gebhart/patrepeval huggingface dataset:
Covalent and Noncovalent Phthalocyanine−Carbon Nanostructure Systems: Synthesis, Photoinduced Electron Transfer, and Application to Molecular Photovoltaics (2010)

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTCovalent and Noncovalent Phthalocyanine−Carbon Nanostructure Systems: Synthesis, Photoinduced Electron Transfer, and Application to Molecular PhotovoltaicsGiovanni Bottari†, Gema de la Torre†, Dirk M. Guldi*‡, and Tomás Torres*†§View Author Information Departamento de Química Orgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain, IMDEA-Nanociencia, Facultad de Ciencias, Ciudad Universitaria de Cantoblanco, 28049 Madrid, Spain, and Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen, Germany* To whom correspondence should be addressed. E-mail: [email protected] (T.T.); [email protected] (D.M.G.).†Universidad Autónoma de Madrid.‡Friedrich-Alexander-Universität Erlangen-Nürnberg.§IMDEA-Nanociencia.Cite this: Chem. Rev. 2010, 110, 11, 6768–6816Publication Date (Web):April 5, 2010Publication History Received17 July 2009Published online5 April 2010Published inissue 10 November 2010https://pubs.acs.org/doi/10.1021/cr900254zhttps://doi.org/10.1021/cr900254zreview-articleACS PublicationsCopyright © 2010 American Chemical SocietyRequest reuse permissionsArticle Views14189Altmetric-Citations732LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Carbon nanomaterials,Carbon nanotubes,Layers,Nanospheres,Solar cells Get e-Alerts
Online Measurement of Brain Glutamate with an Enzyme/Polymer-Coated Tubular Electrode (1994)

An on-line tubular electrode system is described which provides real time measurements of glutamate in brain microdialysate. It is based on the enzyme glutamate oxidase (EC 1.4.3.11) and the detection of H2O2 on a platinum electrode at 600 mV vs Ag/AgCl. The enzyme is immobilized in a layer of o-phenylenediamine electropolymerized at 750 mV in a phosphate buffer, pH 7.0. The layer is 10-15 nm thick and enables good enzyme loading and fast response time. The ability of the polymer to block out electroactive interferents like ascorbate and uric acid combined with a preoxidation system run at 600 mV resulted in a virtually interference free glutamate assay with a lower detection limit of 0.3 microM in the presence of physiological levels of interferents, a sensitivity of 4 nA/microM, and a linear region up to 30 microM. The system is optimized for use with a microdialysis probe implanted in the brain and perfused at 2 microL/min. It provides a time resolution of < 1 min and has been tested in vivo.
Immunization of DBA/2 mice with a T cell hybridoma-derived TsF increases immune resistance to the syngeneic tumors P815 and L1210. (1986)

The ability of a tumor-specific T suppressor factor (TsF) isolated from a T cell hybridoma, A10, to act as an immunogen in DBA/2 mice was investigated. The TsF was affinity purified from ascites over an immunoadsorbent column containing a monoclonal antibody (B16G) that has specificity for the TsF molecule, or over columns containing membrane extracts of the P815 mastocytoma (the tumor for which A10 is specific). The specificity control was BW5147 (the fusion partner for A10) membrane extracts treated in the same way as A10. DBA/2 mice were immunized with the affinity-purified material or PBS and were subsequently challenged with either the P815 tumor or the L1210 DBA/2 thymoma. When mice were immunized with material affinity purified over B16G, eluted material from both A10 ascites and BW5147 membrane extracts enhanced resistance to both P815 and L1210 challenge, indicating that B16G was binding immunogenic material derived from both preparations, which exerted a tumor-protective effect. However, when a P815 affinity column was used, protective material was eluted only from A10 ascites, and this bestowed resistance to both P815 and L1210. When irradiated whole cells were used as immunogens, only A10 cells stimulated anti-tumor immunity, and this appeared to be directed specifically to the P815 tumor. The implications of these findings in terms of the potential for immune modulation with anti-suppressor therapy, and the specificity of the B16G monoclonal, are discussed. The demonstration of B16G binding material (TsF) in the membranes (but not the ascites) of the BW5147 line is also of significance to investigators using BW5147 fused suppressor hybridomas.
A protein covalently linked to poliovirus genome RNA. (1977)

Poliovirion [32P]RNA, after digestion with RNase T2, yields mononucleotides and a labeled compound "X," which is not negatively charged at pH 5. X contains, relative to the label in virion RNA, one to two phosphates and is partially acid insoluble. It can be labeled with tritiated amino acids 3 hr after infection, is insoluble in chloroform/methanol, and can be digested with Pronase. These observations suggest that X is a protein. The protein cannot be removed from the polio genome when the RNA is (i) sedimented through a sucrose gradient in 0.5 M NaCl, (ii) heated to 100 degrees in the presence of sodium dodecyl sulfate followed by sedimentation through a sucrose gradient in 80% dimethylsulfoxide, or (iii) banded in 4 M cesium trichloroacetate. Digestion of the 32P-labeled protein with Pronase yields one major 32P-labeled product, which contains pUp. The protein migrates faster than capsid protein VP4 in a polyacrylamide gel. Our data show that the genome of poliovirus, but not poliovirus mRNA [A. Nomoto, Y. F. Lee, and E. Wimmer (1976) Proc. Natl. Acad. Sci. USA 73, 375-380], is covalently attached to a small virus-coded protein (molecular weight less than 7000), which we call VPg. VPg is probably linked to the 5' end of the polio genome. Possible functions of VPg in viral replication are discussed.
The autism-associated chromatin modifier CHD8 regulates other autism risk genes during human neurodevelopment (2015)

Recent studies implicate chromatin modifiers in autism spectrum disorder (ASD) through the identification of recurrent de novo loss of function mutations in affected individuals. ASD risk genes are co-expressed in human midfetal cortex, suggesting that ASD risk genes converge in specific regulatory networks during neurodevelopment. To elucidate such networks, we identify genes targeted by CHD8, a chromodomain helicase strongly associated with ASD, in human midfetal brain, human neural stem cells (hNSCs) and embryonic mouse cortex. CHD8 targets are strongly enriched for other ASD risk genes in both human and mouse neurodevelopment, and converge in ASD-associated co-expression networks in human midfetal cortex. CHD8 knockdown in hNSCs results in dysregulation of ASD risk genes directly targeted by CHD8. Integration of CHD8-binding data into ASD risk models improves detection of risk genes. These results suggest loss of CHD8 contributes to ASD by perturbing an ancient gene regulatory network during human brain development.
Exploring case-based reasoning for web hypermedia project cost estimation (2005)

This paper compares several methods of analogy-based effort estimation, including the use of adaptation rules as a contributing factor to better estimation accuracy. Two data sets are used in the analysis. Results show that best predictions were obtained for the dataset that presented a continuous 'cost' function and was more 'unspoiled'.
Development of Water-Based Drilling Fluids Customized for Shale Reservoirs (2011)

Summary Drilling activity has increased dramatically in unconventional shale gas reservoirs. The drilling fluid of choice in these shale plays is often nonaqueous-based fluid (NAF). While NAFs can provide advantages such as shale stabilization, lubricity, and contamination tolerance, environmental consequences and associated costs are an issue. These disadvantages cause operators to seek water-based muds (WBMs) for drilling many of these gas reservoirs. Despite some operational similarities, a wide variety of unique downhole conditions can be found in the shale plays. Shale mineralogy and bottomhole temperature (BHT) represent just two highly variable critical factors in unconventional gas reservoirs. Therefore, a single water-based solution for addressing shale plays globally is not a realistic option. Instead, a customized approach that delivers WBMs formulated specifically for a given shale play has been pursued. Customization relies on detailed analysis of the well parameters of a given shale play. This analysis includes not only the shale morphology and lithology but also well drilling program plans, environmental factors, and other reservoir-specific considerations. Applying appropriate drilling-fluid chemistries on the basis of this detailed analysis has led to the successful field deployment of a number of new shale fluids. Details of the process used for customizing a WBM for a shale play, as well as specific examples of new fluids developed for the Barnett, Fayetteville, and Haynesville shales, are presented in this paper. Full laboratory development and testing are described. Additionally, field-trial results are presented that show that specially designed WBMs can provide performance comparable to that of NAFs, but with enhanced environmental and economic benefits. Application of the customization process to develop WBMs for other shale plays around the globe is also discussed.
Measuring cognitive load and cognition: metrics for technology-enhanced learning (2014)

This critical and reflective literature review examines international research published over the last decade to summarise the different kinds of measures that have been used to explore cognitive load and critiques the strengths and limitations of those focussed on the development of direct empirical approaches. Over the last 40 years, cognitive load theory has become established as one of the most successful and influential theoretical explanations of cognitive processing during learning. Despite this success, attempts to obtain direct objective measures of the theory's central theoretical construct – cognitive load – have proved elusive. This obstacle represents the most significant outstanding challenge for successfully embedding the theoretical and experimental work on cognitive load in empirical data from authentic learning situations. Progress to date on the theoretical and practical approaches to cognitive load are discussed along with the influences of individual differences on cognitive load in order to assess the prospects for the development and application of direct empirical measures of cognitive load especially in technology-rich contexts.
Facial Action Units Detection with Multi-Features and -AUs Fusion (2017)

In this paper, we present our methods for the facial AU occurrence subtask in the FG 2017 Facial Expression Recognition and Analysis challenge (FERA 2017). The task is to detect 10 AUs that occur frequently in the BP4D database. In our approach, we utilized the hand-crafted features (LBPTOP) and learned features (CNN features) which encode the temporal dynamics and static facial appearance respectively. Multiple classifiers including SVM and Random Forest are used to recognize the AU occurrence. Among all different features, the learned CNN features are the most discriminative feature for the task. And the combinations of the multiple features are beneficial. To capture the relationships among AUs, we also apply multi-AUs late fusion, which further boost the performance. Our system achieves an average macro F1 of 49.8% and an average accuracy of 69.4% in the testing set which outperforms the baseline (macro F1 45.2% and average accuracy 56.1%).
Precoding in OFDM-based multi-antenna ultra-wideband systems (2009)

Next-generation ultra-wideband systems will be required to operate in a robust manner over short distances while achieving data rates on the order of gigabits per second. Sophisticated multiantenna techniques can be employed to meet these objectives; in particular, multi-antenna precoding (or beamforming) methods are promising solutions. However, due to the strict power regulations placed on UWB transmissions, conventional precoding techniques are not always suitable for use in UWB networks. In this article we present new theoretical results and practical approaches to performing precoding in OFDM-based multi-antenna UWB systems.
Coded Multiple Exposure Holograms (1968)

Experiments have been performed in which 1000 holograms have been superimposed one upon the other in the same area of photographic emulsion. Each hologram was formed with a uniquely coded reference beam allowing reconstruction of only one of the superimposed holograms while the unaddressed holograms contribute incoherent noise. Signal-to-noise ratios are calculated and measured as a function of the number of superimposed exposures. For the 1000-exposure hologram, the observed signal-to-noise ratio for any one of the individual holograms was 10 dB.
Chemical Analysis of Polar Stratospheric Cloud Particles (1999)

A balloon-borne gondola carrying a particle analysis system, a backscatter sonde, and pressure and temperature sensors was launched from Kiruna, Sweden, on 25 January 1998. Measurements within polar stratospheric cloud layers inside the Arctic polar vortex show a close correlation between large backscatter ratios and enhanced particle-related water and nitric acid signals at low temperatures. Periodic structures in the data indicate the presence of lee waves. The H2O/HNO3 molar ratios are consistently found to be above 10 at atmospheric temperatures between 189 and 192 kelvin. Such high ratios indicate ternary solution particles of H2O, HNO3, and H2SO4 rather than the presence of solid hydrates.
Nighttime Fire/Smoke Detection System Based on a Support Vector Machine (2013)

Currently, video surveillance-based early fire smoke detection is crucial to the prevention of large fires and the protection of life and goods. To overcome the nighttime limitations of video smoke detection methods, a laser light can be projected into the monitored field of view, and the returning projected light section image can be analyzed to detect fire and/or smoke. If smoke appears within the monitoring zone created from the diffusion or scattering of light in the projected path, the camera sensor receives a corresponding signal. The successive processing steps of the proposed real-time algorithm use the spectral, diffusing, and scattering characteristics of the smoke-filled regions in the image sequences to register the position of possible smoke in a video. Characterization of smoke is carried out by a nonlinear classification method using a support vector machine, and this is applied to identify the potential fire/smoke location. Experimental results in a variety of nighttime conditions demonstrate that the proposed fire/smoke detection method can successfully and reliably detect fires by identifying the location of smoke.
Distinct cellular expression pattern of annexins in Hydra vulgaris. (1992)

The annexins are a structurally related family of Ca2+ and phospholipid binding proteins whose function has not been clearly defined. Further investigations of annexin function may be enhanced by studying simpler organisms that express fewer annexin gene products. We previously characterized annexin XII from the freshwater cnidarian Hydra vulgaris (Schlaepfer, D. D., D. A. Fisher, M. E. Brandt, H. R. Bode, J. Jones, and H. T. Haigler. 1992. J. Biol. Chem. 267:9529-9539). In this report, we detected one other hydra annexin (40 kD) by screening hydra cell extracts with antibodies raised against peptides from highly conserved regions of known annexins. The 40-kD protein was expressed at less than 1% of annexin XII levels. These biochemical studies indicate that hydra contain a very limited number of annexin gene products. The cellular hydra annexin distribution was analyzed by indirect immunofluorescence. Using affinity-purified antibodies to annexin XII, the epithelial battery cells were stained throughout the tentacle. A lower level of annexin XII staining was detected in peduncle region epithelial cells. No other cell types showed detectable annexin XII staining. The anti-peptide antibody that specifically detected the 40-kD hydra annexin, maximally stained the cytoplasm of nematocytes. The immunofluorescent results showed that annexin XII and the 40-kD annexin were not co-expressed in the same cells. Since the hydra annexins localized to specific subsets of the total hydra cell types, it is likely that these proteins perform specialized biological roles, and not general "housekeeping" functions which are part of the essential molecular machinery of all cells.
Energy states in short period strain‐balanced GaAsN‐InAs superlattices lattice‐matched to InP(001) (2005)

The electronic structure and band discontinuities of strain balanced GaAs1–xNx (x < 0.05)/InAs superlattices lattice matched to InP(001) is investigated. A six-band Kane Hamiltonian modified for the strain has been used to extract conduction and valence band structure. For nitrogen composition for x < 0.05, type I and type II band alignments between GaAs1–xNx and InAs are predicted for mj = ±3/2 and mj = ±1/2 holes respectively. Finally a transfer matrix method has been used to study the miniband electronic structure of the strain balanced GaAs1–xNx (x < 0.05)/InAs short period superlattice on InP revealing them to reach operating wavelengths beyond 2 µm. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
In Vivo Biodistribution, PET Imaging, and Tumor Accumulation of <sup>86</sup>Y- and <sup>111</sup>In-Antimindin/RG-1, Engineered Antibody Fragments in LNCaP Tumor–Bearing Nude Mice (2009)

The larger antibody formats (IgG and miniantibody) gave higher tumor uptake levels than did the smaller formats (diabody and scFv). These larger formats may be more suitable for radioimmunotherapy applications, evidenced by the preclinical efficacy previously shown by a report on the IgG format. The smaller formats were rapidly cleared from circulation, and the diabody, which accumulated in the tumor, may be more suitable for radiodiagnostic applications.
Single-Crystalline (KC <sub>60</sub> ) <sub> <i>n</i> </sub> : A Conducting Linear Alkali Fulleride Polymer (1994)

Single crystals of a linear cycloadduct conducting polymer, (KC(60))n, have been grown that are a few tenths of a millimeter in length. Partial oxidation under toluene transformed these crystals into bundles of fibers. The degree of polymerization exceeded 100,000.
Japanese LVCSR on the spontaneous scheduling task with JANUS-3 (1997)

This paper presents our ndings during the development of the recognition engine for the Japanese part of the VERBMOBIL speech-to-speech translation project.We describe an e cient method to bootstrap a large vocabulary speech recognizer for spontaneously spoken Japanese speech from a German recognizer and show that the amount of e ort in developing the system could be reduced by using this rapid cross language bootstrapping technique.The Japanese recognizer is integrated into the VERBMO-BIL system and shows very promising results achieving 9.3 word error rate.
(110)-Exposed Gold Nanocoral Electrode as Low Onset Potential Selective Glucose Sensor (2010)

A straightforward electrochemical deposition process was developed to grow gold nanostructures, including nanocoral, nanothorn, branched belt, and nanoparticle, on carbon electrodes by reducing HAuCl4 under constant potentials in mixtures containing CTAC and/or NaNO3. Among the nanostructures, the quasi-one-dimensional nanocoral electrode showed the highest surface area. Because of this, it provided excellent electrochemical performances in cyclic voltammetric (CV) studies for kinetic-controlled enzyme-free glucose oxidation reactions. In amperometric studies carried out at 0.200 V in PBS (pH 7.40, 0.100 M), the nanocoral electrode showed the highest anodic current response. It also offered the greatest sensitivity, 22.6 μAmM(-1)cm(-2), an extended linear range, 5.00×10(-2) mM to 3.00×10(1) mM, and a low detection limit, 1.00×10(1) μm among the electrodes investigated in this study. In addition, the glucose oxidation by the nanocoral electrode started at -0.280 V, more negative than the one of using a commercial Au electrode as the working electrode. This is attributed to the presence of exposed Au (110) surfaces on the electrode. The feature was applied to oxidize glucose selectively in the presence of ascorbic acid (AA) and uric acid (UA), common interferences found in physiological analytes. With an applied voltage at -0.100 V, the AA oxidation (started at -0.080 V) can be avoided while the glucose oxidation still provides a significant response.
Conidial Germination and Appressorial Formation of<i>Colletotrichum capsid</i>and<i>C. gloeosporioides</i>Isolates from Pepper (1995)

Conidial germination and appressorial formation of Colletotrichum capsici and C. gloeosporioides were examined on pepper fruits and in association with some inorganic and organic compounds. Conidial germination and appressorial formation were greater on immature green or ripe red fruits of pepper (Capsicum annuum) variety Long Fruit than in water droplets on glass slides. Conidial germination was significantly (P= 0.05) higher for both fungi as concentrations of either sucrose of KCl increased. Appressorial formation for C. capsici was highest when sucrose was 10 mM and for C. gloeosporioides at 0.1 mM. Appressorial formation was reduced and mycelia formed for both fungi at higher sucrose concentrations, but not at 1-100 mM of KCl. Among six compounds tested for induced conidial germination and appressorial formation, CaCl 2 and sucrose caused a significant (P = 0.05) increase, KCl an intermediate one, and AlCl 3 was lowest. β-resorcilic acid did not stimulate conidial germination and appressorial formation, and Fe-resorcilic acid stimulated conidial germination only for C. capsici. Three test melanin biosynthesis inhibitors at 1 μm per milliliter stimulated conidial germination but varied in causing appressorial formation for both fungi. Appressorial formation of C. capsici was completely inhibited by tricyclazole and stimulated by fthalide and isoprothiolane; appressorial formation of C. gloeosporioides was completely inhibited and stimulated by isoprothiolane and tricyclazole, respectively, and only slightly inhibited by fthalide. Inorganic and organic compounds that affect conidial germination and appressorial formation may play a role in the preinfection process of Colletotrichum spp. on pepper fruits