Li2O.ZnO.SiO2 esaslı cam seramiklerinin kontrollü kristalizasyonu ve mekaniksel özellikleri
The controlled crystallization and mechanical properties of Li2O-ZnO-SiO2 base glasses
Yazar: ALTAN ERDOĞAN
Danışman: DOÇ.DR. ERDEM DEMİRKESEN
İstanbul Teknik Üniversitesi / Fen Bilimleri Enstitüsü
Derece: Yüksek Lisans, 1993
Konu: Seramik Mühendisliği = Ceramic Engineering
Dizin: CAM =   ; Cam = Glass ; Kristalleşme = Crystallization ; Malzemeler = Materials ; Mekanik özellikler = Mechanical properties ; Seramikler = Ceramics

Özet:
ÖZET Cam-seramikler, uygun bileşimdeki camların kontrollü kristalizasyonu ile üretilen ve endüstrinin bir çok dalın da önemli uygulama potansiyeli kazanmış olan çok kristalli malzemelerdir. Değişik mühendislik uygulamaları için geliştirilmiş bir çok cam-seramik sistemi vardır. Bu çalışmada incelenen Li?0-ZnD-SiO? esaslı cam-seramikler, yüksek mekaniksel muravemet gösterebilen, bileşimleri geniş sınırlar içinde değişebilen, P^Og ile çekirdeklendirilen cam-seramiklerdir. Deneysel çalışmalarda PpOc içeriği değiştirilmiş, bileşimleri birbirine yakın iki camın üretimi, camlaşma ve kontrollü kristalizasyon özellikleri incelenmiştir. Saf başlangıç maddeleri kullanılarak hazırlanan ve 135D C'de dökülen cam örneklerine değişik ısıl işlemler uygulanarak bu ısıl işlem koşullarında meydana gelen faz dönüşümleri ve mikroyapılar, diferansiyel termal analiz, Taramalı Elektron Mikroskobu ve X-ışınları difraksiyon teknikleri ile incelenmiştir. Kristalize olmuş camların kırılma modülleri üç noktalı eğme testi ile ölçülmüştür. Kristal- S" leşmiş camların mikroyapı ve mukavemetleri, uygulanan ısıl işlem koşullarına göre irdelenmiştir. v

Abstract:
THE CONTROLLED CRYSTALLIZATION AND HECHANICAL PROPERTIES OF Li20-Zn0-Si02 BASE GLASSES Glass-ceramics are polycrystalline solids prepared by the controlled crystallisation of glasses. Crystallisation is accomplished by subjecting suitable. glasses to a carefully requlated heat-treatment schedule which results in the nucleation and growth of crystal phases within the glass. In many cases, the crystallisation process can be taken almost to completion but a small proportion of residual glass-phase is often present. In glass-ceramics, the crystalline phases are entirely produced by crystal growth from a homogenous glass phase and this distinguishes these materials from tradional ceramics where most of the crystalline material is introduced when the ceramic composition is prepared although some recrystallisation may occur or new crystal types may arise due to solid state reactions. Elass- * ceramics are distinguished from glasses by the presence of major amounts of crystals since glasses are amorphous or non-crystalline. One of the most important criterion in selecting a glass composition for glass-ceramic production is that it shall be capable of being crystallised without the use of prohibitively long heat-treatments. It is also important that the constituents of the glass and their proportions shall be chosen so that crystal types can "be developed which will confer upon the final glass-ceramic the. desired charocteristics, Ü ' There are certain glasses which are extremly difficult, if not impossible, to devitrify even with prolonged heating at temperatures at which crystal VIi The dependence of crystallizing phases on the heat- treatment schedule and the influence of PpüV content used as nucleating catalyst on the controlled crystallization process were examined. The aim of the investigation was to understand the relation between properties and microstructure of the glass-ceramics so that suitable heat-treatments schedules could be chosen for producing glass-ceramics with desired properties. amoun Si02x in a quenc was c homog held proph glass by X- sched therm of s scann etchi addit in co cryst All ts o H20, plat hed rush eniz at 1 ite es a ray ules al a ever ing ng i ion, mpos alii glas f an and inum in w ed, e th 350° mild fter diff wer naly al d elec n HF f ra tion sati ses alyt 5b2 cr ater mixe e me C fo s. var ract e de sis evit tron sol ctur Gla on c were ical °3* ucibl. Th d and It. r 2 h The c ious ion ( vised (DTA) rif ie micr ution e mod ss II ondit prepare reagent The mix e at 1 2 e resul remelt The horn and po rystall heat-tr XRD). on the inform d glass oscope, and c ulus of were m ions» d by s Li ture 00-1 ting ed a ogen ured ine eatm The bas atio es a (SEM oati hea easu mixing pCO-j Zn, were m 259°C fo glass a t 1200-1 eous mel into pr phases a ents wer heat-tre is of di n. The re inves ) after ng with t-treate red as a the appropriate 0,Ca,(P0^)2, elted in 75 g. r 2-3h and fter drying 250DC to ts were then eheated ppearing in e identified atment f ferential microstructures tigated by polishing, carbon. In d samples function of XRD alii th c es w 0°C SiO^ was.ass ;nt i, ve 650UC in 2 ho cryst in bo sampl at k5 Li2Zn size of Gl conte stage pattern sation omposit ere hel for 2 h and wa determi I. Thi n Glass ry fine Glass I urs at s indie product ions, d at 51 ours. s obser ned to s was a II. A grains I and a these t ated with It w 0°C f The s ved a be sm ttrib fter d cry t 750 emper that, a sph as fir or 1 5 econd bove 6 aller uted t this i s t a 1 s °C in atures. erulis st ob minut cryst oo°c. in Gl o the nital were Glass Or. was.. 5 :ic mar served es afte alline The s ass II higher crysta observe II aft the first phology when the r holding phase is pherulite than that P20 llisation d at er holding ixThese microstructural changes may be due to the allotrophic transformation of Li?ZnSiO, as indicated in the literature. It uias therefore concluded that, the microstructure can be controlled by the phase transformations rather than the P?0,- content, although the latter have an effect on the microsturcture at temperatures at which no phase transformations occur» Hi The dependence of crystallizing phases on the heat- treatment schedule and the influence of PpüV content used as nucleating catalyst on the controlled crystallization process were examined. The aim of the investigation was to understand the relation between properties and microstructure of the glass-ceramics so that suitable heat-treatments schedules could be chosen for producing glass-ceramics with desired properties. amoun Si02x in a quenc was c homog held proph glass by X- sched therm of s scann etchi addit in co cryst All ts o H20, plat hed rush eniz at 1 ite es a ray ules al a ever ing ng i ion, mpos alii glas f an and inum in w ed, e th 350° mild fter diff wer naly al d elec n HF f ra tion sati ses alyt 5b2 cr ater mixe e me C fo s. var ract e de sis evit tron sol ctur Gla on c were ical °3* ucibl. Th d and It. r 2 h The c ious ion ( vised (DTA) rif ie micr ution e mod ss II ondit prepare reagent The mix e at 1 2 e resul remelt The horn and po rystall heat-tr XRD). on the inform d glass oscope, and c ulus of were m ions» d by s Li ture 00-1 ting ed a ogen ured ine eatm The bas atio es a (SEM oati hea easu mixing pCO-j Zn, were m 259°C fo glass a t 1200-1 eous mel into pr phases a ents wer heat-tre is of di n. The re inves ) after ng with t-treate red as a the appropriate 0,Ca,(P0^)2, elted in 75 g. r 2-3h and fter drying 250DC to ts were then eheated ppearing in e identified atment f ferential microstructures tigated by polishing, carbon. In d samples function of XRD alii th c es w 0°C SiO^ was.ass ;nt i, ve 650UC in 2 ho cryst in bo sampl at k5 Li2Zn size of Gl conte stage pattern sation omposit ere hel for 2 h and wa determi I. Thi n Glass ry fine Glass I urs at s indie product ions, d at 51 ours. s obser ned to s was a II. A grains I and a these t ated with It w 0°C f The s ved a be sm ttrib fter d cry t 750 emper that, a sph as fir or 1 5 econd bove 6 aller uted t this i s t a 1 s °C in atures. erulis st ob minut cryst oo°c. in Gl o the nital were Glass Or. was.. 5 :ic mar served es afte alline The s ass II higher crysta observe II aft the first phology when the r holding phase is pherulite than that P20 llisation d at er holding ixThese microstructural changes may be due to the allotrophic transformation of Li?ZnSiO, as indicated in the literature. It uias therefore concluded that, the microstructure can be controlled by the phase transformations rather than the P?0,- content, although the latter have an effect on the microsturcture at temperatures at which no phase transformations occur» H