gebhart/patrepeval huggingface dataset:
Quantitative determination of Mn3+ content in LiMn1.5Ni0.5O4 spinel cathodes by magnetic measurements (2012)

The magnetic properties of cation-disordered and cation-ordered LiMn1.5Ni0.5O4 spinel samples with different morphologies synthesized by hydrothermal and co-precipitation methods have been investigated. Extrapolation of the magnetization values measured below the ferrimagnetic ordering temperature to 0 K has been employed to quantitatively determine the Mn3+ content. The Mn3+ contents calculated on the basis of collinear spin ferrimagnetism from the extrapolated magnetic moment values at 0 K agree closely with those obtained from the capacity values in the 4 V region of lithium-ion cells. This study demonstrates that the magnetic method presented here could become a valuable tool to quantitatively determine the Mn3+ content in high-voltage spinel cathodes.
Protocol for monitoring metals in Ozark National Scenic Riverways, Missouri: Version 1.0 (2008)

The National Park Service is developing a monitoring plan for the Ozark National Scenic Riverways in southeastern Missouri. Because of concerns about the release of lead, zinc, and other metals from lead-zinc mining to streams, the monitoring plan will include mining-related metals. After considering a variety of alternatives, the plan will consist of measuring the concentrations of cadmium, cobalt, lead, nickel, and zinc in composite samples of crayfish (Orconectes luteus or alternate species) and Asian clam (Corbicula fluminea) collected periodically from selected sites. This document, which comprises a protocol narrative and supporting standard operating procedures, describes the methods to be employed prior to, during, and after collection of the organisms, along with procedures for their chemical analysis and quality assurance; statistical analysis, interpretation, and reporting of the data; and for modifying the protocol narrative and supporting standard operating procedures. A list of supplies and equipment, data forms, and sample labels are also included.
HOOD: Hierarchical Graphs for Generalized Modelling of Clothing Dynamics (2022)

We propose a method that leverages graph neural networks, multi-level message passing, and unsupervised training to enable real-time prediction of realistic clothing dynamics. Whereas existing methods based on linear blend skinning must be trained for specific garments, our method is agnostic to body shape and applies to tight-fitting garments as well as loose, free-flowing clothing. Our method furthermore handles changes in topology (e.g., garments with buttons or zippers) and material properties at inference time. As one key contribution, we propose a hierarchical message-passing scheme that efficiently propagates stiff stretching modes while preserving local detail. We empirically show that our method outperforms strong baselines quantitatively and that its results are perceived as more realistic than state-of-the-art methods.
Tuning of the Reflection Properties of Templated Cholesteric Liquid Crystals using Phase Transitions (2012)

Abstract The magnitude of the color changes induced by heating chiral templated polymer structures formed in spatially heterogeneous cells is examined. The large blue and subsequent red tuning of the selective reflection wavelength, caused by deswelling/reswelling of the network at the transition temperatures, is affected by the network crosslink density, heating/cooling rates, and architecture of the cell. The system is stable to multiple heat/cool cycles and shows large scale coloration changes at heating rates up to 10°C/min. At higher heating rates, a distortion of the selective reflection notch shape occurs during tuning. The magnitude of the color change is not affected by rate. At both high and low crosslink density, no tuning is observed. A window of network elasticity and responsiveness is needed to enable the anisotropic contraction/expansion processes to be observed macroscopically. Finally, the magnitude of tuning relative to the cell thickness and spatial heterogeneity across the thickness direction is explored. In thin cells, the tuning range was substantially diminished. Keywords: Cholesteric LCLC gelphase transitiontemperature tuningtemplated polymerwavelength tuning
Abstract A266: Leucovorin rescue of high dose pralatrexate in mesothelioma xenografts. (2013)

Abstract Pralatrexate is a second generation antifolate that targets dihydrofolate reductase. It was found to have a higher affinity to reduced folate carrier type 1 (RFC-1), the primary folate transporter, and has high intracellular retention via enhanced polyglutamylation. Mucositis, rather than bone marrow toxicity, is the dose limiting toxicity (DLT) in patients. In this study, we examine whether the use of leucovorin (folinic acid) can reduce pralatrexate DLT when used in mouse xenografts, and possibly enable high dose pralatrexate treatment. Nude mice bearing H2052 mesothelioma xenografts were treated with pralatrexate at normal and toxic doses with or without leucovorin administration 24 hours later. Tumors were measured three times weekly and toxicity monitored through weight loss. Leucovorin was found to abrogate pralatrexate toxicities at high doses without sacrificing efficacy. These results demonstrate that high dose pralatrexate with subsequent leucovorin rescue may be a viable treatment strategy in mesothelioma and other cancers. Citation Information: Mol Cancer Ther 2013;12(11 Suppl):A266. Citation Format: Philip M. Tedeschi, Iqra Farooqi, Yamini Kathari, Joseph R. Bertino. Leucovorin rescue of high dose pralatrexate in mesothelioma xenografts. [abstract]. In: Proceedings of the AACR-NCI-EORTC International Conference: Molecular Targets and Cancer Therapeutics; 2013 Oct 19-23; Boston, MA. Philadelphia (PA): AACR; Mol Cancer Ther 2013;12(11 Suppl):Abstract nr A266.
Creating a Solar-Powered Drip Irrigation Optimal Performance model (SDrOP) to lower the cost of drip irrigation systems for smallholder farmers (2022)

Smallholder farmers, who hold 84% of the approximately 570 million farms worldwide, are vital stakeholders in the process of sustainable agricultural intensification, but often lack the capital to invest in sustainable farming practices. Solar-powered drip irrigation has the potential to increase crop productivity for minimal water use, but these systems are prohibitively expensive for smallholders. Reducing the life cycle cost (LCC) of solar-powered drip irrigation systems could make this technology more accessible, enabling smallholders to increase their household incomes and contribute to greater global food security. This paper presents the Solar-Powered Drip Irrigation Optimal Performance model (SDrOP), which optimizes solar-powered drip irrigation system designs. Unlike existing commercial software, SDrOP models the behavior of the entire system and simulates seasonal performance to reduce LCC while maintaining operational reliability. SDrOP improves on previous design optimization frameworks by taking in all location-dependent parameters as inputs, which makes the model independent of case specifics and, therefore, broadly applicable. To demonstrate the model theory, the sensitivity of the optimal design to field area, the system reliability constraint, and varying weather conditions are explored for a Moroccan olive orchard case study. The results demonstrate opportunities for system cost reduction, including operational changes to reduce the system power requirement, irrigation pump opportunities for the smallholder market, and reductions in system reliability when it is shown to have minimal impact on crop yield. When benchmarked against a commercially available software, SDrOP was able to reduce system LCC by up to 56%. The simulated performance of an SDrOP optimal design was benchmarked against operational data from an existing field site, and was shown to be capable of operating 92% of the recorded irrigation events. These results indicate that SDrOP offers an advantage over existing software as it produces significantly reduced cost designs that can operate in real-world conditions.
ChemInform Abstract: Preparation of the 14‐Membered L,L‐Cycloisodityrosine Subunit of RP 66453. (2002)

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Energetics of Adsorbed CH3 on Pt(111) by Calorimetry (2013)

The enthalpy and sticking probability for the dissociative adsorption of methyl iodide were measured on Pt(111) at 320 K and at low coverages (up to 0.04 ML, where 1 ML is equal to one adsorbate molecule for every surface Pt atom) using single crystal adsorption calorimetry (SCAC). At this temperature and in this coverage range, methyl iodide produces adsorbed methyl (CH(3,ad)) plus an iodine adatom (I(ad)). Combining the heat of this reaction with reported energetics for Iad gives the standard heat of formation of adsorbed methyl, ΔH(f)(0)(CH3,ad), to be −53 kJ/mol and a Pt(111)–CH3 bond energy of 197 kJ/mol. (The error bar of ±20 kJ/mol for both values is limited by the reported heat of formation of I(ad).) This is the first direct measurement of these values for any alkyl fragment on any surface.
Effects of Different Atrioventricular Intervals During Dual‐Site Right Atrial Pacing on Left Atrial Mechanical Function (2000)

Recent studies have suggested that dual-site right atrial (RA) pacing via the high RA and coronary sinus ostium (CSos) prevents atrial fibrillation (AF). However, the programming of the atrioventricular (AV) interval associated with optimal left atrial (LA) mechanical function during high RA and dual-site RA pacing has not been defined. LA mechanical function was studied by measuring transmitral pulsed Doppler echocardiographic peak A wave velocity and percent A wave filling, in six women and three men, 67 +/- 8 years of age, who had received dual-site RA pacemakers in a randomized study. Serial echocardiographic measurements were performed during high RA or dual-site RA pacing at 80 beats/min with AV intervals of 50, 100, 150, or 200 ms tested in random order. High RA and dual-site RA pacing at an AV interval of 50 ms were associated with significantly lower peak A wave velocity and percent A wave filling, compared to the other AV intervals (all P < 0.05). Compared with high RA pacing, dual-site RA pacing was associated with significantly higher peak A wave velocity (85 +/- 12 vs 72 +/- 17 cm/s, P = 0.04) and percent A wave filling (24 +/- 3 vs 20 +/- 4%, P = 0.02) at an AV interval of 100 ms, but a lower peak A wave velocity at an AV interval of 200 ms (77 +/- 10 vs 84 +/- 8 cm/s, P = 0.004). In conclusion, variations in the AV interval during atrial pacing have significant effects on LA function. As a consequence of altered atrial activation, the AV interval associated with optimal LA mechanical function during dual-site RA pacing was significantly shorter than that during RA pacing. This observation has important implications with respect to the programming of dual-site RA pacemakers implanted to prevent AF for hemodynamic purpose.
Whistleblowing and Copyright (2022)

Abstract A worker may want to make a disclosure using documents of which their employer or another person is the copyright owner. This chapter outlines the nature of the proprietary right to copyright under the Copyright Designs and Patents Act 1988 (CDPA) and how copyright is infringed. It then describes the defence of fair dealing and the limitations of the utility of that defence to the whistleblower, given that the work in question must have been ‘made available to the public’. The public interest defence which is preserved by section 171(3) of the CDPA is then explained with the impact of the passing of the Human Rights Act 1998 on the development of the law as to the public interest defence. The chapter concludes with consideration of the interrelationship of rights under the CDPA and those in relation to the making of protected disclosures under the Employment Rights Act 1996.
Observation of well-defined Kohn-anomaly in high-quality graphene devices at room temperature (2022)

Due to its ultra-thin nature, the study of graphene quantum optoelectronics, like gate-dependent graphene Raman properties, is obscured by interactions with substrates and surroundings. For instance, the use of doped silicon with a capping thermal oxide layer limited the observation to low temperatures of a well-defined Kohn-anomaly behavior, related to the breakdown of the adiabatic Born-Oppenheimer approximation. Here, we design an optoelectronic device consisting of single-layer graphene electrically contacted with thin graphite leads, seated on an atomically flat hexagonal boron nitride (hBN) substrate and gated with an ultra-thin gold (Au) layer. We show that this device is optically transparent, has no background optical peaks and photoluminescence from the device components, and no generation of laser-induced electrostatic doping (photodoping). This allows for room-temperature gate-dependent Raman spectroscopy effects that have only been observed at cryogenic temperatures so far, above all the Kohn-anomaly phonon energy normalization. The new device architecture by decoupling graphene optoelectronic properties from the substrate effects, allows for the observation of quantum phenomena at room temperature.
Mapping the mouse genome: current status and future prospects. (1995)

The mouse is the best model system for the study of mammalian genetics and physiology. Because of the feasibility and importance of studying genetic crosses, the mouse genetic map has received tremendous attention in recent years. It currently contains over 14,000 genetically mapped markers, including 700 mutant loci, 3500 genes, and 6500 simple sequence length polymorphisms (SSLPs). The mutant loci and genes allow insights and correlations concerning physiology and development. The SSLPs provide highly polymorphic anchor points that allow inheritance to be traced in any cross and provide a scaffold for assembling physical maps. Adequate physical mapping resources--notably large-insert yeast artificial chromosome (YAC) libraries--are available to support positional cloning projects based on the genetic map, but a comprehensive physical map is still a few years away. Large-scale sequencing efforts have not yet begun in mouse, but comparative sequence analysis between mouse and human is likely to provide tremendous information about gene structure and regulation.
525 Blood Flow Simulator using Medical Images without Mesh Generation (2006)

Conventional blood flow simulators needed to generate meshes. So, to generate ideal meshes, excellent ability in mesh generation itself was essential, at the same time, detailed knowledge in flow analysis was important. These had been reasons why the flow simulation was not widely used in medical field. We developed a new blood flow simulator without mesh generation. Our system used voxel model as simulation. The voxel models were directly made from grey scale medical modalities such as CT-Angiography, MR-Imaging or 3D-Angiography. We applied our system to the model of coil embolization for brain aneurysm. In coil embolization model, flow pattern change in aneurysm sac were calculated giving various amount of coils. Increasing volume embolization ratio, flow velocity in the sac was decreased. Our simulator can work stably even extremely complex structure without detailed knowledge on the computational fluid dynamics nor mesh generation.
Optimizing Nucleus Size Metrics for Liquid–Solid Nucleation from Transition Paths of Near-Nanosecond Duration (2011)

We determine the mechanism for the liquid-solid phase transition in the Lennard-Jones fluid close to coexistence with aimless shooting and likelihood maximization. The reaction coordinate for this process is a product of a structural descriptor and the size of the nascent solid nucleus and is quantitatively verified with the committor probability histogram test. This study identifies the first accurate scalar reaction coordinate for the liquid-solid nucleation process in Lennard-Jonesium, which will likely extend to nucleation processes in other spherically symmetric fluids. On the basis of our results, we propose a structural correction factor for the commonly cited nucleus size reaction coordinate from classical nucleation theory that enables connection of simulation data to stochastic models of nucleation kinetics. In addition, we show that aimless shooting is able to obtain reasonable acceptance rates for transitions with highly diffusive characteristics, which has been problematic for transition path sampling methods for diffusive processes such as nucleation and macromolecular transitions.
Abstract 14589: Mechanisms for Persistent Atrial Fibrillation - Comparing Multiple Mapping Methods at Sites of Termination: The International COMPARE-AF Registry (2017)

Introduction: Mechanisms for persistent AF are unclear. On the basis that sites where ablation terminates persistent AF may have mechanistic relevance, we performed the first systematic mapping of ...
Chapter 1. A Brief Introduction to Lignin Structure (2018)

Lignin is an alkyl-aromatic polymer found in the cell walls of terrestrial plants. Lignin provides structure and rigidity to plants, is a natural, highly effective barrier against microbial attack, and enables water and nutrient transport through plant tissues. Depending on the plant species, the constituents of lignin can vary considerably, leading to substantial diversity in lignin chemistry and structure. Despite nearly a century of research and development attempting to convert lignin into valuable products, lignin in most current and planned biorefinery contexts remains underutilized, most often being burned to generate heat and power. However, the drive towards effective lignin valorization processes has witnessed a significant resurgence in the past decade, catalyzed by advances in improved understanding of lignin chemistry, structure, and plasticity in parallel with new catalytic and biological approaches to valorize this important, prevalent biopolymer. As a preface to the subsequent chapters in this book, this chapter briefly highlights the known aspects of lignin structure.
A high image quality organic light‐emitting diode display with motion blur reduction for ultrahigh resolution and premium TVs (2020)

Abstract In this paper, we present a high image quality organic light‐emitting diode (OLED) display with motion blur reduction technology. Our latest work includes driving method that reduces motion blur using an adaptive black data insertion, brightness compensation technology, the simple structure pixel with low capacitance coupling for horizontal noise, and the multifunction integrated gate driver. The moving picture response time (MPRT) value of the OLED display panel with a fast response time was significantly affected by the frame frequency and the compensation driving method. The MPRT value of the large‐size OLED display panels was significantly decreased by using the integrated gate driver circuit with an MPRT reduction method. The decrease in the MPRT value originated from the turning of the emitting pixels off in advance resulting from providing black data. The integrated gate drivers were designed to achieve the normal display, the black data insertion, and the compensation mode. The MPRT value of the 65‐in. ultrahigh‐definition (UHD) OLED panels was decreased to 3.4 ms by using an integrated gate driver circuit. The motion blur of large‐size OLED display panels was significantly reduced due to a decrease in the MPRT value.
Utilization of aerial heterogeneous cellular networks: Signal-to-interference ratio analysis (2018)

As a component of future communication networks, aerial telecommunication platforms are a promising solution to meet surging traffic demands. These platforms can be used as aerial base stations (ABSs) to build an aerial heterogeneous network architecture. In this study, we explore the promising utilization of high- and low-altitude platforms (HAPs and LAPs) working on the same network as macrocells and femtocells, respectively. First, using stochastic geometry, we determine the probability of each user being associated with either a HAP or a LAP. The association probability is used for deriving the cell load of ABSs. Next, we derive the outage probability of a typical user in a certain tier that is equivalent to the downlink signal-to-interference ratio cumulative distribution function in aerial heterogeneous cellular networks. Moreover, we propose a dynamic placement and sizing algorithm for cells established by LAPs to achieve load balancing and enhance the overall quality of service for users inside the coverage of a HAP. Our simulation results show that the algorithm provides considerable gains over static aerial cellular networks. Furthermore, we derive the coverage probability of a target receiver when the downlink paths are correlated or uncorrelated. The results demonstrate the impact of the difference in elevation angles between HAPs and LAPs on the coverage probability of the target receiver.
Cores, Cache, Content, and Characterization: IBM’s Second Generation 14-nm Product, z15 (2020)

The IBM z15 system improves upon the prior-generation z14 design within the same chip footprint and technology node, while featuring the addition of two cores, 33%/100%/43% additional L2/L3/L4 cache, as well as additional core features and on-chip accelerators. The largest 5-drawer system configuration includes 20 central processor (CP) chips, five system controller (SC) chips, and 40 TB of memory. With ~200 cores across all CP chips operating with 99.99999% uptime at 5.2 GHz, z15 achieves a 25% increase in system capacity and a 14% single thread performance improvement over the z14 system. In this article, we describe the key design factors and system/characterization refinement that enabled these results, including the novel 2-Mb embedded dynamic random access memory (eDRAM) cell, a new voltage droop monitor, a more comprehensive power reduction infrastructure to reduce power-limited yield, results on reliability-limited versus power-limited yield, and a characterization effort for exploring even higher frequencies, with our first reported 6-GHz values achieved in the lab at customer temperatures and voltages.