gebhart/patrepeval huggingface dataset:
High‐density polyethylene/ultrahigh‐molecular‐weight polyethylene blend. I. The processing, thermal, and mechanical properties (2005)

Abstract Various blend ratios of high‐density polyethylene (HDPE) and ultrahigh‐molecular‐weight polyethylene (UHMWPE) were prepared with the objective of determining their suitability as biomaterials. Although the presence of HDPE in the blends enabled melt processing, the presence of UHMWPE helped to improve the toughness of the resulting blends. The processability of the blends was investigated with the Brabender torque, which was used as an indication of the optimum blend conditions. The blends were characterized with differential scanning calorimetry. The mechanical tests performed on the blends included tensile, flexural, and impact tests. A 50:50 (w/w) blend yielded optimum properties in terms of the processability and mechanical properties. The tensile property of the 50:50 blend was intermediate between those of HDPE and UHMWPE, but the strain at break increased 200% in comparison with that of both neat resins. The energy at break of the 50:50 blend revealed an improvement in the toughness. The fracture mechanism was also investigated with scanning electron microscopy. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 413–425, 2005
Perthiyl radicals, trisulfide radical ions, and sulfate formation: a combined photolysis and radiolysis study on redox processes with organic di- and trisulfides (1992)

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPerthiyl radicals, trisulfide radical ions, and sulfate formation: a combined photolysis and radiolysis study on redox processes with organic di- and trisulfidesSteven A. Everett, Christian Schoeneich, John H. Stewart, and Klaus Dieter AsmusCite this: J. Phys. Chem. 1992, 96, 1, 306–314Publication Date (Print):January 1, 1992Publication History Published online1 May 2002Published inissue 1 January 1992https://pubs.acs.org/doi/10.1021/j100180a058https://doi.org/10.1021/j100180a058research-articleACS PublicationsRequest reuse permissionsArticle Views511Altmetric-Citations59LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts
Securinine, a GABAA receptor antagonist, enhances macrophage clearance of phase II<i>C. burnetii</i>: comparison with TLR agonists (2007)

Innate immune cell stimulation represents a complementary approach to vaccines and antimicrobial drugs to counter infectious disease. We have used assays of macrophage activation and in vitro and in vivo phase II Coxiella burnetii infection models to compare and contrast the activity of a novel innate immune cell agonist, securinine, with known TLR agonists. As expected, TLR agonists, such as LPS (TLR4) and fibroblast-stimulating lipopeptide-1 (FSL-1; TLR2), induced macrophage activation and increased macrophage killing of phase II C. burnetii in vitro. FSL-1 also induced accelerated killing of C. burnetii in vivo. Securinine, a gamma-aminobutyric acid type A receptor antagonist, was found to induce TLR-independent macrophage activation in vitro, leading to IL-8 secretion, L-selectin down-regulation, and CD11b and MHC Class II antigen up-regulation. As seen with the TLR agonists, securinine also induced accelerated macrophage killing of C. burnetii in vitro and in vivo. In summary, as predicted by the literature, TLR agonists enhance macrophage killing of phase II C. burnetii in vitro, and at least for TLR2 agonists, this activity occurs in vivo as well. Securinine represents a novel macrophage agonist, which has similar effects as TLR agonists in this model yet apparently, does not act through known TLRs. Securinine has minimal toxicity in vivo, suggesting it or structurally similar compounds may represent novel, therapeutic adjuvants, which increase resistance to intracellular pathogens.
Influence of Glucose, Alcohol and Glycerol on Galactose Tolerance in Man (1987)

Six volunteers were given 0.5 g galactose/kg body weight alone (A) or with 0.5 g glucose/kg (B) or with 0.5 g glycerol/kg body weight (C). Meals A and B were also given 15 min after ingestion of 300 mg ethanol/kg body weight. Glycerol did not influence the serum galactose response to galactose. Glucose reduced the serum galactose response as was expected. Administration of alcohol prior to a galactose test meal increased the mean area under the serum galactose response curve (p less than 0.01); when glucose was given with galactose after alcohol ingestion, the serum galactose response was significantly reduced (p less than 0.01) when compared to the serum galactose response to galactose after alcohol, but remained higher than after the galactose and glucose test meal. Glucose, therefore, can reduce the effect of alcohol on galactose levels but alcohol can abolish the effect of glucose on galactose metabolism.
Harnessing the Liquid‐Phase Exfoliation of Graphene Using Aliphatic Compounds: A Supramolecular Approach (2014)

The technological exploitation of the extraordinary properties of graphene relies on the ability to achieve full control over the production of a high-quality material and its processing by up-scalable approaches in order to fabricate large-area films with single-layer or a few atomic-layer thickness, which might be integrated in working devices. A simple method is reported for producing homogenous dispersions of unfunctionalized and non-oxidized graphene nanosheets in N-methyl-2-pyrrolidone (NMP) by using simple molecular modules, which act as dispersion-stabilizing compounds during the liquid-phase exfoliation (LPE) process, leading to an increase in the concentration of graphene in dispersions. The LPE-processed graphene dispersion was shown to be a conductive ink. This approach opens up new avenues for the technological applications of this graphene ink as low-cost electrodes and conducting nanocomposite for electronics.
The Effects of Lipo-Prostaglandin E1 on Axial Pattern Flaps in Rabbits (1995)

The effects of lipo-prostaglandin E1 (lipo-PGE1), lipid microspheres containing PGE1, on axial pattern flaps were examined using 12 x 20 cm axial pattern flaps based on the right superficial inferior epigastric vessels on the abdomens of rabbits. The surviving area of the skin flap in the lipo-PGE1 group (0.197 +/- 14.1 cm2; n = 10) was significantly increased (p < 0.02) compared with the saline control group (110.4 +/- 5.5 cm2; n = 10). Changes in pedicle blood flow after lipo-PGE1 administration were determined using an ultrasonic pulsed Doppler flowmeter (n = 5). Blood flow in the artery was increased immediately after administration, and it was maintained for 40 minutes. The surface blood flow at the caudal end of the flap on the nonpedicle side, where it was poor, was measured using laserflowgraphy. Blood flow in the skin flap surface was improved 5 to 15 minutes after lipo-PGE1 administration, and it was maintained for as long as 60 minutes. Venous occlusion of the skin flap was also improved (n = 3). In conclusion, lipo-PGE1 increased the blood flow in the axial pattern flaps, resulting in significant enlargement of the surviving skin flap area.
Treatment of Oily Cafeteria Wastewater by Single-Phase and Two-Phase Anaerobic Filter (1990)

Cafeteria wastewater containing about 30% of lipid on COD basis was treated at 20°C by laboratory-scale anaerobic filter in single-phase system and two-phase systems. Stable COD removal (about 80%) was achieved in spite of large fluctuation in influent COD concentration (normal range of 1,300 - 2,500 mg−l) both in the single-phase system (hydraulic retention time (HRT) longer than 1.3 d) and in the two-phase system (HRT longer than 3.3 d). The single-phase system gave better effluent quality than the two-phase system because the former entrapped suspended solids better than the latter. However, material balance revealed that methane conversion from removed COD was higher in the two-phase system than the single-phase system. The single-phase system perhaps removed lipids by entrapment with filter media without biodegradation, and this might cause clogging problems in long-term operation. The two-phase system is recommended since it degrades lipids better than the single-phase system.
16-ALKYLATED CORTICOIDS. II. 9α-FLUORO-16α-METHYLPREDNISOLONE 21-ACETATE<sup>1</sup> (1958)

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT16-ALKYLATED CORTICOIDS. II. 9α-FLUORO-16α-METHYLPREDNISOLONE 21-ACETATE1Eugene P. Oliveto, Richard Rausser, Lois Weber, A. L. Nussbaum, William Gebert, C. Thomas Coniglio, E. B. Hershberg, S. Tolksdorf, Milton Eisler, P. L. Perlman, and M. M. PechetCite this: J. Am. Chem. Soc. 1958, 80, 16, 4431Publication Date (Print):August 1, 1958Publication History Published online1 May 2002Published inissue 1 August 1958https://pubs.acs.org/doi/10.1021/ja01549a090https://doi.org/10.1021/ja01549a090research-articleACS PublicationsRequest reuse permissionsArticle Views369Altmetric-Citations48LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
Synthèse Facile de Pyrazines Disubstituées en 2 et 3 (1973)

Recemment le groupe de pyrazines a ete trouve comme les constituants importants d'arome de l'aliment brule (le cafe, le cacao, la cacahouete etc.). Pour la synthese de pyrazines disubstituees en 2 et 3, la condensa (1967).
Energy balance in wireless networks using connection segmentation and range control (2004)

In a wireless network some nodes incur a disproportionate share of the packet forwarding burden than the others: nodes lying toward the center tend to lie on more paths and therefore expend more energy in forwarding packets than other nodes, resulting in a shorter lifetime. While routes can be selected to alleviate this problem, we explore an entirely different and complementary approach by exploiting a wireless node's capability to adjust its transmission power. Each connection is partitioned into two segments, each of which uses the regular network or direct transmission between the source and the destination. The relative durations of each segment are optimized to balance energy consumption across the network. This paper formulates an energy balance optimization problem in terms of the segmentation time, and an algorithm is presented that reduces variance in energy consumption at the cost of a modest increase in average energy consumption. The paper also presents a distributed algorithm for this optimization problem.
<i>Streptococcus mutans</i> Strains Harboring Collagen-binding Adhesin (2004)

A previously unidentified 120-kDa protein was detected in Streptococcus mutans strain Z1 and was involved in the cold-agglutination of the strain. We have identified the gene, designated cnm, as being involved in the agglutination of strain Z1 following random mutagenesis. The amino acid sequence of the deduced Cnm protein exhibited high similarity to those of collagen-binding adhesins from staphylococci and other organisms. To confirm whether the protein is involved in collagen-binding, we cloned a cnm gene fragment, overexpressed it in E.coli, and prepared crude extracts. The extracts containing recombinant protein exhibited binding to immobilized collagen and laminin but not to fibronectin. Compared with the parental strain Z1, the cold-agglutination-negative mutant 05A02 exhibited reduced binding to collagen and laminin but retained that to fibronectin. This gene was detected in some strains of S. mutans. Therefore, the cnm gene encoded a new strain-specific member of the collagen-binding adhesin family.
Colloid Formation During Waste Form Reaction: Implications for Nuclear Waste Disposal (1992)

Insoluble plutonium- and americium-bearing colloidal particles formed during simulated weathering of a high-level nuclear waste glass. Nearly 100 percent of the total plutonium and americium in test ground water was concentrated in these submicrometer particles. These results indicate that models of actinide mobility and repository integrity, which assume complete solubility of actinides in ground water, underestimate the potential for radionuclide release into the environment. A colloid-trapping mechanism may be necessary for a waste repository to meet long-term performance specifications.
Optimization and application of riblets for turbulent drag reduction (1984)

Riblet surfaces have been tested in boundary layers having different upstream histories and at higher Reynolds numbers than previously reported. The drag reduction for the riblet surfaces was found to be dependent on the height and spacing of the riblets in law-of-the-wall variables regardless of the free-stream Reynolds number or upstream boundary-layer history. Micro-photographs of the actual riblet geometries are examined to determine the effect of rib details on the riblet drag-reduction performances. To further increase drag-reduction performance, riblet surfaces are combined with another drag-reduction concept, the large-eddy breakup device (LEBU). In addition, the yaw sensitivity of riblets is evaluated, as well as the characteristics of riblet surfaces manufactured out of a thin vinyl sheet.
Microbial Community Dynamics during Production of the Mexican Fermented Maize Dough Pozol (2000)

The dynamics of the microbial community responsible for the traditional fermentation of maize in the production of Mexican pozol was investigated by using a polyphasic approach combining (i) microbial enumerations with culture media, (ii) denaturing gradient gel electrophoresis (DGGE) fingerprinting of total community DNA with bacterial and eukaryotic primers and sequencing of partial 16S ribosomal DNA (rDNA) genes, (iii) quantification of rRNAs from dominant microbial taxa by using phylogenetic oligonucleotide probes, and (iv) analysis of sugars and fermentation products. A Streptococcus species dominated the fermentation and accounted for between 25 and 75% of the total flora throughout the process. Results also showed that the initial epiphytic aerobic microflora was replaced in the first 2 days by heterofermentative lactic acid bacteria (LAB), including a close relative of Lactobacillus fermentum, producing lactic acid and ethanol; this heterolactic flora was then progressively replaced by homofermentative LAB (mainly close relatives of L. plantarum, L. casei, and L. delbrueckii) which continued acidification of the maize dough. At the same time, a very diverse community of yeasts and fungi developed, mainly at the periphery of the dough. The analysis of the DGGE patterns obtained with bacterial and eukaryotic primers targeting the 16S and 18S rDNA genes clearly demonstrated that there was a major shift in the community structure after 24 h and that high biodiversity-according to the Shannon-Weaver index-was maintained throughout the process. These results proved that a relatively high number of species, at least six to eight, are needed to perform this traditional lactic acid fermentation. The presence of Bifidobacterium, Enterococcus, and enterobacteria suggests a fecal origin of some important pozol microorganisms. Overall, the results obtained with different culture-dependent or -independent techniques clearly confirmed the importance of developing a polyphasic approach to study the ecology of fermented foods.
Geometric Constellation Shaping for Fiber Optic Communication Systems via End-to-end Learning (2018)

In this paper, an unsupervised machine learning method for geometric constellation shaping is investigated. By embedding a differentiable fiber channel model within two neural networks, the learning algorithm is optimizing for a geometric constellation shape. The learned constellations yield improved performance to state-of-the-art geometrically shaped constellations, and include an implicit trade-off between amplification noise and nonlinear effects. Further, the method allows joint optimization of system parameters, such as the optimal launch power, simultaneously with the constellation shape. An experimental demonstration validates the findings. Improved performances are reported, up to 0.13 bit/4D in simulation and experimentally up to 0.12 bit/4D.
Role of fibrillin-1 in hypertensive and diabetic glomerular disease (2005)

The microfibrillar protein fibrillin-1 is a component of the mesangial matrix. Defects in fibrillin-1 predisposes individuals to vascular damage in Marfan syndrome, but the role of fibrillin-1 in kidney disease is unknown. We hypothesized that fibrillin-1 is involved in hypertensive or diabetic glomerular disease. DOCA-salt hypertension or streptozotocin (STZ) diabetes led to a significant increase in glomerular fibrillin-1 deposition. To test the functional role of fibrillin-1, DOCA hypertension and STZ diabetes were induced in mice homozygous for a mutation leading to a fivefold lower expression of fibrillin-1 (mgR/mgR). Untreated male mgR/mgR mice usually die from aortic dissection during the first 4 mo of life. All DOCA-treated mgR/mgR mice died within 2 wk after onset of DOCA treatment. DOCA-treated heterozygous (mgR/+) and their wild-type littermates displayed similar blood pressure levels, but albuminuria was significantly lower in mgR/+ than in wild-type mice after DOCA treatment. Similarly, STZ diabetic mgR/mgR and mgR/+ developed lower albuminuria than wild-type mice despite higher blood glucose levels in mgR/mgR and mgR/+ compared with wild-type mice. Blood pressure, blood glucose, and albuminuria did not differ among untreated mgR/mgR, mgR/+, and wild-type mice, respectively. In diabetic mgR/+ and mgR/mgR, but not in wild-type mice, an induction of glomerular decorin expression was observed. Thus underexpression of fibrillin-1 predisposes individuals to lethal aortic dissection in the presence of hypertension. On the other hand, albuminuria as a parameter of microvascular damage in hypertension and diabetes was ameliorated in fibrillin-1-underexpressing mice, possibly due to a compensatory upregulation of decorin. We conclude that fibrillin-1 may contribute to glomerular damage in hypertensive and diabetic kidney disease.
Idiopathic dilated cardiomyopathy: familial prevalence and HLA distribution. (1997)

The present finding supports an HLA linked predisposition to familial dilated cardiomyopathy. The HLA type DR4 was significantly more common in familial than in non-familial cases. The DR4 halotype was associated with two thirds of the families at risk for dilated cardiomyopathy.
A high-throughput device for size based separation of C. elegans developmental stages (2014)

Caenorhabditis elegans is a widely used model organism to study development, aging and behavior. Many of these biological studies require staging a large number of worms to assay a synchronized population of animals. Conventional synchronization techniques such as manual picking, gravity stratification and chemical bleaching are labor-intensive and could perturb animals' physiology. Thus, there is a need for a simple inexpensive technology to sort a mixed population of worms based on their developmental stages with minimal perturbation. Here we demonstrate a simple but accurate and high-throughput technique to sort based on animal size, which correlates well with developmental stages. The device consists of an array of geometrically optimized pillars that act as a sieve to allow worms of specific sizes to rapidly move through. With optimized chamber heights, pillar spacing and driving pressures, these binary separation devices are capable of independently separating a mixture of worms at two different stages at average efficiency of around 95%, and throughput of hundreds of worms per minute. In addition, when four devices are used sequentially, we demonstrate the ability to stratify a mixture of worms of all developmental stages with >85% overall efficiency.
Growth, fatty acid profile in major lipid classes and lipid fluidity of Aurantiochytrium mangrovei Sk-02 as a function of growth temperature (2012)

Aurantiochytrium mangrovei Sk-02 was grown in a medium containing glucose (40 g/l), yeast extract (10 g/L) and sea salts (15 g/L) at temperatures ranging from 12 to 35°C. The fastest growth (µmax= 0.15 h(-1)) and highest fatty acid content of 415 mg/g-dry cell weight were found in the cells grown at 30°C. However, the cells grown at 12°C showed the highest percentage of polyunsaturated fatty acid (PUFA) (48.6% of total fatty acid). The percentage of docosahexaenoic acid (DHA) and pentadecanoic acid (C15:0) decreased with an increase in the growth temperature, whereas, palmitic acid (C16:0), stearic acid (C18:0) and DPA (C22:5n6) increased with an increase in the growth temperature. The composition of the major lipid class (%w/w) was slightly affected by the growth temperature. The fluidity of the organelle membrane or intracellular lipid (by DPH measurement) decreased with an increase in the growth temperatures, while the plasma membrane fluidity (by TMA-DPH measurement) could still maintain its fluidity in a wide range of temperatures (15 - 37°C). Furthermore, the distribution of DHA was found to be higher (36 - 54%) in phospholipid (PL) as compared to neutral lipid (NL) (20 - 41%).
A 38-GHz 32-Element Phased-Array Transmitter Based on Scalable 8-Element Phased-Array Modules for 5G MMW Data Links (2020)

This paper presents a 38-GHz 32-element phased-array Tx (transmitter) for the 5G millimeter wave (MMW) communications. The 8-element phased-array Tx modules with 2 GHz IF/5 GHz LO are implemented, and four pieces of the module are stacked to realize an 8×4 brick array. The 38 GHz measurements of the 32-element Tx show 41.8 dBm EIRP at <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$OP_{1dB}$</tex> with -41.8 dBc image rejection ratio (IMRR) and -35 dBc ×8 LO rejection ratio (×8 LORR). The EIRPs at <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$OP_{1dB}$</tex> in beam scanning around ±60° azimuth/± 30° elevation planes are 41.8 to 38.3 dBm. The Tx is utilized for data links with a horn antenna module in 35 m that demonstrates 256 QAM/100M-BR (baud rate) with -33.1 dB EVM. The data links of the Tx with a 4-element phased-array Rx (receiver) in 6 m demonstrates 64 QAM/200M-BR with -26.4 dB EVM. The scalable Tx module shows potential for 5G sub-6 GHz/MMW coexistent applications and can be expanded as a massive phased-array using the simple/low-cost stacked methods.