Sandviç ftalosiyanin içeren dendrimerlerin sentezi ve özelliklerinin incelenmesi
Investigation of properties and synthesis of dendrimers contains sandwich phthalocyanine
Yazar: EBRU YABAŞ
Danışman: DOÇ.DR. MUSTAFA SÜLÜ
İnönü Üniversitesi / Fen Bilimleri Enstitüsü / Kimya Ana Bilim Dalı
Derece: Yüksek Lisans, 2005
Konu: Kimya = Chemistry

Özet:
ÖZETYüksek Lisans TeziSANDVİÇ FTALOSİYANİN İÇEREN DENDRİMERLERİN SENTEZİ VEÖZELLİKLERİNİN İNCELENMESİEbru YABAŞİnönü ÜniversitesiFen Bilimleri EnstitüsüKimya Anabilim Dalıix + 60 sayfa2005Danışman: Doç.Dr.Mustafa SÜLÜ4-(2-dimetilaminoetilsülfonil)ftalonitril in, 2-(dimetilamino)etanol desikliktetramerizasyonu ile simetrik tetrakis(2-dimetilaminoetilsülfonil)ftalosiyanin hazırlandı.Trietil metantrikarboksilat ın sodyum tuzunun (NaC(CO2C2H5)3),tris(hidroksimetil)aminometanın (tris) (H2NC(CH2OH)3) ve hekzil bromürün sırasıylasimetrik ftalosiyanin ile reaksiyonuyla birinci, ikinci ve üçüncü jenerasyon metalsiz dendritikftalosiyanin hazırlandı. Simetrik ftalosiyanin lityum tuzu, dendritik ftalosiyanin veLu(OAc)3.nH2O veya Eu(OAc)3.nH2O karışımının 1-oktanol da ısıtılmasıyla dendritiksandviç ftalosiyanin bileşikleri hazırlandı. Hazırlanan bileşikler 1H-NMR, UV-VIS ve IRspektroskopileri ile karakterize edildi.CH3 H CCH3 3H3CCH3CH3H3CCH3OOOH3COO OONH H(Me)2N OO ON CH3HNH3C O CH3OSH3CSCH3O OOOH3C HN O CH3OH3C NO OHN NNN O OONNNH H N CH3SO NN S OH3C+N Li N(Me)2S HLiN HOS(Me)2N OO NN NHNO ON CH3ON N H3C O NH CH3OO O OH3CS CH3SOOH3C CH3NHNH3C OO OH NHOOOON(Me)2CH3OO OH3CCH3H3CH3C200oC CH3H3CCH3 H CLu(OAc)3.nH2O 31-oktanol veya Eu(OAc)3.nH2OH3CCH3 CH3H3CCH3CH3H3C CH3 CH3H3C CH3H 3C CH3OO OOOO OH3C OOO CH3OO HN O NHNHH3C ONH O CH3H OO O NOHNO OH3COSO O SN CH3H3 CNNNH3C CH3NN NHOOHOOONN NH3C CH3O OOOSSO HH OOH 3C CH3NNOO O NHHN O OOH 3C CH3OOOOLu (Eu)OOH3 C CH3H3C CH3CH3H3CSS CH3H 3CNN(Me)2N N(Me)2NNNN NNS S(Me)2N N(Me)2Anahtar Kelimeler: Ftalosiyaninler, Sandviç Ftalosiyaninler, Dendritik FtalosiyaninlerLutesyum, Evropiyum

Abstract:
ABSTRACTMaster ThesisINVESTIGATION OF PROPERTIES AND SYNTHESIS OF DENDRIMERS CONTAINSSANDWICH PHTHALOCYANINEEbru YABAŞInönü UniversityGraduate School of Natural and Applied SciencesDepartment of Chemistryix + 60 sayfa2005Supervisor: Assoc.Prof.Dr.Mustafa SÜLÜSymmetric tetrakis(2-dimethylaminoethylsulphanyl)phthalocyanine was preparedcyclotetramerization of 4-(2-dimethylaminoethylsulphanyl)phthalonitrile in 2-(dimethylamino)ethanol. First, second and third generation metal-free dendriticphthalocyanine were obtained by the reaction of symmetric phthalocyanine and triethylmethanetricarboxylate sodium salt (NaC(CO2C2H5)3), tris(hidroksomethyl)-aminomethane(tris) (H2NC(CH2OH)3) and hexyl bromide, respectively. The dendritic sandwichphthalocyanines were prepared by heating the mixture of Lithium salt of symmetricphthalocyanine, dendritic phthalocyanine and Lu(OAc)3.nH2O or Eu(OAc)3.nH2O in 1-1octanol. Prepared compounds were characterized by H-NMR, UV-VIS and IRspectroscopies.CH3 H CCH3 3H3CCH3CH3H3 CCH3OOOH3COO OO(Me)2N NH HOO ON CH3HNH3C O CH3OS SH3CCH3O OOOH3 C HN O CH3OH3C NO ON HN NNNN O OONH H N CH3SO NN S ON Li N(Me)2 H3 CS LiN S+(Me)2N HHO OO NN NHNN ON N O CH3OH3C O NH CH3OO O OH3CS CH3SOOH3 C CH3NHNH3C OO OH NHOON(Me)2OOCH3OO OH3CCH3H3CH3C200oC CH3H3CCH3 H CLu(OAc)3.nH2O 31-octanol veya Eu(OAc)3.nH2OH 3CCH3 CH3H3CCH3CH3H 3C CH3 CH3H3C CH3H 3C CH3OO OOOO OH3C OOO CH3OO HN O NHNHH 3C ONH O CH3H OO O NOHNO OH 3COSO O SN CH3H3 CNNNH3C CH3NN NHOOHOOONN NH 3C CH3O OOOSSO HH OOH 3C CH3NNOO O NHHN O OOH 3C CH3OOOOLu (Eu)OOH3C CH3H3C CH3CH3H3CSS CH3H3CNN(Me)2N N(Me)2NNNN NNS S(Me)2N N(Me)2Key Words: Phthalocyanines, Sandwich Phthalocyanines, Dendritic Phthalocyanines,Lutetium, Europium.