hotchpotch/wikipedia-multilingual-ir-related-lead-pairs huggingface dataset:
Intervalence charge transfer
In chemistry, intervalence charge transfer, often abbreviated IVCT or even IT, is a type of charge-transfer band that is associated with mixed valence compounds.  It is most common for systems with two metal sites differing only in oxidation state. Quite often such electron transfer reverses the oxidation states of the sites. The term is frequently extended to the case of metal-to-metal charge transfer between non-equivalent metal centres. The transition  produces a characteristically intense absorption in the electromagnetic spectrum.  The band is usually found in the visible or near infrared region of the spectrum and is broad.

The process can be described as follows:

LnM+-bridge-M'Ln  + hν  →   LnM-bridge-M'+Ln

Mixed-valence complex
Mixed valence complexes contain an element which is present in more than one oxidation state.  Well-known mixed valence compounds include the Creutz–Taube complex, Prussian blue, and molybdenum blue.  Many solids are mixed-valency including indium chalcogenides.
Baruch Ivcher
Baruch Ivcher (Hebrew: ברוך איבצ'ר) is an Israeli-born billionaire business tycoon who lives in Peru. Ivcher was a majority shareholder of the Peruvian television station Frecuencia Latina.  President Alberto Fujimori ordered Ivcher stripped of his Peruvian citizenship when the station's investigative program Contrapunto exposed government corruption.

Latina Televisión
Latina Televisión (also known as Latina TV or simply Latina, and previously known as Frecuencia Latina Televisión or Frecuencia Latina) is a Peruvian free-to-air television channel that has been broadcasting since 1983.

It is the third private channel to start broadcasting. In 2005, it was the fourth most-watched channel according to CPI, and in 2008, it reached the third position according to Kantar Ibope Media. Its broadcast headquarters are located on Av. San Felipe in the Jesús María District of Lima. The channel is owned by Grupo Enfoca.
Lucy Rose
Lucy Rose Parton (born 20 June 1989), professionally known as Lucy Rose, is an English singer-songwriter. She signed with Columbia Records to release her debut studio album, Like I Used To (2012), which was met with critical praise and entered the UK Albums Chart, along with each of her subsequent releases. Her fifth and latest studio album, This Ain't The Way You Go Out, was released in April 2024. She founded her own record label, Real Kind Records, an imprint of Communion Music in January 2020.

Like I Used To (album)
Like I Used To is the debut studio album by English singer-songwriter Lucy Rose. It was released on 24 September 2012 by Columbia Records. It reached number 13 in the UK Albums Chart in its first week of release.
Queenstown Ice Arena
The Queenstown Ice Arena is an ice sports and public skate centre, opened originally in 1966 as an outdoor ice rink it was later rebuilt as an indoor arena in 1996 and is located at Queenstown Gardens, next to the town of Queenstown, Otago, New Zealand. It is the current home venue of the Skycity Stampede in the New Zealand Ice Hockey League (NZIHL) and Wakatipu Wild in the New Zealand Women's Ice Hockey League (NZWIHL). Queenstown Ice Arena is the only ice rink in Queenstown and is one of only two in Otago, along with Dunedin Ice Stadium.

Wakatipu Wild
The Wakatipu Wild is a New Zealand amateur ice hockey team from Queenstown, Otago, New Zealand. Founded in 2020, the Wild are a member of the New Zealand Women's Ice Hockey League (NZWIHL). The Wild are based at Queenstown Ice Arena, located at Queenstown Gardens. Wakatipu are one time NZWIHL champions and premiers.
Justin Meyer
Justin Meyer (born Raymond Meyer, 11 November 1938 – 6 August 2002) was an American vintner, enologist, and member of the Christian Brothers. He was the founder along with Raymond Twomey Duncan of Silver Oak Cellars in 1972, a successful winery based in the Napa Valley and Alexander Valley. Today Duncan's sons David Duncan and Tim Duncan run Silver Oak Cellars, as well as Twomey Cellars, established in 1999. Meyer sold his share of the company to Duncan in 2001. One of California's top wine experts, he was president of the American Vineyard Foundation in the 1990s and also held numerous other positions in the wine industry. The San Francisco Chronicle cites Meyer as "one of the legends of the Napa Valley".

David Duncan (vintner)
David Duncan (born 1965) is an American vintner and entrepreneur. The President and Chief Executive Officer of Duncan Oil, he is also the President and Chief Executive Officer of Silver Oak Cellars and Managing Partner of Twomey Cellars, successful wineries in northern California, operating in the Napa, Alexander and Russian River Valleys. He is the son of late Raymond Twomey Duncan, an oil and wine entrepreneur who co-founded Silver Oak in 1972 with Justin Meyer. Silver Oak is a family-run and owned business, and his brother Tim Duncan is Executive Vice President of the company. ColoradoBiz says that David Duncan is "as much a hands-on winery president as he can be", as president of a winery that has "reached cult status" for its Cabernet Sauvignon production.
National Route 243 (Costa Rica)
National Secondary Route 243, or just Route 243 (Spanish: Ruta Nacional Secundaria 243, or Ruta 243) is a National Road Route of Costa Rica, located in the San José, Puntarenas provinces. It connects Route 2 and Route 34.

San Isidro de El General
San Isidro de El General (Spanish pronunciation: [san iˈsiðɾo ðe el xeneˈɾal]) is the first district of the canton of Pérez Zeledón, in the southern part of the province of San José in Costa Rica, as well as the name of said district's main city.

San Isidro de El General is the most populous city in the Brunca region. It is located at 130 km from San José and 212 km from Paso Canoas, a border town with Panama.
91st Grey Cup
The 91st Grey Cup was the 2003 Canadian Football League championship game played between the Edmonton Eskimos and the Montreal Alouettes on November 16 at Taylor Field, in Regina, Saskatchewan before 50,909 fans. The two teams had played during the previous year with Montreal winning, but this time the Eskimos won the game by a score of 34–22.

Mike Pringle (gridiron football)
Michael A. Pringle (born October 1, 1967) is an American former professional football player who was a running back in the Canadian Football League (CFL). He set or tied almost every significant league record for the position. He played college football for the Cal State Fullerton Titans, earning third-team All-American honors. He was twice signed by National Football League (NFL) teams, though he saw very limited playing time.

Along with George Reed and Johnny Bright, Pringle is one of the players most often mentioned as being the greatest running back in CFL history. In November 2006, Pringle was voted one of the CFL's Top 50 players (#4) of the league's modern era by Canadian sports network TSN. In April 2008, Pringle was inducted into the Canadian Football Hall of Fame in his first year of eligibility.
Eyes on This
Eyes on This is the second studio album by American hip hop recording artist MC Lyte. It was released on October 3, 1989, via First Priority and Atlantic Records, and was produced by Audio Two, Grand Puba, the King of Chill, Marley Marl, and PMD.

The album became the first by a female solo rapper to appear on the Billboard 200 (then called Billboard Top Pop Albums), on which it remained for 20 weeks, peaking No. 86 in November 1989. It also peaking No. 6 on the Billboard Top Black Albums, being the first female solo rapper to break into the top 10 of that chart, as well as the highest position reached by Lyte.

The lead single Cha Cha Cha reached No. 35 on the Billboard Hot Black Singles and spent 19 weeks on the Billboard Hot Rap Singles, peaking at No. 1. Later, Stop, Look, Listen and Cappucino would become top 10 in the Hot Rap Singles (in No. 9 and No. 8, respectively).

Cha Cha Cha (MC Lyte song)
Cha Cha Cha is the lead single from MC Lyte's second album Eyes on This. Produced by King Of Chill, who also has songwriting credits, it was released on September 8, 1989.

The song stayed 18 weeks on the recently created Billboard Hot Rap Singles and became one of the first songs to peak at No. 1 on that chart, staying there for two weeks in December 1989. Although MC Lyte had already reached #1 on Rap chart a few months earlier with the collaborative single "Self Destruction", this was the first time that a woman had achieved it as the lead artist. In turn, it would also become Lyte's first appearance on the Billboard Hot R&B/Hip-Hop (then called "Billboard Hot Black Singles"), peaking No. 35.

In 2008 "Cha Cha Cha" was No. 54 on VH1's 100 Greatest Songs of Hip Hop list and Lil' Kim performed a rewritten version on her mixtape, Ms. G.O.A.T.
Metz-Tessy
Metz-Tessy (French pronunciation: [mɛtɛsi]; Arpitan: Mèznyi) is a former commune in the Haute-Savoie department in the Auvergne-Rhône-Alpes region in south-eastern France. On 1 January 2016, it was merged into the new commune of Épagny Metz-Tessy.

Épagny Metz-Tessy
Épagny Metz-Tessy (French pronunciation: [epaɲi mɛtɛsi]) is a commune in the Haute-Savoie department of southeastern France. The municipality was established on 1 January 2016 and consists of the former communes of Épagny and Metz-Tessy. It is part of the urban area of Annecy.
When Love Finds You
When Love Finds You is the sixth studio album from American country music artist Vince Gill. It was released in 1994 on MCA Nashville. It features the singles "Whenever You Come Around," "What the Cowgirls Do," "When Love Finds You," "Which Bridge to Cross (Which Bridge to Burn)," "You Better Think Twice" and "Go Rest High on That Mountain."

What the Cowgirls Do
"What the Cowgirls Do" is a song co-written and recorded by American country music artist Vince Gill.  It was released in July 1994 as the second single from the album When Love Finds You.  The song reached number 2 on the Billboard Hot Country Singles & Tracks chart.  It was written by Gill and Reed Nielsen and features lead guitar from Gill and session guitarist Steuart Smith.
Circles (film)
Circles (Serbian: Кругови/Krugovi) is a 2013 Serbian drama film directed by Srdan Golubović. The film was selected as the Serbian entry for the Best Foreign Language Film at the 86th Academy Awards, but it was not nominated. The film won the Prize of the Ecumenical Jury at the 63rd Berlin International Film Festival and the Grand Prix, Golden Apricot at the 2013 Yerevan International Film Festival, Armenia, for Best Feature Film as well as the Grand Prix at 2013 CinEast Festival.

63rd Berlin International Film Festival
The 63rd annual Berlin International Film Festival took place in Berlin, Germany, between 7 and 17 February 2013. Chinese film director Wong Kar-wai was announced as the president of the jury and his film The Grandmaster was the opening film of the festival.

The Golden Bear was awarded to Child's Pose directed by Călin Peter Netzer, which also served as the closing film.

The French documentary filmmaker Claude Lanzmann was awarded with the Honorary Golden Bear. Italian actress Isabella Rossellini and German film director Rosa von Praunheim were awarded with the Berlinale Camera.
2015–16 Old Dominion Monarchs men's basketball team
The 2015–16 Old Dominion Monarchs men’s basketball team represented Old Dominion University during the 2015–16 NCAA Division I men's basketball season. The Monarchs, led by third year head coach Jeff Jones, played their home games at the Ted Constant Convocation Center as members of Conference USA. They finished the season 25–13, 12–6 in C-USA play to finish in a three way tie for third place. They defeated Florida Atlantic, Louisiana Tech, and WKU to advance to the championship game of the C-USA tournament where they lost to Middle Tennessee. The received an invitation to the inaugural Vegas 16, which only had eight teams, where they defeated Tennessee Tech, UC Santa Barbara, and Oakland to become Vegas 16 champions.

2015–16 Tennessee Tech Golden Eagles men's basketball team
The 2015–16 Tennessee Tech Golden Eagles men's basketball team represented Tennessee Technological University during the 2015–16 NCAA Division I men's basketball season. The Golden Eagles, led by fifth year head coach Steve Payne, played their home games at the Eblen Center and were members of the East Division of the Ohio Valley Conference. They finished the season 19–12, 11–5 in OVC play to finish in a three way tie for second place in the East Division. They lost in the first round of the OVC tournament to Austin Peay. They were invited to the inaugural Vegas 16, which only had 8 teams, where they lost in the quarterfinals to Old Dominion.
Diomeneia
In Greek mythology, Diomeneia (Ancient Greek: Διομένειαν) was an Arcadian princess as the daughter of King Arcas.According to Pausanias bronze portrait-statue of a woman said to be Diomeneia existed in a Mantineian market place.

Arcas
In Greek mythology, Arcas (/ˈɑːrkəs/; Ancient Greek: Ἀρκάς) was a hunter who became king of Arcadia. He was remembered for having taught people the arts of weaving and baking bread and for spreading agriculture to Arcadia.
Battle of Alcolea Bridge
The Battle of Alcolea Bridge was a minor battle that took place on 7 June 1808, during the Peninsular War, at Alcolea, a small village 10 km from Córdoba, the city that would be invaded by French troops later that same afternoon.

Sailors of the Imperial Guard
The Sailors of the Imperial Guard (French: Marins de la Garde Impériale) were a naval unit within Napoleon's Imperial Guard. The unit's soldiers not only operated as naval infantry but as gunners (after the training they had received in naval gunnery), sailors and engineers. Napoleon himself stated, "They were good sailors, then they were the best soldiers. And they did everything - they were soldiers, gunners, sappers, everything!".
Patch Adams (film)
Patch Adams is a 1998 American comedy-drama film directed by Tom Shadyac, written by Steve Oedekerk, and starring Robin Williams in the title role, Monica Potter, Philip Seymour Hoffman, Bob Gunton, Daniel London and Peter Coyote. Set in the late 1960s and early 1970s, it is loosely based on the life story of medical doctor Hunter "Patch" Adams and the book Gesundheit: Good Health Is a Laughing Matter by Adams and Maureen Mylander.

Patch Adams was released by Universal Pictures on December 25, 1998. The film received generally negative reviews from critics, with criticism for the sentimentality and direction. However, it was a box-office success, grossing $202.3 million against a $50–90 million budget.

Bob Gunton
Robert Patrick Gunton Jr. (born November 15, 1945) is an American character actor of stage and screen. He is known for playing strict authoritarian characters, including Warden Samuel Norton in the 1994 prison drama The Shawshank Redemption, Chief George Earle in 1993's Demolition Man, Dr. Walcott, the domineering dean of Virginia Medical School in Patch Adams, and Secretary of State Cyrus Vance in Argo. He also played Leland Owlsley in the Daredevil television series, Secretary of Defense Ethan Kanin in 24, and Noah Taylor in Desperate Housewives.

In addition to his film and television careers, Gunton is a prolific theatre actor. He originated the role of Juan Perón in the Broadway premiere of Evita and the titular character in the 1989 revival of Sweeney Todd: The Demon Barber of Fleet Street, roles for which he received Tony Award nominations. He has received a Drama Desk Award, an Obie Award, and a Clarence Derwent Award.
Abby Martin
Abby Martin is an American journalist, television presenter, and activist. She helped found the citizen journalism website Media Roots and serves on the board of directors for the Media Freedom Foundation which manages Project Censored. Martin appeared in the documentary film Project Censored The Movie: Ending the Reign of Junk Food News (2013), and co-directed 99%: The Occupy Wall Street Collaborative Film (2013).

She hosted Breaking the Set on the Russian state-funded network RT America from 2012 to 2015 and gained attention for condemning the Russian annexation of Crimea on-air, and then launched The Empire Files in that same year as an investigative documentary and interview series on Telesur, later released as a web series. In 2019, she released the film documentary The Empire Files: Gaza Fights for Freedom.

Project Censored
Project Censored is a nonprofit media watchdog organization in the United States. The group's stated mission is to "educate students and the public about the importance of a truly free press for democratic self-government."

Project Censored produces an annual book and a weekly radio program. Both the annual books and the weekly radio programs, as well as public events sponsored by the Project, focus on issues of news censorship, propaganda, free speech, and media literacy. Past editions of the yearbook were published by Seven Stories Press.

Project Censored was founded at Sonoma State University in 1976 by Carl Jensen (1929-2015). Since 2010, Mickey Huff has been the group's director. It is sponsored by the Media Freedom Foundation, a 501(c)(3) non-profit organization, established in 2000. The organization is based in Ithaca, New York.
A Message to You Rudy
"A Message to You Rudy" is a 1967 rocksteady song by Dandy Livingstone. Originally titled "Rudy a Message to You", the song later achieved broader success when, in 1979, a cover version by the Specials reached number 10 on the UK Singles Chart.

Rico Rodriguez (musician)
Emmanuel "Rico" Rodriguez MBE (17 October 1934 – 4 September 2015), also known as Rico, Reco or El Reco, was a Cuban-born Jamaican ska and reggae trombonist. He recorded with producers such as Karl Pitterson, Prince Buster, and Lloyd Daley. He was known as one of the first ska musicians. Beginning in the 1960s, he worked with the Members, the Specials, Jools Holland, and Paul Young.
Lars Bom
Lars Bom (Olesen) (born 8 April 1961) is a Danish actor, educated at The Danish National School of Theatre in 1985. Lars Bom has worked in various roles in Theatre, Film and Television, and won the Best Actor award at the Italian Fantafestival in 1999, for his starring role in the cyberpunk-thriller Skyggen (1998). However, he is best known for his roles in Strisser på Samsø and Rejseholdet.

Besides acting, Lars Bom is also passionate about running and has released a DVD/book about it in 2007.

Strisser på Samsø
Strisser på Samsø (A Cop on Samsø) is a Danish television series consisting of 12 episodes, written and directed by Eddie Thomas Petersen. Produced by Per Holst Filmproduktion, it was first broadcast on TV2 in 1997-1998.

The story tells how Christian Torp, a police officer who has lost his wife in an unsuccessful robbery, brings his daughter Sille to the Danish island of Samsø looking for peace and quiet. They have difficulty in integrating into a society full of problems where everyone knows everything about everybody, but they find a friend in Ulla, a secretary. Among others, it stars Lars Bom, Andrea Vagn Jensen, Trine Pallesen, Amalie Dollerup, Jesper Milsted and Sidse Babett Knudsen. The series was entitled "Island Cop" when broadcast in subtitled form on Ireland's TG4 channel.
Healthcare in Lancashire
Healthcare in Lancashire in 2015 was the responsibility of seven clinical commissioning groups covering Blackpool, Chorley and South Ribble, East Lancashire, Fylde and Wyre, Greater Preston, Lancaster North and West Lancashire. In 1 April 2017 32 GP practices from Cumbria Clinical Commissioning Group merged with Lancashire North CCG to form Morecambe Bay CCG which was abolished in July 2022 when integrated care systems were introduced.

Integrated care system
In England, an integrated care system (ICS) is a statutory partnership of organisations who plan, buy, and provide health and care services in their geographical area.

The organisations involved include the NHS, local authorities, voluntary and charity groups, and independent care providers. The NHS Long Term Plan of January 2019 called for the whole of England to be covered by ICSs by April 2021. On 1 July 2022, ICSs – by then 42 in number – replaced clinical commissioning groups in England.
1994 Sun Belt Conference men's basketball tournament
The 1994 Sun Belt Conference men's basketball tournament was held March 4–7 at the E. A. Diddle Arena at Western Kentucky University in Bowling Green, Kentucky.

Southwestern Louisiana defeated top-seeded hosts Western Kentucky in the championship game, 78–72, to win their second Sun Belt men's basketball tournament. It was USL's second Sun Belt title in three years.

The Ragin' Cajuns, in turn, received an automatic bid to the 1994 NCAA tournament. Fellow Sun Belt member Western Kentucky joined them in the tournament, earning an at-large bid.

1993–94 Southwestern Louisiana Ragin' Cajuns men's basketball team
The 1993–94 Southwestern Louisiana Ragin' Cajuns men's basketball team represented the University of Southwestern Louisiana as a member of the Sun Belt Conference during the 1993–94 NCAA Division I men's basketball season. The Ragin' Cajuns, led by 8th-year head coach Marty Fletcher, played their home games at Cajundome in Lafayette, Louisiana. The team finished second in the conference regular season standings, and won the Sun Belt tournament to earn an automatic bid to the NCAA tournament. As the No. 11 seed in the Southeast region, SW Louisiana lost to No. 6 seed Marquette in the opening round, 81–59.
2016 in Rizin Fighting Federation
The year 2016 was the second year in the history of the Rizin Fighting Federation, a mixed martial arts promotion based in Japan. The first event of the year was Rizin 1 on April 17, 2016, in Nagoya.

Rizin events are broadcast through a television agreement with Fuji Television.

Heath Herring
Heath Herring (born March 2, 1978) is an American former professional mixed martial artist who competed in the Heavyweight division. While perhaps best known for competing in PRIDE, he also competed for the UFC, K-1 and Rizin.
Kill Devil Hills (album)
DJ Muggs vs. Ill Bill: Kill Devil Hills is a collaborative studio album by American Los Angeles-based record producer DJ Muggs and New York-based rapper Ill Bill. It was released on August 31, 2010, via Fat Beats, serving as Muggs' third album in his "DJ Muggs vs." series. Production was handled by DJ Muggs, except for two track produced by G. Rocka and DJ Khalil. It features guest appearances from B-Real, Sick Jacken, Chace Infinite, Everlast, O.C., Q-Unique, Raekwon, Slaine, Sean Price, Vinnie Paz and Uncle Howie. The album is dedicated to Ill Bill's uncle, Howard Tenebaum, who died five months before the record release. Kill Devil Hills peaked at number 86 on the Top R&B/Hip-Hop Albums, number 21 on the Top Rap Albums and number 17 on Heatseekers Albums charts in the United States, and also named one of 'Top 25 Albums of 2010' by HipHopDX.

Psycho Realm
The Psycho Realm is a Mexican-American hip hop group started in 1989 by the brothers Sick Jacken and Big Duke both born in Mazatlán, Sinaloa, Mexico raised in the Downtown neighborhood of Pico-Union area of Los Angeles.