## 4 Extraction Methods
\begin{table}
\begin{tabular}{c c c c c c c c c c} \hline \hline
**Matrix** & **Extraction** & \multirow{2}{*}{**Detector**} & \multirow{2}{*}{**Column**} & \multirow{2}{*}{**Mobile Phase**} & \multirow{2}{*}{**Gradient**} & \multicolumn{2}{c}{**How Rate**} & \multirow{2}{*}{**LOQ**} & \multicolumn{2}{c}{**Recovery**} & \multirow{2}{*}{**Reference**} \\  & and **Clean-Up** & & & & & & & & \\ \hline \multirow{8}{*}{Bicouts} & Addination of MCMU & \multirow{8}{*}{MS/MS} & Phenomenence kinetics & A 0.17\% female acid in & 1 min, 5\% B; & & & \\  & evaporate Addition & & CIS & & & & 2 min, 10\% B; & & \\  & of baseline, & & (100 mm \(\times\) 30 mm, & water) & 3.5 min, 80\% B; & & & & \\  & centrifuge, and & & 2.6 μm) & & 3.5 min, 80\% B; & & & & \\  & flinkinkink with 0.2 μm & & & 2.6 μm) & & & & & \\  & PBS membrane & & & & & & & \\ \hline \multirow{2}{*}{Soy since} & \multirow{2}{*}{MMIP} & \multirow{2}{*}{POA-233 mm} & Sino-Chron & \multirow{2}{*}{A- MoCH} & \multirow{2}{*}{Iocratic 88\% B; } & \multirow{2}{*}{I.0} & \multirow{2}{*}{5.64 \(\mu\)g L\({}^{-1}\)} & \multirow{2}{*}{97.33-104.57} & \multirow{2}{*}{[81]} \\  & & O(230 mm) \(\times\) 5 mm, & & & & & & \\  & & & & & & & \\  & & & & & & & \\  & & & & & & & \\  & & & & & & & \\  & & & & & & & \\  & & & & & & & \\  & & & & & & & \\  & & & & & & & \\ \hline \multirow{2}{*}{Bicouts} & SFE with Onis MC & \multirow{2}{*}{it VGG-MS} & Edigent Polaris & A. ACN & 0.1 min, 95\% B; & 0.5 & 0.5 mg mL\({}^{-1}\) & 103-108 & \\  & cartridge & & & & & & & \\  & DLIM with dany1 & & Ion trap-MS & (150 mm \(\times\) 4.0 mm, & hydroxide in water) & 101.0m, 95\% B; & & & \\  & chloride derivatization & & & & & & \\  & & & & & & & \\  & & & & & & \\  & & & & & & & \\  & & & & & & \\ \hline \multirow{2}{*}{SPE: Solid phase extraction, \({}^{2}\) SFE: Supercritical fluid extraction; \({}^{3}\) MIP-SFE: Molecularly implemented polymer-solid phase extraction; \({}^{4}\) PLM: Dispersive liquid-liquid microstructure; \({}^{5}\) PAD: Drade large; \({}^{5}\) MS: Mass spectrometry; \({}^{6}\) SH: Single ion monitoring \({}^{6}\) PLM: Photodiode array; \({}^{7}\) MLM: Magnetic molecularly imprinted polymer; \({}^{11}\) IMPONS: Time of flight mass spectrometry; \({}^{7}\) IMPONS: High resolution mass spectrometry; \({}^{7}\) PIP: Polyitenitenwoerly; \({}^{9}\) QQ-QNet Triple quadrupole-mass spectrometry.} & & & \\ \hline \hline \end{tabular}
\end{table} 
Table 2: Conf. \begin{table}
\begin{tabular}{c c c c c c c c} \hline \hline
**Matrix** & **Extraction** and **Clean-Up** & **Detector** & **Column** & **Conditions** & \begin{tabular}{c} **Oven Temperature** \\ **Program** \\ \end{tabular}  & **LOQ** & **Recovery** (\%) & **Reference** \\ \hline \multirow{4}{*}{Cranamel colors} & Addition of 2-methylimidazole, & \multirow{2}{*}{MS} & HPSMS & Split ratio of 30:1 at & 75\({}^{\circ}\)C for 10 min, & \multirow{2}{*}{-} & \multirow{2}{*}{[19]} \\  & Cellie 58: Extraction with hot & MS & (0.0 m \(\times\) 0.25 mm, & 240\({}^{\circ}\)C & then 320\({}^{\circ}\)C & & \\  & dichichoremente, evaporation, & & 0.25 mm) & & & & \\  & and addition of acetic anhydride & & & & & \\ \hline \multirow{2}{*}{Soft drinks} & \({}^{1}\) SPME fibers (100 mm \(\times\) 2 FDMS, & \multirow{2}{*}{MS} & HP-InnovaMix & \multirow{2}{*}{Splitless mode at 270\({}^{\circ}\)C} & 70\({}^{\circ}\)C for 1 min, & \multirow{2}{*}{6.0 mg L\({}^{-1}\)} & \multirow{2}{*}{-} & \multirow{2}{*}{[40]} \\  & 65 mm \({}^{2}\) FDMS-DVR, 85 mm FD, & MS & (60.0 m \(\times\) 0.25 mm, & & &  
\begin{table}
\begin{tabular}{c c c c c c c c} \hline \hline  
\begin{table}
\begin{tabular}{c c c c c c c c} \hline \hline
Good to excellent recovery rates have been obtained from the previously described extraction methods. The best recoveries have been reported from [PERSON] et al. [17] and [PERSON] et al. [18] (>98%) who both used the water extraction and SPE clean-up, [PERSON] et al. [78] (101.2 \(\pm\) 1.8%) who applied a simple water dilution, [PERSON] et al. [35] (99.4%) with MeOH/water extraction and subsequent filtration, [PERSON] et al.