gebhart/patrepeval huggingface dataset:
O QUE É PARTIDO DE PROJETO (2012)

A expressao “partido de projeto” e de uso corrente entre arquitetos brasileiros e ja ganhou lugar nos dicionarios da lingua. Contudo, nao se encontra na bibliografia uma caracterizacao formal enquanto conceito. Neste estudo, investigamos o sentido da mesma enquanto designacao do modo de operar que distingue a arquitetura das disciplinas universitarias com as quais coopera na construcao do ambiente humano. Enquanto na tecnologia deve haver uma correspondencia ponto a ponto entre as caracteristicas do objeto e a performance esperada do mesmo, no projeto de arquitetura isto e pouco provavel pois este nao pode satisfazer no mesmo grau todos os criterios que sobre ele incidem, sendo o “partido do projeto” aquele ato de escolha de prioridades funcionais, tecnologicas ou esteticas de modo a obter um objeto possivel e cuja significacao supera qualquer tabela previa de desempenhos. Palavras-chave : projeto arquitetonico, projeto tecnologico, arquitetura, engenharia, estetica da arquitetura. Abstract “Partido de projeto” is a current expression amongst brazilian architects with no English equivalent.   So usual it has become that dictionaries  have already granted a place to it. However, nowhere in the professional literature a formal conceptualization thereof can be found. We here undertake to investigate its meaning as the operative way which is peculiar to architecture and sets it off all disciplines with which it shares the building of human environment. Whereas in technology one can always expect a one to one relationship between every characteristic of the object and its assigned performance, in the architectural design such mode of correspondence is not supposed to be matched up, for the latter can’t meet up all the requirements  that bear on it to the same extent and with equal emphasis. The “Partido de projeto” stands out then as the act of choice by way of which some requirements are brought to the fore, be them of functional, constructive or of aesthetic nature, so as to lead up to a possible object, whereas other aspects are meant to play a secondary role and to stand in the background. The unity that turns out of the processes however bears a signification to itself that can’t be put forth in advance by any formal set of requirements. Keywords : architectural design, technological design, engineering, architecture, architectural aesthetics.
Aerobic Oxidative Coupling of Amines by Carbon Nitride Photocatalysis with Visible Light (2010)

Coupling on sunshine: A simple and efficient synthesis of benzoxazoles, benzimidazoles, and benzothiazoles is realized through a one-pot preparation driven by a photocatalytic cascade reaction. Carbon nitride and visible light are employed to achieve this metal-free aerobic oxidation of amines to imines (see scheme; mpg-C3N4=mesoporous graphite carbon nitride).
Singular spectrum analysis of two-photon interference from distinct quantum emitters (2023)

Two-photon interference underlies the functioning of many quantum photonics devices. It also serves as the prominent tool for testing the indistinguishability of distinct photons. However, as their time-spectral profile becomes more involved, extracting relevant parameters, foremost the central frequency difference, may become difficult. In a parametric approach, these arise from the need for an exhaustive model combined with limited count statistics. Here we discuss a solution to curtail these effects on the evaluation of frequency separation relying on a semiparametric method. The time trace of the quantum interference pattern of two photons from two independent solid-state emitters is preprocessed by means of singular spectral analysis before inspecting its spectral content. This approach allows one to single out the relevant oscillations from both the envelope and the noise, without resorting to fitting. This opens the way for robust and efficient on-line monitoring of quantum emitters.
Surface-Engineered Paper Hanging Drop Chip for 3D Spheroid Culture and Analysis (2018)

Protein corona coated onto the hydrophilic cellulose fiber turns into hydrophobic upon UV irradiation without hindering the porosity of the paper while simultaneously reducing nonspecific adsorption. Taking advantage of the biofouling-resistant, hydrophobic, and fluid transport through property, we demonstrated hanging drop three-dimensional (3D) spheroid culture and in-site analysis, including drug testing, time-dependent detection of secreted protein, and fluorescence staining without disturbing the spheroids. This single hanging drop system can also be extended to a networked hanging drop chip to mimic in vivo microphysiology by combining with wax-patterned microfluidic channels, where well-to-well interaction can be accurately controlled in a passive manner. As a proof of concept, the effects of a concentration gradient of nutrient and variable dosage of anticancer drugs were studied in the 3D spheroids cultured on paper. The experimental results suggested that a complex network device could be fabricated on a large scale on demand at a minimal cost for 3D spheroid culture. Our method demonstrates a future possibility for paper as a low cost, high-throughput 3D spheroid-based "body-on-a-chip" platform material.
Prophylactic Insulin Treatment of Syngeneically Transplanted Pre-diabetic BB-DP Rats (2003)

These results suggest that insulin-treatment of syngeneically transplanted BB-DP rats considerably decreases the incidence of diabetes and that this model is well suited for studying molecular changes in the islet transplants.
COMPOSITE 700 BAR-VESSEL FOR ON-BOARD COMPRESSED GASEOUS HYDROGEN STORAGE (2009)

SUMMARY Hydrogen storage is the key to enable an extensive use of hydrogen as an energy carrier. None of the current technologies are able to satisfy all car manufacturers’ specifications. The French Atomic Energy Comission (CEA) has, since 1998, been involved in the development of innovative materials and processes dedicated to the manufacturing of full composite 10,000-psi vessels for on-board storage of gaseous H2, and the present paper reviews the most recent technical and scientific achievements, comparing them to state-of-the-art CGH2 storage systems.
Micropropagation: an important tool for conserving forest trees. (2013)

Forest trees are renewable sources of food, fodder, fuel wood, timber and other valuable non-timber products. The ever increasing human and livestock populations have put heavy demands for plant products, resulting in over exploitation of forest trees. Therefore, there is an urgent need for conservation of germplasm and also for propagation of a sustainable utilization of forest trees. Micropropagation of tree species offers a rapid means of producing clonal planting stock for afforestation, woody biomass production and conservation of elite and rare germplasm. This review provides an overview of the success achieved on in vitro work done for a number of important forest trees.
Identification of phenolic secondary metabolites from Schotia brachypetala Sond. (Fabaceae) and demonstration of their antioxidant activities in Caenorhabditis elegans (2016)

A pronounced antioxidant activity <i>in vivo</i>, which can be attributed to its ability to promote the nuclear translocation of DAF-16/FOXO, the main transcription factor regulating the expression of stress response genes. The remarkable antioxidant activity <i>in vitro</i> and <i>in vivo</i> correlates to SBE rich phenolic profile.
Systematic Examination of the Updated Framingham Heart Study General Cardiovascular Risk Profile (2009)

The inclusion of noncoronary end points in this tool expands the range of predicted risks for men and women at all ages studied. Nevertheless, many younger individuals with high risk factor burden have low 10-year predicted risk. Wide ranges of "vascular age" are available for most chronological ages to assist with risk communication.
Table S2 from USP9X Downregulation Renders Breast Cancer Cells Resistant to Tamoxifen (2023)

&lt;p&gt;Directionality of USP9XKD-tamoxifen classification genes&lt;/p&gt;
Fully Aerosol Jet Printed Interconnects and Fill Materials for Millimeter Wave Circuits (2021)

Recent work has shown significant progress in the fabrication of chip-to-chip and board-to-chip interconnects using additive manufacturing (AM or 3D printing) to replace wire-bond and ribbon-bond interconnects for high frequency applications. To reduce parasitics associated with chip-board interconnects, the chips are mounted in a pocket formed in LCP substrate and the interconnect is printed between the chip and the board using Aerosol Jet Printing (AJP). In this paper, Benzocyclobutene (BCB) is explored as a filling material in the space between the chip and the board. Advantages of this process include tailoring of impedance of printed interconnect and reduction in parasitics, leading to wideband frequency operation. Chip in pocket allows for efficient heat removal and thus useful for high power applications. In this paper a high power Ku-band transmit module is demonstrated using this process.
Ultrathin Patterned Polymer Films on Surfaces Using Thiol−Ene Polymerizations (2006)

A simple and straightforward method for growing ultrathin, micropatterned polymer films on surfaces with precise thickness and spatial control is presented. A difunctional ene monomer and a difunctional thiol were photopolymerized on a surface terminated with thiol groups. The surface thiols participate in the polymerization, and a linear polymer is formed on the surface. Brush growth was spatially controlled by selectively polymerizing the monomers through a photomask, while the brush thickness was controlled by changing the ratio of thiol and ene monomers or by changing the monomer functionality. Further, the surface was passivated by attaching a patterned, cross-linked polymer film, which was then backfilled with another monomer, demonstrating the attachment of multiple functionalities on the surface in a controlled, photolithographically patternable manner. Thiol−ene polymerizations were carried out without an initiator and used to graft patterned, polymer films. The films were observed using scanning probe microscopy and characterized using ellipsometry.
Capsule Growth in Cryptococcus neoformans Is Coordinated with Cell Cycle Progression (2014)

Cryptococcus neoformans is a pathogenic fungus that has significant incidence worldwide. Its main virulence factor is a polysaccharide capsule that can increase in size during infection. In this work, we demonstrate that this process occurs in a specific phase of the cell cycle, in particular, in G1. In agreement, mutants that have an abnormal longer G1 phase show larger capsule sizes. We believe that our findings are relevant because they provide a link between capsule growth, cell cycle progression, and virulence in C. neoformans that reveals new aspects about the pathogenicity of this fungus. Moreover, our findings indicate that cell cycle elements could be used as antifungal targets in C. neoformans by affecting both the growth of the cells and the expression of the main virulence factor of this pathogenic yeast.
Ein Methylen‐di‐λ5‐phosphazen durch Amidspaltung von Tetramethylphosphoniumsalzen (1976)

Eine fluktuierende Verbindung ist das Diphosphazen ( 1 ). Mit Säuren oder ihren Ammoniumsalzen bilden sich die bisher nur schwer zugänglichen Produkte ( 2 ), und mit Organometall‐Verbindungen bildet ( 1 ) Komplexe vom Typ ( 3 ). magnified image
Social Learning, Learning Organizations, and Adaptive Environmental Management (2019)

As outlined in chapter 1, complexity, uncertainty, and ambiguity present challenges for resource and environmental management. In this chapter, three interrelated responses to deal with surprise, change, and wicked problems are examined: social learning, learning organizations, and adaptive environmental management. The characteristics of social learning and learning organizations are identified and reviewed. Then, basic ideas associated with adaptive environmental management are considered. Experience with applying adaptive environmental management is analyzed with regard to managing fish and wildlife, hydro-electricity production, and flood damage reduction in the Columbia River Basin in the United States. In her guest statement, Beate Ratter analyzes the collaborative approach to protecting the coastline of the EuropeanWalden Sea, shared by the Netherlands, Germany and Denmark.
Supplemental Table and Figure Legends from Targeting Hippo-Dependent and Hippo-Independent YAP1 Signaling for the Treatment of Childhood Rhabdomyosarcoma (2023)

&lt;p&gt;Supplemental Table and Figure Legends for Tables 1-2 and Figures 1-5&lt;/p&gt;
Unimpeded skin carcinogenesis in K14‐HPV16 transgenic mice deficient for plasminogen activator inhibitor (2010)

Angiogenesis, extracellular matrix remodeling and cell migration are associated with cancer progression and involve at least, the plasminogen activating system and its main physiological inhibitor, the plasminogen activator inhibitor-1 (PAI-1). Considering the recognized importance of PAI-1 in the regulation of tumor angiogenesis and invasion in murine models of skin tumor transplantation, we explored the functional significance of PAI-1 during early stages of neoplastic progression in the transgenic mouse model of multistage epithelial carcinogenesis (K14-HPV16 mice). We have studied the effect of genetic deletion of PAI-1 on inflammation, angiogenesis, lymphangiogenesis and tumor progression. In this model, PAI-1 deficiency neither impaired keratinocyte hyperproliferation or tumor development nor affected the infiltration of inflammatory cells and development of angiogenic or lymphangiogenic vasculature. We are reporting evidence for concomitant lymphangiogenic and angiogenic switches independent to PAI-1 status. Taken together, these data indicate that PAI-1 is not rate limiting for neoplastic progression and vascularization during premalignant progression, or that there is a functional redundancy between PAI-1 and other tumor regulators, masking the effect of PAI-1 deficiency in this long-term model of multistage epithelial carcinogenesis.
Halide Diffusion in MAPbX3: Limits to Topotaxy for Halide Exchange in Perovskites (2020)

We study halide exchange in the prototypical halide perovskite, methylammonium lead trihalide, MAPbX3 (X = halide), to test and possibly experimentally use halide diffusion in these materials. We use macroscopic single crystals to study the fundamental exchange process(es) so as to minimize possible grain boundary and surface diffusion effects. Initially, halide exchange creates normal concentration gradients of the outgoing and incoming halides, on a scale of a few microns to a few hundred microns. The depth (from the surface) of the substituted volume depends on the halide pair and on which one is exchanged and which is exchanging. The concentration gradient of the incoming halides decreases from the crystal surface toward its inner core and vice versa for the out-going halides; the profiles roughly fit diffusion in a semi-infinite specimen. This concentration gradient changes slowly with time, with the crystal becoming more homogeneous with storage time. Using the Boltzmann–Matano method and diffusion profiles from electron-dispersive spectroscopy, we evaluate the halide diffusion coefficients; these are not constant and depend on the halide couple. Although these gradients cause a lattice parameter change and may cause a symmetry change, X-ray diffraction shows that if the exchanging halides are of similar size (e.g., Br– and Cl–, Br– and I–, but not Cl– and I–), the resulting material remains single crystalline, prima facie evidence for bulk halide diffusion. These findings are valid, irrespective of which is the exchanged halide. These results suggest that for the similar-sized halide pairs the solid-state chemical exchange is topotactic such that the resulting crystal orientation is determined by that of the initial crystal. I–Cl exchange leads to loss of single crystallinity, suggesting lack of miscibility, a finding that might bear on the difficulty in finding Cl in MAPbI3 samples grown from Cl-containing solutions.
Bipolar varieties and real solving of a singular polynomial equation (2010)

We introduce the concept of a bipolar variety of a real algebraic hypersurface. This notion is then used for the design and complexity estimations of a novel type of algorithms that finds algebraic sample points for the connected components of a singular real hypersurface. The complexity of these algorithms is polynomial in the maximal geometric degree of the bipolar varieties of the given hypersurface and in this sense intrinsic.
NQR and NMR of139La in Antiferromagnetic La2CuO4-δ (1987)

Rather complex Nuclear Quadrupole Resonance (NQR) spectrum of 139 La in La 2 CuO 4-δ , observed at low temperatures is successfully interpreted as a signal from a single La site which suffers a combined effect of a quadrupole coupling (coupling constant ν Q =6.38±0.02 MHz with asymmetry parameter η=0.01±0.01) and a small Zeeman term where the internal field ( H N =0.997±0.010 kOe) is nearly perpendicular to the direction of the maximum field gradient. The spin structure of Cu at low temperatures is suggested to be a simple antiferromagnet with sublattice moments parallel to the a -axis. The temperature dependences of ν Q and H N have been measured in detail. The fractional decrease of H N which is proportional to the Cu sublattice moments is found to be in general accord with the prediction of spin fluctuations theory for weak itinerant antiferromagnets.
The dust coma of Comet Austin (1989c1) (1991)

Thermal-infrared (10 and 20 micron) images of Comet Austin were obtained on UT 30.6 Apr., 1.8, 2.8, and 3.6 May 1990. The NASA-Marshall Space Flight Center 20 pixel bolometer array at the NASA 3 meter Infrared Telescope Facility in Hawaii was used. The 10.8 micron (FWHM = 5.3 microns) maps were obtained with maximum dimensions of 113 arcsec (57,500 km) in RA and 45 arcsec (23,000 km) in declination, with a pixel size of 4.2 x 4.2 arcsec. A smaller, 45 x 18 arcsec, map was obtained in the 19.2 micron (FWHM = 5.2 microns) bandpass. At the time of these observations Comet Austin's heliocentric and geocentric distances were 0.7 and 0.5 AU respectively. The peak flux density (within the brightest pixel) was 23 + or - 2 Janskys for the first three dates and only marginally lower the last day; i.e., within the observational uncertainties no evidence was found for day-to-day variability like that observed in Comet Halley. A dynamical analysis of the morphology of the extended dust emission is used to constrain the size distribution and production rate of the dust particles. The results of this analysis are compared with similar studies carried out on comets P/Giacobini-Zinner, P/Brorsen-Metcalf, P/Halley, P/Tempel 2, and Wilson (1987).
SpeakingFaces: A Large-Scale Multimodal Dataset of Voice Commands with Visual and Thermal Video Streams (2021)

We present SpeakingFaces as a publicly-available large-scale multimodal dataset developed to support machine learning research in contexts that utilize a combination of thermal, visual, and audio data streams; examples include human–computer interaction, biometric authentication, recognition systems, domain transfer, and speech recognition. SpeakingFaces is comprised of aligned high-resolution thermal and visual spectra image streams of fully-framed faces synchronized with audio recordings of each subject speaking approximately 100 imperative phrases. Data were collected from 142 subjects, yielding over 13,000 instances of synchronized data (∼3.8 TB). For technical validation, we demonstrate two baseline examples. The first baseline shows classification by gender, utilizing different combinations of the three data streams in both clean and noisy environments. The second example consists of thermal-to-visual facial image translation, as an instance of domain transfer.
m -Azipropofol (AziP m ) a Photoactive Analogue of the Intravenous General Anesthetic Propofol (2010)

Propofol is the most commonly used sedative-hypnotic drug for noxious procedures, yet the molecular targets underlying either its beneficial or toxic effects remain uncertain. In order to determine targets and thereby mechanisms of propofol, we have synthesized a photoactivateable analogue by substituting an alkyldiazirinyl moiety for one of the isopropyl arms but in the meta position. m-Azipropofol retains the physical, biochemical, GABA(A) receptor modulatory, and in vivo activity of propofol and photoadducts to amino acid residues in known propofol binding sites in natural proteins. Using either mass spectrometry or radiolabeling, this reagent may be used to reveal sites and targets that underlie the mechanism of both the desirable and undesirable actions of this important clinical compound.
Aligning where to see and what to tell: image caption with region-based attention and scene factorization (2015)

Recent progress on automatic generation of image captions has shown that it is possible to describe the most salient information conveyed by images with accurate and meaningful sentences. In this paper, we propose an image caption system that exploits the parallel structures between images and sentences. In our model, the process of generating the next word, given the previously generated ones, is aligned with the visual perception experience where the attention shifting among the visual regions imposes a thread of visual ordering. This alignment characterizes the flow of "abstract meaning", encoding what is semantically shared by both the visual scene and the text description. Our system also makes another novel modeling contribution by introducing scene-specific contexts that capture higher-level semantic information encoded in an image. The contexts adapt language models for word generation to specific scene types. We benchmark our system and contrast to published results on several popular datasets. We show that using either region-based attention or scene-specific contexts improves systems without those components. Furthermore, combining these two modeling ingredients attains the state-of-the-art performance.
Energetic Superiority of Two-Center Hydrogen Bonding Relative To Three-Center Hydrogen Bonding in a Model System (1998)

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTEnergetic Superiority of Two-Center Hydrogen Bonding Relative To Three-Center Hydrogen Bonding in a Model SystemJihong Yang and Samuel H. GellmanView Author Information Department of Chemistry, University of Wisconsin Madison, Wisconsin 53706 Cite this: J. Am. Chem. Soc. 1998, 120, 35, 9090–9091Publication Date (Web):August 21, 1998Publication History Received8 May 1998Published online21 August 1998Published inissue 1 September 1998https://pubs.acs.org/doi/10.1021/ja981604uhttps://doi.org/10.1021/ja981604urapid-communicationACS PublicationsCopyright © 1998 American Chemical SocietyRequest reuse permissionsArticle Views363Altmetric-Citations83LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (2)»Supporting Information Supporting Information SUBJECTS:Amides,Conformation,Equilibrium,Mathematical methods,Physical and chemical processes Get e-Alerts