Authors: M. Ibrahim | Dunia Alatoom | Tibor Furtenbacher | Attila G. Császár | S. N. Yurchenko | Ala’a Azzam | Jonathan Tennyson
Source: Journal of Computational Chemistry (article, 2024-01-08)
Field: Chemistry — Spectroscopy

MARVEL analysis of high‐resolution rovibrational spectra of 13C 16O 2 A set of empirical rovibrational energy levels, obtained through the MARVEL (measured active rotational-vibrational energy levels) procedure, is presented for the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mn>13</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> C <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mn>16</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> O <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msub><mml:mo> </mml:mo> <mml:mrow><mml:mn>2</mml:mn></mml:mrow> </mml:msub> </mml:mrow> </mml:math> isotopologue of carbon dioxide. This procedure begins with the collection and analysis of experimental rovibrational transitions from the literature, allowing for a comprehensive review of the literature on the high-resolution spectroscopy of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mn>13</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> C <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mn>16</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> O <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msub><mml:mo> </mml:mo> <mml:mrow><mml:mn>2</mml:mn></mml:mrow> </mml:msub> </mml:mrow> </mml:math> , which is also presented. A total of 60 sources out of more than 750 checked provided 14,101 uniquely measured and assigned rovibrational transitions in the wavenumber range of 579-13,735 cm <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mo>-</mml:mo> <mml:mn>1</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> . This is followed by a weighted least-squares refinement yielding the energy levels of the states involved in the measured transitions. Altogether 6318 empirical rovibrational energies have been determined for <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mn>13</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> C <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msup><mml:mo> </mml:mo> <mml:mrow><mml:mn>16</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:math> O <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow><mml:msub><mml:mo> </mml:mo> <mml:mrow><mml:mn>2</mml:mn></mml:mrow> </mml:msub> </mml:mrow> </mml:math> . Finally, estimates have been given for the uncertainties of the empirical energies, based on the experimental uncertainties of the transitions. The detailed analysis of the lines and the spectroscopic network built from them, as well as the uncertainty estimates, all serve to pinpoint possible errors in the experimental data, such as typos, misassignment of quantum numbers, and misidentifications. Errors found in the literature data were corrected before including them in the final MARVEL dataset and analysis. Rotational–vibrational spectroscopy ; Isotopologue ; Spectral line ; Quantum number ; Wavenumber ; Range (aeronautics) ; Resolution (logic) ; Spectroscopy ; Computational physics ; Physics ; Atomic physics ; Chemistry ; Computer science ; Optics ; Materials science ; Quantum mechanics Spectroscopy and Laser Applications ; Atmospheric Ozone and Climate ; Atmospheric and Environmental Gas Dynamics