## 3 Results and Discussion
### Fingerprint of Lilium from Different Producing Areas
\begin{table}
\begin{tabular}{c c c c c c c c c c c c} \hline \hline
**Number** & **S1** & **S2** & **S3** & **S4** & **S5** & **S6** & **S7** & **S8** & **S9** & **S10** & **R** \\ \hline S1 & 1.000 & 0.996 & 0.998 & 0.992 & 0.996 & 0.997 & 0.929 & 0.878 & 0.872 & 0.840 & 0.996 \\ S2 & 0.996 & 1.000 & 0.999 & 0.998 & 0.999 & 0.999 & 0.899 & 0.839 & 0.829 & 0.804 & 0.986 \\ S3 & 0.998 & 0.999 & 1.000 & 0.996 & 0.999 & 0.999 & 0.912 & 0.857 & 0.847 & 0.822 & 0.991 \\ S4 & 0.992 & 0.998 & 0.996 & 1.000 & 0.999 & 0.998 & 0.880 & 0.818 & 0.806 & 0.796 & 0.980 \\ S5 & 0.996 & 0.999 & 0.999 & 0.998 & 1.000 & 0.999 & 0.897 & 0.838 & 0.828 & 0.811 & 0.987 \\ S6 & 0.997 & 0.999 & 0.999 & 0.998 & 0.999 & 1.000 & 0.906 & 0.852 & 0.840 & 0.824 & 0.991 \\ S7 & 0.929 & 0.899 & 0.912 & 0.880 & 0.897 & 0.906 & 1.000 & 0.966 & 0.987 & 0.913 & 0.953 \\ S8 & 0.878 & 0.839 & 0.857 & 0.818 & 0.838 & 0.852 & 0.966 & 1.000 & 0.973 & 0.918 & 0.909 \\ S9 & 0.872 & 0.829 & 0.847 & 0.806 & 0.828 & 0.840 & 0.987 & 0.973 & 1.000 & 0.914 & 0.904 \\ S10 & 0.840 & 0.804 & 0.822 & 0.796 & 0.811 & 0.824 & 0.913 & 0.918 & 0.914 & 1.000 & 0.884 \\ R & 0.996 & 0.986 & 0.991 & 0.980 & 0.987 & 0.991 & 0.953 & 0.909 & 0.904 & 0.884 & 1.000 \\ \hline \hline \end{tabular}
\end{table} 
Table 4: The similarity analysis results of ten batches of Lilium. Figure 3: The Custer analysis of ten batches of Lilium. \begin{table}
\begin{tabular}{c c c c c c c} \hline \hline
**No. ** & **Time** & \ \begin{tabular}{c} **Molecular** \\ **Weight** \\ \end{tabular}  & **Chemical Compound** & \begin{tabular}{c} **Molecular** \\ **Formula** \\ \end{tabular}  & **References** & **Category** \\ \hline
4 & 8.275 & 399.1293 & \ \begin{tabular}{c} (2R)-1-O-\(\beta\)-D-glucopyranosyl-2-O-p- \\ coumaroylglycerol \\ (regaloside H) \\ \end{tabular}  & C\({}_{18}\)H\({}_{24}\)O\({}_{10}\) & [29,31] & \begin{tabular}{c} phenolic \\ compounds \\ \end{tabular}  \\
5 & 8.494 & 399.1307 & \ \begin{tabular}{c} 1-O-coumaroyl-2-O-p-feruloylglycerol \\ (2S)-1-O-p-coumaroyl-2-O-\(\beta\)-D-glucopyranosyl-3-O- \\ acetylglycerol \\ (regaloside B) \\ (2S)-1-O-caffeoyl-2-O-\(\beta\)-D-glucopyranosyl-3-O- \\ acetylglycerol \\ \end{tabular}  & C\({}_{21}\)H\({}_{20}\)O\({}_{8}\) & [29,32] & \begin{tabular}{c} phenolic \\ compounds \\ \end{tabular}  \\
7 & 15.578 & 819.4392 & \begin{tabular}{c} 22\(\alpha\), 26-tetraol 3-O-\(\alpha\)-L-Hammopyranosyl(l(1\(\rightarrow\)2)-O- \\ [\(\beta\)-D-glucopyranosyl(l(1\(\rightarrow\)4))]-\(\beta\)-D-glucopyranoside \\ (22R, 25R)-spirosol-5-en-3\(\beta\)-yl \\ 3-O-\(\alpha\)-L-Hammopyranosyl(l(1\(\rightarrow\)2)-O-[\(\beta\)-D-glucopyranosyl(l(25R, 26R)-26-methoxyspiroset-5-ene-3\(\beta\),17\(\alpha\), 3-O-\(\alpha\)-L-Hammopyranosyl(l(1\(\rightarrow\)2))-O-[\(\beta\)-D- \\ 9 17.502 & 930.5076 & \ \begin{tabular}{c} 26\(\alpha\), 26-tetraol 3-O-\(\alpha\)-L-Hammopyranosyl(l(1\(\rightarrow\)2))-O- \\ [\(\beta\)-D-glucopyrananoyl(l(1\(\rightarrow\)4))]-\(\beta\)-D-glucopyranoside \\ (25R, 26R)-17-\(\alpha\)-hydroxy-26-methoxyspiroset-5-en-3\(\beta\)-yl \\ \end{tabular}  & C\({}_{39}\)H\({}_{62}\)O\({}_{18}\) & [33] & \begin{tabular}{c}steroidal \\ saponins \\ \end{tabular}  \\
8 & 17.264 & 928.4924 &
\begin{tabular}{c} 3-O-\(\alpha\)-L-Hammopyranosyl(l(1\(\rightarrow\)2)-O-[\(\beta\)-D- \\ -D-glucopyranosyl(l(1\(\rightarrow\)4))]-\(\beta\)-D-glucopyranoside \\ (25R, 26R)-26-methoxyspiroset-5-ene-3\(\beta\),17\(\alpha\), \\ 3-O-\(\alpha\)-L-Hammopyranosyl(l(1\(\rightarrow\)2))-O-[\(\beta\)-D- \\ -  
\begin{table}
\begin{tabular}{c c c c c c} \hline \hline
**No. ** & **Time** & \ \begin{tabular}{c} **Molecular** \\ **Weight** \\ \end{tabular}  & **Chemical Compound** & \begin{tabular}{c} **Molecular** \\ **Formula** \\ \end{tabular}  & **References** & **Category** \\ \hline
1 & 14.643 & 576.3904 & Daucosterol & C\({}_{35}\)H\({}_{60}\)O\({}_{6}\) & [42] & \begin{tabular}{c}steroidal \\ saponins \\ steroidal \\ saponins \\ steroidal \\ saponins \\ steroidal \\ saponins \\ steroidal \\ saponins \\ steroidal \\ saponins \\ \\ \hline \hline \end{tabular}