## 3 Results and Discussion
### Volatile Compounds
\begin{table}
\begin{tabular}{c c c c c c c c c} \hline \hline  & \multicolumn{2}{c}{**LRI \({}^{*}\)**} & \multicolumn{2}{c}{**LRI \({}^{*}\)**} & \multicolumn{2}{c}{**Identification \({}^{\textbf{d}}\)**} & \multicolumn{2}{c}{**CT \({}^{\textbf{s}}\)NT \({}^{\textbf{s}}\)**} & \multicolumn{2}{c}{**PT30**} & \multicolumn{2}{c}{**PT45**} \\  & **Literature \({}^{\textbf{b}}\)** & **Calculated \({}^{\textbf{c}}\)** & **Identification \({}^{\textbf{d}}\)** & **CT** & **NT** & **PT15** & **PT30** & **PT45** \\ \hline \multicolumn{1}{c}{**Aldehydes**} & & & & & & & & \\ \hline \multicolumn{1}{c}{**Hexanal**} & 1073 & 1077 & MS + LRI & 2773.56 + 423.64 \({}^{\textbf{a}}\) & ND & 131.09 \(\pm\) 41.18 \({}^{\textbf{c}}\) & 1572.25 \(\pm\) 120.73 \({}^{\textbf{b}}\) & 224.03 \(\pm\) 9.84 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**Hepunal**} & 1163 & 1180 & MS + LRI & 786.22 + 270.82 \({}^{\textbf{a}}\) & ND & ND & 3452.28 \(\pm\) 21.8 \({}^{\textbf{b}}\) & ND \\ \multicolumn{1}{c}{**Octual**} & 1275 & 1283 & MS + LRI & 484.85 + 136.37 \({}^{\textbf{a}}\) & 203.66 \(\pm\) 6.54 \({}^{\textbf{c}}\) & ND & 252.42 \(\pm\) 20.73 \({}^{\textbf{b}}\) & 91.30 \(\pm\) 7.52 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**(F)-2-Hepunal**} & 1334 & 1311 & MS + LRI & 172.25 \(\pm\) 6.05 & ND & ND & ND & ND \\ \multicolumn{1}{c}{**Nomal**} & 1385 & 1387 & MS + LRI & 86.56 + 159.97 \({}^{\textbf{a}}\) & 47.40 \(\pm\) 11.09 \({}^{\textbf{a}}\) & 192.82 \(\pm\) 33.66 \({}^{\textbf{c}}\) & 483.85 \({}^{\textbf{c}}\) & 16.69 \({}^{\textbf{b}}\) & 226.28 \(\pm\) 21.93 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**(F)-2-Octual**} & 1414 & 1419 & MS + LRI & 38.28 \(\pm\) 10.28 \({}^{\textbf{a}}\) & ND & ND & 16.37 \(\pm\) 7.92 \({}^{\textbf{a}}\) & ND \\ \multicolumn{1}{c}{**Decanal**} & 1483 & 1492 & MS + LRI & 11.71 \(\pm\) 0.33 \({}^{\textbf{a}}\) & ND & 1.95 \(\pm\) 0.39 \({}^{\textbf{a}}\) & 104.0 \(\pm\) 0.38 \({}^{\textbf{b}}\) & 4.99 \(\pm\) 0.43 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**Benaaldehyde**} & 1508 & 1506 & MS + LRI & 43.30 \(\pm\) 54.0 \({}^{\textbf{a}}\) & 287.5 \(\pm\) 68.1 \({}^{\textbf{b}}\) & 31.55 \(\pm\) 469 \({}^{\textbf{b}}\) & 36.15 \(\pm\) 22.38 \({}^{\textbf{b}}\) & 30.27 \(\pm\) 22.88 \({}^{\textbf{b}}\) \\ \multicolumn{1}{c}{**(F)-2-Nonneal**} & 1535 & 1526 & MS + LRI & 28.57 \(\pm\) 7.64 \({}^{\textbf{a}}\) & ND & ND & 14.50 \(\pm\) 52.42 \({}^{\textbf{b}}\) & ND \\ \multicolumn{1}{c}{**Dodecanal**} & 1710 & 1704 & MS + LRI & 6.24 \(\pm\) 12.33 \({}^{\textbf{a}}\) & ND & ND & 4.47 \(\pm\) 0.87 \({}^{\textbf{b}}\) & ND \\ \multicolumn{1}{c}{**(F)-2-Independent**} & 1755 & 1745 & MS + LRI & 79.8 \(\pm\) 22.32 \({}^{\textbf{a}}\) & ND & ND & ND & ND \\ \multicolumn{1}{c}{**(E,E)-2-4-Decadienal**} & 1766 & 1757 & MS + LRI & 11.12 \(\pm\) 2.80 \({}^{\textbf{a}}\) & ND & ND & ND & ND \\ \multicolumn{1}{c}{**Mystistaldehyde**} & 1931 & 1918 & MS + LRI & 8.77 \(\pm\) 27.9 \({}^{\textbf{a}}\) & ND & ND & 4.27 \(\pm\) 10.0 \({}^{\textbf{b}}\) & ND \\ \multicolumn{1}{c}{**Femadecan**} & 2042 & 2025 & MS + LRI & 11.86 \(\pm\) 42.93 \({}^{\textbf{a}}\) & ND & 1.32 \(\pm\) 07.0 \({}^{\textbf{b}}\) & 7.19 \(\pm\) 3.14 \({}^{\textbf{a}}\) & ND \\ \multicolumn{1}{c}{**Hexadecan**} & 2141 & 2132 & MS + LRI & 4.41 \(\pm\) 0.34 \({}^{\textbf{a}}\) & ND & 2.36 \(\pm\) 0.43 \({}^{\textbf{b}}\) & 4.22 \(\pm\) 0.35 \({}^{\textbf{a}}\) & 1.90 \(\pm\) 0.27\({}^{\textbf{b}}\) \\ \hline \multicolumn{1}{c}{**Alcohoids**} & & & & & & & \\ \hline \multicolumn{1}{c}{**Pentanol**} & 1252 & 1250 & MS + LRI & 177.44 \(\pm\) 30.82 \({}^{\textbf{a}}\) & ND & 7.62 \(\pm\) 1.74 \({}^{\textbf{c}}\) & 77.33 \(\pm\) 12.57 \({}^{\textbf{b}}\) & 9.84 \(\pm\) 1.83 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**Hexanol**} & 1344 & 1352 & MS + LRI & 45.99 \(\pm\) 8.11 \({}^{\textbf{a}}\) & ND & 4.80 \(\pm\) 0.72 \({}^{\textbf{c}}\) & 33.02 \(\pm\) 10.66 \({}^{\textbf{b}}\) & 5.74 \(\pm\) 1.46 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**Propyl disulfide**} & 1378 & 1369 & MS + LRI & 26.31 \(\pm\) 4.54 \({}^{\textbf{a}}\) & 63.9 \(\pm\) 18.74 \({}^{\textbf{a}}\) & ND & 46.30 \(\pm\) 3.39 \({}^{\textbf{a}}\) & 4.29 \(\pm\) 0.70 \({}^{\textbf{c}}\) \\ \multicolumn{1}{c}{**1-Octa-3-0**-3-0**1} & 1430 & 1449 & MS + LRI & 43.03 \(\pm\) 0.96 \({}^{\textbf{a}}\) & 15.58 \(\pm\) 4.35 \({}^{\textbf{a}}\) & 42.73 \(\pm\) 8.22 \({}^{\textbf{a}}\) & 20.297 \(\pm\) 17.34 \({}^{\textbf{b}}\) & 57.32 \(\pm\) 8.22 \({}^{\textbf{a}}\) \\ \multicolumn{1}{c}{**Hepunal**} & 1456 & 1454 & MS + LRI & 46.41 \(\pm\) 8.66 \({}^{\textbf{a}}\) & ND & ND & 2457 \(\pm\) 25.1 \({}^{\textbf{b}}\) & ND \\ \multicolumn{1}{c}{**2-Ethyl-1-hexanol**} & 1484 & 1488 & MS + LRI & ND