TCVN5142:2008

Tiêu chuẩn Việt Nam TCVN 5142:2008 (CODEX STAN 229-1993, Rev.1-2003) về phân tích dư lượng thuốc bảo vệ thực vật - các phương pháp khuyến cáo TIÊU CHUẨN VIỆT NAM TCVN 5142:2008 PHÂN TÍCH DƯ LƯỢNG THUỐC BẢO VỆ THỰC VẬT – CÁC PHƯƠNG PHÁP KHUYẾN CÁO Analysis of pesticide residues – recommended methods Lời nói đầu TCVN 5142:2008 thay thế TCVN 5142:1990; TCVN 5142:2008 hoàn toàn tương đương với CODEX STAN 229-1993, Rev.1-2003; TCVN 5142:2008 do Ban kỹ thuật tiêu chuẩn TCVN/TC/F13 Phương pháp phân tích và lấy mẫu biên soạn, Tổng cục Tiêu chuẩn Đo lường Chất lượng đề nghị, Bộ Khoa học và Công nghệ công bố. PHÂN TÍCH DƯ LƯỢNG THUỐC BẢO VỆ THỰC VẬT – CÁC PHƯƠNG PHÁP KHUYẾN CÁO Analysis of pesticide residues – recommended methods 1. Giới thiệu 1.1. Phạm vi áp dụng Các phương pháp phân tích liệt kê dưới đây được tổng kết từ kinh nghiệm thực hành của Ủy Ban Codex về Dư lượng Thuốc bảo vệ thực vật, được xem xét để xác định dư lượng thuốc bảo vệ thực vật theo quy định. Danh mục đưa ra trong điều 2 chưa đề cập hết mọi khía cạnh và có thể áp dụng các phương pháp không có trong danh mục này miễn là chúng có thể cho kết quả chính xác khi sử dụng các phương pháp đó. 1.2. Tiêu chí để lựa chọn phương pháp phân tích Bất cứ khi nào có thể, việc lựa chọn phương pháp phân tích dư lượng thuốc bảo vệ thực vật được dựa trên các tiêu chí sau đây: i. Sẵn có các tài liệu tạp chí, sổ tay hoặc trên mạng điện tử của các tổ chức tiêu chuẩn quốc tế hoặc quốc gia; ii. Đã có sự nghiên cứu phối hợp của một số phòng thí nghiệm hoặc đã được kiểm tra xác nhận. Việc kiểm tra xác nhận phương pháp đối với phòng thí nghiệm riêng rẽ tối thiểu đã tuân thủ hướng dẫn thực hành tốt về phân tích dư lượng thuốc bảo vệ thực vật. iii. Có khả năng xác định nhiều hơn một loại thuốc bảo vệ thực vật, nghĩa là phương pháp đa dư lượng; iv. Thích hợp cho nhiều loại sản phẩm có nồng độ dưới mức quy định MRLs; v. Có thể áp dụng đối với các phòng thí nghiệm được trang bị các thiết bị, dụng cụ phân tích có sẵn thông thường. Ưu tiên sử dụng sắc ký khí hoặc sắc ký lỏng hiệu năng cao như là bước tách chiết của các phương pháp. Tuy nhiên, trong các điều kiện xác định, phương pháp sàng lọc quy định trong hướng dẫn thực hành tốt về phân tích dư lượng thuốc bảo vệ thực vật có thể áp dụng. Phương pháp sàng lọc được chỉ ra trong danh mục. 1.3. Áp dụng phương pháp Trước khi áp dụng phương pháp cần phê chuẩn phương pháp và chứng minh năng lực của người phân tích. Trong quá trình sử dụng, định kỳ cần phải đánh giá xác nhận các đặc tính của phương pháp. Việc phê chuẩn và xác nhận đặc tính của phương pháp được mô tả trong Hướng dẫn thực hành tốt về phân tích dư lượng. 1.4. Tài liệu tham khảo Các khuyến cáo liên quan khác của Codex về giới hạn tối đa dư lượng thuốc bảo vệ thực vật thuộc phạm vi bắt buộc như sau: 1. Các phương pháp lấy mẫu khuyến cáo để xác định dư lượng thuốc bảo vệ thực vật (tham khảo Codex Alimentarius tập 2, chương 3). 2. Bộ phận hàng hóa áp dụng giới hạn dư lượng tối đa và được dùng để phân tích [tham khảo TCVN 5140:2008 (Volume 2A, Part 1 – 2000)]. 3. Các giải thích về giới hạn tối đa về dư lượng thuốc bảo vệ thực vật của Codex (tham khảo Codex Alimentarius tập 2, chương 1). 4. Hướng dẫn thực hành tốt khi phân tích dư lượng thuốc bảo vệ thực vật của Codex (tham khảo Codex Alimentarius phần bổ sung 1, tập 2, chương 4). Ở 3 đoạn của tài liệu tham khảo có thể tìm thấy: ● Các bài báo chung về phương pháp luận đối với dư lượng thuốc bảo vệ thực vật (đoạn 3.1); ● Sổ tay (đoạn 3.2); ● Các bài báo cụ thể (đoạn 3.3). Sau mỗi tài liệu tham khảo trong đoạn 3.3, các hợp chất liên quan đến áp dụng các phương pháp phân tích được chỉ ra bằng số CCPR của chúng. 2. Danh mục các phương pháp phân tích Các số hiệu đối với sổ tay và sách được liệt kê trong 3.2, tên đối với tác giả (thứ nhất) của các bài báo được liệt kê trong đoạn 3.3. Số CCPR Hợp chất Tài liệu tham khảo 001 Aldrin/dieldrin 1a, 1n, 1o, 1p, 2a, 2d, 2f, 3, 4 (XII-5, 6; S8 – 10, S12, S19), 5, 7a (5, 6), 7c (S8-10, S12, S19), 8a, 8b, 8c, 8d, 9a (M1, M12), 10 Ambrus, Abbott (2), Panel (4), Stijve (2,3) 002 Azinphos-metyl 2c, 2d, 2e, 2f, 3, 4 (XII- 6; S5, S8, S19, 63,63A), 7a (6), 7c (S8, S19), 7d (22), 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Panel (3) 003 Binapacryl 2a, 2d, 3, 4 (XII-4,6; S19; 8, 43), 7a (6), 7a (S19), 9b, 10 Baker, PB (2) 004 Bromophos 2a, 2c, 2d, 4 (XII- 3, 6; S5, S8 – 10, S13, S17, S19; 210, 210A), 6d, 7a (3,6), 7c (S8 – 10, S13, S17, S19), 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Bottomley, Panel (7,8), Stijve (7) 005 Bromophos – etyl 2a, 2c, 2d, 3, 4 (XII – 3, 6; S8, S13, S17, S19; 263), 6d, 7a (3,6), 7c (S13, S17, S19), 9a (M2, M5, M12), 10 006 Captafol 2d, 2e, 4 (XII – 6; S8, S19, S20; 266, 266A); 6d, 7a (6), 7b, 7c (S8, S19, S20), 9a (M1, M12), 10 Ambrus, Baker, PB (1), Buettler, Gilvydis, Pomerantz 007 Captan 2d, 2d, 2e, 3, 4 (XII – 6; S8, S12, S19; 20, 12, 12A), 7a (6), 7b, 7c (S8, S12, S19, S20), 9a (M1, M12), 10 Ambrus, Baker, PB (1), Buettler, Gilvydis, Pomerantz 008 Carbaryl 1q, 2d, 2e, 2f, 2g, 3, 4 (XII- 6; 100), 6c, 7a (6), 9a (M2, M13), 10 Brauckhoff, Chaput, Lawrence (1) 009 Cacbon disulfua 9a (M8) 010 Cacbon tetraclorua Mestres (2) Daft, Mestres (2), Panel (5) 011 Cacbonphenothion 2a, 2c, 2d, 2e, 2f, 3, 3d, 4 (XII- 5, 6; S8, S10, S13, S16, S19), 7a (5,6), 7c (S8, S10, 13, S16, S19), 8b, 8e, 9a (M2, M5, M12), 10 Abbottt (1), Ambrus 012 Clodan 1a, 1o, 2a, 2d, 2f, 3, 4 (XII-5,6; S9, S10, S12, S19), 5, 7a (5, 6), 7c (S9, S10, S12, S19), 6c, 6d, 8a, 8b, 8c, 8d 013 Clodimeform 2e, 6a, 9a (M4), 10 014 Clofenviphos 2c, 2d, 2e, 2f, 3,4 (XII – 3, 5, 6; S8, S13, S17, S19, 239), 5, 7a(3,5,6), 7c (S8, S13, S17, S19); 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Panel (7,8), Stijve (7) 015 Clomequat 6a, 9b Sachse, Stijve (5) 016 Clobenzilat 2a, 2d, 2e, 3, 4 (XII – 6; S19, 7a (6), 7c (S19), 10 017 Clopyrifos 1p, 2a, 2c, 2d, 2e, 2f, 3, 4 (XII – 6; S8, S9, S13, S19), 5, 7a(6), 7c, (S8, S9, S13, S19), 8b, 8e, 9a (M2, M5, M12), 10 (Ambrus, Stijve (7)) 018 Coumaphos 2c, 2d, 2e, 3, 4 (XII – 6; S19), 7a (6), 7c (S19), 8b, 8e, 9a (M2, M5, M12) Ambrus, Stijve (7) 019 Crufomat 2d, 2e, 2f, 4 (XII – 6; S19), 7a (6), 7c (S19), 8b, 8e Stijve (7) 020 2,4 – D 2b, 2f, 3, 4 (27,27A-380), 5, 7d (27A-28A), 9a (M6) Ebing, Specht (1) 021 DDT 1a, 1n, 1o, 1p, 2a, 2f, 3, 4 (XII – 4, 5, 6; S1-5, S8-10, S12, S19), 5, 6c, 7a (4,5,6), 7c (S8-10, S12, S19), 8a, 8b, 8c, 9a (M1, M12), 10 Abbott (2), Ambrus, Bottomley, Panel (4), Stijve (2,3), Veierov 022 Diazion 1a, 2a, 2c, 2d, 2f, 3, 4 (XII – 5, 6; S5, S8, S10, S13, S17, S19; 35A, 35B), 6c, 7a (5, 6), 7c (S8, S10, S13, S17, S19), 8e, 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Bottomley, Panel (7), Stijve (7) 023 1,2-dibromoetan 1d, 8f, 9a (M8) Daft, Heikes, Mestres (2), Panel (5), Rains 024 1,2-dicloetan 1d, 9a (M8) Daft, Mestres (2), Panel (5) 025 Diclovos 2c, 2d, 2e, 2f, 3, 4 (XII – 3, 6; S5, S8, S13, S17, S19; 200), 7a (3,6), 7c (S13, S17, S19), 8b, 8e, 9a (M2, M5), 10 Abbott (1), Ambrus, Bottomley, Panel (1, 3, 7), Stijve (7) 026 Dicofol 2a, 2d, 2f, 3, 4 (XII – 6; S8, S9, S12, S19; 69, 69A, 7a (6), 7c (S8, S9, S12, S19), 9a (M1, M12), 10 027 Dimethoat 2c, 2d, 2f, 3, 4 (XII – 3, 6; S5, S8 S13, S17, S19; 42, 236), 5, 7a (3,6), 7c (S8, S13, S17, S19), 9a (M5, M12), 10 Abbott (1), Ambrus, Panel (3, 7, 8), Stijve (7) 028 Dioxathion 2c, 2d, 4 (XII – 6; S8, S13, S19), 7a (6), 7c (S8, S9, S19), 8e, 9a (M2, M5, M12), 10 Abbott (1), Stijve (7) 029 Diphenyl 2d, 4 (XII – 6; 256A), 7a (6), 10 Farrow, Kitada, Lord, Mestres (1), Player, Pyysalo 030 Diphenylamin 2d, 2se, 4 (XII – 6), 7a (6), 10 Allen (1), Luke 031 Diquat 2e, 4 (37), 6d Calderbank (2), King 032 Endosulfan 1b, 2a, 2d, 2f, 3, 4 (XII – 5, 6; S5, S8, S12, S19, 50), 5, 7a (5,6), 7c (S9 – 10, S12, S19), 8a, 8b, 8c, 8d, 9a (M1, M12), 10 Abbott (1), Ambrus 033 Andrin 1b, 1o, 2a, 2d, 2f, 3, 4 (XII – 5, 6; S5, S9, S10, S12, S19), 5, 7a (5,6), 7c (S9 – 10, S12, S19), 8a, 8b, 8c, 8d, 9a (M1, M12), 10 Abbott (2), Ambrus, Panel (4) 034 Ethion 1a, 2a, 2c, 2d, 2f, 3, 4 (XII – 5,6; S5, S9, S10, S12, S19), 7a (3, 5, 6), 7c (S8, S9, S13, S17, S19), 8e, 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Stijve(7) 035 Etoxyquin 2d, 2e, 4 (XII – 6; 500) Winell 036 Fenclophos 1a, 2a, 2c, 2d, 2f, 3, 4 (XII – 3, 5, 6; S8-10, S13, S17, S19), 7a (3, 5, 6), 7c (S8 – 10, S13, S17, S19), 8b, 8e, 9a (M2, M5), 10 Abbott (1), Ambrus, Panel (7, 8), Stijve (7) 037 Fenitrothion 2a, 2c, 2d, 2f, 3, 4 (XII – 3, 6; S5, S8, S13, S17, S19; 58), 6a, 8e, 9a (M2, M5), 10 Abbott (1), Ambrus, Bottomley, Desmarchelier, Panel (7, 8), Stijve (7) 038 Fensulfothion 2c, 2d, 2e, 3, 4 (XII – 3, 6; S8, S13, S16, S17, S19), 6a, 7a (3, 6), 7c (S8, S13, S16, S17, S19), 9a (M2, M5), 10 039 Fenthion 2c, 2d, 2e, 2f, 3, 4 (XII – 3, 6; S5, S8, S13, S16, S17, S19), 7a (3, 6), 7c (S8, S13, S16, S17, S19), 8e, 9a (M2, M5), 10 Abbott (1), Ambrus, Hill 040 Fentin 2e, 4 (S24; 55A, 55B) 6e Baker, PG (1) 041 Folpet 2a, 2c, 2d, 3, 4 (XII – 6; S8, S12, S19, S20, 91, 91A), 7a (6), 7b, 7c (S8, S12, S19, S20), 9a (M1, M12), 10 Ambrus, Baker, PB (1), Buettler, Gilvydis, Pomerantz 042 Fomothion 2d, 4 (XII – 6; S5, S8, S19, 236A), 6b, 7a (6), 7c (S8, S19), 9a (M2, M5, M12), 10 Abbott (1), Ambrus 043 Heptaclo 1a, 1n, 1o, 2a, 2d, 2f, 3, 4 (XII – 1, 5, 6; S 1 – 4, S8 – 10, S12, S19), 5, 6c, 6d, 7a (5, 6), 7c (S8-10, S12, S19), 8a, 8b, 8c, 8d, 9a (M1, M12), 10 Abbott (2) Ambrus, Stijve (2,3), Veierov 044 Hexaclobenzen 1k, 1o, 2a, 2d, 3, 4 (XII – 1, 5, 6; S9, S10, S12, S19), 5, 6c, 7a (1, 5, 6), 7c (S9, S10, S12, S19), 8a, 8b, 8c, 8d, 9a (M1, M12), 10 Ambrus, Panel (4), Stijve (2,3), Veierov, Zimmerli 045 Hydro xyanua 2e, 4 (11), 9b Darr 046 Hydro phosphit 2e, 4 (13), 9a (M8) Scudamore (2) 047 Bromua vô cơ 2e, 4 (S18; 149), 7c (S18), 9b Panel (2), Roughan, Stijve (1,4), VanWees 048 Lindan 1a, 1o, 2a, 2d, 3, 4 (XII – 5, 6; S 1 – 5, S8 – 10, S12, S19), 5, 7a (5, 6), 7c (S8 – 10, S12, S19), 8a, 8b, 8c, 8d, 9a (M1, M12), 10 Abbott (2), Ambrus, Panel (4), Stijve (2,3), Veierov 049 Malathion 1a, 2a, 2c, 2d, 2f, 3, 4 (XII – 3, 5, 6; S5; S8; S10, S13, S17, S19; 72), 7a (3, 5, 6), 7c (S8, S10, S13, S17, S19), 8a, 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Bottomley, Desmarchelier, Panel (1, 3, 7, 8), Stijve (7). 050 Mancozeb See 105: dithiocarbamates 051 Methidathion 2a, 2c, 2d, 2e, 3, 4 (XII – 6; S5, S8, S13, S19; 232), 6b, 7a(6), 7c (S8, S13, S19), 9a (M2, M5, M12), 10 Ambrus 052 Metylbromide 9a (M8) Mestres (2), Panel (5) 053 Mevinphos 2c, 2d, 2f, 3, 4 (XII – 3, 6; S5, S8, S13, S17, S19; 93), 7a (3, 6), 7c (S13, S17, S19), 9a (M2, M5, M12), 10 Abbott (1), Ambrus 054 Monocrotophos 1p, 2c, 2d, 2e, 2f, 4 (XII – 6; S19), 7c (S19), 9a (M2, M5), 10 Ambrus 055 Omethoate 1p, 2c, 2d, 4 (XII – 6; S13, S17, S19; 236), 5, 7a (6), 7c (S13, S17, S19), 9a (M2, M5), 10 Abbott (1), Panel (3) 056 Othophenylphenol 2d, 2e, 10 Farro, Kitada, Lord, Mestres (1), Player, Pyysalo 057 Paraquat 2e, 4 (134), 6d, 7a Calderbank (1), Khan, King, lott 058 Parathion 1a, 2a, 2c, 2d, 2f, 3, 4 (XII – 3, 4, 5, 6; S5, S8, S10, S13, S17, S19; 87A, 87B), 7a (3, 4, 5, 6), 7c (S8, S10, S13, S17, S19), 8e, 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Panel (3) 059 Parathion-metyl 1a, 2a, 2c, 2d, 2f, 3, 4 (XII – 3, 5, 6; S5, S8, S13, S17, S19; 88A, 88B), 7a (3, 5, 6), 7c (S8, S13, S17, S19), 8e, 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Panel (3) 060 Phosalon 2a, 2c, 2d, 2e, 3, 4 (XII – 5, 6; S8, S19), 5, 6a, 7a (5, 6), 7c (S8, S19), 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Stijve (7) 061 Phosphamidon 2c, 2d, 2e, 3, 4 (XII – 6; S5, S13, S19), 7a (5, 6), 7c (S8, S19), 9a (M2, M5, M12), 10 Abbott (1), Ambrus, Sijve (7) 062 Piperonyl butylat 2e, 4 (XII – 6; S19, S22; 163), 7a (6), 7c (S19), 9b Krause (2) 063 Pyrethrins 2a, 2d, 2e, 4 (XII – 6; S19, S22), 6b, 7a (6), 7c (S19), 9b 064 Quitiozen 2a, 2d, 2f, 3, 4 (XII – 4, 5, 6; S8, S9, S12, S19; 99), 7a (4, 5, 6), 7c (S8, S19, S12, S19), 9a (M2, M5, M12), 10 065 Thiabendazol 2a, 2e, 2h, 4 (XII – 6; 256A, 256B), 7d (256A, 256B), 8g, 9a (M3), 10 Farrow, Kitada, Mestres (1,3), Rajzman, Yamada 066 Trichlorfon 2c, 2d, 2e, 2f, 3, 4 (XII – 6; S5, S13, S19, 112), 5, 7a (6), 7c (S13, S19), 8e, 9a (M2, M5, M12) Abbott (1), Ambrus, Bottomley 067 Xyhexatin 2e, 4 (S24), 6a, 9b Moellhoff (2) 068 Azinphos – etyl 2c, 2d, 4 (XII – 3, 5, 6; S5, S8, S13, S17, S19; 62, 62A), 7a (3, 5, 6), 7c (S8, S13, S17, S19), 9a (M2, M5, M12), 10 Abbott (1), Ambrus 069 Benomyl See 072: carbendazim 070 Bromopropylat 2a, 2d, 4 (XII – 6; S19), 7a (6), 7c (S19), 9a (M12), 10 Stijve (6) 071 Campheclo 2a, 2d, 4 (XII – 5, 6, S9, S19), 7a (5, 6), 7c (S9, S19) Stijve (2) 072 Carbendazim 2e, 2h, 4 (261, 378), 6a, 6d, 7d (261, 370, 378), 9a (M3), 1- Ambrus, Farrow, Mestres (3), VanHaver 073 Demeton – S – metyl 2d, 2f, 4 (XII – 6; S5, S13, S16, S19), 7a (6), 7c (S13, S16, S19) 9a (M2, M5), 10 Abbott (1), Ambrus, Hill, Wagner 074 Disulfoton 2a, 2c, 2d, 2e, 2f, 3, 4 (XII – 3, 6; S5, S8, S13, S16, S17, S19), 7a (3, 6), 7c (S8, S13, S16, S19, S19), 8e, 9a (M2, M5) Abbott (1), Ambrus, Panel (7) 075 Propoxur 1e, 2d, 2g, 4 (XII – 6; S19, S25; 216), 6a, 7a (6), 7c (S19), 9a (M2, M13), 10 Ambrus, Brauckhoff, Chaput, Lawrence (1) 076 Thiometon 2d, 4 (XII – 6; S13) 6b, 7a (6), 7c (S13), 9a (M2, M5, M10, M12) Abbott(1), Ambrus, Hill 077 Thiophanat – metyl 2e, 2h, 4 (261), 5, 7d (261, 370, 378), 9a (M2, M5, M10) Ambrus, Mestres (3), VanHaver 078 Vamidothion 4 (XII – 3, 6; S17), 6a, 7a (3, 6), 7c (S17), 9a (M2, M5, M10) 079 Amitrol 2e (4a), 7d (4a) Galoux, Lokke (1), v.d.Poll 080 Chinomethionat 2d, 2e, 4 (XII – 6; S19; 189), 7a (6), 7c (S19), 9b, 10 Ambrus, Francoeur, Karause (1), Tjan 081 Clorothalonil 2a, 2d, 3, 4 (XII – 6; S19), 6b, 7a (6), 7c (S19), 9a (M1, M12), 10 Ambrus, Lokke (2) 082 Diclofluanit 2a, 2d, 4 (XII – 6; S8, S12, S19; 203; 203A, 203 – (371)), 7a (6), 7c (S8, S12, S19), 7d (203, 371; 203A, 371A), 9a (M1, M12), 10 Ambrus, Lokke (2), Brennecke (4) 083 Dicloran 2d, 3, 4 (XII – 6; S19), 7a (6), 7c (S19), 9a (M1), 10 Ambrus 084 Dodin 2e Newsome (1) 085 Fenamiphos 2c, 2d, 2e, 4 (XII – 6; S8; S16; S19), 7a(6), 7c (S6, S19), 9a (M5, M12) Hill 086 Pirimiphos – metyl 2a, 2c, 2d, 2e, 4 (XII – 6; S8; S19; 476), 6b, 7a (6), 7c (S8, S19), 9a (M2, M5, M12), 10 Ambrus, Desmarchelier, Panel (7, 8), Stijve (7) 087 Dinicap 2a, 2d, 2e, 4 (XII – 6; S19; 68), 7a (6), 7c (S19), 9a (M9), 9b Ambrus 088 Leptophos Withdrawn 089 Sec-butylamin 2e, 6b Day, Hunter, Scudamore (1) 090 Clopyrifos – metyl 2c, 2d, 4 (XII – 6; S8, S19), 7a (6), 7c (S19), 9a (M2, M5), 10 Ambrus, Bottomley, Desmarchelier, Panel (4, 8), Stijve (7) 091 Xynofenphos 2d, 4 (XII – 6; S8; S19), 7a (6), 7c (S19), 9a (M2, M5), 10 092 Dementon 2c, 2d, 2e, 4 (XII – 6; S5, S16), 7a (6), 7c (S16), 9a (M5) Abbott (1) 093 Boiresmethrin 6c, 6d, 9a M(11) Baker, PG (2), Bottomley 094 Methomyl 1q, 2d, 2e, 2g, 4 (299), 6a, 7b, 9a (M13) Ambrus, Chaput 095 Axephat 1p, 2c, 2d, 2e, 4 (XII – 6; S19; 358), 6a, 7a (6), 7b, 7c (S19), 9a (M5, M12), 10 096 Carbofuran 1e, 1q, 2e, 2g, 3, 4 (XII – 6; S25), 6a, 7a (6), 7d (658, 344), 9a (M13), 10 Ambrus, Brauckoff, Chaput, Lawrence (1), Moellhoff (1), Leppert (1, 2) 097 Cartap Official Gazette 098 Dialifos 2a, 2d, 2e, 4 (XII – 6; S19; 281), 7a (6), 7c (S19), 9a (M2, M5, M12), 10 099 Edifenphos 2d, 4 (XII – 6; S19), 7a (6), 7c (S19) 100 Methamidophos 1p, 2c, 2d, 3, 4 (XII – 6; S19; 358, 365), 5, 6a, 7a (6), 7c (S19), 9a (M5), 10 101 Pirimicarb 2d, 4 (XII – 6; S19; 309), 5, 6a, 7b, 10 102 Maleic 1m, 4 (297) Lane, Newsome (3) 103 Dainozit 2c, 2d, 4 (XII – 6), 7a (6), 9a (M2, M5, M12), 10 Ambrus 104 Dithiocarbamat 2e, 6b Allen (2), Newsome (5), Saxton, Wright, Conditt 105 Dithiocarbamat 2e, 3, 4 (S15, S21), 7c(S2), 9b Newsome (2), Panel (6), Ptt 106 Ethephon 2e, 9b Cochrane 107 Ethifencarb 2d, 2g, e (S25; 393), 9a (M13); 10 108 Etylen thioure lj, 4 (389), 7b, 9b Panel (9), Hirvi, Otto, Rosenberg 109 Fenbutatin oxit 2e, 4 (S24), 6d Sano 110 Imazalil 2d, 2e, 4 (XII-6; S19) 111 Iprodion 2c, 2d, 2e, 4 (XII-6; S8, S19, 419), 6e, 7a (6), 7c (S8, S19), 9a (M1, M12), 10 112 Phorat 2a, 2c, 2d, 2e, 4 (XII-3, 6; S8, S13, S16, S17, S19), 7a (3, 6), 7c (S8, S13, S16, S17, S19), 9a (M2, M5) Abbott (1), Ambrus, Hill 113 Propargit 2a, 2d, 3, 4 (XII-6), 6a, 7a (6), 9a (M1) Ambrus 114 Guazatin Kobayashi 115 Tecnazen 2a, 2d, 2e, 3, 4 (XII-6; S8, S12, S19; 108), 7a (6), 7c (S8, S12, S19), 9a (M1), 10 116 Triforin 2e, 4 (338), 6d, 9b Bourke, Newsome (4) 117 Aldicarb 1q, 2e, 2g, 4 (XII-6; 250), 6a, 7a, (6), 7c (S8, S12, S19), 9a(M1), 10 118 Xypermethrin 2a, 2d, 4 (XII-6; S19, S23), 6g, 7a(6), 7c(S19), 9a(M11), 10 Ambrus, Baker, PG (2), Bottomley 119 Fenvalereta 2a. 2d. 2e, 4(XII-6; S19. S23). 6g. 7a(6). 7c(S19). 9a(M11). 10 Ambrus. Baker, PG (2), Bottomley 120 Permethrin 2a, 2d, 4(XII-6; S19, S23), 6g, 7a(6), 7c(S19), 9a(M11), 10 Ambrus, Baker PG (2), Bottomley 121 2,4,5-T 2b, 4(XII-6; 105), 6c, 7a(6), 9a(M6) Ebing, Lokker (3), Specht (1) 122 Amitraz 2e, 4 (XIỈ-6), 7a (6), 9b 123 Etrimtos 2a, 2c, 2d, 4 (XII-6; S8, S19), 7a(6),7c(S19), 6c, 9a (M2, M5) Ambrus, Bottomley, Panel (7,8) 124 Mecarbam 2c, 2d, 4 (XII-6; S19), 6b, 7a (6), 7c (S19), 9a (M2), 10 Abbott 125 Methacrifos 4 (XII-6), 7a (6) Ambrus, Desmarchelier, Panel (7, 8) 126 Oxamyl 1q, 2e, 2g, 4 (XII-6: 441), 5, 7a (6), 7d (441), 9a (M13), 10 Arnbrus 127 phenophrin 4 (XII-6), 7a (6), 9 Baker, PG (2), Bottomley 128 phenthoat 2a, 2c, 2d, 4 (XII-6; S19), 6b, 7a (6), 7c (S19), 9a (M11), 10 Ambrus 129 azocyclolin 4(S24) Moellhoff (2) 130 Diflubenzuron 2e, 6d, 6f, 9a (M4) Austin 131 Isofenphos 2a, 2c, 2d, 2 e, 4 (XII-6; S8), 7a (6), 9a (M5, M12), 10 132 Methiocarb 1q, 2d, 2g, 4 (79, 79a), 9a (M2, M13), 10 Chaput 133 Triadimefon 2d, 2e, 4 (XII-6; S8, S19; 425- (605)), 7a (6), 7c (S8, S19), 7d (613,425,605), 10 Ambrus, Brennecke (2), Ragab 134 Aminocarb 2d, 10 Brauckhoff 135 Deltamethrin 2a,2d, 4 (XII-6; S19, S23), 6g, 7a (6), 7c (S19), 9a (M11) Ambrus, Beker, PG (2), Bottomley 136 Procymidone 2a, 2d, 2e, 4 (XII-6; S8, S19), 7a (6), 7c (S8, S19), 10 137 bendiocarb 2d, 2g, 6d,4 (XII-6), 7a(6), 9a (M2, M13) Ambrus 138 Metalaxyl 2c, 2d, 2e, 4 (XII-6; S8, S19; 517), 7a (6), 7b, 7c (S19), 9a (M4), 10 Ambrus 139 Butocarboxim 2g, 9a (M13) Aharonson, Brauckhoff, Li, Musskat 140 Nitrofen 1a, 2a, 2d, 2e, 4 (XII-6; S19; 340), 6d, 7a (6), 7b, 7c (S19) Adler, Ambrus, Yu 141 Phoxim 2d, 4 (XII-6; S19, 307), 7a (6), 7c (S19), 9a (M2, M12) Ambrus 142 Prochloraz 2d Maclaine Pont, Somerville 143 Triazopho 2c, 2d, 4 (XII-4,6; S8, S19, 501), 6d, 7a (6), 7c (S19), 9a (M2, M5, M12), 10 Ambrus 144 Bitertanol 2d, 4 (XII-6: S19, 613; 613A), 7a (6), 7c (S19), 7d (613A, 426, 605) 9a (M12) Brennecke 145 Carbusulfan 2d, 4 (658 - (344)) Leppeert (1,2) 146 Xyhalothrin 2d, 6g 147 Methopren 2e, 6d 148 propamocarb Gentile 149 ethoprofos 2c, 2d, 2e, 4 (XII 6; S6, S19) 7a (6), 7b, 7c (S19), 9a (M2, M5) 150 Propylen thioure Lembo, Nitz 151 Dimethipin 2e 152 Flucythrinat 2d, 2e 153 Pyrazophos 2d, 4 (XII-4,6; S8, S19; 328), 8d, 7a (6), 7b, 7c (S19), 9a (M2, M5, M12), 10 154 Thiocarb 2g 155 benalaxyl 4 (S19) 156 clofentezin Bichi, Snowdon 157 xyfluthrin 2d, 4(S23), 9a(M11) 158 Glyphosat 2e, 4 (405), 6 h, 7d (405) 9b Cowell, Tuinstra, Wigfield 159 Vinclozolin 2a, 2d, 4 (XII 6; S8, S19; 412), 9a (M1, M12) 160 Propiconazol 2d, 4 (S19; 624), 7d (624) 161 Paclobutrazol 2d Reed 162 lolylfluanit 2d, 4 (XII -6; S8; S19; 371; 203- (371)), 7c (S8, S19), 7d (203A, 371A), 9a (M1.M12) Brennecke (4), Specht (2), Anderson 163 Anilazin 4 (Xll-6; S19: 186), 7c (S19), 7d (186) 2d, 2e Lawrence (2), Brennecke(5) 164 Demeton-S-metyl- su lphon 4 (XII-6; S16, S19), 7c (S16), 9a (M5), 2d, 2e Adersson, Thomton, Wagner 165 Flusilazol 2d, 4(S19) (only parent compuund) 166 Oxydemeton-metyl 4 (XII-6; S16, S19), 7c (S16), 9a (M5) 2c, 2d,2e Thomton, Wagner 167 Terbufos 4 (S8; S19), 9a (M5) (only parent compuund) 2c, 2d,2e Westcott 168 Triadimenol 4 (XIl-6, S19, 425 - (605)) 7a (6), 7c (S19), 9a (M12), 2d Allmendinger, Andersson, Brennecke (2), Ragab, Mendes 169 Xyromazin 2e Cabras, Bardalaye 170 Hexaconazol 2d, 11 171 Profenofos 2c, 2d, 2e Andersson 172 Bentazon 2e Cessna, Hogendoorn 173 Buprofezin Nishizawa JAOAC accepted for publication, Ishii (1) 174 Cadusafos 2d 175 Glufosinat- mamonium 4(651), 7d (651) 176 Hexathiazox 2e 177 Abemectin 2e Prabhu, Vuik 178 befentrin 2a, 2e 179 xycloxydim 180 dithianon Beker, Kadenczki 181 Myclobutanil 2e 182 Penconazol 2d 183 Propham 2d, 4(s11), 6e (343 - 350) 7c (S11) 184 Etofenprox 185 Fenpropathrin 2, 7 d (S23) Nakamura 186 Metiram See 105: dithiocarbamater 187 Clethodim 188 Fenpropimorph Kadenczki, v, Z oonen, Dieckmann, Lafuente (1,2), Tadeo 189 Tebuconazol 7c (S19) Brennecke (6), Allmendinger, Maasfeld 190 Teflubenzuron 191 Tolcofos-metyl 4 (S19), 7a (6), 7c (S19), 7d (S8) Becker, Ishii, Stan, Philips 3. Tài liệu tham khảo 3.1. Các bài báo chung Các bài báo hoặc sách liên quan đến các vấn đề về phân tích dư lượng thuốc bảo vệ thực vật (xem thêm sổ tay đã được viện dẫn trong đoạn 3.2). Ambrus, A. & Thier, H.-P., Application of multi-residue procedures in pesticides residues analysis, Pure Appl. Chem., 58, 1035-1062 (1986). Beck, H., Untersuchungsmethoden zur Bestimmung der Ruckstande von Chlorkohlenwasserstoff- Pestiziden in oder auf Lebensmitteln, Bundesgesundheitsblatt, 17, 269-274 (1974). Becker, G. et al., Dunnschichtchromatographie in der Ruckstandsanalytik von Pflanzenschutzmitteln und deren Metaboliten, Verlag Chemie VCH, Weinheim, FRG (1987). Burke. J.A., The interlaboratory study in pesticide residue analyses, in: Advances in Pesticide Science, H. Geissbuehlor (edit.), Pergamon Press, Oxford, UK, 633-642 (1979). Carl, M., Internal laboratory quality control in the routine determination of chlorinated pesticides, in: Advances in Pesticide Science, H. Geissbuehler (edit.), Pergamon Press, Oxford, UK, 660-663 (1979). Cochrane, W .P., Chemical derivatization in pesticide analysis, Plenum Press, New York, N.Y., USA, (1981). Egli, H., Storage stability of pesticide residues, J. Agr. Fd. Chem., 30, 861-866 (1982) Frehse. H. & Timme. G., Quantitative residue analytical reliability: beatitude through the application of latitude, Res. Revs., 73, 27-47 (1980). Gunther, F.A., Interpreting pesticide residue data at the analytical level, Res. Revs., 76, 155-171 (1980). Horwitz, W ., The role of the analyst in analytical chemistry, FDA Bylines, 4. 169-178 (1979). Horwitz, W. , The inevitability of variability in pesticide residue analysis, in: Advances in Pesticide Science. H. Geissbuehler (edit.), Pergamon Press, Oxford, UK, 649-655 (1979). Horwitz, W . et al., Quality assurance in the analysis of foods for trace constituents, JAOAC, 63, 1344 - 1354(1980). Horwitz, W ., Evaluation of analytical methods used for regulation of foods and drugs, Anal. Chem., 54, 67A-76A (1982). ISO Document ISO 5725, 2nd edit. (1986), Precision of test methods: determination of repeatability and reproducibility. IUPAC Reports on Pesticides (13), Development and evaluation of simplified approaches to residues analysis, Pure Appl. Chem., 53. 1039-1049 (1981). Moye, H.A. (edit.), Analysis of pesticide residues, Vol. 58 of: Chemical Analysis, John Wiley and Sons, New York, N.Y., USA (1981). Pesticide Residue Analysis, Health Aspects of Chemical Safety, Interim Document 14, WHO, Regional Office for Europe, Copenhagen, Denmark (1984). Safe, S . & Hutzinger, O., Mass spectrometry of pesticides and pollutants, CFC Press Inc., Boca Raton, Florida, USA (1979). Smart, N., Samples used for interlaboratory studies of methods for pesticide residues analysis in foodstuffs, Res. Revs., 96, 1-12 (1985). Steiner, E.H., Planning and analysis of results of collaborative tests, in: Statistical Manual of the AOAC, Washington, D.C., USA (1974). The Agrochemical Handbook, The Royal Society of Chemistry, The University, Nottingham, UK, (1983). Thier, H.-P. & Frehse, H., Rỹckstandsanalytik von Pflanzenschutzmitteln, Georg Thieme Verlag, Stuttgart - New York (1986). Youden. W.J., Statistical techniques for collaborative tests, in: Statistical Manual of the AOAC, Washington, D.C., USA (1974). Zweig, G. (edit.), Analytical methods for pesticides, plant growth regulators and food additives Academic Press, New York - San Francisco - London, Vol. XIV and XV (1986). 3.2. Sổ tay (1) Official Methods of AOAC INTERNATIONAL, 16th edition (1995) (a) 970.52 (b) 976.23 (d) 977.18 (e) 975.40 (j) 978.16 (k) 977.19 (I) 960.43 (m) 963.24 (n) 983.21 (o) 984.21 (p) 985.22 (q) 985.23 (2) Pesticide Analytical Manual, Food and Drug Administration, Washington, D.C., USA 2nd edition 3rd edition (a) Vol. I Table 201-A and sections, 211.1, 212.1, 231.1, 232.1 and 252 Nonfat foods: Section 303 Fatty foods: Section 304, E1-E5+C1-C4 (b) Vol. I, Table 201-D and section 221.1 Section 402 (c) Vol. I, Table 201-H and section 232.3 [method not in PAM | 3rd edition] (d) Vol. I, Table 201-I and section 232.4 Section 302 E1-E4, no cleanup (e) Vol. II, Method under compound name (when in this reference several methods have been given, they are generally listed in order of preference) (f) Vol. I, Table 651-A and sections 650 and 651 [not in PAM | 3rd edition] (g) Vol. I, Table 242.2-1 and section 242.2 Section 401 (h) Vol. I, Section 242.3 Section (3) Manual on Analytical Methods for Pesticide Residues in Foods, Health Protection Branch, Health and Welfare Canada, Ottawa, Ont., Canada (1985) (available in English and French) (4) Methodensammlung zur Rỹckstandsanalytik von Pflanzenschutzmitteln, 1.- 11. Lieferung, VCH Verlagsgesellschaft, Weinheim, FRG (1991) (the numbers in parentheses refer to the numbers of the methods in this manual; methods preceeded by "S" are multi-residue methods; the manual is also available in English, see ref. 7). (5) Laboratory Manual for Pesticide Residues Analysis in Agricultural Products, compiled by R.B. Maybury, Pesticide Laboratory, Food Production and Inspection Branch, Agriculture Canada, Ottawa, Ont., Canada (1984) (available in English and French). (6 ) Zweig, G. (edit.), Analytical Methods for Pesticides, Plant Growth Regulators , Academic Press, New York - San Francisco - London (a) Vol. VII (1974) (b) Vol. VIII (1976) (c) Vol. IX (1977) (d) Vol. X (1978) (e) Vol. XI (1980) (f) Vol. XII (1982) (Lawrence J.F. Editor) (g) Vol. XIII (1984) (Zweig. G. and Sherma, J. Editors (h) Vol. XVI (1988) (Sherma, J. Editor) (7) Manual of Pesticide Residue Analysis, Deutsche Forschungsgemeinschaft, VCH Verlagsgesellschaft, Weinheim, FRG (1987) (English translation of ref. 4) (a) Vol. I, Section Clean-up Methods (the numbers in parentheses refer to the numbers of the clean-up methods in this volume) (b) Vol. I, Section Individual Pesticide Residue Analytical Methods (c) Vol. I, Section Multiple Residue Analytical Methods (the numbers in parentheses refer to the numbers of the multi-residue methods in this volume) (d) Vol.II (1992). (8) Chemistry Laboratory Guidebook, United States Department of Agriculture, Food Safety and Inspection Service, Science Program, Washington, D.C., USA (a) Section 5.001 (b) Section 5.002 (c) Section 5.003 (d) Section 5.004 (e) Section 5.006 (f) Section 5.005 (g) Section 5.050 (9) Analytical Methods for Residues of Pesticides in Foodstuffs, P.A. Greve (edit.), 5th edition. Government Publishing Office, The Hague, Netherlands (1988) (a) Part I: Multi-residue Methods (the numbers in parentheses refer to numbers of themulti-residue methods in this volume) (b) Part II: Special Methods (methods given under compound name) (10) Materials and Methods Used for Pesticide Residues Monitoring in Sweden, Var Foda, 38, Suppl.2, 79-136 (1986) (11) Comprehensive Analytical Profiles of Important Pesticides (Modern methods for pesticides analysis) e.d. J. Sherma & T Cairns 1992. 3.3. Bài báo cụ thể The numbers in italics after the references refer to the compounds, indicated by their CCPR- number, to which the methods involved apply. Abbott (1), D.C. et al., Pest. Sci., 1. 10-13 (1970) Pesticide residues in the total diet in England and Wales, 1966-1967; Part III: Organophosphorus pesticide residues in the total diet 2, 4, 5, 11, 14, 22, 25, 27, 28, 34, 36 , 37, 39, 42, 49, 53, 55, 58, 59, 60, 66, 68, 73, 74, 76, 92, 112, 124 Abbott (2). D.C. et al., J. Chromatog., 16, 481-487 (1964) Some observations on the thin-layer chromatography of organochlorine pesticides 1, 21, 32, 33, 43, 48 Adachi, K. et al., JAOAC, 67, 798-800 (1984) Simple analytical method for organophosphorus pesticide determination in unpolished rice, using removal of fats by zinc acetate 22, 27, 37, 49, 58, 128 Adler, I.L. & Wargo Jr, J.P., JAOAC, 58, 551-553 (1975) Determination of residues from the herbicide 2,4-dichloro-1-(4-nitrophenoxy)-benzene in rice and wheat by electron-capture gas-liquid chromatography 140 Aharonson, N. & Muszkat. L., Z . Lebensm. Unters. Forsch., 180, 96-100 (1985) Direct gas chromatographic determination of the two isomeric insecticides, aldicarb and butocarboxime and their toxic metabolites: application to residue analysis in crops and leaves 117, 139 Allen (1), J.G. & Hall. K.J., J. Agr. Fd. Chem., 28, 255-258 (1980) Methods for the determination of diphenylamine residues in apples 30 Allen (2), J.G., Pest. Sci., 11,347-350(1980) Daminozide residues in sWeet cherries, and their determination by colorimetric and gas-liquid chromatographic methods 104 Allmendinger H. Pflanzensch. Nachr. Bayer, 44, 5-66 (1991) A method for determining residues of the fungicides folicur and Bayfidan in plant material and soil by gas chromatography. 168, 189 Ambrus, A. et al., JAOAC, 64, 733-768 (1981) General method for determination of pesticide residues in samples of plant origin, soil, and water 1, 2, 4, 6, 7, 8, 14, 17, 21, 22, 25, 27, 32, 33, 37, 39, 41, 42, 43, 48, 49, 51, 53, 54, 58, 59, 60, 61, 66, 73 , 74, 75 , 76 , 77 , 80 , 81 , 82 , 83 , 86, 87 , 94, 96, 101 , 103 , 112, 113 , 117, 118 , 119 , 120 , 123 , 128 , 133 , 135 , 137 , 140, 141 , 143, 159 Andersson, A and Ohlin, B. Vồr Fửda 38, 79-109 (1986) A capillary gaschromatographic multiresidue method for the determination pesticide residues in fruit and vegetables. 162, 164, 168, 171 Austin, D.J. & Hall, K.J. Pest. Sci., 12, 495-502 (1981) A method of analysis for the determination of binapacryl, bupirimate and diflubenzuron on apple foliage and fruit, and its application to persistence studies 3,130 Baker, P.B. (1) & Flaherty. B., Analyst, 97, 713-718 (1972) Fungicide residues; Part II: The simultaneous determination of residues of folpet, captan and captafol in selected fruits by gas chromatography 6, 7, 41 Baker, P.B. (2) & Hoodless, R.A., Analyst, 98, 172-175 (1973) Fungicide residues; Part III: The determination of binapacryl in selected fruits by gas chromatography 3 Baker, P.G. (1) et al., Analyst. 105, 282-285 (1980) Fungicide residues; Part VII: Determination of residues of fentin in vegetables and cocoa products by spectrofluorimetry 40 Baker, P.G. (2) & Bottomley, P., Analyst, 107, 206-212 (1982) Determination of residues of synthetic pyrethroids in fruit and vegetables by gas-liquid and high-performance liquid chromatography 93, 118, 119, 120, 127, 135 Baker, P.G. & Clarke, P.G., Analyst 109, 81-83 (1984) Determination of residues of dithianon in apples by HPLC Bardalaye, C , Wheeler, W.B. & Meister C .W. JAOAC 70, 455-457 (1987) Gas chromatographic determination of cyromazine and its degradation product melamine in chinese cabbage. 169 Becker, G., Schug, P., Deutsche Lebensm. Rundschau 86, 239-242 (1990) Eine miniaturmethode zur schnellen Bestimmung von Pestizidrỹckstonden in pflanzlichen Lebensmitteln. 191 Bichi, C . et al. Pestic. Sci. 30. 13-19 (1990) Simultaneous determination of clofentezine, fenoxycarb and hexthiazox by HPLC on apples, pears and their pulps 156 Bottomley, P. & Baker, P.G., Analyst, 109, 85-90 (1984) Multi-residue determination of organochlorine, organophosphorus and synthetic pyrethroid pesticides in grain by gas-liquid and high-performance liquid chromatography 1, 4, 21, 22, 25, 37, 44, 49, 61, 66, 86, 90, 93, 118, 119, 120 . 123, 127, 135 Bourke, J.B. et al., J. Agr. Fd. Chem., 25, 36-39 (1977) Residues and disappearance of triforine from various crops 116 Brauckhoff, S . & Thier, H.-P., Z . Lebensm. Unters, Forsch., ; 184, 91-95 (1987) Analysenmethode fỹr Rỹckstọnde von Methylcarbamat-lnsecticiden in pflanzlichen Lebensmitteln 8, 75, 94, 96, 101, 107, 117, 132, 134, 137, 139 Brennecke (1), R., Pflanzensch. Nachr. Baycr, (Engl. edit.)38, 33-54 (1985) Method for gas-chromatographic determination of residues of Baycor fungicide in plant material, soil and Water (Engl. edit.: 38, 33-54 (1985)) 144 Brennecke (2), R., Pflanzensch. Nachr. Bayer, 37, 68-93 (1984) Method for gas-chromatographic determination of residues of Bayleton and Bayfidan fungicides in plant material, soil and Water (German edit.: 37, 66-91 (1984)) 133, 168 Brennccke (3), R., Pflanzensch. Nachr. Bayer, 41,113-131 (1988) Method for the determination of residues of the fungicide Baycor in plant material and beverages by high pressure liquid chromatography with fluorescence detection (German edit.: 41, 113-135 (1988)) 144 Brennecke (4), R., Pflanzensch. Nachr. Bayer, 41, 137-174 (1988). A method for the determination of residues of the fungicides Euparen and Euparen M in plant material and beverages by gaschromatography (German edit. 41. 136-172 (1988)). 82, 162 Brennecke (5), R., Pflanzensch. Nachr. Bayer. 38, 11-32 (1985) Method for gas-chromatographic determination of Dyrene residues in plant material, soil and water (German edit.: 38, 11-32 (1985)). 163 Brennecke (6), R., Pflanzensch. Nachr. Bayer, 42, 223-284 (1989) German edit. A method for determining residues of the fungicides Euparen, Euparen M and Folicur in plant material and beverages by gaschromatography. 189 Buettler, B. & Hoermann, W.D., J. Agr. Fd. Chem., 29, 257-260 (1981) High-pressure liquid chromatographic determination of captan, captafol, and tolpet residues in plant material 6, 7, 41 Cabras, P., Meloni, M., & Spaneddal, J. Chromatogr. 505, 413-416 (1990) High-performance liquid chromatographic separation of cyromazine and its metabolite melamine. 169 Calderbank (1), A. & Yuen, S.H., Analyst, 90, 99-106 (1965) An ion-exchange method for determining paraquat residues in food crops 57 Calderbank (2), A. & Yuen, S.H., Analyst, 91, 625-629 (1966) An improved method for determining residues of diquat 31 Cessna, A.J. J.Agr.Fd.Chem. 33, 108-110 (1985) Gas chromatograohic analysis of the herbicide bentazone in leeks 172 Chaput, D. JAOAC, 71, 542-546. (1988) Simplified multiresidue method for liquid chromatographic determination of N-methylcarbamate insecticides in fruits and vegetables. 8, 75, 94, 96, 117, 132 Cochrane, W.P. et al., JAOAC, 59, 617-621 (1976) Gas-liquid chromatographic analysis of ethephon and fenoprop residues in apples and their decline before and after harvest 106 Conditt, M et al, JAOAC, 71, 735-739 (1988). Gas chromatography/mass spectrometric determination of daminozide in high protein food products. 104 Cowell, J.E., Kunstman, J.L., Nord, P.J., Steinmetz, J.R. and Wilson, G.R. J. Agric. Fd. Chem. 34, 955- 960(1986) Validation of an analytical method for analysis of glyphosate and Metabolite: An interlaboratory study 158 Daft, J.L., JAOAC. 66, 228 (1983) Gas chromatographic determination of fumigant residues in stored grains, using isooctane partitioning and dual column packings 10, 23, 24 Day, E.W. et al., JAOAC, 51. 39-44 (1968) Determination of sec-butylamine residues in fruit 89 Desmarchelier, J. et al., Pest. Sci., 8, 473-483 (1977) A collaborative study of residues on Wheat of chlorpyrifos-methyl, fenitrothion, malathion, methacrifos and pirimiphos-metyl 37, 49, 86, 90, 125 Dieckmann H. et al, Fresenius J. Anal. Chem. 345, 784-786 (1993) Simultaneous determination of fenpropimorph and the corresponding metabolite fenpropimorphic acid in soil. 188 Ebing, W. et al., Lebensm. gerichtl. Chem., 39. 126-130 (1985) Zur Ruckstandsanalytik von Phenoxyalkancarbonsoure-Herbiziden in Getreidekornern 20 , 121 Farrow, J.E. et al., Analyst, 102. 752-758 (1977) Fungicide residues; Part VI: Determination of residues of post-harvest fungicides on citrus fruit by high-performance liquid chromatography 29 , 56 , 65 , 72 Francoeur, Y. & Mallet, V., JAOAC, 59, 172-173 (1976) Determination of quinomethionate (6-methylquinoline-2,3-diyldithiocarbamate) residues in crops by in situ fluorimetry 80 Galoux, M. et al.. JAOAC, 65, 24-27 (1982) Colorimetric determination of 3-amino-1,2,4-triazole in grain or meal 79 Gentile, I.A. & Passera. E., J. Chromatog., 236, 254-257 (1982) Separation and detection of propamocarb by thin-layer chromatography 148 Gilvydis, D.M. & Walters, S.M., JAOAC, 67, 909-912 (1984) Determination of captan, folpet, and captafol in fruits and vegetables, using two multiresidue methods 6 , 7 , 41 Heikes, D.L., JAOAC, 68, 431-436 (1985) Purge and trap method for determination of ethylene dibromide in table-ready foods 23 Hill, A.R.C. et al., Analyst, 109, 483-487 (1984) Organophosphorus sulphides, sulphoxides and sulphones; Part I: Determination of residues in fruit and vegetables by gas-liquid chromatography 38, 39, 73, 74, 76, 85, 112 Hirvi, T. et al., J. Agr. Fd. Chem., 27, 194-195 (1979) A glass capillary gas-liquid chromatography method for determining ethylenethiourea Without derivatization 108 Hogendoorn, E.A. and Goewie, C.E. J. Chromatogr. 475, 432-441 (1989) Residue analysis of the herbicides cyanizine and bentazone in sugar maize and surface water using high-performance liquid chromatography and an on-line clean-up column-sitching procedure 172 Hunter, K. & Lindsay, D., Pest. Sci., 12, 319-324 (1981) High-pressure liquid chromatographic determination of sec-butylamine residues in potatoes 89 Ishii, Y. (1) et al., J. Pest. Sci., 15, 205-209 (1990) Clean up procedure for determination of pesticide residues in crops using charcoal - Florisil mini column Ishii, Y. (2) et al., J. Pest. Sci. 15, 231-236 (1990) Residue analysis of organochlorine pesticides by GC equipped with a Hall electrolytic conductivity detector (Halogen mode) 191 Kadenczki, L., et al, JAOAC 75, 53-61 (1992) Column extraction of residues of several pesticides from fruits and vegetables: A simple multi residue analysis method Khan, S.U., Bull. Envir. Cont. Tox., 14, 745-749 (1975) Determination of paraquat residues in food crops by gas chromatography 57 King, R.R., J. Agr. Fd. Chem., 26, 1460-1463 (1978) Gas chromatographic determination of diquat residues in potato tubers 31 Kitada, Y. et al., JAOAC, 65, 1302-1304 (1982) Simultaneous liquid chromatographic determination of thiabendazole, o-phenylphenol, and diphenyl residues in citrus fruits, Without prior cleanup 29 , 56 , 65 Kobayashi, H. et al., J . Pest. Sci., 2. 427-430 (1977) Gas chromatographic determination of guanidino fungicide, guazatine, in rice grain 114 Krause (1), R.T. & August, E.M., JAOAC, 66, 1018-1022 (1983) Applicability of a multiresidue method and high performance liquid chrornatography for the determination of chinomethionate in apples and oranges 80 Krause (2), R.T. & August, E.M., JAOAC, 66. 234-240 (1983) Applicability of a carbamate insecticide multiresidue method for determining additional types of pesticides in fruits and vegetables 62 Lafuente (1) M.T. et al, JAOAC 69, 859-862 (1986) GC determination of fenpropimorph residues in citrus fruit 8 Lafuente (2) M.T. et al, Fres. J. Anal. Chem. 328, 105-107 (1987) GLC multiresidue analysis of postharvest fungicides in citrus fruit 188 Lane (1). J.R., JAOAC, 46, 261-268 (1963) Collaborative study of maleic hydrazide residue analysis 102 Lane (2), J.R., JAOAC, 48, 744-748 (1965) Collaborative study of maleic hydrazide residue analysis 102 Lawrence(1), J.F., J. Agr. Fd. Chem., 25. 211-212 (1977) Direct analysis of some carbamate pesticides in foods by high-pressure liquid chromatography 8, 75, 96 Lawrence (2), J.F. & Panopio, L.G. JAOAC 63, 1300-1303 (1980) Comparison of gas and liquid chromatography for determination of anilazine in potatoes and tomatoes. 163 Lembo, S . et al., J. Chromatog., 267, 427-430 (1983) Gas-liquid chromatographic method for determining propylenethiourea in rat tissues and fluids 150 Leppert (1), B.C. et al., J. Agr. Fd. Chem., 31, 220-223 (1983) Determination of carbosulfan and carbofuran residues in plants, soil, and Water by gas chromatography 145 Leppert (2), B.C. et al., J. Agr. Fd. Chem., 32, 1441 (1984) Comment on recovery of carbosulfan residues from acidic crops 145 Li Yu-Chang et al., Fres. Z. Anal. Chem., 316, 290-292 (1983) Methode zur Bestimmung von Rỹckstọnden an Butocarboxim in Pflanzen und Boden mit Hilfe der HPLC 139 Lokke (1), H., J. Chromatog., 200, 234-237 (1980) Determination of amitrole by ion-pair high-performance liquid chromatography 79 Lokke (2), H., J. Chromatog., 179, 259-270 (1979) Investigation on loss of chlorothalonil, dichlofluanid, tolylfluanid and vinclozolin by column chromatography clean-up on silver-loaded alumina in a gas chromalographic multiresidue procedure 81 , 82 Lokke (3), H. & Odgaard, P., Pest. Sci., 12, 375-384 (1981) Residues in blackcurrants, fodder peas, spinach and potatoes treated with sublethal doses of 2,4,5-T to simulate wind drift damage 121 Lord, E. et al., J. Assoc. Publ. Anal., 16, 25-32 (1978) The determination of biphenyl and 2-hydroxybiphenyl in citrus fruit 29 , 56 Lott, P.F. et al., J. Chromat. Sci., 16, 390-395 (1978) The determination of paraquat 57 Love, J.L. & Patterson, J.E., JAOAC, 61, 627-628 (1978) Atomic absorption spectrometric determination of cyhexatin 67 Lubkowitz, J.A. et al., J. Agr. Fd. Chem., 21, 143-144 (1973) Residue studies of O.S-dimetylphosphoroamidothioate on tomatoes 100 Luke. B.G. & Cossens, S.A., Bull. Envir. Cont. Tox., 24, 746-751 (1980) Determination of diphenylamine residues in apples 30 Maasfeld, Pflanzenschutz Nachr. Bayer 40, 29-48 (1987) German Ed. Method for GC determination of residues of the fungicide Folicur in plant material 189 Maclaine Pont, M.A. et al., Meded. Fac. Landbouww. Rijksuniv. Gent, 45, 835-840 (1980) The residue analysis of prochloraz in combination with dicloran 142 Mendes, M.C.S. J. Agric. Fd. Chem. 38 174-178 (1990) Evaluation and confirmation of acetylation gas liquid chromatographic method for the determination of triadimenol in foods. 168 Mestres (1), R. et al., Trav. Soc. Pharm. Montpellier, 35, 87-100 (1975) Méthode rapide de contrôle et de dosage des résidus d’ortho-phényl phénol et de biphényle dans les agrumes 29, 56, 72, 77 Mestres (2), R. et al., Ann. Fals. Exp. Chim., 73, 407-420 (1980) Méthode de recherche et de dosage des résidus de pesticides dans les produits céréaliers; 2o: Fumigants 9, 10, 23, 24, 52 Mestres (3), R. et al., Proc. Int. Soc. Citricult., 3, 1103-1106 (1977) Thiophanate-metylpostharvest residues in oranges 65, 72, 77 Moellhoff (1), E., Pflanzensch. Nachr. Bayer (Engl. edit.). 28, 370-381 (1975) Method for gas-chromatographic determination of Curaterr residues in plants and soil samples With consideration to metabolites 96 Moellhoff (2), E., Pflanzensch. Nachr. Bayer (Engl. edit.), 30, 249-263 (1977) Method for gas-chromatographic determination of Peropal acaricide and its metabolites in plants, soil, Water and laboratory animal chow 67, 129 Muszkat, L. & Aharonson, N., J. Chromat. Sci.. 21, 411-414 (1983) GC/CI/MS analysis of aldicarb, butocarboxime, and their metabolites 117, 139 Nakamura et al., J. AOAC 76, 1348-1361 (1993) Determination of pyrethroid residues in vegetables, fruits, grains, beans and green tea. 185 Newsome (1). W.H., J. Agr. Fd. Chem., 24, 997-999 (1976) A gas-liquid chromatographic method for the determination of dodine residues in foods 84 NeWsome (2). W.H., J. Agr. Fd. Chem., 22. 887-889 (1974) A method for determining ethylenebis(dithiocarbamate) residues on food crops as bis(trifluoro-acetamido) ethane 105 Newsome (3), W.H., J. Agr. Fd. Chem., 28, 270-272 (1980) A method for the determination of maleic hydrazide and its b-D-glucoside in foods by high-pressure anion-exchange liquid chromatography 102 Newsome (4). W.H., J. Agr. Fd. Chem., 30, 778-779 (1982) Determination of triforine in fruit crops as N,N’-bis(pentafluorobenzoyl)piperazine 116 NeWsome (5), W.H., J. Agr. Fd. Chem., 28, 319-321 (1980) Determination of daminozide residues on foods and its degradation to 1,1-dimethylhydrazine by cooking 104 Nishizawa, H., et al, JAOAC accepted for publication Simple clean-up procedure for residue analysis of buprofezin and its metabolites in crops by GC Nitz, S . et al., J. Agr. Fd. Chem., 30, 593-596 (1982) A capillary gas-liquid chromatographic method for deterrnination of ethylenethiourea and propylene thiourea in hops, beer, and grapes 108 , 150 Official Gazette, no. 4 of the Notification issued on March 20, 1979, by the Japan Environment Agency Residue analysis of cartap hydrochloride 97 Ott, D.E. & Gunther, F.A., JAOAC, 909-912 (1982) Field screening method for above-tolerance residues of dithiocarbamate fungicides 105 Otto. S . et al., J. Envir. Sci. Health, Part B, 12, 179-191 (1977) A new gas chromatographic determination of ethylene thiourea residues without derivatization 108 Panel (1) of the Committee for Analytical Methods for Residues of Pesticidos and Veterinary Products in F oo dstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 98, 19-24 (1973) The determination of malathion and dichlorvos residues in grain 25, 49 Panel (2) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 101, 386-390 (1976) Determination of residues of inorganic bromide in grain 4 Panel (3) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture. Fisheries and Food, Analyst, 102, 858-868 (1977) Determination of residues of organophosphorus pesticides in fruits and vegetables 2, 27, 49, 55, 58 Panel (4) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 104, 425-433 (1979) Determination of organochlorine pesticides in animal fats and eggs 1, 21, 33, 44, 48 Panel (5) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 99, 570-576 (1974) The determination of residues of volatile fumigants in grain 10, 23 Panel (6) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 106, 782-787 (1981) Determination of residues of dithiocarbamate pesticides in foodstuffs by a headspace method 105 Panel (7) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 105, 515-517 (1980) Determination of a range of organophosphorus pesticide residues in grain 4, 22, 27, 37, 49, 74, 86, 112 Panel (8) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 110, 765-768 (1985) Determination of a range of organophosphorus pesticide residues in grain 4, 27 , 37 , 49 , 86 , 90, 123 , 125 Panel (9) of the Committee for Analytical Methods for Residues of Pesticides and Veterinary Products in Foodstuffs of the Ministry of Agriculture, Fisheries and Food, Analyst, 112, 1559-1563 (1987) Determination of ethylenethiourea in canned fruits and vegetables 108 Phillips, A.J.L., Phytophylactica 24 289-292 (1992). Bioassay of tolclofos-metylin bean seed. 191 Player, R.B. & Wood. R., J. Assoc. Publ. Anal., 18, 109-117 (1980) Methods of analysis - collaborative studies; Part III: Determination of biphenyl and 2-hydroxy-biphenyl in citrus fruit 29, 56 Van der Poll, J.M., Vink, M. and Quirijns, J.K. Chromatographia, 30, 155-158, 1990. Determination of amitrole in plant tissues and sandy soils by capillary gaschromatography With alkali flame ionization detection. 79 Pomerantz, I.H. & Ross. R., JAOAC, 51. 1058-1062 (1968) Captan and structurally related compounds: thin layer and gas-liquid chromatography 6 , 7 , 41 Prabhu, S.V., Varsolona, R.J., Welmer. T.A. , Egan, R.S. and TWay, P .C. J. Agr. Fd. Chem. 40,622-625 (1992) Rapid and sensitive high performance liquid chromatographic method for the quantificxation of abamectine and its delta 8,9 isomer. 177 Pyysalo, H. et al., J. 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Rundsch., 76, 119-122 (1980) The determination of bromopropylate residues 70 Stijve (7), T., Challenges to Contemporary Dairy Analytical Techniques, Royal Society of Chemistry (London), Publ. no. 49, 293-302 (1984) Determination and occurrence of organophosphorus pesticide residues in milk 4,14 , 17 , 18 , 19 , 22 , 25 , 27 , 28 , 34 , 37 , 49 , 60 , 86 , 90 Tadeo, J.L. et al, J. Chrom. 391. 338-342 (1987) Determination of fenpropimorph in citrus fruit by reverse phase HPLC Thornton, J.S., Olsen. T.J. and Wagber, K., Agr. Food Chem. 25, 573-576 (1977) Determination of residues of metsystox-R and metabolite in Plant and animal tissue and soil 164 Tjan, G.H. & Konter, Th., JAOAC, 54, 1122-1123 (1971) Gas-liquid chromatography of Morestan residues in plants 80 Tuinstra, L.G.M.Th. & Kienhuis, P.G.M., Chromatographia, 24, 696-700 (1987) Automated two-dimensional HPLC residue procedure for glyphosate on cereals and vegetables With postcolumn fluoregenic labelling 158 VanHaver, W., Z. Lebensm. Unters. Forsch., 172, 1-3 (1981) Determination of carbendazim and thiophanate-metylresidues in some vegetables and fruits by highpressure liquid chromatography 72, 77 VanWees, A.M.P. et al., in: Chromatography and Mass Spectrometry in Nutrition Science and Food Safety, A.Frigerio & H. Milon (edits.), Elsevier, Amsterdam, Netherlands, 19-25 A(1984) Chromatographic methods for the determination of inorganic bromide in vegetables 47 Veierov, D. & Aharonson, N., JAOAC, 63. 532-535 (1980) Economic method for analysis of fluid milk for organochlorine residues at the 10 ppb level 1 (not applicable to dieldrin), 12, 21, 43, 44, 48 Vuik, J. J. Chromatogr. 553 299-304 (1991) Rapid determination of abamectin in letluce and cucumber by high-performance liquid chromatography. 177 Wagner, K. and Thomton, J.S. Pflanzensch. Nachr. Bayer, 30 1-17 (1977) Method for the gas-chromatographic determination of metasystox(i) and Metasystox R residues in plants, soil and water (German edit.: 30, 1-17 (1977) 73, 164, 166 Westcott. N.D., J Environm. Science and Health 323, 317-330 (1988). Terbufos residues in wheat and barley. 167 Wigfield, Y.Y. and Lanquette, M. JAOAC, 74. No.5. 842-847 (1991) Rcsidue analysis of glyphosate and its principal metabolite in certain cereals, oilseeds and pulses by liquid chromatography and post-column fluorescence detection. 158 Winell, B., Analyst, 101, 883-886 (1976) Quantitative determination of ethoxyquin in apples by gas chromatography 35 Wright, D., JAOAC 70, 718-720 (1987) New method for the determination of 1,1-dimethylhydrazine residues in apples and peaches 104 Yamada. T. et al., Agric. Biol. Chem., 48. 1883-1885 (1984) Determination of residual thiabendazole in citrus fruits and bananas by high performance liquid chromatography 65 Zimmerli, B. & Marek, B., Mitt. Geb. Lebensm. Unters. Hyg., 63, 273-289 (1972) Entwicklung einer gaschromatographischen Bestimmungs- und Bestatigungsmethode fur Hexachlorbenzolrỹckstọnde in Fetten und Oelen 44 Van Zoonen, P., E.A. Hogendoorn, D.C. van Harten, Meded. Fac. Landbouwwetenschappen Rijksuniversiteit Gent, 55 (3b), 1285-1290 (1990) Determination of tenpropimorph residues in grains by LC followed by confirmation by GC-MPD. 188