## 3 Results
Between the ten main compounds identified using all three methods, the following were above 5%: \(\alpha\)-pinene 1x, \(\beta\)-pinene 1x, \(\beta\)-myrrene--3x, limonene--3x, \(\beta\)-carryophyllene--3x, \(\gamma\)-selinene--2x, and selina-3,7(11)-diene--2x. Altogether, there were 20 different terpen/terpenoids between the ten main compounds. The same 21 compounds were found in all three types of analysis. Altogether, 56 compounds were identified by HS (96.45%), 49 compounds by SPME (85.43%), and 44 compounds by Liq (86.85%) GC/MS, together comprising 84 different volatile compounds. A comparison of all three methods of analysis is presented in Figure 7. \begin{table}
\begin{tabular}{c c c c c c c} \hline \hline
**Peak** & **RT** & **\% (Liq)** & **\% (HS)** & **\% (SPME)** & **Compound** & **Type** & **RI** \\ \hline
81 & 30.158 & 1.06 & 0.17 & & **caryophyllene oxide** & bicyclic sesquiterpenoid & 1581 \\ \hline
82 & 30.334 & **3.60** & 0.15 & 0.34 & **guaiol** & bicyclic sesquiterpenoid & 1596 \\ \hline
83 & 30.455 & 0.18 & traces & & 5-_epi-7-epi-\(\alpha\)-eudesmol_ & bicyclic sesquiterpenoid & 1616 \\ \hline
84 & 30.527 & & traces & & humulene epoxide II & bicyclic sesquiterpenoid & 1606 \\ \hline
85 & 30.663 & **4.97** & 0.18 & 0.58 & 10-_epi-\(\gamma\)-eudesmol_ & bicyclic sesquiterpenoid & 1619 \\ \hline
86 & 30.799 & 1.17 & traces & & \(\gamma\)-eudesmol & bicyclic sesquiterpenoid & 1631 \\ \hline
87 & 30.859 & 0.23 & & & agarospirol & bicyclic sesquiterpenoid & 1645 \\ \hline
88 & 31.040 & 1.66 & traces & & \(\beta\)-eudesmol & bicyclic sesquiterpenoid & 1649 \\ \hline
89 & 31.072 & **2.99** & traces & & \(\alpha\)-eudesmol & bicyclic sesquiterpenoid & 1653 \\ \hline
90 & 31.224 & **4.25** & traces & 0.11 & bulnesol & bicyclic sesquiterpenoid & 1667 \\ \hline
91 & 31.320 & & & 0.10 & cadalene & bicyclic aromatic hydrocarbon & 1674 \\ \hline
92 & 31.575 & 0.35 & & juniper camphor & bicyclic sesquiterpenoid & 1691 \\ \hline
93 & 32.523 & & & 0.09 & \(\alpha\)-phellandrene dimer & tricyclic terpene & 1801 \\ \hline
94 & 33.733 & & traces & hexadecanoic acid & saturated fatty acid & 1968 \\ \hline  & & 80.02\% & 97.87\% & 90.80\% & & \\ \hline  & & 38 cpd & 74 cpd & 57 cpd & & \\ \hline \hline \end{tabular}
\end{table} 
Table 2: _Cont._ \begin{table}
\begin{tabular}{c c c c c c c} \hline \hline
**Peak** & **RT** & **\% (Liq)** & **\% (HS)** & **\% (SPME)** & **Compound** & **Type** & **RI** \\ \hline
1 & 8.987 & & traces & & 3-hexen-1-ol & & 856 \\ \hline
2 & 9.398 & traces & & & 4-methyl-octane & hydrocarbon & 863 \\ \hline
3 & 9.528 & 0.10 & & & \(p\)-xylene & aromatic hydrocarbon & 865 \\ \hline
4 & 9.508 & 0.14 & 0.48 & 0.22 & 1-hexanol & organic alcohol & 868 \\ \hline
5 & 11.239 & & traces & & 5,5-dimethyl-1- & & \\  & & & & vinylbicyclo[2.1.1]hexane & bicyclic monoterpene & 921 \\ \hline
6 & 11.608 & & 0.14 & traces & \(\alpha\)-thujene & bicyclic monoterpene & 929 \\ \hline
7 & 11.824 & 1.61 & **6.92** & 0.57 & \(\alpha\)**-pinene** & bicyclic monoterpene & 937 \\ \hline
8 & 12.345 & 0.46 & **2.00** & 0.13 & **camphene** & bicyclic monoterpene & 952 \\ \hline
9 & 13.388 & 2.33 & **9.41** & 0.68 & \(\beta\)**-pinene** & bicyclic monoterpene & 979 \\ \hline
10 & 14.045 & **5.58** & **21.60** & **9.79** & \(\beta\)**-myrrene** & acyclic monoterpene & 991 \\ \hline
11 & 14.406 & & traces & & \(\alpha\)-phellandrene & monocyclic monoterpene & 1005 \\ \hline
12 & 14.646 & & & **4.14** & \(\Delta^{3}\)**-carene** & bicyclic monoterpene & 1011 \\ \hline \hline \end{tabular}
\end{table} 
Table 3: GC/MS identification of the dry flowering tops—sample **LOH LI3** chemotype.