hotchpotch/wikipedia-multilingual-ir-related-lead-pairs huggingface dataset:
Sigma complex
In chemistry,  a sigma complex or σ-complex usually refers to a family of coordination complexes where one or more ligands interact with the metal using the bonding electrons in a sigma bond. Transition metal silane complexes are often especially stable sigma complexes. A particularly common subset of sigma complexes are those featuring an agostic interaction where a C–H σ-bond on one of its ligands 'leans' towards and interacts with the coordinatively unsaturated metal center to form a chelate. Transition metal alkane complexes (e.g., a methane complex) that bind solely through the C–H bond are also known but structurally characterized examples are rare, as C–H σ-bonds are generally poor electron donors, and, in many cases, the weakened C–H bond cleaves completely (C–H oxidative addition) to form a complex of type M(R)(H).  In some cases, even C–C bonds function as sigma ligands.

Agostic interaction
In organometallic chemistry, agostic interaction refers to the intramolecular interaction of a coordinatively-unsaturated transition metal with an appropriately situated C−H bond on one of its ligands.  The interaction is the result of two electrons involved in the C−H bond interaction with an empty d-orbital of the transition metal, resulting in a three-center two-electron bond. It is a special case of a C–H sigma complex.  Historically, agostic complexes were the first examples of C–H sigma complexes to be observed spectroscopically and crystallographically, due to intramolecular interactions being particularly favorable and more often leading to robust complexes.  Many catalytic transformations involving oxidative addition and reductive elimination are proposed to proceed via intermediates featuring agostic interactions. Agostic interactions are observed throughout organometallic chemistry in alkyl, alkylidene, and polyenyl ligands.
The Alphabet of Manliness
The Alphabet of Manliness is the debut book by American humorist and Internet personality Maddox, published in 2006. It reached the #2 position on the New York Times Best Seller list in the "Advice, How-To, and Miscellaneous" category.

Maddox (writer)
George Ouzounian (born 1977 or 1978), known as Maddox, is an American blogger, YouTuber, and author. He gained fame on the internet in the early 2000s for his opinion-oriented website, The Best Page in the Universe, which he still maintains. His first book, The Alphabet of Manliness (2006), became a New York Times bestseller.
Ben Böhmer
Ben Böhmer (born 1993) is a German DJ, producer and remixer from Göttingen, Germany. He primarily produces and performs indie electronica and melodic house music, and has released tracks on labels Ninja Tune, Anjunadeep, Keller Records, and Cercle Music. He lives in Berlin.

Cercle (company)
Cercle is a music company headquartered in Paris, France. It operates as a livestreaming platform for music, an event and festival producer and a record label.

Founded in 2016 by Derek Barbolla, Cercle originally specialized in organizing, filming and broadcasting electronic music concerts in unconventional venues of cultural, natural, aesthetic or artistic significance. While the music programming originally focused on various subgenres of electronic music (deep house, house, techno, dance music, electronica), it broadened its spectrum as of 2021 by featuring neoclassical and jazz artists such as Sofiane Pamart (2021) and Hania Rani (2022) or Ólafur Arnalds (2023).
Dietrich Eckart
Dietrich Eckart (German: [ˈɛkaʁt]; 23 March 1868 – 26 December 1923) was a German völkisch poet, playwright, journalist, publicist, and political activist who was one of the founders of the German Workers' Party (DAP), the precursor of the Nazi Party (National Socialist German Workers' Party or NSDAP). Eckart was a key influence on Adolf Hitler in the early years of the Party, the original publisher of the party newspaper, the Völkischer Beobachter ("Folkist Observer"), and the lyricist of the first party anthem, "Sturmlied" ("Storming Song"). He was a participant in the failed Beer Hall Putsch in 1923 and died on 26 December of that year, shortly after his release from Landsberg Prison, of a heart attack.

Eckart was elevated to the status of a major thinker upon the establishment of Nazi Germany in 1933. He was acknowledged by Hitler to be the spiritual co-founder of Nazism and "a guiding light of the early National Socialist movement."

Gottfried Feder
Gottfried Feder (27 January 1883 – 24 September 1941) was a German civil engineer, a self-taught economist, and one of the early key members of the Nazi Party and its economic theoretician. One of his lectures, delivered on 12 September 1919, drew Adolf Hitler into the party.
German Clock Museum
The German Clock Museum (German: Deutsches Uhrenmuseum) is situated near the centre of the Black Forest town of Furtwangen im Schwarzwald (Germany), a historical centre of clockmaking. It features permanent and temporary exhibits on the history of timekeeping. The museum is part of the local technical college (Hochschule Furtwangen).

Hochschule Furtwangen University
Furtwangen University (HFU) is a German University of applied science with its main location in Furtwangen im Schwarzwald, Baden-Württemberg, Germany and two more campuses in Villingen-Schwenningen and Tuttlingen. The HFU is part of the "International Lake Constance University Network" (IBH) as well as part of the Franco-German University (FGU).

It offers degree programmes in the health sciences, computer science, engineering, international business, digital media, business information systems and business administration and engineering.
Seckel syndrome
Seckel syndrome, or microcephalic primordial dwarfism (also known as bird-headed dwarfism, Harper's syndrome, Virchow–Seckel dwarfism and bird-headed dwarf of Seckel) is an extremely rare congenital nanosomic disorder. Inheritance is autosomal recessive. It is characterized by intrauterine growth restriction and postnatal dwarfism with a small head, narrow bird-like face with a beak-like nose, large eyes with down-slanting palpebral fissures, receding mandible and intellectual disability.

A mouse model has been developed. This mouse model is characterized by a severe deficiency of ATR protein. These mice have high levels of replicative stress and DNA damage. Adult Seckel mice display accelerated aging. These findings are consistent with the DNA damage theory of aging.

Ataxia telangiectasia and Rad3 related
Serine/threonine-protein kinase ATR, also known as ataxia telangiectasia and Rad3-related protein (ATR) or FRAP-related protein 1 (FRP1), is an enzyme that, in humans, is encoded by the ATR gene. It is a large kinase of about 301.66 kDa. ATR belongs to the phosphatidylinositol 3-kinase-related kinase protein family. ATR is activated in response to single strand breaks, and works with ATM to ensure genome integrity.
Kelli Stack
Kelli Allison Stack (born January 13, 1988) is an American former ice hockey forward, who played for Kunlun Red Star in the Canadian Women's Hockey League. She is a member of the United States women's national ice hockey team. Stack competed for the Boston College Eagles women's ice hockey program and after completing her Olympic commitment, returned to Boston College for her senior year of 2010–11. She was drafted 14th overall by the Boston Blades in the 2011 CWHL Draft.

Boston College Eagles women's ice hockey
The Boston College Eagles women's ice hockey team represent Boston College in the NCAA and participate in Hockey East. The Eagles are coached by former Olympic gold medallist Katie King-Crowley and play their home games at Conte Forum. They have won the Hockey East championship three times, and made seven trips to the Frozen Four of the NCAA tournament.
Lawrence-Jones baronets
The Jones, later Lawrence-Jones Baronetcy, of Cranmer Hall in the County of Norfolk, is a title in the Baronetage of the United Kingdom. It was created on 30 September 1831 for Major-General Sir John Jones, 1st Baronet, who had earlier fought with distinction in the Peninsular War. He married Catherine, daughter of Effingham Lawrence.

The second Baronet was murdered by robbers at Macri near Dalaman in Turkey. The fifth Baronet was an author and published several memoirs as L. E. Jones. His works include "Victorian Boyhood", "Edwardian Youth" and "Georgian Afternoon". The sixth Baronet assumed the additional surname of Lawrence.

Herbert Jones, second son of the third Baronet, was suffragan Bishop of Lewes.

John Thomas Jones
Major General Sir John Thomas Jones, 1st Baronet KCB (25 March 1783 – 26 February 1843) was a British officer in the Royal Engineers who played a leading engineering role in a number of European campaigns of the early nineteenth century. Jones was revered by the Duke of Wellington and asked to advise on fortifications including the modernisation of the defences in Gibraltar. He was also notable as an English amateur cricketer who made six appearances.
The Adventures of Sherlock Holmes and Dr. Watson
The Adventures of Sherlock Holmes and Dr. Watson (Russian: Приключения Шерлока Холмса и доктора Ватсона) is a series of Soviet television films portraying Arthur Conan Doyle's fictional English detective, starting in 1979. They were directed by Igor Maslennikov.

The Hound of the Baskervilles (1981 film)
The Hound of the Baskervilles (Russian: Приключения Шерлока Холмса и доктора Ватсона: Собака Баскервилей) is a 1981 Soviet television film adaptation of Arthur Conan Doyle's 1902 novel The Hound of the Baskervilles. It was the third instalment in the TV series about adventures of Sherlock Holmes and Doctor Watson.

Director Igor Maslennikov received acclaimed reviews from abroad, including a letter from Conan Doyle's daughter, who wrote: "Had my father lived to see this film, he would have been happy"; the Daily Mirror published a review quoting Margaret Thatcher, who called it "the best Sherlock Holmes film she had ever seen."[1]

At the Sherlock Holmes Museum at 221b Baker Street, London, very "British" music, written for this film by Vladimir Dashkevich,  plays on a loop.
Thornton W. Burgess House
The Thornton W. Burgess House is a historic house at 789 Main Street in Hampden, Massachusetts.  Built between 1780 and 1784, it is a well-preserved vernacular house built by one of the area's early settlers, and was for many years home to children's author Thornton W. Burgess.  The property is now owned by the Massachusetts Audubon Society, which uses it for staff housing.  It is adjacent to the Society's Laughing Brook Wildlife Sanctuary.  It was listed on the National Register of Historic Places in 1983.

Thornton W. Burgess
Thornton Waldo Burgess (January 14, 1874 – June 5, 1965) was an American conservationist and author of children's stories. By the time he retired, he had written more than 170 books and 15,000 stories for his daily newspaper column.
Astromantic
Astromantic is the third studio album by the Japanese hip-hop group M-Flo. It was released on May 26, 2004, through Rhythm Zone. Remixes of songs from this album were released as Astromantic Charm School. The album spawned three singles featuring different singers: "Reeewind!" with Crystal Kay, "Miss You" with singer Melody, and "The Love Bug" with BoA.

Commercially, the album peaked at number two on the Oricon Albums Chart and was certified platinum by the Recording Industry Association of Japan (RIAJ) for physical sales in June 2004.

Melody (Japanese singer)
Melody Ishikawa (born February 24, 1982), known mononymously as Melody, stylized as melody., is a Japanese American J-pop singer. She debuted in February 2003 with the song "Dreamin' Away", under Toy's Factory. In October 2008, Melody announced on her blog ending her career as a music artist to focus on pursuing a career as a fashion designer.
ReverbNation
ReverbNation.com is a website, launched in 2006, that focuses on the independent music industry. It aims to provide a central site for musicians, producers, and venues to collaborate and communicate. ReverbNation was bought for an undisclosed sum by music creation platform, BandLab Technologies, in November 2021.

BandLab Technologies
BandLab Technologies is a Singaporean company founded in 2015 that operates a social music platform, called BandLab, and also owns a variety of music-related brands, including Harmony and Heritage Guitars; media platforms Guitar.com, NME, Uncut and MusicTech.com ; and  musical instrument retailer and distributor Swee Lee.

In December 2021, the company announced a reorganisation under the newly formed parent company Caldecott Music Group (CMG). BandLab Technologies is the music technology division of CMG.
Guy Aldonce de Durfort, 1st Duke of Quintin
Guy Aldonce de Durfort, 1st Duke of Lorges, Marshal of France, (1630–1702) fought in the Franco-Dutch War mostly on the Rhine under his uncle Marshal Turenne, but in 1673 he was seconded to the Siege of Maastricht. Back on the Rhine, he fought at Entzheim in 1674, at Turckheim in January 1675, and at Sasbach in July 1675, where Turenne fell. He distinguished himself at the retreat from Sasbach and the ensuing Battle of Altenheim.

In the Nine Years' War he commanded the Rhine army and took the city and the castle of Heidelberg in 1693. He is often mentioned in Saint-Simon's Mémoires as he was the author's father-in-law. Created the 2st Duke of Quintin in 1691, he was known as the 1st Duke of Lorges.

Marshal of France
Marshal of France (French: Maréchal de France, plural Maréchaux de France) is a French military distinction, rather than a military rank, that is awarded to generals for exceptional achievements. The title has been awarded since 1185, though briefly abolished (1793–1804) and for a period dormant (1870–1916). It was one of the Great Officers of the Crown of France during the Ancien Régime and Bourbon Restoration, and one of the Grand Dignitaries of the Empire during the First French Empire (when the title was Marshal of the Empire, not Marshal of France).

Between the end of the 16th century and the middle of the 19th century, six Marshals of France were given the even more exalted rank of Marshal General of France: Biron, Lesdiguières, Turenne, Villars, Saxe, and Soult.

The distinction of Admiral of France is the equivalent in the French Navy.
Bara massacre
The Bara massacre was a caste based carnage that took place in 1992 in Bihar. At midnight on 12–13 February 1992, the Maoist Communist Centre of India (now the Communist Party of India (Maoist)) killed 40 Bhumihars at Bara Village in Gaya district of Bihar, India. The MCC's armed group brought the 35 men of Bara village to the bank of a nearby canal, tied their hands and slit their throats. As many as 36 people were accused of the crime, but 13 were charged. The police failed to arrest the others, who had defied their summons.

Laxmanpur Bathe massacre
The Laxmanpur Bathe massacre was a massacre conducted in the Laxmanpur Bathe village in Arwal district of Bihar on 1 December 1997, where 58 scheduled caste people were killed by members of the Ranvir Sena in retaliation for the Bara massacre in which 37 upper castes were killed. Laxmanpur Bathe is a village in Arwal district in Bihar, on the Son river about 90–km from Patna.
You Know Me movement
The You Know Me movement is a 2019 movement by abortion rights advocates in the United States to fight abortion stigma. A similar campaign and movement from 2015 is called #ShoutYourAbortion.

The You Know Me movement is a response to the successful 2019 passage of six-week abortion bans in five U.S. states, most notably the passing of anti-abortion laws in Georgia (House Bill 381), Ohio (House Bill 68), and Alabama (House Bill 314).

Abortion-rights movement
Abortion-rights movements, also self-styled as pro-choice movements, are movements that advocate for legal access to induced abortion services, including elective abortion. They seek to represent and support women who wish to terminate their pregnancy without fear of legal or social backlash.  These movements are in direct opposition to anti-abortion movements.

The issue of induced abortion remains divisive in public life, with recurring arguments to liberalize or restrict access to legal abortion services. Some abortion-rights supporters are divided as to the types of abortion services that should be available under different circumstances, including periods in the pregnancy such as late term abortions, in which access may or may not be restricted.
Le Gavroche
Le Gavroche (The Urchin) was a restaurant at 43 Upper Brook Street in Mayfair, London. It was opened in April 1967 by Michel and Albert Roux at 61 Lower Sloane Street, its premises until 1981. Albert's son Michel Roux Jr was the chef patron from 1991 until its closure in 2024. It was the first restaurant in the UK to be awarded three Michelin stars, which it held from 1982 to 1993.

The restaurant offered classical French food, although some dishes were more modern. Notable dishes included the Soufflé Suissesse (cheese soufflé baked on double cream); Le Caneton Gavroche (whole poached duck in a light consommé served with three sauces for two); and Omelette Rothschild. Its name came from the character Gavroche in Victor Hugo's Les Misérables.

In August 2023, Michel Roux Jr. announced that the restaurant would close at the end of its lease in January 2024, after over 56 years of business. The restaurant's final day of trading was on 13 January 2024.

Michel Albert Roux
Michel Albert Roux (born 23 May 1960) also known as Michel Roux Jr., is an English-French chef. He owned the 2 Michelin-starred restaurant Le Gavroche in London, which was opened by his father Albert Roux and uncle Michel Roux, until it closed on 13 January 2024.
Montmorency series
The Montmorency series are five young adult historical crime novels written by Eleanor Updale and first published from 2003 to 2013. It features Montmorency, an English ex-convict turned gentleman detective and spy, for whom both the first book and the series are named. The first book is set in London, frequently in its sewers, and London remains a primary setting. The last novel was released in 2013 after a six-year break.

London sewer system
The London sewer system is part of the water infrastructure serving London, England. The modern system was developed during the late 19th century, and as London has grown the system has been expanded. It is currently owned and operated by Thames Water and serves almost all of Greater London.
Catilia gens
The gens Catilia was a minor plebeian family at ancient Rome, found from the first century BC and throughout imperial times.  Only a few members of this gens are mentioned in history, though others occur in epigraphy.  The most illustrious of the Catilii was Lucius Catilius Severus, consul in AD 120, and one of the ancestors of Marcus Aurelius.  Another Catilius Severus was among the advisors of Severus Alexander.

Lucius Catilius Severus
Lucius Catilius Severus Julianus Claudius Reginus was a Roman senator and general active during the reigns of Trajan and Hadrian. He was appointed consul twice: the first time in 110 CE (as consul suffectus) with Gaius Erucianus Silo as his colleague; the second in the year 120 (as consul ordinarius) with the future emperor Antoninus Pius as his colleague. Catilius was also the step-great-grandfather of the emperor Marcus Aurelius.

Catilius is called Lucius Catilius Severus Julianus in Bithynian inscriptions, Lucius Catilius Severus as a consul, and Catilius Severus in literary sources. His family origins probably lie in Apamea, a town of Bithynia. In his monograph of naming practices in the first centuries of the Roman Empire, Olli Salomies notes that this polyonymous name implies an adoption, "no doubt the son of a Cn. Catilius, not the son of a Cn. Claudius adopted by a L. Catilius, in spite of the existence of senatorial Cn. Claudii Severi from Asia Minor."
Bella Cooper
Isabella Jane "Bella" Durville (also Cooper) is a fictional character on the New Zealand soap opera Shortland Street who was portrayed by Amelia Reid-Meredith between her arrival in September 2010 and her departure in November 2016. She was the eldest sibling in the Cooper family unit.

Wendy Cooper
Wendy Cooper is a fictional character on the New Zealand soap opera Shortland Street and has been portrayed by Jacqueline Nairn since her debut in mid-2010. The character arrived as the matriarch of the new family unit, the Coopers.
Starscream
Starscream is a character in the Transformers media franchise produced by the American toy company Hasbro and the Japanese toy company Takara Tomy. He is the second-in-command of the Decepticons, a villainous faction of alien robots that seeks to conquer their home planet of Cybertron and the rest of the known universe. As with all Cybertronians, Starscream can disguise himself by transforming into vehicles, in his case a fighter jet, and he is usually portrayed as a treacherous and cowardly air commander who seeks to overthrow the Decepticon leader, Megatron, and assume control of the Decepticons.

Bumblebee (Transformers)
Bumblebee is a fictional robot character appearing in the many installments of the Transformers franchise. The character is a member of the Autobots — a group of sentient, self-configuring, modular, extraterrestrial robotic lifeforms.

In the original line of toys and in the animated series, Bumblebee is a small yellow Volkswagen beetle. In the live action movies, he has appeared as vehicles inspired by the Chevrolet American muscle cars, with the live-action film versions being a yellow Camaro with black racing stripes. The original vehicle-mode design was based on a classic European Type 1 Volkswagen Beetle. The character is named after the bumblebee, a black-and-yellow striped insect, which inspired his paint scheme. Bumblebee is a fan-favorite, and appears in most of the series, later becoming the main protagonist in Transformers: Robots in Disguise, Bumblebee, and Transformers: Cyberverse. Bumblebee has also taken the form of a Willys Jeep in the 2018 film, Bumblebee.
Sereď
Sereď (Slovak pronunciation: [ˈserec]; Hungarian: Szered [ˈsɛrɛd]) is a town in southern Slovakia near Trnava, on the right bank of the Váh River on the Danubian Lowland. It has approximately 15,500 inhabitants.

Trnava
Trnava (Slovak pronunciation: [ˈtr̩naʋa] ⓘ, German: Tyrnau, German: [ˈtʏrnaʊ̯] ⓘ; Hungarian: Nagyszombat [ˈnɒcsombɒt], also known by other alternative names) is a city in western Slovakia, 47 km (29 mi) to the northeast of Bratislava, on the Trnávka river. It is the capital of the Trnava Region and the Trnava District. It is the seat of a Roman Catholic archbishopric (1541–1820 and then again since 1977). The city has a historic center. Because of the many churches within its city walls, Trnava has often been called "Little Rome" (Slovak: Malý Rím, Latin: parva Roma), or more recently, the "Slovak Rome".
5-Carboxamidotryptamine
5-Carboxamidotryptamine (5-CT), also known as 5-(aminocarbonyl)tryptamine, is a tryptamine derivative closely related to the neurotransmitter serotonin.

5-CT acts as a non-selective, high-affinity full agonist at the 5-HT1A, 5-HT1B, 5-HT1D, 5-HT5A, and 5-HT7 receptors, as well as an agonist of the 5-HT2, 5-HT3, 5-HT6 receptors with lower affinity. It has negligible affinity for the 5-HT1E and 5-HT1F receptors. 5-CT binds most strongly to the 5-HT1A receptor and it was once thought to be selective for this site.

In 2018, a close derivative of 5-CT, AH-494 has been shown to function as an agonist of 5-HT7, although being more selective over 5-HT1A. Structural study indicated residue Ser5x43 might play critical roles in the selectivity of 5-CT across the serotonin receptor family.

AH-494
AH-494 is a potent and selective, water-soluble full agonist at the 5-HT7 serotonin receptor of the imidazolylindole family. It is a close derivative of the known chemical probe 5-Carboxamidotryptamine, as well as of the more lipophilic imidazolylindoles: AGH-107 and AGH-192. It has been shown to exhibit favorable ADMET profile in in vitro assays.