Authors: Espen Doedens
Source: Chalmers Research (Chalmers University of Technology) (article, 2020-01-01)
Field: Materials Science — Materials Chemistry

Topographical Impact on Space Charge Injection, Accumulation and Breakdown in Polymeric HVDC Cable Interfaces Extruded HVDC cable systems feature a variety of interface types, for which physio-chemical properties will depend on the type of application. Such applications can be joints, terminations or the cable itself, all introducing different material combinations and manufacturing methods. To ensure beyond 40 years of faultless cable system operation, the interface’s design and quality control procedures are essential. Interfacial control requires detailed knowledge on how measurable physio-chemical properties of polymer surfaces relate to their electrical performance, through features such as localized electric field strength, space charge injection and breakdown strength. This work aims to expand such understanding by assessing polymer surfaces created with different, industrialized preparation methods, featuring different degrees of surface roughness. Surface preparation was carried out on real HVDC cable prototypes, from which cable peelings were extracted, ensuring replication of the material’s bulk and interfacial natures into the small-scale tests. Also, DC breakdown tests on medium voltage cables revealed strong impact of surface roughness, pinpointing the need for an accurate roughness evaluation. While chemical characterization assessed certain features brought about in the preparation, physical assessments such as optical profilometry quantified the surfaces’ topographies. It was found that, the topography, featuring micro and sub micrometer geometrical variation, could be readily adopted in a mesoscopic modelling approach. Thereby, the geometric impact on local quantities of field strength, charge density and injection current density was estimated. Also, a set of roughness enhanced charge injection equations were derived for charge injection types such as Schottky, Fowler-Nordheim and hopping injection mechanisms. Such equations, featuring surface specific field (β) parameters, were employed in a one-dimensional bipolar charge transport model. Through careful model calibration against the results of space charge measurements, the parameters for roughness enhanced charge injection, together with parameters for charge transport, trapping, detrapping and recombination, were estimated. This calibration verified roughness enhanced injection and generated a description of the density of states in the material’s bulk. Furthermore, DC breakdown tests performed on the cable peelings for establishing the relationship between surface roughness and breakdown strength. An adopted multi-scale simulation approach, based on the calibrated parameter set, estimated local field strength, charge density and other quantities in the surface domain. Conclusively, surface topography causes a local redistribution of the electric field, in turn locally increasing charge injection due to its strong field dependency at the rough asperities. Ultimately, coinciding high field strength and high charge density, at repeated positions along the surface, yields a lower breakdown strength. Such knowledge allows for tailoring the methodologies of surface preparation and quality control in HVDC cable systems, and other HV apparatuses. Control over mesoscopic surface effects will allow engineers to design ever more advanced and long-lasting HV components, meeting humanity’s renewable energy transmission needs for decades to come. Space charge ; Surface roughness ; Materials science ; Surface finish ; Breakdown voltage ; Voltage ; Mechanical engineering ; Electric field ; Composite material ; Electrical engineering ; Engineering ; Physics High voltage insulation and dielectric phenomena ; Thermal Analysis in Power Transmission ; Power Transformer Diagnostics and Insulation