Studies of Synthesis Temperature Effects on Cubic Lithated-Spinel to Layered Phase Transformation and Electrochemical Performance of LiMn0.5Ni0.5O2 Cathode Materials (2022)

Recently, our group has reported a novel Li-ion battery cathode, ‘LT-LiMn 0.5 Ni 0.5 O 2 ’, where LT refers to its relatively low synthesis temperature (400 °C). By collecting high energy X-ray diffraction and high-angle, annular-dark-field (HAADF) scanning-transmission electron microscopy (STEM) data, we confirm that the LT-LiMn0.5Ni0.5O2 features a unique partially disordered rock salt structure with predominant lithiated-spinel-like character. The electrochemical data indicates that the Li/LT-LiMn 0.5 Ni 0.5 O 2 cells shows good cycle stability when operate between 2.5-5.0V. The 1 st cycle specific discharge capacity was determined to be 225mAh/g. Two distinct voltage plateaus can be identified at approximately at ~4.6 V and ~3.5 V during discharge. The ~1 voltage separation of the plateaus is caused by the octahedral and tetrahedral site energy difference during lithium extraction and insertion. 1 The discovery of LT-LiMn 0.5 Ni 0.5 O 2 not only expand the compositional space for the known lithated-spinel family but also provide a practical way to increase the operational capacity of traditional spinels such like LiMn 2 O 4 and LiMn 1.5 Ni 0.5 O 2 . 2-5 It is well known that when synthesized at 900°C, LiMn 0.5 Ni 0.5 O 2 features a layered structure. 6 The existence of lithated-spinel like LiMn 0.5 Ni 0.5 O 2 at low temperature (400°C) immediately raise another question: How does the synthesis temperature affect the structure and electrochemical performance of LiMn 0.5 Ni 0.5 O 2 ? We synthesized a series of different temperature of LiMn 0.5 Ni 0.5 O 2 powders. By collecting high energy X-ray diffraction and high-resolution transmission electron microscopy (HR-TEM) data, we confirm that, the LiMn 0.5 Ni 0.5 O 2 exhibits a lithated spinel → disordered layered → ordered layered structure transformation as temperature increase from 400-900 °C. The Rietveld refinements results also reveals a gradual decrease of the Li/Ni exchange ratio accompanied by the synthesis temperature changes. The evolution of specific discharge capacity for different temperature LiMn 0.5 Ni 0.5 O 2 shows a parabola-like curve behavior with the lowest discharge capacity at 700 °C. This unique behavior is likely to be related to the diffusion channels reconstruction along with the structure changes. 3D diffusion channels are incorporated with 2D diffusion channels at low temperature (400°C) for lithated-spinel LiMn 0.5 Ni 0.5 O 2 . Within the middle temperature range (500°C-700°C), the 3D channels destroy rapidly while 2D diffusion channels are not well established due to the highly disorder ratio resulting in a decrease of capacity. At higher temperature (800-900°C), the 2D diffusion channels are more well established enabling an increase of the capacity. Shi, B.; Gim, J.; Li, L.; Wang, C.; Vu, A.; Croy, J. R.; Thackeray, M. M.; Lee, E., LT-LiMn 0.5 Ni 0.5 O 2: a unique co-free cathode for high energy Li-ion cells. Chemical Communications 2021, 57 (84), 11009-11012. Thackeray, M. M.; Lee, E.; Shi, B.; Croy, J. R., Review–From LiMn2O4 to Partially-Disordered Li2MnNiO4: The Evolution of Lithiated-Spinel Cathodes for Li-Ion Batteries. Journal of The Electrochemical Society 2022, 169 (2), 020535. Gummow, R.; Thackeray, M.; David, W.; Hull, S., Structure and electrochemistry of lithium cobalt oxide synthesised at 400 C. Materials research bulletin 1992, 27 (3), 327-337. Lee, E.; Blauwkamp, J.; Castro, F. C.; Wu, J.; Dravid, V. P.; Yan, P.; Wang, C.; Kim, S.; Wolverton, C.; Benedek, R., Exploring lithium-cobalt-nickel oxide spinel electrodes for≥ 3.5 V Li-ion cells. ACS applied materials &amp; interfaces 2016, 8 (41), 27720-27729. Lee, E.; Kwon, B. J.; Dogan, F.; Ren, Y.; Croy, J. R.; Thackeray, M. M., Lithiated Spinel LiCo1–x Al x O2 as a Stable Zero-Strain Cathode. ACS Applied Energy Materials 2019, 2 (9), 6170-6175. Yang, X.-Q.; McBreen, J.; Yoon, W.-S.; Grey, C. P., Crystal structure changes of LiMn0. 5Ni0. 5O2 cathode materials during charge and discharge studied by synchrotron based in situ XRD. Electrochemistry communications 2002, 4 (8), 649-654