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Rio Grande, sebatang sungai Amerika Utara

Rio Grande Do Sul, sebuah negeri Brazil

Río Bec, tapak arkeologi Mayan

Río Bravo, Suchitepéquez, sebuah bandar dalam Guatemala

Río Bravo, Tamaulipas, sebuah bandaraya Mexico

Rio Creek, Wisconsin, an unincorporated community in Kewaunee County, USA

Rio, Florida, sebuah bandar kecil dalam Martin County, USA

Rio, Illinois, sebuah kampung Knox County, USA

Rio, West Virginia, sebuah kampung di Hampshire County, USA

Rio, Wisconsin, sebuah kampung di Columbia County, USA

Rio, Greece, a community in suburban Patras, Greece

Rio, sebuah tempat di Deerpark, New York, USA

Rio Grande Valley sebuah tempat di Texas selatan

Rio do Sul, sebuah bandar dalam negeri Santa Catarina, Brazil

Tina Yuzuki (lahir 1986), juga dikenali sebagai Rio, Japanese AV idol

Rio Dewanto (lahir 1987), seorang pelakon lelaki Indonesia

Rio Ferdinand (lahir 1978), seorang pemain bola sepak Inggeris

Rio Mavuba (lahir 1984), seorang pemain bola sepak Perancis

Rio Reiser (1950-1996), penyanyi Jerman

Rostam Afendi bin Abdul Rashid (lahir 1975), seorang kartunis Malaysia

Alphonse Rio (1873-1949), a French politician and minister in the French Third Republic

Michel Rio (b. in 1945), a French writer and novelist.

Patrice Rio (b. in 1948), a former French footballer

Rio (album), sebuah album 1982 oleh kumpuolan new wave/rock group Duran Duran

"Rio" (lagu), the title song from the above Duran Duran album

Rio (Lee Ritenour album), a 1979 jazz album by Lee Ritenour

R.I.O., a German dance music act

Los del Rio, the Spanish music duo that gained international fame for their 1995 song "Macarena"

Rock in Rio, an series of music festivals held in Brazil and Portugal

Rock in Rio (album), a 2001 live album recorded in Brazil by the rock group Iron Maiden

Rush in Rio, a 2003 live album by the rock group Rush

RIO, for Rock in Opposition, a musical movement in the 1970s

"Rio", a song by Michael Nesmith which appears on his 1977 album From a Radio Engine to the Photon Wing

Rio (Aterciopelados album), 2008 album by the band Aterciopelados