gebhart/patrepeval huggingface dataset:
Dielectric Anomalies of (K 0.5 Na 0.5 ) 0.2 (Sr 0.75 Ba 0.25 ) 0.9 Nb 2 O 6 Single Crystals with the Tungsten Bronze Structure (2003)

Tetragonal tungsten bronze (K 0.5 Na 0.5 ) 0.2 (Sr 0.75 Ba 0.25 ) 0.9 Nb 2 O 6 single crystals have been investigated by dielectric spectroscopy. Ferroelectric phase transition at about 420 K shows a thermal hysteresis with some diffuseness, implying a first-order nature of the phase transition. Below the transition temperature where domain wall contribution is expected to be dominant in the dielectric susceptibility, logarithmic dielectric dispersion in addition to the polydispersive freezing loss peak has been observed. The former seems to exist in a wide temperature range and may be understood within the framework of relaxations of elastic interfaces in disordered media. Upon further decreasing temperature, very active transverse dynamics were revealed along the directions perpendicular to the polar c axis by dielectric and pyroelectric measurements. The dielectric relaxation rate followed the Arrhenius law, and the distribution of the relevant activation energy has been obtained from the scaling of the temperature- and frequency-dependent dielectric losses.
Diagnosis and management of lymphoma in a green iguana (Iguana iguana) (2011)

CASE DESCRIPTION-A 2-year-old female green iguana was examined for anorexia and swelling and pain on palpation in the cranial cervical area. CLINICAL FINDINGS-Marked soft tissue swelling in the cranial cervical area with corresponding cystic swellings in the pharynx were noted. The iguana was considered to be 50% under the expected body weight, given diet and husbandry conditions. The WBC count was markedly elevated, characterized by heterophilia and lymphocytosis. Surgical exploration of the cranial cervical area and histologic and microbial testing identified lymphoma with secondary infection as the cause of the swelling. TREATMENT AND OUTCOME-The tumor was initially treated with a single 10-Gy fraction of radiation directed at the masses in the neck. A vascular access port was placed in the ventral abdominal vein, and a canine chemotherapy protocol was modified for use in the iguana. During the course of treatment, the protocol was modified twice. At 1,008 days from the initiation of treatment, the iguana appeared to be in remission. CLINICAL RELEVANCE-To our knowledge, this is the first reported use of radiation with doxorubicin, vincristine, cyclophosphamide, and prednisone to successfully manage lymphoma in a reptile. A vascular access port was used effectively for drug administration for an extended period. The doxorubicin, vincristine, cyclophosphamide, and prednisone protocol appeared to be safe and effective in this iguana for the management of lymphoma.
Segmentation of High Angular Resolution Diffusion MRI Using Sparse Riemannian Manifold Clustering (2013)

We address the problem of segmenting high angular resolution diffusion imaging (HARDI) data into multiple regions (or fiber tracts) with distinct diffusion properties. We use the orientation distribution function (ODF) to model diffusion and cast the ODF segmentation problem as a clustering problem in the space of ODFs. Our approach integrates tools from sparse representation theory and Riemannian geometry into a graph theoretic segmentation framework. By exploiting the Riemannian properties of the space of ODFs, we learn a sparse representation for each ODF and infer the segmentation by applying spectral clustering to a similarity matrix built from these representations. In cases where regions with similar (resp. distinct) diffusion properties belong to different (resp. same) fiber tracts, we obtain the segmentation by incorporating spatial and user-specified pairwise relationships into the formulation. Experiments on synthetic data evaluate the sensitivity of our method to image noise and to the concentration parameters, and show its superior performance compared to alternative methods when analyzing complex fiber configurations. Experiments on phantom and real data demonstrate the accuracy of the proposed method in segmenting simulated fibers and white matter fiber tracts of clinical importance.
Exploratory Synthesis for Reactive f-Element Separations without Solvent (2023)

Solvent extraction is commonly used to separate different f-metals found in spent nuclear fuel, but this process results in large volumes of highly contaminated liquid waste that must be remediated or stored at significant expense. The project funded under this award was aimed at addressing solvent-related issues encountered in conventional f-metal separations. Our strategy focused on using solvent-free mechanochemical reactions to prepare lanthanide and actinide borohydride complexes so that they could be separated based on differences in their volatility. Key deliverables described in this report include proof-of-principle results demonstrating that borohydrides called aminodiboranates can be used for volatile lanthanide/lanthanide and lanthanide/uranium separations, as we proposed. Moreover, exploration of a closely related class of borohydrides called phosphinodiboranates allowed us to identify underlying chemical factors that control the volatility of trivalent lanthanide and uranium borohydride complexes with identical structures. Details of published and pending research products are provided, and these include comprehensive synthesis and characterization efforts required to support fundamental studies related to the proposed separations. These technical efforts supported the training of nine graduate students and three undergraduate researchers, and they established air-sensitive transuranic capabilities at the University of Iowa to enhance radiochemical workforce development.
Using multi-agent systems to simulate dynamic infrastructures populated with large numbers of web service enabled devices (2009)

A common practice in enterprise environments is the usage of Service Oriented Architectures (SOA) which implies heavy usage of web services. Lately the trend is to extend these approaches down to the embedded device layer i.e. have devices running web services natively and offer their functionality as a service. The Internet of Things (IoT) envisions millions of such heterogeneous, usually mobile, devices communicating with each other creating a very dynamic infrastructure. In this paper we concentrate on our efforts to use a multi-agent system to simulate this emerging dynamic infrastructure populated with large number of web-service enabled devices.
Beyond the <i>g</i>‐factor limit in sensitivity encoding using joint histogram entropy (2005)

The maximum practical speed-up that can be achieved using parallel imaging methods is widely accepted to be limited by g-factor noise. An approximate expression for the g-factor noise as a function of the principal eigenvector of the inverse sensitivity matrix is derived. This formulation allows g-factor enhanced noise to be reduced by a constrained optimization procedure with joint image histogram entropy between a reference image and a SENSE image as an image quality metric. The reference image does not need to have identical resolution or contrast. The reference image may also be used for coil calibration. The limits of the method are explored using simulated and real array coil data with high g-factor using a variety of contrast and resolution combinations. The method preserves image structure, contrast, and lesions even when these were not observable in the reference data. In all cases g-factor was dramatically reduced.
Oligomers-model building in protonation equilibria of sitagliptin (2013)

Abstract Mixed protonation constants of sitagliptin phosphate at various ionic strengths I (mol kg−1) in range 0.01 and 0.50 and at 298.15 K are determined using FBSTAC4 and HYPERQUAD nonlinear regression analyses of the potentiometric titration curve. At a low concentration c L = 1.1 mmol kg−1 the monomers L, LH, LH2, LH3 and LH4 dominate, while for a concentration range from c L = 13.7 to 24.7 mmol kg−1 dimers L2H2, L2H3, L2H4 and L2H are mainly present. The regression programme has almost no influence on the precision of the protonation constants. The accuracy of the protonation constants log βqr depends on the accuracy of the group parameters. As two group parameters c L,0, c H,T are ill-conditioned in a model, their determination is therefore uncertain: both can significantly cause a systematic error in the estimated common parameters log10βqr . Fitness tests using regression diagnostics have proven the reliability of the parameter estimates.
Spectral Analysis of Site-Directed Mutants of Human Growth Hormone (1993)

Site directed mutagenesis has been used to identify receptor binding determinants on (hGH) by the substitution of alanine for residues in the hGH molecule (Cunningham and Wells, Science 244:1081-1985 (1989)). A number of these engineered molecules show greater than a 10-fold reduction in binding affinity to the human growth hormone binding protein (hGHbp) (ΔΔG >1.3 kcal/mole). Presently, although a crystal structure is available for hGH, there is no structure available for the mutants that would allow an accurate assessment of the perturbations occurring in hGH mutant molecular structure. In this report we use the spectroscopic tools, circular dichroism, second derivative absorption spectroscopy, and fluorescence spectroscopy to assess the structural integrity of the mutant proteins. Overall we detect little change in the structure of these engineered molecules. The structural changes we do observe in these mutants appears to be largely confined to alterations in the packing of the interior of the four helix bundle but in no case is there any significant change in the helix content of these molecules. For one of the mutant proteins (hGH D169N) though, there is a change in the permeability of the collisional quenching reagent, acrylamide, to the interior of the four helix bundle. The single tryptophan, Trp86, is a major spectral determinant of the hydrophobic core of hGH and is sensitive to subtle structural changes induced by site directed mutagenesis.
Laser spectroscopy of molecular cesium near 1064 nm enhanced by a Fabry–Perot cavity (1995)

We made Doppler-broadened and Doppler-free absorption measurement of a cesium cell that was placed inside an external Fabry-Perot ring cavity, using a Nd:YAG laser. We achieved a cavity finesse of ~85, and the sensitivity of the measurement was improved by as much as 26.5 with respect to single-pass absorption. The sensitivity enhancement by the external cavity may enable one to lock the laser frequency to (133)Cs(2) lines at relatively low temperatures, in which the frequency-dependent temperature shift, as well as the collision broadening, is reduced significantly.
Evaluating the Reliability and Interaction of Recursively Used Feature Classes for Terminology Extraction (2017)

Feature design and selection is a crucial aspect when treating terminology extraction as a machine learning classification problem. We designed feature classes which characterize different properties of terms, and propose a new feature class for components of term candidates. By using random forests, we infer optimal features which are later used to build decision tree classifiers. We evaluate our method using the ACL RD-TEC dataset. We demonstrate the importance of the novel feature class for downgrading termhood which exploits properties of term components. Furthermore, our classification suggests that the identification of reliable term candidates should be performed successively, rather than just once.
Photophysics of capped CdSe microcrystallites exhibiting quantum confinement (1990)

We use nanosecond and picosecond optical spectroscopic techniques to isolate and study the photodynamics of the single particle spectrum of 35A CdSe nanoclusters exhibiting three-dimensional quantum confinement.
Short circuit current improvement in planar heterojunction organic solar cells by multijunction charge transfer (2012)

A multijunction structure was applied on an organic photovoltaic (OPV) device for broadening the absorption spectrum and enhancing the power conversion efficiency through charge transfer process. By inserting the tris[4-(2-thienyl)]amine (TTPA) into a boron subphthalocyanine chloride (SubPc)/C60 OPV device, the short circuit current density (Jsc) showed a 47.5% increases from 3.05 to 4.50 mA/cm2 in the bilayer planar heterojunction device, while the open circuit voltage (Voc) remained constant. Based on the single junction (TTPA/SubPc) device and photoluminescence absorption results, we confirmed both TTPA/SubPc and SubPc/C60 junctions are contributing to the exciton dissociation process hence the efficiency enhancement.
Effective energy storage from a triboelectric nanogenerator (2016)

To sustainably power electronics by harvesting mechanical energy using nanogenerators, energy storage is essential to supply a regulated and stable electric output, which is traditionally realized by a direct connection between the two components through a rectifier. However, this may lead to low energy-storage efficiency. Here, we rationally design a charging cycle to maximize energy-storage efficiency by modulating the charge flow in the system, which is demonstrated on a triboelectric nanogenerator by adding a motion-triggered switch. Both theoretical and experimental comparisons show that the designed charging cycle can enhance the charging rate, improve the maximum energy-storage efficiency by up to 50% and promote the saturation voltage by at least a factor of two. This represents a progress to effectively store the energy harvested by nanogenerators with the aim to utilize ambient mechanical energy to drive portable/wearable/implantable electronics.
Crosslinking cotton with poly(itaconic acid) and <i>in situ</i> polymerization of itaconic acid: Fabric mechanical strength retention (2003)

Abstract Polycarboxylic acids have been used as nonformaldehyde durable press finishing agents for cotton fabrics. Previously, we found that itaconic acid (IA) polymerized in situ on cotton fabric and also in an aqueous solution in the presence of a K 2 S 2 O 8 /NaH 2 PO 2 initiation system. Both poly(itaconic acid) (PIA) and the polymer formed by in situ polymerization of IA are able to crosslink cotton cellulose, thus imparting wrinkle resistance to cotton. In this research, we compared the performance of the cotton fabric crosslinked by PIA and that crosslinked by in situ polymerization of IA. The fabric treated with PIA and that treated with IA had similar wrinkle recovery angles. The cotton fabric treated with IA, however, lost more tensile strength than that treated with PIA due to cellulose degradation. We determined the magnitude of the fabric tensile strength loss attributed to crosslinking by separating the tensile strength loss due to cellulose degradation from the total tensile strength loss, and found that the tensile strength loss caused by crosslinking for the fabric treated with PIA was significantly higher than that for the fabric treated with IA. This can probably be attributed to more concentrated crosslinkages formed on the near surface of the PIA‐treated cotton fabric. PIA had poorer penetration into the amorphous cellulose region in fiber interior due to its much larger molecular size, thus increasing its concentration on the fabric's near surface. The data also suggest that more concentrated crosslinkages on the fabric surface reduced fabric abrasion resistance. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2023–2030, 2003
Plasmonic Oligomers: The Role of Individual Particles in Collective Behavior (2011)

We present a comprehensive experimental study of the optical properties of plasmonic oligomers. We show that both the constitution and configuration of plasmonic oligomers have a large influence on their resonant behavior, which draws a compelling analogy to molecular theory in chemistry. To elucidate the constitution influence, we vary the size of individual nanoparticles and identify the role of the target nanoparticle from the spectral change. To illustrate the configuration influence, we vary the positions and numbers of nanoparticles in a plasmonic oligomer. Additionally, we demonstrate experimentally a large spectral redshift at the transition from displaced nanoparticles to touching ones. The oligomeric design strategy opens up a rich pathway for the implementation of optimized optical properties into complex plasmonic nanostructures for specific applications.
Behavior of Uranium and Zirconium in Direct Transport Tests with Irradiated EBR-II Fuel (1999)

A theoretical model is used to analyze the transport of U and Zr in electrorefining of irradiated binary Experimental Breeder Reactor-II fuel. A limiting-current hypothesis is advanced to explain the observed dissolution of Zr in the presence of U at high, intermediate, and low cell voltages. The internal diffusion model predicts the existence of a critical current and a critical voltage for Zr oxidation. Experimental results are presented for a test designed and run based on optimum conditions determined from the model to dissolve U expediently while retaining Zr in the anode baskets. A simple model of kinetic exchange reactions between salt-phase U and Cd-phase Zr is formulated to explain the measured electrodeposition of Zr on the solid cathode. It is shown that the Zr content of the deposit is overpredicted if the pool is considered isolated and grossly underpredicted if the salt phase is equilibrated instantaneously with the Cd pool. Finally, the aspects of anodic current efficiency and cathodic collection efficiency are discussed taking into account shorting between the dissolution baskets and the Cd pool, multiple oxidation states of Zr, and the exchange reactions between the fuel and UCl3 prior to electrotransport.
Role of thromboxane A2 in the cardiovascular response to intracoronary C5a. (1990)

Intracoronary administration of complement component C5a induces transient decreases in coronary blood flow and regional left ventricular segment shortening, associated with intramyocardial granulocyte trapping. We evaluated the influence of a cyclooxygenase inhibitor (acetylsalicylic acid, n = 8) or a thromboxane A2/prostaglandin H2 receptor antagonist (SQ29548, n = 6) on these C5a-induced cardiovascular responses. Open-chest anesthetized pigs were instrumented to monitor heart rate, arterial blood pressure, left anterior descending coronary blood flow, regional left ventricular segment shortening, and dP/dt. Oxygen content, lactate concentration, leukocyte count, and thromboxane B2, the stable metabolite of thromboxane A2, were measured in arterial and regional coronary venous blood. Repetitive injections of intracoronary C5a (500 ng) given 60 minutes apart showed no tachyphylaxis of the hemodynamic response. However, tachyphylaxis was seen in coronary blood flow changes when injections were spaced 30 minutes apart. An increase in myocardial oxygen extraction and lactate production was observed after intracoronary C5a. Administration of acetylsalicylic acid (50 mg/kg i.v.) attenuated C5a-induced decreases in coronary blood flow (-8 +/- vs. -3 +/- 1 ml/min) and regional left ventricular segmental shortening (-10 +/- 3% vs. -2 +/- 1%) and blocked the maximal increase in coronary venous thromboxane B2 (2.0 +/- 0.1 vs. 0.2 +/- 0.1 pmol/ml plasma). Furthermore, SQ29548 (30 micrograms/kg/min) reduced C5a-induced changes in coronary blood flow (-13 +/- 2 vs. -4 +/- 2 ml/min) and segmental shortening (-14 +/- 2% vs. -3 +/- 1%). Neither cyclooxygenase inhibition nor thromboxane A2/prostaglandin H2 antagonism blocked the decrease in coronary venous granulocyte count.(ABSTRACT TRUNCATED AT 250 WORDS)
Dna methylation status of the <i>MUC</i>1 gene coding for a breast‐cancer‐associated protein (1995)

The MUC1 gene codes for protein products that are highly expressed in human breast-cancer tissue and that serve as tumor markers for disease progression. The factors contributing to the disease-specific over-expression of the MUC1 gene are under intensive investigation and are yet to be determined. A large transcribed region of the human MUC1 gene is a CpG island that consists of 60-bp tandemly repeating units, each of which contains one SmaI restriction site. The methylation status of regulatory regions, upstream to the transcriptional start site, is essential for the regulation of gene expression. We therefore evaluated whether the methylation status of the various regions of the MUC1 gene may affect its expression. Using SmaI, and its isoschizomer XmaI endonucleases, we demonstrated that in peripheral-blood leukocytes (PBL-DNA) that do not express the MUC1 gene, the repeat array is completely methylated, whereas the same sequences are entirely non-methylated in breast-tumor-tissue DNA (BT-DNA). In contrast, sequences upstream and downstream to the repeat array showed no difference in the methylation pattern in PBL-DNA and BT-DNA. Hypomethylation within the repeat array was also observed in other epithelial tissues that express the MUC1 gene at much lower levels to those seen in breast-cancer tissue. These studies demonstrate that hypomethylation of the tandem repeat array is an absolute requirement for MUC1 gene expression in epithelial tissues, although in breast-cancer tissue additional regulatory mechanisms must pertain for its over-expression.
A kernel formula for regularized Wasserstein proximal operators (2023)

We study a class of regularized proximal operators in Wasserstein-2 space. We derive their solutions by kernel integration formulas. We obtain the Wasserstein proximal operator using a pair of forward-backward partial differential equations consisting of a continuity equation and a Hamilton-Jacobi equation with a terminal time potential function and an initial time density function. We regularize the PDE pair by adding forward and backward Laplacian operators. We apply Hopf-Cole type transformations to rewrite these regularized PDE pairs into forward-backward heat equations. We then use the fundamental solution of the heat equation to represent the regularized Wasserstein proximal with kernel integral formulas. Numerical examples show the effectiveness of kernel formulas in approximating the Wasserstein proximal operator.
Automated scoring using a hybrid feature identification technique (1998)

This study exploits statistical redundancy inherent in natural language to automatically predict scores for essays. We use a hybrid feature identification method, including syntactic structure analysis, rhetorical structure analysis, and topical analysis, to score essay responses from test-takers of the Graduate Management Admissions Test (GMAT) and the Test of Written English (TWE). For each essay question, a stepwise linear regression analysis is run on a training set (sample of human scored essay responses) to extract a weighted set of predictive features for each test question. Score prediction for cross-validation sets is calculated from the set of predictive features. Exact or adjacent agreement between the Electronic Essay Rater (e-rater) score predictions and human rater scores ranged from 87% to 94% across the 15 test questions.