gebhart/patrepeval huggingface dataset:
Modeling Ground-Air Wireless Connectivity: Continuous Connection Probability Analysis (2021)

In this paper, we consider three ground-aircraft communication issues, namely, ground-centric connectivity, aircraft-centric connectivity, and link capacity analysis. Particularly, we propose the continuous connection probability over at least τ seconds, termed as τ-connectivity, for the ground-centric link and aircraft-centric link respectively, which are derived in the expression of several key parameters such as the aircraft/ground station density, the aircraft velocity, and the connectable elevation angle threshold. Theoretical tradeoff between ergodic outage capacity and the number of connected aircraft is analyzed for low and high transmit power regimes. The hypotheses in the ground-centric τ-connectivity model are tested, and we observe a good match between the theoretic probability and the real world data-based probability although some real world aircraft statistic characters do not match the ideal assumption perfectly. Next, the aircraft-centric τ-connectivity is analyzed theoretically. Approximate yet practically accurate closed form aircraft-centric connection probabilities are derived and verified with Monte Carlo simulations. Furthermore, considering atmospheric gas and cloud attenuation, we compare the link budget and capacity between the ground-centric ground-to-aircraft link and the ground-to-satellite link under the τ-connectivity and demonstrate the advantage of ground-aircraft communication.
LaRVAE: Label Replacement VAE for Semi-Supervised Disentanglement Learning (2020)

Learning interpretable and disentangled representations is a crucial yet challenging task in representation learning. In this work, we focus on semi-supervised disentanglement learning and extend work by Locatello et al. (2019) by introducing another source of supervision that we denote as label replacement. Specifically, during training, we replace the inferred representation associated with a data point with its ground-truth representation whenever it is available. Our extension is theoretically inspired by our proposed general framework of semi-supervised disentanglement learning in the context of VAEs which naturally motivates the supervised terms commonly used in existing semi-supervised VAEs (but not for disentanglement learning). Extensive experiments on synthetic and real datasets demonstrate both quantitatively and qualitatively the ability of our extension to significantly and consistently improve disentanglement with very limited supervision.
Development and Validation of LAMP Primer Sets for Rapid Identification of Aspergillus Fumigatus Carrying the cyp51A TR46 Azole Resistance Gene (2021)

Abstract Infections due to triazole resistant Aspergillus fumigatus are increasingly reported worldwide and are associated with treatment failure and mortality. The principal class of azole resistant isolates is characterized by the presence of tandem repeats of 34 bp or 46 bp within the promoter region of the cyp51A gene. Loop-mediated isothermal amplification (LAMP) is a widely used nucleic acid amplification system which is fast and specific. Here 2 we describe a LAMP assay method to detect the 46 bp tandem repeat insertion in the cyp51A gene promoter region based on novel LAMP primer sets. It also differentiated strains with TR46 tandem repeats from those with TR34 tandem repeats. These results showed this TR46-LAMP method is specific, rapid, and also provides crucial insights to enable development of novel antifungal therapeutic strategies against severe fungal infections due to A. fumigatus with TR46 tandem repeats.
Identification of Genes Associated with Chlorophyll Accumulation in Flower Petals (2014)

Plants have an ability to prevent chlorophyll accumulation, which would mask the bright flower color, in their petals. In contrast, leaves contain substantial amounts of chlorophyll, as it is essential for photosynthesis. The mechanisms of organ-specific chlorophyll accumulation are unknown. To identify factors that determine the chlorophyll content in petals, we compared the expression of genes related to chlorophyll metabolism in different stages of non-green (red and white) petals (very low chlorophyll content), pale-green petals (low chlorophyll content), and leaves (high chlorophyll content) of carnation (Dianthus caryophyllus L.). The expression of many genes encoding chlorophyll biosynthesis enzymes, in particular Mg-chelatase, was lower in non-green petals than in leaves. Non-green petals also showed higher expression of genes involved in chlorophyll degradation, including STAY-GREEN gene and pheophytinase. These data suggest that the absence of chlorophylls in carnation petals may be caused by the low rate of chlorophyll biosynthesis and high rate of degradation. Similar results were obtained by the analysis of Arabidopsis microarray data. In carnation, most genes related to chlorophyll biosynthesis were expressed at similar levels in pale-green petals and leaves, whereas the expression of chlorophyll catabolic genes was higher in pale-green petals than in leaves. Therefore, we hypothesize that the difference in chlorophyll content between non-green and pale-green petals is due to different levels of chlorophyll biosynthesis. Our study provides a basis for future molecular and genetic studies on organ-specific chlorophyll accumulation.
Optimizations of GaAs Nanowire Solar Cells (2016)

The efficiency of GaAs nanowire (NW) solar cells can be significantly improved with no new processing steps or material requirements. We report coupled optoelectronic simulations of a GaAs NW solar cell with a vertical p-i-n junction and a high-bandgap AlInP passivating shell. Our frequency-dependent model facilitates calculation of quantum efficiency for the first time in NW solar cells. For passivated NWs, we find that short-wavelength photons can be most effectively harnessed by using a thin emitter, while long-wavelength photons are best utilized by extending the intrinsic region to the NW/substrate interface and using the substrate as a base. These two easily implemented changes, coupled with the increase of NW height to 3.5 μm with realistic surface recombination in the presence of a passivation shell, result in an NW solar cell with greater than 19% efficiency.
Novel Cake Washer for Removing Oil-Based Calcium Carbonate Filter Cake in Horizontal Wells (2020)

An impermeable layer “filter cake” usually forms during the overbalanced drilling technique. Even though it helps in protecting the formation from a further invasion of drilling fluids, the removal of this layer is essential for a proper cement job and to avoid any reduction in wellbore deliverability. The design of the removal process is complicated and depends on the filter cake composition and homogeneity. This paper presents an experimental evaluation on the usage of a novel cake washer (NCW) in the removal of a filter cake formed by an invert emulsion oil-based drilling fluid that contains calcium carbonate as a weighting material while drilling a horizontal reservoir. The proposed NCW is a mixture of organic acid, mutual solvent and nonionic surfactant. It is designed to enable restored wellbore permeability for a sustainable production. Since the filter cake mainly consists of the weighting material, the solubility of calcium carbonate in NCW at different ranges of temperature, duration and concentration was investigated. An actual casing joint was used to test the corrosion possibility of the treating solution. High-pressure and high-temperature (HPHT) filtration tests on ceramic discs and Berea sandstone core samples were conducted to measure the efficiency of the filter cake removal and the retained permeability. Ethylene glycol mono butyl ether (EGMBE) was used as a mutual solvent and the solubility was higher compared to when the mutual solvent was not used in the washer formulation. A significant increase in calcium carbonate dissolution with time was observed for a duration of 24 h. The solubility was found to be proportional to the concentration of NCW with optimum results of 99% removal at a temperature of around 212 °F. At those conditions, no major corrosion problems were detected. Permeability of the core retained its pristine value after the treatment.
Iridium oxide/platinum gray composite coatings on microelectrodes for neural stimulation (2017)

The shrinking size of microelectrodes leads to high electrode/tissue interfacial impedance and low charge injection ability. In order to achieve safe, efficient and durable electrode performances, we proposed a layer-by-layer electrodeposition method to modify the bare platinum microelectrodes with nanostructures. Combining the advantages of platinum gray (Pt gray) with iridium oxide (IrO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> ), herein a low impedance, high cathodic charge storage capacity (CSC <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">c</sub> ) and high charge injection IrO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> /Pt gray microelectrode was fabricated with nanoscale roughness, which was much higher than each simple coating. Furthermore, it demonstrated superior mechanical and electrochemical stability. Morphological tests showed that nanocone-shaped Pt gray provided large area and hence good adhesion for dense IrO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> deposition, which was beneficial for long-term mechanical stability of the composite coating.
ChemInform Abstract: Enantioselective Domino Heck‐Allylic Amination Reactions. (1999)

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
New concepts of cellular fatty acid uptake: role of fatty acid transport proteins and of caveolae (2004)

Efficient uptake and channelling of long-chain fatty acids (LCFA) are critical cell functions. Evidence is emerging that proteins are important mediators of LCFA-trafficking into cells and various proteins have been suggested to be involved in this process. Amongst these proteins is a family of membrane-associated proteins termed fatty acid transport proteins (FATP). So far six members of this family, designated FATP 1-6, have been characterized. FATP 1, 2 and 6 show a highly-conserved AMP-binding region that participates in the activation of very-long-chain fatty acids (VLCFA) to form their acyl-CoA derivatives. The mechanisms by which FATP mediate LCFA uptake are not well understood, but several studies provide evidence that uptake of LCFA across cellular membranes is closely linked to acyl-CoA synthetase activity. It is proposed that FATP indirectly enhance LCFA uptake by activating VLCFA to their CoA esters, which are required to maintain the typical structure of lipid rafts in cellular membranes. Recent work has shown that the structural integrity of lipid rafts is essential for cellular LCFA uptake. This effect might be exerted by proteins, e.g. caveolin-1 and FAT/CD36, that use lipid rafts as platforms and bind or transport LCFA. The proposed molecular mechanisms await further experimental investigation.
High-Precision Jet Finishing for Optics(Surface and edge finishing) (2005)

Ultra precision finishing of conformal, free form, steeply concave or millimeter-size optics is challenging, particularly with sub-aperture processes required to ensure the necessary determinism. Newly developed technology based on the impingement of a jet on a work-piece surface is, on the other hand, well suited for finishing these classes of optics. This will be demonstrated through a series of examples spanning a wide range of materials, geometries and specifications including steeply concave shapes such as domes, and millimeter-sized optics. In particular, a 23mm diameter steep concave lens with a 20mm radius of curvature was polished from λ/10 to better than λ/100 RMS in two iterations. The same precision was achieved on a concave optic with only a 2mm diameter and < 5mm radius of curvature. Roughness better than 1nm RMS is routinely achieved.
A comparative study of contrast agents for endoscopic retrograde pancreatography. (1991)

Pancreatitis is a major cause of morbidity and mortality secondary to endoscopic retrograde pancreatography (ERP). One factor that may cause post-ERP pancreatitis is the type of contrast media utilized during the procedure. The purpose of this prospective, double-blind, randomized study was to evaluate the effects of three contrast agents of differing osmolality and ionicity on changes between pre- and post-ERP chemical changes in serum amylase and lipase and development of clinical symptoms of acute pancreatitis. Our study of 53 patients showed that those who received Omnipaque a non-ionic, relatively iso-osmolar contrast agent, had a significantly lower serum amylase (p = 0.0038) and serum lipase (p = 0.0002) in post-ERP serological markers, compared with patients who received the ionic agents, Hypaque meglumine 60% or Hexabrix. In addition, the development of clinical symptoms of pancreatitis was less in patients who received Omnipaque than in those who received Hexabrix or Hypaque (1 vs. 3 vs. 4). No significant difference was found between patients who received ionic agents. No patient who received Omnipaque needed hospitalization, whereas one (6%) patient who received Hexabrix was hospitalized compared to three (20%) hospitalized patients who received Hypaque. When the initial cost and cost of hospitalization were compared, the non-ionic contrast medium was also found to be more cost-effective for the patient. In summary, the risk of post-ERP acute pancreatitis was significantly lower for patients who received the non-ionic contrast agent than for those who received the ionic agents.
Accumulation of some heavy metals in plants and soils adjacent to Cairo – Alexandria agricultural highway (2017)

Automobile exhausts are considered the main source of air pollution with heavy metals. Airborne pollutants are precipitated on soils surrounding highways causing serious ecological hazards. The current study aimed at evaluating levels of Pb, Ni, Co and Cd in surface (0-15 cm) and subsurface (15-40 cm) soils nearby Cairo-Alexandria agricultural highway, and their accumulation in plants grown thereon. Seven locations were sampled at interval distances 50 meters on both sides of the highway road near Toukh city (Qualubya Governorate). Cabbage and citrus plants were also sampled and separated into its parts. Results revealed that the investigated soils are contaminated with Pb, Ni and Cd. These contaminants were brought to the subsurface layers of the soil at relatively high concentrations. Total and DTPA-extractable contents of Pb and Ni in the top surface soil decreased with increasing the distance from the high way on both sides of the road. Moreover, concentrations of these metals in the cabbage parts were significantly correlated with their total and DTPA-extractable contents. However, Co and Cd in soils seemed to be not affected by the exhausts of the cars on the highway. Heavy metals decreased in cabbage parts as follows: root > stem > outer leaves > inner leaves > core. Calculated BAF values for Pb, Ni and Co were very low indicating that cabbage might be an excluder for these metals whereas, their transfer from roots to shoots (transfer factor, Ts) were high. Heavy metal concentrations in citrus decreased as leaves > flavedo > albedo > segments. Generally, concentrations of heavy metals in plants particularly Pb exceeded the permissible limits.
Measurement of $b$-quark fragmentation properties in jets using the decay $B^{\pm} \to J/\psi K^{\pm}$ in $pp$ collisions at $\sqrt{s} = 13$ TeV with the ATLAS detector (2021)

The fragmentation properties of jets containing $b$-hadrons are studied using charged $B$ mesons in 139 fb$^{-1}$ of $pp$ collisions at $\sqrt{s} = 13$ TeV, recorded with the ATLAS detector at the LHC during the period from 2015 to 2018. The $B$ mesons are reconstructed using the decay of $B^{\pm}$ into $J/ψK^{\pm}$, with the $J/ψ$ decaying into a pair of muons. Jets are reconstructed using the anti-$k_t$ algorithm with radius parameter $R=0.4$. The measurement determines the longitudinal and transverse momentum profiles of the reconstructed $B$ hadrons with respect to the axes of the jets to which they are geometrically associated. These distributions are measured in intervals of the jet transverse momentum, ranging from 50 GeV to above 100 GeV. The results are corrected for detector effects and compared with several Monte Carlo predictions using different parton shower and hadronisation models. The results for the longitudinal and transverse profiles provide useful inputs to improve the description of heavy-flavour fragmentation in jets.
Complex Tetrahydrofurans from Carbohydrate Lactones: THF Amino Acids as Building Blocks for Unnatural Biopolymers. (2003)

Abstract For Abstract see ChemInform Abstract in Full Text.
Varying whole body vibration amplitude differentially affects tendon and ligament structural and material properties (2020)

Whole Body Vibration (WBV) is becoming increasingly popular for helping to maintain bone mass and strengthening muscle. Vibration regimens optimized for bone maintenance often operate at hypogravity levels (<1 G) and regimens for muscle strengthening often employ hypergravity (>1 G) vibrations. The effect of vibratory loads on tendon and ligament properties is unclear though excessive vibrations may be injurious. Our objective was to evaluate how tendon gene expression and the mechanical/histological properties of tendon and ligament were affected in response to WBV in the following groups: no vibration, low vibration (0.3 G peak-to-peak), and high vibration (2 G peak-to-peak). Rats were vibrated for 20 min a day, 5 days a week, for 5 weeks. Upon sacrifice, the medial collateral ligament (MCL), patellar tendon (PT), and the Achilles Tendon (AT) were isolated with insertion sites intact. All tissues were tensile tested to determine structural and material properties or used for histology. Patellar tendon was also subjected to quantitative RT-PCR to evaluate expression of anabolic and catabolic genes. No differences in biomechanical data between the control and the low vibration groups were found. There was evidence of significant weakness in the MCL with high vibration, but no significant effect on the PT or AT. Histology of the MCL and PT showed a hypercellular tissue response and some fiber disorganization with high vibration. High vibration caused an increase in collagen expression and a trend for an increase in IGF-1 expression suggesting a potential anabolic response to prevent tendon overuse injury.
Carbonate and Ionic Liquid Mixes as Electrolytes To Modify Interphases and Improve Cell Safety in Silicon-Based Li-Ion Batteries (2017)

Among the candidates as negative electrode, silicon is now one of the most attractive alternatives to graphite and has been the subject of many investigations for the past decade. The commercialization of Si electrodes is nevertheless blocked by the inability to overcome the mechanical degradation and electrolyte consumption occurring as a result of the inherent volume expansion upon silicon alloying. The unique combination of their properties renders ionic liquids very attractive and promising candidates to replace the benchmark organic carbonates and could enable an enhanced control of species constituting the solid–electrolyte interface (SEI). In the present study, evolutions of ionic liquid-based electrolytes (pure ionic liquid and ionic liquid/carbonate mixes) and the subsequently formed SEI are monitored upon aging and cycling in full Li-ion cells using nonprelithiated silicon electrodes. X-ray photoelectron spectroscopy, typically probing the first few nm of the surface of the sample, allowed monitoring of the evolution and possible degradation of the ionic liquid based electrolytes upon aging and cycling of complete Si/NMC batteries. Magic angle spinning NMR combined with scanning transmission electron microscopy-electron energy loss spectroscopy is more sensitive to changes occurring in the SEI composition. The degradation of ionic liquid components PYR13 and TFSI is evidenced and their influence on the formation of species at the surface of the silicon electrode clearly observed. However, the presence of the ionic liquid components does not prevent the degradation of carbonates in the parasitic reactions that are consuming the cyclable lithium. Therefore, the failure mechanism scenario is similar to that observed for the full cell using benchmark carbonate electrolytes. Hazard level assessments nevertheless reveal that the addition of ionic liquids is in fact able to moderate the intensity of safety relevant events and improve the cell safety.
Correlation of rupture dynamics to the nonlinear backscatter response from polymer-shelled ultrasound contrast agents (2015)

Polymer-shelled ultrasound contrast agents (UCAs) may expel their encapsulated gas subject to ultrasound-induced shell buckling or rupture. Nonlinear oscillations of this gas bubble can produce a subharmonic component in the ultrasound backscatter. This study investigated the relationship between this gas-release mechanism and shell-thickness-to-radius ratios (STRRs) of polymer-shelled UCAs. Three types of polylactide-shelled UCAs with STRRs of 7.5, 40, and 100 nm/μm were studied. Each UCA population had a nominal mean diameter of 2 μm. UCAs were subjected to increasing static overpressure ranging from 2 to 330 kPa over a duration of 2 h in a custom-designed test chamber while being imaged using a 200× magnification video microscope at a frame rate of 5 frames/s. Digitized video images were binarized and processed to obtain the cross-sectional area of individual UCAs. Integration of the normalized cross-sectional area over normalized time, defined as buckling factor (Bf), provided a dimensionless parameter for quantifying and comparing the degree of pre-rupture buckling exhibited by the UCAs of different STRRs in response to overpressure. The UCAs with an STRR of 7.5 nm/μm exhibited a distinct shell-buckling phase before shell rupture (Bf < 1), whereas the UCAs with higher STRRs (40 and 100 nm/μm) did not undergo significant prerupture buckling (Bf ≈ 1). The difference in the overpressure response was correlated with the subharmonic response produced by these UCAs. When excited using 20-MHz ultrasound, individual UCAs (N = 3000) in populations that did not exhibit a buckling phase produced a subharmonic response that was an order of magnitude greater than the UCA population with a prominent pre-rupture buckling phase. These results indicate the mechanism of gas expulsion from these UCAs might be a relevant factor in determining the level of subharmonic response in response to high-frequency ultrasound.