Chaos and quantum-classical correspondence for two- coupled spins (2001)

Two approaches to quantum-classical correspondence are distinguished according to the classical dynamical theory with which quantum theory is compared. The first of these, Ehrenfest correspondence, defines a dynamical regime in which the quantum expectation values follow approximately a classical trajectory. The second of these, Liouville correspondence, applies when the quantum probability distributions remain well approximated by a density in the classical phase space. The former applies only for narrow states, whereas the latter may remain valid even for quantum states that have spread to the system size. A spin model is adopted for this correspondence study because the quantum state is discrete and finite- dimensional, and thus no artificial truncation of the Hilbert space is required. The quantum time-evolution is given by a discrete unitary mapping. The corresponding classical model is volume-preserving (non-dissipative) and the time-evolution is given by a symplectic map. In classically chaotic regimes, the widths of initially narrow quantum states grow, on average, exponentially with time, until saturation at the system size. This initial spreading rate is well approximated by the classical Lyapunov exponent when the accessible classical phase space is predominantly chaotic. Because of the exponential growth rate of the quantum variance, the Ehrenfest regime is delimited by a break-time that grows logarithmically with increasing quantum numbers. The small differences between quantum expectation values and corresponding Liouville averages of dynamical variables also grow exponentially, initially, if the classical behaviour is chaotic. This exponential rate is independent of h and consistently larger than the classical Lyapunov exponent by at least a factor of two. Interestingly, this exponential growth rate does not continue until these differences approach magnitudes of order the system size, but crosses over to power-law growth (or simply saturates), when the differences have reached magnitudes no larger than order &lt;italic&gt;&amp;hstrok;&lt;/italic&gt;. Because of the exponential growth of these quantum-classical differences, the Liouville regime is also delimited by a break-time that grows logarithmically with increasing quantum numbers. However, due to the early saturation of the exponential growth of the differences, the Liouville log break-time applies only in a restricted domain. After spreading to the system size, the quantum states relax to an approximately time-independent state. This is characterised by equilibrium distributions that are subject to rapidly oscillating fluctuations about the coarse-grained classical steady-state. If the accessible classical phase space is predominantly chaotic, then the equilibrium quantum probability distributions are nearly microcanonical. Otherwise the steady-state quantum probability distributions accurately reflect the details of the KAM surfaces in the classical phase space. The equilibrium regime quantum fluctuations, which are quantum-classical differences, are shown to approach zero as a negative power of the quantum numbers. Since the differences between quantum expectation values and &lt;italic&gt; individual&lt;/italic&gt; classical trajectories grow exponentially in time to a magnitude that scales with the system size, the Ehrenfest regime is delimited by an &lt;italic&gt;unrestricted&lt;/italic&gt; log break-time. The log break-time may be short compared to experimental time-scales for some chaotic macroscopic bodies, and, as a result, an observable &lt;italic&gt;breakdown&lt;/italic&gt; of Ehrenfest correspondence may arise for some macroscopic systems. Although the Liouville regime is also delimited by a log break-time, an observable &lt;italic&gt;breakdown &lt;/italic&gt; of correspondence between quantum mechanics and Liouville mechanics for macroscopic bodies is not likely since their differences, expressed relative to the dimensions of the observable, approach zero in the limit of large quantum numbers.