gebhart/patrepeval huggingface dataset:
Image Compression Based on Compressive Sensing: End-to-End Comparison With JPEG (2020)

We present an end-to-end image compression system based on compressive sensing. The presented system integrates the conventional scheme of compressive sampling (on the entire image) and reconstruction with quantization and entropy coding. The compression performance, in terms of decoded image quality versus data rate, is shown to be comparable with JPEG and significantly better at the low rate range. We study the parameters that influence the system performance, including (i) the choice of sensing matrix, (ii) the trade-off between quantization and compression ratio, and (iii) the reconstruction algorithms. We propose an effective method to select, among all possible combinations of quantization step and compression ratio, the ones that yield the near-best quality at any given bit rate. Furthermore, our proposed image compression system can be directly used in the compressive sensing camera, e.g., the single pixel camera, to construct a hardware compressive sampling system.
Stepwise elongation effect on the two-photon absorption of self-assembled butadiyne porphyrins (2008)

Butadiyne-porphyrin dimer arrays, which were generated by complementary coordination of the central zinc atom to imidazolyl followed by metathesis, were elongated stepwise and their 2PA properties were explored.
Group 4 Dimethylmetallocenes:  Improved Synthesis and Reactivity Studies (2001)

Group 4 dimethylmetallocenes are catalyst precursors for the methylmetallocenium/borate catalyst systems for olefin polymerization, and they are usually prepared by methylation (with MeMgCl or MeLi) of the parent metallocene dichlorides. We describe here a simpler preparation of a series of bisindenyldimethylmetallocenes carried out by reacting the pi-ligand with a 2-fold excess of MeLi, and then MtCl(4) (Mt = Ti, Zr, Hf). This simple, one-pot method produces the dimethylated complexes in higher overall yield, and saves on reaction time and solvents. Ind(2)MtMe(2) (1, Mt = Ti; 2a, Mt = Zr; 3, Mt = Hf), (4,7-Me(2)Ind)(2)ZrMe(2) (4), rac/meso-[C(2)H(4)(Ind)(2)]ZrMe(2) (5), meso-[C(2)H(4)(4,7-Me(2)Ind)(2)]ZrMe(2) (m-6a), and meso-[C(2)H(4)(4,7-Me(2)Ind)(2)]HfMe(2) (m-7a) have been prepared in 40-80% isolated yields. 2a reacts with 1-4 equiv of t-BuOH to give the mono-tert-butoxy derivative 2b, Ind(2)ZrMe(O-t-Bu), while reaction with 2 equiv of C(6)F(5)OH cleanly affords Ind(2)Zr(OC(6)F(5))(2) (2c). Analogously, in the presence of 2 equiv of t-BuOH, m-6a gives meso-[C(2)H(4)(4,7-Me(2)Ind)(2)]ZrMe(O-t-Bu) (m-6b) with replacement of the outward methyl group only, as established by NMR analysis; meso-[C(2)H(4)(4,7-Me(2)Ind)(2)]Zr(OC(6)F(5))(2) (m-6c) is obtained by reaction with 2 equiv of C(6)F(5)OH. The molecular structures of m-6a and m-6c are also described.
B06 Mechanical properties and cutting performances of binderless nano-polycrystalline diamond (2010)

Single-phase (binderless) nano-polycrystalline diamond synthesized by direct conversion of graphite under high pressure and high temperature has a very fine texture consisting of small diamond grains (several tens of nanometers in size), having extremely high hardness, no cleavage and high thermal stability. In order to clarify its potentiality for industrial uses in cutting tools, the mechanical properties of nano-polycrystalline diamond were systematically investigated. In addition, the cutting performances of the nano-polycrystalline diamond tool for some materials were evaluated. These results revealed that the nanopolycrystalline diamond has significantly higher cutting performance than conventional sintered diamond tools or mono-crystal diamond tools.
Synthesis of Highly Reactive Subnano-Sized Zero-Valent Iron Using Smectite Clay Templates (2010)

A novel method was developed for synthesizing subnano-sized zero-valent iron (ZVI) using smectite clay layers as templates. Exchangeable Fe(III) cations compensating the structural negative charges of smectites were reduced with NaBH(4), resulting in the formation of ZVI. The unique structure of smectite clay, in which isolated exchangeable Fe(III) cations reside near the sites of structural negative charges, inhibited the agglomeration of ZVI resulting in the formation of subnanoscale ZVI particles in the smectite interlayer regions. X-ray diffraction revealed an interlayer spacing of approximately 5 A. The non-structural iron content of this clay yields a calculated ratio of two atoms of ZVI per three cation exchange sites, in full agreement with the X-ray diffraction (XRD) results since the diameter of elemental Fe is 2.5 A. The clay-templated ZVI showed superior reactivity and efficiency compared to other previously reported forms of ZVI as indicated by the reduction of nitrobenzene; structural Fe within the aluminosilicate layers was nonreactive. At a 1:3 molar ratio of nitrobenzene/non-structural Fe, a reaction efficiency of 83% was achieved, and over 80% of the nitrobenzene was reduced within one minute. These results confirm that non-structural Fe from Fe(III)-smectite was reduced predominantly to ZVI which was responsible for the reduction of nitrobenzene to aniline. This new form of subnanoscale ZVI may find utility in the development of remediation technologies for persistent environmental contaminants, for example, as components of constructed reactive domains such as reactive caps for contaminated sediments.
White Emission from a Polymer Blend Light-Emitting Diode by Incomplete Cascade Energy Transfer (2001)

Abstract White light emission was obtained from a polymer light-emitting diode (LED) made of a ternary polymer blend comprised of poly(9-vinylcarbazole) (PVK), poly(9,9′-dihexlyfluorene-2,7-divinylene-mphenylenevinylene-stat-p-phenylenevinylene) (CPDHFPV), and poly[2-methoxy-5-(2′-(ethyl-hexyloxy)-1,4-phenylenevinylene) (MEH-PPV) (19:1:1 by wt.). Incomplete cascade energy transfer was employed to obtain white emission from the polymer blend LED. Compatibility between PVK and CPDHFPV facilitated the Förster-type energy transfer from PVK to CPDHFPV. However, poor compatibility between CPDHFPV and MEH-PPV resulted in a partial energy transfer between the polymers causing the blend to emit two colors simultaneously. Consequently, pure white color near CIE coordinate (0.33, 0.33) could be obtained with a low sensitivity to the drive voltage.
Building Natural Language Interfaces to Web APIs (2017)

As the Web evolves towards a service-oriented architecture, application program interfaces (APIs) are becoming an increasingly important way to provide access to data, services, and devices. We study the problem of natural language interface to APIs (NL2APIs), with a focus on web APIs for web services. Such NL2APIs have many potential benefits, for example, facilitating the integration of web services into virtual assistants.
Spectrum Sensing for OFDM Systems Employing Pilot Tones and Application to DVB-T OFDM (2008)

Spectrum sensing is one of the core technologies of cognitive radio (CR) systems which provide a viable solution to the problem of sparsity of wireless spectrum. Nowadays, OFDM techniques are adopted by many existing or progressing wireless communication standards. Thus, a robust spectrum sensing algorithm for OFDM modulated signals is highly desired to implement CR when the primary signal uses OFDM modulation. Motivated by this demand, a time-domain symbol cross-correlation based spectrum sensing algorithm (TDSC method) is presented in this paper. The algorithm makes use of the property that the mean of the TDSC of two OFDM symbols is not zero if they have embedded the same frequency-domain pilot tones. The statistical behavior of the proposed spectrum sensor is explicitly analyzed and a theoretical lower bound on the misdetection probability is derived in this paper. An intuitive spectrum sensing method which utilizes the cyclic prefix nature of the OFDM modulated signals (CP method) is also described in this paper as a reference for comparison. Finally, we use the DVB-T Standard [8] as an application example to illustrate the proposed spectrum sensing algorithm. The simulated channel environments are the Ricean and Rayleigh channels defined in the DVB-T Standard and the additive white Gaussian noise (AWGN) channel. Four CP ratios defined in the DVB-T Standard are simulated for the probability of false alarm equaling 0.01 and the sensing time set equal to 50 ms. Simulation results show that the TDSC method can achieve a misdetection probability of 0.1 when the SNR equals -20.5 dB for all four CP ratios. The TDSC method outperforms the CP method in all cases. Furthermore, the proposed method has approximately the same detection performance for different CP ratios while the detection performance of the CP method degrades dramatically when the CP ratio becomes small. Results also reveal that the simulated performance is very close to the theoretical lower bound indicating that the lower bound can be used as a good prediction of performance.
Predicting GPU Performance from CPU Runs Using Machine Learning (2014)

Graphics processing units (GPUs) can deliver considerable performance gains over general purpose processors. However, GPU performance improvement vary considerably across applications. Porting applications to GPUs by rewriting code with GPU-specific languages requires significant effort. In consequence, it is desirable to predict which applications would benefit most before porting to the GPU. This paper shows that machine learning techniques can build accurate predictive models for GPU acceleration. This study presents an approach which applies supervised learning algorithms to infer predictive models, based on dynamic profile data collected via instrumented runs on general purpose processors. For a set of 18 parallel benchmarks, the results show that a small set of easily-obtainable features can predict the magnitude of GPU speedups on two different high-end GPUs, with accuracies varying between 77% and 90%, depending on the prediction mechanism and scenario. For already-ported applications, similar models can predict the best device to run an application with an effective accuracy of 91%.
Branchpoint labeling and matching in human airway trees (2003)

The functional understanding of the pulmonary anatomy as well as the tracking of the natural course of respiratory diseases are critically dependent on our ability to repeatedly evaluate the same region of the lungs time after time and perform accurate and reliable positionally corresponding measurements. We present a method for accurate labeling of airway branchpoints with their anatomical names as well as an approach for accurate matching of airway tree branchpoints beyond those with anatomical names. An intra-subject tree-matching as well as matching across subjects is achieved. The labeling process is based on matching against a population average. This population average incorporates the anatomical variability that is typically observed across the population. The matching algorithm is based on an association graph method. The computing time is drastically reduced by introducing a hierarchical splitting and only matching two sub-trees at a time. Both steps well tolerate possible false branches. Validation against an independent standard provided by human experts shows a high degree of accuracy (> 90%) for both labeling and matching. The average error compares well to the inter-observer variability among human experts.
Single-slice rebinning reconstruction in spiral cone-beam computed tomography (2000)

At the advent of multislice computed tomography ICT) a variety of approximate cone-beam algorithms have been proposed suited for reconstruction of small cone-angle CT data in a spiral mode of operation. The goal of this study is to identify a practical and efficient approximate cone-beam method, extend its potential for medical use, and demonstrate its performance at medium cone-angles required for area detector CT. We will investigate two different approximate single-slice rebinning algorithms for cone-beam CT: the multirow Fourier reconstruction (MFR) and an extension of the advanced single-slice rebinning method (ASSR), which combines the idea of ASSR with a z-filtering approach. Thus, both algorithms, MFR and ASSR, are formulated in the framework of z-filtering using optimized spiral interpolation algorithms. In each view, X-ray samples to be used for reconstruction are identified, which describe an approximation to a virtual reconstruction plane. The performance of approximate reconstruction should improve as the virtual reconstruction plane better fits the spiral focus path. The image quality of the respective reconstruction will be assessed with respect to image artifacts, spatial resolution, contrast resolution, and image noise. It turns out that the ASSR method using tilted reconstruction planes is a practical and efficient algorithm, providing image quality comparable to that of a single-row scanning system even with a 46-row detector at a table feed of 64 mm. Both algorithms tolerate any table feed below the maximum value associated to the detector height. Due to the z-filter approach, all detector data sampled can be used for image reconstruction.
Purification, characterization and identification of cysteine desulfhydrase of<i>Corynebacterium glutamicum</i>, and its relationship to cysteine production (2002)

We highly purified the enzyme having L-cysteine desulfhydrase activity from Corynebacterium glutamicum. According to its partial amino acid sequence, the enzyme was identified as the aecD gene product, a C-S lyase with alpha, beta-elimination activity [I. Rossol and A. Pühler (1992) J. Bacteriol. 174, 2968-2977]. To produce L-cysteine in C. glutamicum, the Escherichia coli-altered cysE gene encoding Met256Ile mutant serine acetyltransferase, which is desensitized to feedback inhibition by L-cysteine, was introduced into C. glutamicum. When the altered cysE gene was expressed in the aecD-disrupted strain, the transformants produced approximately 290 mg of L-cysteine plus L-cystine per liter from glucose. The produced amount of these amino acids was about two-fold higher than that of the wild-type strain.
Lifetime and Electric Characteristics of Encapsulated Organic Light-Emitting Devices (2006)

Organic light-emitting devices (OLEDs) with tris-(8-hydroxyquinoline)aluminum (Alq 3 ), which is typically a green emitter, have been studied by many researchers because of their potential for facilitating the development of flexible electronics. In this paper, the luminance characteristics, current, capacitance, and dispersion factor for degraded OLEDs, which were obtained by applying various bias currents (0.5≤ I Bias ≤9 mA), are studied. The current dependences of lifetime were divided at approximately 2 mA, and they represented nearly linear behaviors but had different slopes in a logarithmic plot of lifetime versus ubias current. With OLEDs emitting, the anomaly of capacitance, as shown in the capacitance–voltage curve, occurred because of two factors, polarization in the bulk of organic materials and the interface between the metal and organic layers. In decayed OLEDs that had lower bias currents of less than 2 mA, it was found that the degradation of luminance was related to both the decrease in polarization and to the lowering of the injection barrier.
Characterization of the anticonvulsant profile and enantioselective pharmacokinetics of the chiral valproylamide propylisopropyl acetamide in rodents (2003)

1. Propylisopropyl acetamide (PID) is a new chiral amide derivative of valproic acid. The purpose of this study was to evaluate the anticonvulsant activity of PID in rodent models of partial, secondarily generalized and sound-induced generalized seizures which focus on different methods of seizure induction, both acute stimuli, and following short-term plastic changes as a result of kindling, and to assess enantioselectivity and enantiomer-enantiomer interactions in the pharmacokinetics and pharmacodynamics of racemic PID and its pure enantiomers in rodents. 2. Anticonvulsant activity of (S)-PID, (R)-PID and racemic PID was evaluated in the 6 Hz psychomotor seizure model in mice, in the hippocampal kindled rat, and in the Frings audiogenic seizure susceptible mouse. The pharmacokinetics of (S)-PID and (R)-PID was studied in mice and rats. 3. In mice (S)-PID, (R)-PID and racemic PID were effective in preventing the 6 Hz seizures with (R)-PID being significantly (P < 0.05) more potent (ED(50) values 11 mg kg(-1), 46 mg kg(-1) and 57 mg kg(-1) at stimulation intensities of 22, 32 and 44 mA, respectively) than (S)-PID (ED(50) values 20 mg kg(-1), 73 mg kg(-1) and 81 mg kg(-1) at stimulation intensities of 22, 32 and 44 mA, respectively). (S)-PID, (R)-PID and racemic PID also blocked generalized seizures in the Frings mice (ED(50) values 16 mg kg(-1), 20 mg kg(-1) and 19 mg kg(-1) respectively). 4. In the hippocampal kindled rat a dose of 40 mg kg(-1) of (R)- and (S)-PID prevented the secondarily generalized seizure, whereas racemic PID also blocked the expression of partial seizures following an i.p. dose of 40 mg kg(-1). Racemic PID also significantly increased the seizure threshold in this model. 5. Mechanistic studies showed that PID did not affect voltage-sensitive sodium channels or kainate-, GABA- or NMDA- evoked currents. 6. The pharmacokinetics of PID was enantioselective following i.p. administration of individual enantiomers to mice, with (R)-PID having lower clearance and longer half-life than (S)-PID. In rats and mice, no enantioselectivity in the pharmacokinetics of PID was observed following administration of the racemate, which may be due to enantiomer-enantiomer interaction. 7. This study demonstrated that PID has both enantioselective pharmacokinetics and pharmacodynamics. The better anticonvulsant potency of (R)-PID in comparison to (S)-PID may be due to its more favorable pharmacokinetic profile. The enhanced efficacy of the racemate over the individual enantiomers in the kindled rat may be explained by a pharmacokinetic enantiomer-enantiomer interaction in rats. This study also showed the importance of studying the pharmacokinetics and pharmacodynamics of chiral drugs following administration of the individual enantiomers as well as the racemic mixture.
Unified Approach to Optimization of Tread Pattern Shape and Cross-Sectional Contour of Tires (2010)

Abstract During the design stage, tire designers have to use trial and error to decide on the design factors in order to satisfy performance requirements, and this involves a great deal of time and expense. Optimization is one of the methods which can be used effectively and efficiently to improve tire performance. There is a lot of literature available about optimal tire contour and structure design. On the other hand, there is little published information available about optimal tread pattern design. In particular, there is little information available about the interaction between optimal tire contour and tread pattern design. In this study, we constructed a tire optimization system in which the design factors of cross-sectional contour and tread pattern shape could both be dealt with as design variables at the same time. This optimization system was then applied to and verified for an actual tire design problem.
2-O-Alkyltyrosine derivatives of 1-deaminoarginine-vasopressin: highly specific and potent antidiuretic agonists (1989)

We report the solid-phase synthesis of eight 2-O-alkyltyrosine analogues of 1-deamino-arginine-vasopressin (dAVP) with enhanced antidiuretic agonistic specificity. These peptides are as follows: 1-deamino[2-O-methyltyrosine]-arginine-vasopressin (dTyr(Me)AVP), 1-deamino[2-O-ethyltyrosine]arginine-vasopressin (dTyr(Et)AVP), 1-deamino[2-O-methyltyrosine,8-D-arginine]vasopressin (dTyr(Me)DAVP), 1-deamino[2-O-ethyltyrosine,8-D-arginine]vasopressin (dTyr(Et)DAVP), 1-deamino[2-O-methyltyrosine,4-valine]arginine-vasopressin (dTyr(Me)VAVP), 1-deamino[2-O-ethyltyrosine,4-valine]arginine-vasopressin (dTyr(Et)VAVP), 1-deamino[2-O-methyltyrosine,4-valine,8-D-arginine]vasopressin (dTyr(Me)VDAVP), and 1-deamino[2-O-ethyltyrosine,4-valine,8-D-arginine]vasopressin (dTyr(Et)VDAVP). All analogues were tested for antidiuretic, antivasopressor, and antioxytocic activities. Deamination, as was expected, significantly enhanced the antidiuretic properties of these analogues relative to their parent N-amino-O-alkyltyrosine peptides. With the exception of dTyr(Me)AVP, all of these analogues are antagonists of the vasopressor responses to AVP and of the uterine response to oxytocin. Thus they all exhibit high antidiuretic agonistic specificity. Due to its remarkable properties, dTyr(Me)VDAVP is a unique compound in this series. It appears to be the most potent antidiuretic agonist (1740 units/mg) and also a vasopressor antagonist and a potent oxytocin antagonist. It is thus a highly specific antidiuretic agonist. In general, all of these new analogues are highly specific and thus are potentially useful as pharmacological tools and clinical agents.
Glycosyl Isocyanide Dichlorides—Novel Synthetic Building Blocks in Sugar Chemistry (1987)

Per-O-acetylglycosyl isocyanide dichlorides of type 1 expand the armamentarium of preparative carbohydrate chemistry. Compounds 1 are readily accessible by chlorination of the corresponding isothiocyanates. Their synthetic potential is exemplified by the transformation of the glucose derivative 1 into the glucosylamino oxadiazole 2.
A Fundamental Model of Mistuning for a Single Family of Modes (2002)

A new reduced order model of mistuned bladed disk vibration is presented. This new approach is shown to accurately represent the response of real turbine geometries when only a single family of modes is excited. Yet its mathematical form is even simpler than that of a mass-spring model. Because it requires only minimal input data, this model is much easier to use than previous reduced order methods. Furthermore, its simplicity allows the fundamental parameters that control mistuning to be readily identified.
ChemInform Abstract: Traceless Directing Groups in Radical Cascades: From Oligoalkynes to Fused Helicenes Without Tethered Initiators. (2015)

Abstract Diynes of type (I) and (III) containing methoxy groups as traceless directing groups undergo radical‐initiated cascades to form fused naphthalenes.
The antiguiding parameter in mid-infrared optically pumped semiconductor lasers (2011)

We describe measurements of the antiguiding parameter for several mid-infrared optically pumped W lasers. The symmetrical gain spectra induced by homogenous broadening resulted in small differential index and hence low antiguiding values of ~1.
ISOMER: Consistent Histogram Construction Using Query Feedback (2006)

Database columns are often correlated, so that cardinality estimates computed by assuming independence often lead to a poor choice of query plan by the optimizer. Multidimensional histograms can help solve this problem, but the traditional approach of building such histograms using a data scan often scales poorly and does not always yield the best histogram for a given workload. An attractive alternative is to gather feedback from the query execution engine about the observed cardinality of predicates and use this feedback as the basis for a histogram. In this paper we describe ISOMER, a new feedback-based algorithm for collecting optimizer statistics by constructing and maintaining multidimensional histograms. ISOMER uses the maximumentropy principle to approximate the true data distribution by a histogram distribution that is as "simple"as possible while being consistent with the observed predicate cardinalities. ISOMER adapts readily to changes in the underlying data, automatically detecting and eliminating inconsistent feedback information in an efficient manner. The algorithm controls the size of the histogram by retaining only the most "important" feedback. Our experiments indicate that, unlike previous methods for feedback-driven histogram maintenance, ISOMER imposes little overhead, is extremely scalable, and yields highly accurate cardinality estimates while using only a modest amount of storage.