact of H 2 S on pipelines. It reviews existing mitigation strategies, highlighting their advantages and limitations, and then analyzes nonmetallic coatings as a promising solution to H 2 S-induced corrosion. The paper demonstrates the benefits of these advanced coatings. It concludes with a summary of key findings and provides industry recommendations for selecting and implementing effective coating technologies, alongside suggestions for future research in this field. Materials science ; Hydrogen sulfide ; Corrosion ; Pipeline transport ; Petroleum industry ; Metallurgy ; Hydrogen ; Fossil fuel ; Materials processing ; Sulfide ; Waste management ; Environmental science ; Sulfur ; Process engineering ; Environmental engineering ; Engineering ; Chemistry ; Organic chemistry Corrosion Behavior and Inhibition ; Gas Sensing Nanomaterials and Sensors ; Smart Materials for Construction
Authors: Jianyu Zhang | Zuping Xiong | Haoke Zhang | Ben Zhong Tang
Source: Nature Communications (review, 2025-04-25)
Field: Materials Science — Materials Chemistry

Emergent clusteroluminescence from nonemissive molecules Once considered the exclusive property of conjugated molecules, efficient and visible-light luminescence from non-conjugated and nonemissive molecules in the clustered state, known as clusteroluminescence (CL), has attracted much attention recently due to its special photophysical behaviors and behind electronic interactions. This perspective discusses the development of the CL phenomenon, followed by the typical photophysical features, examples, mechanisms, and potential applications of CL materials, to provide a comprehensive picture of this emerging field. Starting with organic clusters, inorganic, metallic, and hybrid clusters with CL properties are also introduced, and the perspective shift from covalent interactions at the molecular level to non-covalent interactions at the aggregate level is invoked. Conjugated system ; Covalent bond ; Molecule ; Luminescence ; Nanotechnology ; Perspective (graphical) ; Chemistry ; Chemical physics ; Materials science ; Combinatorial chemistry ; Computer science ; Polymer ; Organic chemistry ; Optoelectronics Luminescence and Fluorescent Materials ; Nanocluster Synthesis and Applications ; Organic Light-Emitting Diodes Research
Authors: Latifat Abdulsalam | Sadam Abubakar | Ikfa Permatasari | Abdulazeez T. Lawal | Shihab Uddin | Saleem Ullah | Irshad Ahmad
Source: Polymers (review, 2025-10-30)
Field: Materials Science — Biomaterials

Advanced Biocompatible and Biodegradable Polymers: A Review of Functionalization, Smart Systems, and Sustainable Applications The growing dependence on plastics is driving a sharp increase in environmental pollution, posing serious risks to human health. This issue necessitates immediate attention and proactive measures to mitigate its impact on both individuals and the broader ecosystem. From this viewpoint, biocompatible and biodegradable polymers, both synthetic and natural, have emerged as vital materials for applications in biomedicine, packaging, and environmental sustainability. The main advantages of biodegradable polymer materials lie in conserving fossil fuel resources, utilizing inedible biomass, and enabling environmentally friendly production processes. In this context, this review thoroughly discusses the categorization of biocompatible and biodegradable polymers into natural and synthetic types, detailing their structural characteristics, mechanisms of biodegradation, and compatibility matrices appropriate for biomedical, environmental, and industrial uses. It also addresses recent advancements in polymer synthesis technology, highlighting significant progress in polymer functionalization, responsiveness to stimuli, and environmentally friendly biobased synthesis methods. Additionally, it identifies challenges such as mechanical constraints, control over degradation, and expense, while also discussing future opportunities in the field of polymer science. Biocompatible material ; Environmentally friendly ; Natural polymers ; Compatibility (geochemistry) ; Biodegradable polymer ; Sustainability ; Fossil fuel ; Polylactic acid biodegradable polymer synthesis and properties ; Polymer Science and PVC ; Microplastics and Plastic Pollution
Authors: Weiwang Wang | Fan Jiaqi | Changshen Li | Yue Yu | Anding Wang | Shengtao Li | Jinjun Liu
Source: Energies (article, 2025-01-22)
Field: Materials Science — Electronic, Optical and Magnetic Materials

Low-Loss Soft Magnetic Materials and Their Application in Power Conversion: Progress and Perspective Amorphous and nanocrystalline alloys, as novel soft magnetic materials, can enable high efficiency in a wide range of power conversion techniques. Their wide application requires a thorough understanding of the fundamental material mechanisms, typical characteristics, device design, and applications. The first part of this review briefly overviews the development of amorphous and nanocrystalline alloys, including the structures of soft magnetic composites (SMCs), the key performance, and the underlying property-structure correction mechanisms. The second part discusses three kinds of high-power conversion applications of amorphous and nanocrystalline alloys, such as power electronics transformers (PETs), high-power inductors, and high-power electric motors. Further detailed analysis of these materials and applications are reviewed. Finally, some critical issues and future challenges for material tailoring, device design, and power conversion application are also highlighted. Perspective (graphical) ; Soft power ; Power loss ; Power (physics) ; Materials science ; Environmental science ; Engineering physics ; Engineering ; Computer science ; Physics ; Political science ; Thermodynamics Magnetic Properties and Applications ; Magnetic properties of thin films ; Metallic Glasses and Amorphous Alloys
Authors: Keshav Narayan Alagarsamy | Leena Regi Saleth | Kateryna Diedkova | Veronika Zahorodna | Oleksiy Gogotsi | Maksym Pogorielov | Sanjiv Dhingra
Source: Nanoscale (review, 2025-01-01)
Field: Materials Science — Materials Chemistry

MXenes in healthcare: transformative applications and challenges in medical diagnostics and therapeutics MXenes, a novel class of two-dimensional transition metal carbides, exhibit exceptional physicochemical properties that make them highly promising for biomedical applications. Their application has been explored in bioinstrumentation, tissue engineering, and infectious disease management. In bioinstrumentation, MXenes enhance the sensitivity and response time of wearable sensors, including piezoresistive, electrochemical, and electrophysiological sensors. They also function effectively as contrast agents in MRI and CT imaging for cancer diagnostics and therapy. In tissue engineering, MXenes contribute to both hard and soft tissue regeneration, playing a key role in neural, cardiac, skin and bone repair. Additionally, they offer innovative solutions in combating infectious and inflammatory diseases by facilitating antimicrobial surfaces and immune modulation. Despite their potential, several challenges hinder the clinical translation of MXene-based technologies. Issues related to synthesis, scalability, biocompatibility, and long-term safety must be addressed to ensure their practical implementation in medical applications. This review provides a comprehensive overview of MXenes in next-generation medical diagnostics, including the role they play in wearable sensors and imaging contrast agents. It further explores their applications in tissue engineering and infectious disease management, highlighting their antimicrobial and immunomodulatory properties. Finally, we discuss the key barriers to clinical translation and propose strategies for overcoming these limitations. This review aims to bridge current advancements with future opportunities for integration of MXenes in healthcare. MXenes ; Transformative learning ; Nanotechnology ; Healthcare system ; Carbide ; Patient care ; Health care ; Materials science ; Computer science ; Medicine ; Political science ; Psychology MXene and MAX Phase Materials ; Advanced Memory and Neural Computing ; Graphene and Nanomaterials Applications