ghanaopendata/ghanaian-research-english huggingface dataset:
Geochemical characteristics and U–Pb zircon LA-ICPMS ages of granitoids from the Pan-African Dahomeyide orogen, West Africa

The Dahomeyide orogen in southeastern Ghana and adjoining parts of Togo and Benin records the suture of West African craton (WAC) into northwest Gondwana. The suture zone is characterized by distinctive high-pressure mafic rocks that mark the collision of WAC with exotic blocks to the east. Granitoids to the east of the suture zone, which are postulated to be juvenile crust representing the arc terrane that formed during subduction and oceanic closure, were investigated. We compiled a map of granitoid gneisses in Ghana, Togo, and Benin which allows us to distinguish between two main rock types: (1) migmatitic gneisses with biotite as the dominant mafic mineral and (2) dioritic gneiss characterized by hornblende as the main mafic mineral and with occasional garnet. These rocks types are separated by a shear zone inferred to be a splay of Kandi shear zone, a segment of the Trans-Saharan shear zone that extends for 2500 km from the Sahara to the Gulf of Guinea. The granitoids are characterized by I-type signatures, display variable amounts of LREE enrichment, Eu depletion and Sr/Y ratios that are consistent with a subduction origin. The migmatitic gneiss unit, within a zone of highly strained granitoids (straight gneiss) that forms a sliver just east of the suture zone, yielded U–Pb zircon ages ranging from 615 to 589 Ma. This age range is similar to the metamorphic crystallization age of the suture zone rocks. The zircons analyzed display concentric zoning (in CL images) and are inferred to be magmatic. On the other hand, zircon separates from the dioritic gneiss, with grains also showing igneous zoning in CL images, yielded U–Pb zircon crystallization ages ranging from 2.19 to 2.14 Ga. These are the first U–Pb zircon ages to document Paleoproterozoic rocks in the postulated juvenile terrane, west of the Kandi fault zone. Nd model ages of rocks in the suture zone are also consistent with the existence of widespread involvement of older crust in the Pan-African collision zone, similar to the isotopic data from the correlative Medio Coreau domain of the northwest Borborema province in Brazil.

Source: UG
Geochemical Characteristics of Granitoids (Ho Gneiss) from the Pan – African Dahomeyide Belt, Southeastern, Ghana: Implications for Petrogenesis and Tectonic Setting

The Pan-African Dahomeyide belt exposed in Southeastern, Ghana, consist of granitoid gneisses locally known as Ho gneiss. These rocks are thought to be part of the West African Craton (WAC) which was reworked during the Pan-African Orogeny, and may be time equivalent with the Kara gneisses. Petrographical and whole rock geochemical analyses have been used to evaluate the characteristics, petrogenesis and mode of emplacement of the granitoids. The new data reasonably suggest that the Ho gneiss consist mainly of biotite augen gneisses of both mafic and felsic rock suites. Geochemically, these rocks show tonalitic to quartz monzonite but mainly granodiorites affinities. They are metaluminous to weakly peraluminous, I-type, magnesian to ferroan and calcic to alkali calcic. With these varying features, the granitoids mimic mantle derived magma source which mixed or mingled with crustally derived melt. The rocks display varying REEs and trace elements patterns but, their LREEs and LILE enrichment with the noticeable enrichment in Rb, Ba, K and especially Pb and negative Ti, Ta, Nb observed among majority of the samples are typical signature of ‘‘arc rocks’’ or continental crustal materials. Their incompatible trace element ratios, such as Th/U (1.07 – 13.87), K/Rb (272 – 574.47), Th/Yb (0.79 –15.09), Ta/Yb (0.25 -0.64 ), Ce/Pb (mainly 1.62 – 7.88 ) and high Ba/Nb (19.55 – 314.17, with TA = 1565.00), are similar to those of the continental crust. The rocks are characterised by subduction related Sr/Y content (<100), except sample MA8 that shows high concentration of Sr/Y (227.71). The magnesian affinity reflects relatively hydrous, oxidizing source which is consistent with origins that are broadly subduction related. Their high – K nature also points to an important petrogenetic role of remelting and differentiation of arc – accretionary complex crust. These geochemical signatures are likely to be related to metasomatism of the sub – continental lithospheric mantle via crustal recycling. In conclusion, the granitoids may have from melting of igneous source in a subduction related environment.

Source: UG
Geochemical compositions of Neoproterozoic to Lower Palaeozoic (?) shales and siltstones in the Volta Basin (Ghana): Constraints on provenance and tectonic setting

Many researchers have investigated the provenance and tectonic setting of the Voltaian sediments using the geochemistry of sandstones in the basin. The shales and siltstones in the basin have not been used much in the provenance studies. In this paper, the geochemistry of shales and siltstones in the Kwahu Group and Oti Group of the Voltaian Supergroup from Agogo and environs in the southeastern section of the basin has constrained the provenance and tectonic setting. Trace element ratios La/Sc, Th/Sc and Cr/Th and REEs sensitive to average source compositions revealed sediments in the shales and siltstones may mainly be from felsic rocks, though contributions from old recycled sediments and some andesitic rock sediments were identified. The felsic rocks may be granites and/or granodiorites. Some intermediate rocks of andesitic composition are also identified, while the recycled sediments were probably derived from the basement metasedimentary rocks. The enrichment of light REE (LaN/YbN c. 7.47), negative Eu anomalies (Eu/Eu* c. 0.59), and flat heavy REE chondrite-normalized patterns, denote an upper-continental-crustal granitic source materials for the sediments. Trace-element ternary discriminant diagrams reveal passive margin settings for sediments, though some continental island arc settings sediments were also depicted. Mixing calculations based on REE concentrations and modeled chondrite-normalized REE patterns suggest that the Birimian basement complex may be the source of detritus in the Voltaian Basin. REEs are more associated with shales than siltstones. On this basis chondrite-normalized REE patterns show that shale lithostratigraphic units may be distinguished from siltstone lithostratigraphic units. The significant variability in shales elemental ratios can therefore be used to distinguish between shales of the Oti Group from that of the Kwahu Group.

Source: UG
Geochemical constraints on provenance and source area weathering of metasedimentary rocks from the Paleoproterozoic (~2.1 Ga) Wa-Lawra Belt, southeastern margin of the West African Craton

The Wa-Lawra Belt which is situated in the northern part of Ghana consists of Paleoproterozoic Birimian fine metasedimentary rocks metamorphosed to greenschist facies, particularly, in the western part. A whole-rock geochemical study of these metasedimentary rocks was undertaken to unravel their source area weathering, provenance and tectonic setting. Geochemical characteristics of the studied shales show that they are immature in nature and first cycle in origin, with little or no recycled component. Compared to Post- Archaean Australian Shales (PAAS), the studied shales indicate reduction in Zr, Hf, La, Nb, Th and Ta being the high field strength elements and evidences of transition metal enrichments in V, Ni, Sc, Co, and Cr. Major element geochemistry indicates that the shales were subjected to slight potassium metasomatism after deposition. Pre-metasomatized Chemical Index of Alteration calculations indicates that weak to moderate degree of chemical weathering took place at the sediment source area. Co-Th-La-Sc systematics reveals a combination of mafic and felsic provenances for the shales. Eu/Eu* together with values of Th/U and some abundances of trace elements show that the shales were mainly derived from juvenile rocks. Average REE model calculations suggest that the source materials are composed of about 49% basalt, 16% TTG and 35% granite.

Source: UG
Geochemical Dispersion of Elements and Their Correlation with Gold in the Regolith at the Tetteh Prospect of the Chirano Gold Mines in the Sefwi Belt of the Birimian, Southwestern Ghana

The processes controlling gold (Au) mineralization in Chirano, a gold prospect in south-western Ghana have been investigated using a detailed geochemical dataset of 45 variables from 197 sampling locations. The data were subjected to advanced statistical analyses and bivariate graphical interpretations in the light of the underlying lithology. Four processes of significance have been identified from the multivariate analysis in terms of the geochemistry of the soil in the area. The most important process accounts for almost half of the total variance in the dataset and also correlates strongly with Au. Although Arsenic (As) registers the highest loading under this factor, Aluminium (Al), Silver (Ag), Manganese (Mn), Copper (Cu), and Iron (Fe) record higher correlations and could serve as better pathfinders than As in the study area. This study also shows that there is a second, less prominent process contributing to the availability of Au in the area. This process ranks third amongst the processes of significance in terms of the geochemistry, and correlates negatively with As, suggesting that the latter is not suitable as a pathfinder for Au in the traditional sense. However, since this third process is weaker compared to the first, the implication of this interpretation may be limited to only some locations in the study area. In addition to the revelations from the multivariate statistics, the regolith in the study area has evolved over the years and therefore the changes in regolith should be factored into the exploration protocols. The pre-existing preserved surfaces were found to be masked predominantly by transported materials consisting of ferruginized and exotic sediments. Within the surficial regolith and especially in the Feoxyhydroxide rich horizons, Au concentrations increase to significant values that are higher than those of the bedrock or saprolite thereby showing the significant Au re-distribution within the regolith. This study also highlights the apparent Au depletion in the mottled clay zones and in the saprolite and the enrichment of the metal in lateritic residuum and the topsoil. The high Au expressions in the upper parts of the regolith generally are transported whereas the residual soil anomalies have low Au concentrations and do not merit further exploration follow up.

Source: UG
Geochemical syntheses among the cratonic, off-cratonic and orogenic garnet peridotites and their tectonic implications

Garnet-bearing mantle peridotites, occurring as either xenoliths in volcanic rocks or lenses/massifs in high-pressure and ultrahigh-pressure terrenes within orogens, preserve a record of deep lithospheric mantle processes. The garnet peridotite xenoliths record chemical equilibrium conditions of garnet-bearing mineral assemblage at temperatures (T) ranging from ~700 to 1,400°C and pressures (P) &gt; 1.6-8.9 GPa, corresponding to depths of ~52-270 km. A characteristic mineral paragenesis includes Cr-bearing pyropic garnet (64-86 mol% pyrope; 0-10 wt% Cr2O3), Cr-rich diopside (0.5-3.5 wt% Cr2O3), Al-poor orthopyroxene (0-5 wt% Al2O3), high-Cr spinel (Cr/(Cr + Al) × 100 atomic ratio = 2-86) and olivine (88-94 mol% forsterite). In some cases, partial melting, re-equilibration involving garnet-breakdown, deformation, and mantle metasomatism by kimberlitic and/or carbonatitic melt percolations are documented. Isotope model ages of Archean and Proterozoic are ubiquitous, but Phanerozoic model ages are less common. In contrast, the orogenic peridotites were subjected to ultrahigh-pressure (UHP) metamorphism at temperature ranging from ~700 to 950°C and pressure &gt;3.5-5.0 GPa, corresponding to depths of &gt;110-150 km. The petrologic comparisons between 231 garnet peridotite xenoliths and 198 orogenic garnet peridotites revealed that (1) bulk-rock REE (rare earth element) concentrations in xenoliths are relatively high, (2) clinopyroxene and garnet in orogenic garnet peridotites show a highly fractionated REE pattern and Ce-negative anomaly, respectively, (3) Fo contents of olivines for off-cratonic xenolith are in turn lower than those of orogenic garnet and cratonic xenolith but mg-number of garnet for orogenic is less than that of off-cratonic and on-cratonic xenolith, (4) Al2O3, Cr2O3, CaO and Cr# of pyroxenes and chemical compositions of whole rocks are very different between these garnet peridotites, (5) orogenic garnet peridotites are characterized by low T and high P, off-cratonic by high T and low P, and cratonic by medium T and high P and (6) garnet peridotite xenoliths are of Archean or Proterozoic origin, whereas most of orogenic garnet peridotites are of Phanerozoic origin. Taking account of tectonic settings, a new orogenic garnet peridotite exhumation model, crust-mantle material mixing process, is proposed. The composition of lithospheric mantle is additionally constrained by comparisons and compiling of the off-cratonic, on-cratonic and orogenic garnet peridotite. © 2010 Springer-Verlag.

Source: UG
Geochemistry and geochronology of acidic rocks in the Beishan region, NW China: Petrogenesis and tectonic implications

The dacites and granites from the Beishan region are characterized by highly-fractionated REE, enrichments in LILE, and depletion in Nb, Ta and Sr. The dacites contain zircons with ages ranging from 265 to 748Ma. These features suggest that they were probably derived from the older lower continental crust and were later on subjected to significant crustal assimilation. The rhyolites, diorites and diabases, all of which share similar geochemical features such as trace element patterns, zircon U-Pb ages of ~280Ma, positive εHf(t) and εNd(t), high initial (87Sr/86Sr)i and δ18O‰ values, were most likely derived from the juvenile crustal sources and subsequently experienced fractional crystallization and crustal contamination. These acidic igneous rocks (except dacites and granites) and coeval mafic-ultramafic intrusions form a bimodal igneous series. This implies that the Beishan region was a Late Paleozoic rift probably developed in association with the early Permian mantle plume activity in the Tarim Basin. © 2010 Elsevier Ltd.

Source: UG
Geochemistry and geochronology of granitoids in the Kibi-Asamankese area of the Kibi-Winneba volcanic belt, southern Ghana

In Ghana the West African Craton is represented by Birimian and Tarkwaian rocks with extensive granitoid bodies. Granitoids from Asamankese area of the Kibi-Winneba volcanic belt, southern Ghana were analysed for major and trace element contents and found to be characterised by highly-fractionated REE, enrichments, in LILE, and depletion in Nb, Ta and Sr. The LILE enrichment relative to strong Nb-Ta depression, indicates that these granitoids were emplaced in an active margin. Based on field relations, geochemical composition and geochronological data, the granitoids from the Kibi-Asamankese area can be divided into three types, namely; the Eburnean biotite granodiorite (2133-2127. Ma) and hornblende granodiorite (2147. Ma), and the Pre-Eburnean gneissic biotite granite (2193. Ma). The geochemical data of the studied rocks plot in the tholeiitic field, whereas on the A/CNK-A/NK diagram, they generally fall within the metaluminous field, with A/CNK values between 0.69 and 0.88. U-Pb dating of zircons in the granitoids yielded ages ranging from 2193 to 2127. Ma, which are among the oldest ages obtained from the granitoid plutons in Ghana. Such high-precision geochronological data indicate that magmatism occurred over a time-span of about 70. Ma. This provides further evidence that the period 2.1-2.2. Ga was one of the important stages of Birimian magmatism that led to the generation of the granitoids. From the above-mentioned ages, it is possible to link the geological activities to crustal processes and establish the cyclic geotectonic evolution in the West African Craton over time as part of an arc-back-arc basin system. © 2014 Elsevier Ltd.

Source: UG
Geochemistry and geochronology of granitoids in the Kibi-Asamankese area of the Kibi-Winneba volcanic belt, southern Ghana.

In Ghana the West African Craton is represented by Birimian and Tarkwaian rocks with extensive gran itoid bodies. Granitoids from Asamankese area of the Kibi-Winneba volcanic belt, southern Ghana were analysed for major and trace element contents and found to be characterised by highly-fractionated REE, enrichments, in LILE, and depletion in Nb, Ta and Sr. The LILE enrichment relative to strong Nb–Ta depres sion, indicates that these granitoids were emplaced in an active margin. Based on field relations, geo chemical composition and geochronological data, the granitoids from the Kibi-Asamankese area can be divided into three types, namely; the Eburnean biotite granodiorite (2133–2127 Ma) and hornblende granodiorite (2147 Ma), and the Pre-Eburnean gneissic biotite granite (2193 Ma). The geochemical data of the studied rocks plot in the tholeiitic field, whereas on the A/CNK–A/NK diagram, they generally fall within the metaluminous field, with A/CNK values between 0.69 and 0.88. U–Pb dating of zircons in the granitoids yielded ages ranging from 2193 to 2127 Ma, which are among the oldest ages obtained from the granitoid plutons in Ghana. Such high-precision geochronological data indicate that magmatism occurred over a time-span of about 70 Ma. This provides further evidence that the period 2.1–2.2 Ga was one of the important stages of Birimian magmatism that led to the generation of the granitoids. From the above-mentioned ages, it is possible to link the geological activities to crustal processes and establish the cyclic geotectonic evolution in the West African Craton over time as part of an arc-back-arc basin system.

Source: UG
Geochemistry and provenance of Neoproterozoic metasedimentary rocks from the Togo structural unit, Southeastern Ghana

Neoproterozoic metasedimentary rocks of greenshist facies, consisting predominantly of quartzites, phyllites, and phyllonites, occur in the Akwapim range of the Togo Structural Unit (TSU) in Ghana. The geochemistry of the phyllites were studied to determine their provenance and tectonic setting. The major element analysis was carried out by the Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) and trace elements, including REEs, by the Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) method. The studied metasedimentary rocks have SiO2 and Al2O3 contents comparable to that of average Neoproterozoic upper crust. The metasedimentary rocks are strongly depleted in CaO, Na2O, and Sr and enriched in K2O, Ba and Rb with respect to average Neoproterozoic upper crust, reflecting K addition during diagenesis. Zr and Hf concentrations are significantly above Neoproterozoic upper crustal values. Chondrite-normalized rare earth element (REE) patterns are characterised by fractionated light-REE (LREE) (average LaN/SmN = 3.68), significant negative europium anomaly (average Eu/Eu* = 0.61) and fairly flat heavy-REE (HREE) (average GdN/YbN = 1.3). The geochemical data, particularly the high La/Sc, Th/Sc, La/Co, Th/Co, Zr/Sc, La/Th ratios, Eu/Eu* values, and high Zr and Hf concentrations, suggest that the metasedimentary rocks of the Togo Structural Units in the Akwapim range were derived mainly from recycled sedimentary sources. Comparison of geochemical signatures of the studied metasedimentary rocks with those of the Paleoproterozoic Birimian rocks suggests that the felsic materials in the Togo Structural Units (TSU) could not have been derived predominantly from the Birimian rocks, implying more distal sources. The studied metasedimentary rocks exhibit provenance characteristics similar to that of the Kwahu/Bombouaka Group of the Voltaian Basin, suggesting derivation from the same source, probably in the Amazon Craton. The metasedimentary rocks exhibit geochemical characteristics indicative of sediments derived from a passive continental margin. This inference supports previous studies that indicate that prior to the Pan-African Dahomeyide orogenic event, the southern margin of the West African Craton (WAC) was under passive margin settings.

Source: UG
Geochemistry and provenance of Neoproterozoic metasedimentary rocks from the Togo structural unit, Southeastern Ghana.

Neoproterozoic metasedimentary rocks of greenshist facies, consisting predominantly of quartzites, phyllites, and phyllonites, occur in the Akwapim range of the Togo Structural Unit (TSU) in Ghana. The geochemistry of the phyllites were studied to determine their provenance and tectonic setting. The major element analysis was carried out by the Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) and trace elements, including REEs, by the Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) method. The studied metasedimentary rocks have SiO2 and Al2O3 contents comparable to that of average Neoproterozoic upper crust. The metasedimentary rocks are strongly depleted in CaO, Na2O, and Sr and enriched in K2O, Ba and Rb with respect to average Neoproterozoic upper crust, reflecting K addition during diagenesis. Zr and Hf concentrations are significantly above Neoproterozoic upper crustal values. Chondrite-normalized rare earth element (REE) pat terns are characterised by fractionated light-REE (LREE) (average LaN/SmN = 3.68), significant negative europium anomaly (average Eu/Eu* = 0.61) and fairly flat heavy-REE (HREE) (average GdN/YbN = 1.3). The geochemical data, particularly the high La/Sc, Th/Sc, La/Co, Th/Co, Zr/Sc, La/Th ratios, Eu/Eu* values, and high Zr and Hf concentrations, suggest that the metasedimentary rocks of the Togo Structural Units in the Akwapim range were derived mainly from recycled sedimentary sources. Comparison of geochemical signatures of the studied metasedimentary rocks with those of the Paleoproterozoic Birimian rocks suggests that the felsic materials in the Togo Structural Units (TSU) could not have been derived predominantly from the Birimian rocks, implying more distal sources. The studied metasedimentary rocks exhibit provenance characteristics si milar to that of the Kwahu/Bombouaka Group of the Voltaian Basin, suggesting derivation from the same source, probably in the Amazon Craton. The metasedimentary rocks exhibit geochemical characteristics indicative of sediments derived from a passive continental margin. This inference supports previous studies that indicate that prior to the Pan-African Dahomeyide orogenic event, the southern margin of the West African Craton (WAC) was under passive margin settings.

Source: UG