hotchpotch/wikipedia-multilingual-ir-related-lead-pairs huggingface dataset:
Frustrated Lewis pair
A frustrated Lewis pair (FLP)  is a compound or mixture containing a Lewis acid and a Lewis base that, because of steric hindrance, cannot combine to form a classical adduct. Many kinds of FLPs have been devised, and many simple substrates exhibit activation.

The discovery that some FLPs split H2 triggered a rapid growth of research into FLPs. Because of their "unquenched" reactivity, such systems are reactive toward substrates that can undergo heterolysis.  For example, many FLPs split hydrogen molecules.  
Thus, a mixture of tricyclohexylphosphine (PCy3) and tris(pentafluorophenyl)borane reacts with hydrogen to give the respective phosphonium and borate ions:

PCy3 + B(C6F5)3 + H2  →  [HPCy3]+ [HB(C6F5)3]−

This reactivity has been exploited to produce FLPs which catalyse hydrogenation reactions.

Hydrogenation
Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate organic compounds. Hydrogenation typically constitutes the addition of pairs of hydrogen atoms to a molecule, often an alkene. Catalysts are required for the reaction to be usable; non-catalytic hydrogenation takes place only at very high temperatures. Hydrogenation reduces double and triple bonds in hydrocarbons.
Juan-Carlos Planas
Juan-Carlos "J.C." Planas (born July 17, 1970 in Miami, Florida) is an American politician.

He received his bachelor's degree from the Florida State University in 1993. A former prosecutor, he received his Juris Doctor from St. Thomas University School of Law in 1998. He lives in the community of Westchester in Miami-Dade County, Florida. He is married to Viviana.

Originally a Republican and former member of Florida House of Representatives, Juan-Carlos switched his party registration to unaffiliated in 2019, and subsequently to Democratic in 2020. This was in part due to Planas' opposition to Donald Trump, the Republican president at the time.

In July 2023, Planas returned to politics and announced his candidacy for the Miami-Dade County Supervisor of Elections in 2024. His opponent was Republican State Representative Alina Garcia., who ultimately defeated him. Planas won 44.16% of the vote, amounting to 458,770 votes.

Alina Garcia
Alina Garcia is a Cuban American businesswoman, civil servant, and politician serving as the first supervisor of elections of Miami-Dade County since 2025. A member of the Republican Party, she previously served as a member of the Florida House of Representatives from 2022 to 2024.
Bad Sisters
Bad Sisters is an Irish black comedy television series developed by Sharon Horgan, Dave Finkel, and Brett Baer. Set in Dublin and filmed on location in Ireland, it is based on the Belgian series Clan, which was created by Malin-Sarah Gozin. The first two episodes aired on Apple TV+ on 19 August 2022.  The second series premiered on 13 November 2024.

The first season received a positive reception from critics and won a 2022 Peabody Award. It received a leading twelve nominations at the 19th Irish Film & Television Awards, winning four including Best Drama, and received the British Academy Television Award for Best Drama Series at the 2023 BAFTA Awards alongside two additional wins. Season 1 received four nominations at the 75th Primetime Emmy Awards, including Outstanding Lead Actress in a Drama Series for Horgan.

Brett Baer
Brett Baer is an American television producer and screenwriter who has worked on many successful television shows. Baer often works with his screenwriting partner Dave Finkel. Brett grew up in Deerfield, Illinois, and attended the USC School of Cinematic Arts.
Lalla Malika Issoufou
Lalla Malika Issoufou (born 14 February 1975) is a Nigerien medical doctor and patron of many charities. She served as First Lady of Niger, alongside Aïssata Issoufou Mahamadou, from 7 April 2011 to 2 April 2021 as the second wife of President Mahamadou Issoufou.

Mahamadou Issoufou
Mahamadou Issoufou (born 1 January 1952) is a Nigerien politician who served as the president of Niger from 7 April 2011 to 2 April 2021. Issoufou was the prime minister of Niger from 1993 to 1994, president of the National Assembly from 1995 to 1996, and a candidate in each presidential election from 1993 to 2016. He led the Nigerien Party for Democracy and Socialism (PNDS-Tarayya), a social democratic party, from its foundation in 1990 until his election as president in 2011. During the presidency of Mamadou Tandja (1999–2010), Issoufou was the main opposition leader.

Having left power by respecting the constitution that limited him to two presidential terms, thus leading to the first ever democratic transition of power in the country, in March 2021 he received the Ibrahim Prize for good governance, democratic election and respect of term limits.
Civic Passion
Civic Passion was a radical, populist, localist, and nativist political party in Hong Kong. Founded by Wong Yeung-tat as an activist group in 2012, it held strong localist views and opposed the involvement of the Chinese government in the governance of Hong Kong. In the 2016 Legislative Council election, the Civic Passion formed an electoral alliance with Wong Yuk-man's Proletariat Political Institute and Chin Wan's Hong Kong Resurgence Order. Cheng Chung-tai became the only candidate of the alliance elected to the legislature and subsequently took over as the leader of the Civic Passion. After the election, Cheng reorganised the group into a political party and pulled out from the social activism. From December 2020 to August 2021, it was the only opposition party in the Legislative Council of Hong Kong.

Cheng Chung-tai
Cheng Chung-tai (Chinese: 鄭松泰; born 5 November 1983) is a Hong Kong academic, social activist, and politician. After winning a seat in the New Territories West constituency in the 2016 legislative election, he took over from Wong Yeung-tat as chairman of Civic Passion until the dissolution in 2021.

Before his disqualification in August 2021, he was the sole remaining opposition member in the Legislative Council after the mass resignation of pro-democracy legislators.
Tyler Cuma
Tyler Cuma (born January 19, 1990) is an Austrian-Canadian professional ice hockey defenceman currently playing for HC TWK Innsbruck of the ICE Hockey League (ICEHL). He was drafted by the Minnesota Wild in the first round, 23rd overall, in the 2008 NHL Entry Draft when he was playing for the Ottawa 67's.

Ottawa 67's
The Ottawa 67's are a major junior ice hockey team based in Ottawa, Ontario, Canada, that plays in the Ontario Hockey League (OHL). Established during Canada's centennial year of 1967 and named in honour of this, the 67's currently play their home games at TD Place Arena. The 67's are three-time OHL champions, and have played in the Memorial Cup five times, winning in 1984 and as host team in 1999.
Doctor Who at the BBC Radiophonic Workshop Volume 3: The Leisure Hive
Doctor Who at the BBC Radiophonic Workshop Volume 3: The Leisure Hive is the third in a series of compilations showcasing the BBC Radiophonic Workshop's work on the science-fiction programme Doctor Who. The album focused mainly on the Peter Howell synthesiser score for the 1980 serial The Leisure Hive, which received its first full release here. The compilation also collected some Dick Mills sound effects from the story as well as some effects from other 1980 serials Meglos and Full Circle, whose music would be the subject of the fourth volume in the series. The final track was a new remix of the original Delia Derbyshire version of the show's theme tune by series compiler Mark Ayres.

Doctor Who at the BBC Radiophonic Workshop Volume 4: Meglos & Full Circle
Doctor Who at the BBC Radiophonic Workshop Volume 4: Meglos & Full Circle is the final installment in the Mark Ayres compiled series of releases of BBC Radiophonic Workshop music. It featured music, by Peter Howell and Paddy Kingsland, for the 1980 Doctor Who serials Meglos and Full Circle. It was the first full releases of both scores, although some sound effects from the serials appeared on the previous volume.
Heidi Zuckerman
Heidi Zuckerman (born 1967 or 1968) is an American museum director and curator who is CEO and director of the Orange County Museum of Art in Costa Mesa, California.

Zuckerman was previously a curator for the Jewish Museum in New York and the Berkeley Art Museum and Pacific Film Archive in California. From 2005 to 2019, she was director and chief curator of Aspen Art Museum in Colorado, during which the museum opened a new building designed by Shigeru Ban and shifted from exhibiting mainly local artists to international contemporary artists. She assumed her current position at the Orange County Museum of Art in 2021, managing the construction of its new building.

Orange County Museum of Art
The UC Irvine Langson Orange County Museum of Art is a modern and contemporary art museum located on the campus of the Segerstrom Center for the Arts in Costa Mesa, California. The museum's collection comprises more than 4,500 objects, with a concentration on the art of California and the Pacific Rim from the early 20th century to present. Exhibits include traditional paintings, sculptures, and photography, as well as new media in the form of video, digital, and installation art.
(385185) 1993 RO
(385185) 1993 RO is a plutino. It was the first plutino discovered after Pluto itself, with 1993 RP and (15788) 1993 SB a day and two days later, respectively. The discovery was made in 1993 at the Mauna Kea Observatory with a 2.2-meter telescope. Very little is known about 1993 RO. The diameter estimate of ~90 km is based on the assumed albedo of 0.09.

Other Kuiper belt objects discovered in 1993 include (15788) 1993 SB, (15789) 1993 SC, and (181708) 1993 FW.

(15789) 1993 SC
(15789) 1993 SC is a trans-Neptunian object of the plutino class. The discovery was made in 1993 at the La Palma Observatory with the Isaac Newton Telescope. The object measures approximately 328 km in diameter. It was the second plutino to receive an MPC number.

Other Kuiper belt objects discovered in 1993 include: (15788) 1993 SB, (181708) 1993 FW, (385185) 1993 RO and 1993 RP.
Thorismund
Thorismund (also Thorismod or Thorismud, as manuscripts of the chief source confusingly attest) (c. 420–453), became king of the Visigoths after his father Theodoric I was killed in the Battle of the Catalaunian Plains (also called Battle of Châlons) in 451 CE. He was murdered in 453 and was succeeded by his brother Theodoric II.

Theodoric I
Theodoric I (Gothic: Þiudarīks; Latin: Theodericus; c. 390 or 393 – 20 or 24 June 451) was the king of the Visigoths from 418 to 451. Theodoric is famous for his part in stopping Attila the Hun at the Battle of the Catalaunian Plains in 451, where he was killed.
The Jester Race
The Jester Race is the second studio album by Swedish melodic death metal band In Flames, released in February 1996. It is the first album to feature Anders Fridén as the band's vocalist, Björn Gelotte as the drummer, and Jester Head as the band's mascot.

Björn Gelotte
Björn Gelotte (born 27 August 1975) is a Swedish guitarist and songwriter, best known as the lead guitarist for melodic death metal band In Flames. He originally joined the band as the drummer in 1995, and continued in this position during The Jester Race (1996) and Whoracle (1997). He switched to his current position on guitar after Niclas Engelin left the band and has played solely guitars since Colony (1999), sharing lead/rhythm guitar duties with former In Flames guitarist Jesper Strömblad.

In March 2004, Gelotte and Strömblad were both ranked No. 70 out of 100 Greatest Heavy Metal Guitarists of all time by Guitar World.
McDonnell CF-101 Voodoo
The McDonnell CF-101 Voodoo was an all-weather interceptor aircraft operated by the Royal Canadian Air Force and the Canadian Forces between 1961 and 1984. They were manufactured by the McDonnell Aircraft Corporation of St. Louis, Missouri for the United States Air Force (as F-101s), and later sold to Canada. CF-101s replaced the obsolete Avro CF-100 Canuck in the RCAF's all-weather fighter squadrons. The Voodoo's primary armament was nuclear AIR-2A Genie unguided air-to-air rockets, and there was significant political controversy in Canada about their adoption. Although they never fired a weapon in wartime, the CF-101 served as Canada's primary means of air defence from Quick Reaction Alert facilities at Canadian airbases. The CF-101s were retired in the 1980s and replaced with McDonnell Douglas CF-18 Hornet fighters. Many examples are preserved in museums and parks in Canada and the United States.

Canadair CF-104 Starfighter
The Canadair CF-104 Starfighter (CF-111, CL-90) is a modified version of the Lockheed F-104 Starfighter supersonic fighter aircraft built in Canada by Canadair under licence. It was primarily used as a ground attack aircraft, despite being designed as an interceptor. It served with the Royal Canadian Air Force (RCAF) and later the Canadian Armed Forces (CAF) until it was replaced by the McDonnell Douglas CF-18 Hornet in 1987.
Mary Hayward Weir
Mary Hayward Weir, born Mary Emma Hayward (1915–1968), was an American steel heiress and socialite. She was the wealthy widow of Pittsburgh steel king Ernest T. Weir, and the former wife of Polish author Jerzy Kosiński. The Mary H. Weir Public Library in Weirton, West Virginia is named after her.

Jerzy Kosiński
Jerzy Kosiński (Polish pronunciation: [ˈjɛʐɨ kɔˈɕij̃skʲi]; born Józef Nikodem Lewinkopf; June 14, 1933 – May 3, 1991) was a Polish-born American writer and two-time president of the American chapter of P.E.N., who wrote primarily in English.

Born in Poland to Jewish parents, he and his family survived World War II with the help of their Polish villager neighbors. After mandatory military service and education under Poland's communist government, he emigrated to the United States and became a U.S. citizen.

He was known for novels including Being There (1971) and the controversial The Painted Bird (1965), which were adapted as films, respectively, in 1979 and 2019.
The Imposter (miniseries)
The Imposter is an Australian-British co-commissioned drama series for 5 and Network 10. The series was created and executively produced by Jason Herbison. The series focuses on matriarch Helen, played by Jackie Woodburne, who refuses to sell her seaside hotel amid pressure from her three children. When the daughter she gave up for adoption appears, a mystery surrounds Helen's secret. In the United Kingdom, The Imposter aired on 15 December 2025 on 5. In Australia, The Imposter aired on 21 December 2025 on Network 10.

Jackie Woodburne
Jacqueline Anne Woodburne (born 5 February 1956) is a Northern Ireland-born Australian actress, known for her numerous roles in television soap operas. After graduating from the National Theatre School, Woodburne played Maggie Gordon in The Young Doctors. She appeared in Cop Shop as Gina Rossi, and then she was cast as inmate Julie "Chook" Egbert in Prisoner. Since 1994, Woodburne has played teacher Susan Kennedy in Neighbours.

In the 1980s, Woodburne appeared in multiple miniseries', including Outbreak of Love, Sara Dane, and 1915, which earned her a Logie Award nomination. By 1985, Woodburne had had a starring role in a major series on every network. Since 2014, Woodburne has starred as Dr Anastasia Black in the sci-fi comedy audio series Night Terrace.
Kikuji Yamashita
Kikuji Yamashita (山下 菊二, Yamashita Kikuji; October 8, 1919 – November 23, 1986) was a Japanese Surrealist painter associated with the postwar avant-garde art movement in Japan. His artworks were featured prominently in the 2010 documentary film ANPO: Art X War by American documentary filmmaker Linda Hoaglund.

Yutaka Bitō
Yutaka Bitō (尾藤 豊, Bitō Yutaka; March 30, 1926 – August 26, 1998) was a Japanese artist closely associated with the postwar avant-garde art movement in Japan. In the 1950s, he was a leading exponent of the "reportage" style of Japanese socialist realist art, and later became known for his Surrealist paintings.
Levantine Army
The Levantine Army was a unit of the Spanish Republican Army that operated during the Spanish Civil War. Under its jurisdiction were the Republican forces originally deployed on the Teruel front and, later, on the Levante front. It played an important role during the Battle of Teruel and the Levante Offensive.

Spanish Republican Army
The Spanish Republican Army (Spanish: Ejército de la República Española) was the main branch of the Armed Forces of the Second Spanish Republic between 1931 and 1939.

It became known as People's Army of the Republic (Ejército Popular de la República) after it was reorganized, following the disbandment of the voluntary militias that were formed in July 1936 at the beginning of the Spanish Civil War.
Hot Stuff (1979 film)
Hot Stuff is a 1979 American action crime comedy film starring Dom DeLuise, Suzanne Pleshette, Jerry Reed and Ossie Davis. DeLuise also directed the film (the only film where he did so), and the song "Hot Stuff" was written and performed by Reed.

Jerry Reed
Jerry Reed Hubbard (March 20, 1937 – September 1, 2008), known professionally as Jerry Reed, was an American country singer, guitarist, composer, songwriter, and actor who appeared in more than a dozen films. His signature songs included "Guitar Man", "U.S. Male", "A Thing Called Love", "Alabama Wild Man", "Amos Moses", "When You're Hot, You're Hot" (which garnered a Grammy Award for Best Country Vocal Performance, Male), "Ko-Ko Joe", "Lord, Mr. Ford", "East Bound and Down" (the theme song for the 1977 film Smokey and the Bandit, in which Reed co-starred), "The Bird", and "She Got the Goldmine (I Got the Shaft)".

Reed was inducted into the Musicians Hall of Fame and Museum. He was announced as an inductee into the Country Music Hall of Fame in April 2017, and he was officially inducted by Bobby Bare on October 24.
Kuchinotsu, Nagasaki
Kuchinotsu (口之津町, Kuchinotsu-chō) was a town located in Minamitakaki District, Nagasaki Prefecture, Japan.

As of 2003, the town had an estimated population of 6,450 and a density of 646.29 persons per km2. The total area was 9.98 km2.

On March 31, 2006, Kuchinotsu, along with the towns of Arie, Fukae, Futsu, Kazusa, Kitaarima, Minamiarima and Nishiarie (all from Minamitakaki District), was merged to create the city of Minamishimabara.

Fukae, Nagasaki
Fukae (深江町, Fukae-chō) was a town located in Minamitakaki District, Nagasaki Prefecture, Japan.

As of 2003, the town had an estimated population of 8,186 and a density of 349.23 persons per km2. The total area was 23.44 km2.

On March 31, 2006, Fukae, along with the towns of Arie, Futsu, Kazusa, Kitaarima, Kuchinotsu, Minamiarima and Nishiarie (all from Minamitakaki District), was merged to create the city of Minamishimabara.
Ambarawa
Ambarawa is a town and an administrative district (kecamatan) of the Semarang Regency, located between the cities of Semarang and Salatiga in Central Java Province of Indonesia. Administratively, it is bordered by the districts of Banyubiru to the south, Jambu to the west, Bandungan to the north, and Bawen to the east.

During colonial times, Ambarawa was an important railway hub connecting through regions in Java as far as Yogyakarta and Magelang.  The Semarang-Ambarawa-Magelang line was fully operational until 1977. It is the site of the Indonesian Railway Museum (Museum Kereta Api Ambarawa), which features a section of rack railway between Ambarawa to Bedono on the former Ambarawa-Magelang mainline. The 19th-century Fort Willem I penitentiary complex and military barrack is also located in Ambarawa.

Semarang Regency
Semarang is a landlocked regency (Indonesian: kabupaten) in Central Java province in Indonesia. It covers an area of 1,019.27 km2 and had a population of 930,727 at the 2010 census and 1,053,094 at the 2020 census; the official estimate at mid 2023 was 1,089,767, comprising 542,392 males and 547,375 females. These figures exclude the independent cities of Semarang and Salatiga, which are administratively separate from the regency. The regency's capital is Ungaran, which lies immediately to the south of Semarang City.
Frank Grillo
Frank Anthony Grillo (born June 8, 1965) is an American actor. He is known for playing Brock Rumlow / Crossbones in the superhero franchise Marvel Cinematic Universe (MCU), Sergeant Leo Barnes in The Purge franchise, and Rick Flag Sr. in the DC Universe (DCU). He has also appeared in Warrior (2011), The Grey (2011), End of Watch (2012), Zero Dark Thirty (2012), Wolf Warrior 2 and Wheelman (both 2017), and Boss Level (2020).

Grillo's television work includes the lead role in Kingdom (2014–2017) as well as recurring roles in Battery Park (2000), For the People (2002–2003), The Shield (2002–2003), Prison Break (2005–2006), Blind Justice (2005), The Kill Point (2007), Billions (2020), Tulsa King (2024), and Peacemaker (2025).

Kingdom (American TV series)
Kingdom (previously titled Navy St.) is an American drama television series created by Byron Balasco. The series premiered on October 8, 2014 on the Audience Network and concluded on August 2, 2017. It stars Frank Grillo, Kiele Sanchez, Matt Lauria, Jonathan Tucker, Nick Jonas, and Joanna Going. Season one consists of ten episodes.

On October 17, 2014, DirecTV announced that the series was renewed for an additional 20 episodes, 10 of which aired in 2014 & 10 in 2015. On July 7, 2016, it was renewed for a third season which premiered on May 31, 2017. On April 1, 2017, it was announced that the third season would be the final season of the series.
Nembrionic
Nembrionic was a Dutch death metal band. They were formed in 1991 under the name Nembrionic Hammerdeath as a black metal band; they changed their name to Nembrionic in 1993. The band released three albums on Displeased Records and another together with Osdorp Posse. They split up in 1999.

Displeased Records
Displeased Records was a Dutch independent record label, founded by Lars Eikema and Ron Veltkamp. The label had many Dutch and other extreme metal bands on its roster, but has also re-released albums by Agathocles, Cryptopsy, Infernäl Mäjesty, Sadus, Toxik and Whiplash. The label also had a large mail order division called Discorder.com.
Ardabur (consul 447)
Ardabur (Ἀρδαβούρ, died 471) was an Eastern Roman magister militum of Alanic descent. He was the son of the influential general Aspar. He served as consul in 447 and as magister militum per Orientem from 453 until 465 or 466. Ardabur apparently often served under his father during his campaigns.

He was removed from this post in 466 after being accused of a treasonous plot involving the Sasanian Empire, probably by his father's political enemies. The accusation contributed to Aspar's fall from power. Both Ardabur and Aspar were killed in 471 as part of a conspiracy between the Isaurians and the emperor Leo I.

Aspar
Flavius Ardabur Aspar (Greek: Ἄσπαρ, fl. 400 – 471) was an Eastern Roman patrician and magister militum ("master of soldiers") of Alanic-Gothic descent. As the general of a Germanic army in Roman service, Aspar exerted great influence on the Eastern Roman Emperors for half a century, from the 420s to his death in 471, through the reigns of Theodosius II, Marcian and Leo I, who, in the end, had him killed. His death led to the ending of the Germanic domination of Eastern Roman policy.