## 3 Results and Discussion
\begin{table}
\begin{tabular}{c c c c c c c c c} \hline
**Peak** & **Identification** & **[M-H]-** & **[M+H]\({}^{*}\)** & **Elemental** & **Error (ppm)** & **MSn ions** & **Rt (min)** & **C.** _sativens_ & _L._ _sicersaria_ \\ \hline
77 & Trhydroxy-dimethoxyoylguan & & 347,1829 & C\({}_{20}\)H\({}_{20}\)O\({}_{3}\)\({}^{*}\) & 5 & 329, 311, 283, 255, 237, 207, & & & \\
**Saponins** & & & & & 195, 183, 163, 137, 123, 107, & 20.5 & - & + \\  & Unknown & & & & & 105 & & \\
78 & O-pentosyl-O-hexedse seponin & & 917,5112 & C\({}_{40}\)H\({}_{77}\)O\({}_{8}\)\({}^{*}\) & 0.3 & 785, 397, 179 & 16.7 & + & - \\  & derivative & & & & & & \\  & -Soyasorgon & & 955,4889 & C\({}_{88}\)H\({}_{75}\)O\({}_{9}\)\({}^{*}\) & 2 & 397, 113 & 17.3 & + & - \\
79 & E-O-diheosyl-O-glucuron & & 1059,5385 & C\({}_{88}\)H\({}_{80}\)O\({}_{2}\)\({}^{*}\) & 0.3 & 927, 397, 113 & 17.8 & + & - \\  & -Soyasorgon & & & & & & & \\
80 & Unknown O-pentosyl-openin & & 1059,5385 & C\({}_{88}\)H\({}_{80}\)O\({}_{2}\)\({}^{*}\) & 0.3 & 927, 397, 113 & 17.8 & + & - \\  & derivative & & & & & & & \\
81 & O-dhamosyl-O-pentosyl-O-glucuronide & & 1073,5534 & C\({}_{88}\)H\({}_{80}\)O\({}_{2}\)\({}^{*}\) & 0.4 & 927, 397, 341 & 18 & + & - \\  & (Meliitoussponin O1) & & & & & & & \\
82 & Soyasorgonin I & & 943,5107 & C\({}_{88}\)H\({}_{75}\)O\({}_{8}\)\({}^{*}\) & 0.9 & 923, 397, 341, 113 & & & \\  & & 943,5275 & C\({}_{88}\)H\({}_{75}\)O\({}_{8}\)\({}^{*}\) & 1.5 & 797, 635, 671, 599, 581, 459, 19.9 & + & - \\
**Fatty acids/amides** & & & & 441, 423, 430, 383. & & & \\
83 & Trhydroxy-butanoic acid & 135,0295 & C\({}_{8}\)H\({}_{75}\)O\({}^{*}\) & 1.8 & 98, 75, 59 & 5.5 & + & - \\
84 & Undacene-tracarboxylic acid & 287.15 & C\({}_{8}\)H\({}_{82}\)O\({}^{*}\) & 0 & 269, 227, 209, 199, 59 & 14.8 & + & - \\
85 & Tetrahydroxy-octadecacyclic acid & 343,2124 & C\({}_{8}\)H\({}_{83}\)O\({}_{6}\)\({}^{*}\) & 0.6 & 325, 307, 289, 273, 229, 209, & 15.5 & + & + \\
86 & Azakic acid & 187,0975 & C\({}_{8}\)H\({}_{83}\)O\({}^{*}\) & 0.2 & 169, 143, 125, 97, 57 & 16.3 & + & + \\
87 & Otataformaldehyde & 201,1132 & C\({}_{81}\)H\({}_{83}\)O\({}^{*}\) & 0.3 & 185, 139, 111, 57 & 18.1 & + & - \\
88 & Trhydroxy-octadecamericic acid & 327,2176 & C\({}_{81}\)H\({}_{80}\)O\({}^{*}\) & 0.2 & 294, 211, 183 & 18.8 & + & - \\
89 & Crudeudeudeudeude & 282,2796 & C\({}_{88}\)H\({}_{80}\)O\({}^{*}\) & 1.7 & 265 & 18.9 & + & + \\
90 & Trithydroydroacetacetonic acid & 329,2332 & C\({}_{81}\)H\({}_{83}\)O\({}^{*}\) & 0.6 & 311, 293, 229, 211, 171 & 19.7 & + & + \\
91 & Unsaturated fatty acid & & 275,2011 & C\({}_{81}\)H\({}_{82}\)O\({}^{*}\) & 2.1 & 251, 219,185, 147, 133, 119. & 22 & + & + \\
92 & Dhydroocytadecadeconic acid & 311,2227 & C\({}_{81}\)H\({}_{83}\)O\({}^{*}\) & 0.2 & 293, 275, 199 & 25.2 & + & + \\
93 & Unsaturated fatty acid & & 277,2161 & C\({}_{81}\)H\({}_{83}\)O\({}^{*}\) & 0.4 & 207, 133, 107, 93, 97, 67 & 254 & + & + \\
94 & Undacetarinco acid & & 279,2318 & C\({}_{81}\)H\({}_{83}\)O\({}^{*}\) & 0.2 & 255, 149, 135, 107, 81,69 & 26 & + & + \\
95 & Lindenic acid derivative & 559,3119 & C\({}_{83}\)H\({}_{83}\)O\({}^{*}\) & 0.8 & 27 & 26.7 & + & - \\ \hline \end{tabular}
\end{table} 
Table 1: Cont.