# Dynamics of Monoterpene Formation in Spike Lavender Plants
## 2 Results
### NMR Data
\begin{table}
\begin{tabular}{c c c c c c c c c c c c c c} \hline
**1,8-cineo** & **Signal** & \multicolumn{3}{c}{**Chemical Shift**} & \multicolumn{3}{c}{**Montiplicity Integral**} & \multicolumn{3}{c}{**Coupling**} & \multicolumn{3}{c}{**Correlation**} \\
**Carbon Atom** & **No.** & \multicolumn{3}{c}{**(ppm)**} & \multicolumn{3}{c}{**Multiplicity Integral**} & \multicolumn{3}{c}{**Constant (Hz)**} & \multicolumn{3}{c}{**COSY**} \\ \hline - & \({}^{1}\)H & \({}^{1}\)H & \({}^{1}\)C (HSCC, HMIBC) & - & - & - & - & COSY & COSYb & \
\begin{tabular}{c} TOSY \\ (long range) \\ \end{tabular} & HMIBC & FISQC & NOISY \\ \hline \(3/5\) & 1 & 2.05 & 22.80 & CH\({}_{2}\) & Multiplet & 2 & - & 2,3,4 (v) & 2,3,4 & 2,3,5 & 1,2,3,4,5,6 & 1,3 & - \\ \hline \(2/6\) & 2 & 1.69 & 31.48 & CH\({}_{2}\) & Multiplet & 2 (2-4) & - & 1,3 & 1,3 & 1,3,4 &
\begin{tabular}{c} 1,2,3,4,6 \\ (strong) \\ \end{tabular} & 2,3 & - \\ \hline - & 3 & 1.52 & 22.80 & CH\({}_{2}\) & Multiplet & 4 & - & 1,2 & 1,2,4 & - & - & - \\ \hline \(4\) & 4 & 1.43 & 29.91 & CH & Multiplet & 1 & - & 1 (weak) & 1 & 1,2,3 & 1,2,3,5 (v) & 4 & - \\ \hline \(9/10\) & 5 & 1.26 & 28.87 & CH\({}_{3}\) & Singulet & 6 & - & - & - & - & 4,5 (strong) & 5 & - \\ \hline \(7\) & 6 & 1.07 & 27.55 & CH\({}_{3}\) & Singulet & 3 & - & - & - & - & 2 (weak), & 6 & - \\ \hline \(1\) & - & - & 69.92 & - & - & - & - & - & - & - & 1,2,3 (weak), & - & - \\ \hline \(8\) & - & - & 73.76 & - & - & - & - & - & - & - & - & 3,5 (strong), & - & - \\ \hline \end{tabular}
\end{table} 
Table 2: NMR Signal assignment for 1,8-cineo. \begin{table}
\begin{tabular}{c c c c c c c c c c c c c} \hline \hline
**Camphor** & **Signal** & \multicolumn{2}{c}{**Chemical Shift**} & \multicolumn{2}{c}{**Coupling**} & \multicolumn{4}{c}{**Correlation**} \\
**Carbon Atom** & **No.** & \multicolumn{2}{c}{**(ppm)**} & \multicolumn{2}{c}{**-**} & \multicolumn{2}{c}{**Multiplicity Integral**} & \multicolumn{2}{c}{**Constant (H2)**} & \multicolumn{2}{c}{**TOCYS**} & \multicolumn{2}{c}{**HMSC**} & \multicolumn{2}{c}{**HMSC**} & \multicolumn{2}{c}{**HMSC**} & \multicolumn{2}{c}{**NOESY**} \\ \hline - & \({}^{1}\)H & \({}^{1}\)H & \({}^{1}\)C (HESC), & - & - & - & - & COSY & COSY & (long range) & HMSC & HSQC & NODS \\  & & & & & & & & & & & & & \\  & & & & & & & & & & & & & \\ \hline
3 & 1 & 2.36 & 43.32 & CH\({}_{2}\) & \(\begin{array}{c}\text{dd}4\\ 4\end{array}\) & \(\begin{array}{c}\text{1}\\ 1\end{array}\) & \(\begin{array}{c}\text{180.45.33}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) \\
5 & 3 & 1.96 & 27.04 & CH\({}_{2}\) & Multiplet & 1 & - & 5.7 & 5.7 & 1, \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) \\
6 & 5 & 1.69 & 29.91 & CH\({}_{2}\) & \(\begin{array}{c}\text{dd}\\ 1\end{array}\) & \(\begin{array}{c}\text{182.1}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) & \(\begin{array}{c}\text{3}\\ 1\end{array}\) \\
7 & - & - & 46.84 & CH\({}_{2}\) & Multiplet & 1 & - & - & - & - & \(\begin{array}{c}\text{4}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) & \(\begin{array}{c}\text{2}\\ 1\end{array}\) \\ \hline \hline \end{tabular}
\end{table} 
Table 3: NMR Signal assignment for camphor.