## 5 Environmental Applications
### Air Samples
\begin{table}
\begin{tabular}{l l l l l l l l l l l l l l} \hline \hline  & & & \multicolumn{6}{c}{**Extraction conditions**} & \multicolumn{6}{c}{**Desorption**} \\  & & & & & & & & & & & & & & & & & \\
**Analyte** & **Environmental Sample** & **Technique** & **Fiber** & **Time** & **Temp. (Salt)** & **Deriv.** & **Time** & **Temp. (min)** & **Detection** & **LOD** & **Rewery** & **Ref.** \\  & & & & **[min]** & **[\({}^{\circ}\)C]** & **Addition** & **[min]** & **[\({}^{\circ}\)C]** & & & & & & & & \\ \hline \multicolumn{11}{c}{_Solil / Sediment and other Solid Matrices_} \\  & & & & & & & & & & & & & & & & \\ \hline \multicolumn{11}{c}{_Odorous compounds_} \\ VOC and odorous compounds & dairy manure & HS-SPME & PDMS-DVB- & 30 & 30 & - & - & - & 230 & MD-GC- & - & - & [373] \\ Odorous volatile compounds & compost & HS-SPME & PDMS-CAR & 60 & 20 & - & - & 40 & 250 & GC-MS & 0.06-2.38 & - & [374] \\  & & & & & & & & & & & & & \\  & & & & & & & & & & & & & \\ \hline \multicolumn{11}{c}{_Volatile and semivolatile organic compounds_} \\ VOC & soil, manure, compost, biochar & HS-SPME & PDMS-DVB- & 20 & 20 & - & - & 5 & 230 & GC-MS & 0.01-310 & - & [375] \\  & cow slurry & HS-SPME & PDMS-DVB- & 15 & 35 & NaCl & - & 3 & 300 & GC-MS & 0.02-141 & - & [376] \\  & & & & & & & & & & & & & \\  & & & & & & & & & & & & & \\  & & & & & & & & & & & & & \\ Volatile and & urban landfill soil & HS-SPME & PDMS-DVB & 30 & 50 & NaCl & - & - & 250 & GC-MS & - & - & [377] \\  & semivolatile organic compounds & & & & & & & & & & & & \\  & & & & & & & & & & & & & \\  & & & & & & & & & & & & & \\ \hline \multicolumn{11}{c}{_Pesticides_} \\ Pytrehroids, organochlorine & agricultural soils & HS-SPME & PA & 30 & 100 & - & - & 5 & 290 & GC- & 0.004–1.2 & 71–147 & [378] \\  & pesticides & & & & & & & & & & & & & \\ \multicolumn{11}{c}{_Pytrehroids_} \\  & sediment pore water & SPME & PDMS & 20 & - & - & - & 3 & 260 & GC-ECD & - & - & [379] \\ \hline \hline \end{tabular}
\end{table} 
Table 4: \(Cont.\) \begin{table}
\begin{tabular}{l l l l l l l l l l l l l l l} \hline \hline  & & \multicolumn{6}{c}{**Extraction conditions**} & \multicolumn{6}{c}{**Description**} \\  & & & & & & & & & & & & & & \\
**Analyte** & **Environmental Sample** & **Technique** & **Fiber** & **Time** & **Temp.** & **(Salt)** & **Deriv.** & **Time** & **Temp.** & **Detection** & **LOD** & **Rewory** & **Ref.** \\  & & & & **[min]** & **[°C]** & **Addition** & & **[min]** & **[°C]** & & & **[\%]** & \\ \hline \multicolumn{11}{c}{_P4H and related compounds_} \\ PAH & sediment pore water, sediments & SPME & PDMS & 500 h & 18 & 1 mL.10 mM - & 15 & & 50 °C to - & - & - & [380] \\  & & sediments & & & NaN\({}_{3}\) & & & & 250 °C at & & & \\  & & & & & & & & & 200 °C & & & \\ PAH & coastal sediments, MAE with acetone prior to & DI-SPME & PDMS & 60 & 60 & - & - & - & 270 & GC-MS & 0.07-0.76 & 70–110 & [381] \\  & SPME & & & & & & & & & & & \\ PAH & sand, sediment & CF-HS- & PDMS & 40 & 150 & - & - & 2 & 300 & GC-FID & 0.3–3 pg/g & - & [54] \\  & SPME & & & & (fiber: & & & & & & \\ Parent and alkyl & sediment pore water & HS-SPME & PDMS & 30 & - & - & - & 5 & 320 & GC-MS & 0.002–0.6 & - & [382] \\ PAH & & & & & & & & & & & & ng/mL & \\ \hline \multicolumn{11}{c}{_Miscellaneous_} \\ \hline
4-\(t\)-octylphenol, nonsylphenol, bisphend & activated sludge & nd-SPME & PA & - & 20 & - & - & 5 & 2800 & GC-MS & - & - & [383] \\  & cow slurry & HS-SPME & PDMS-DVB- & 15 & 35 & NaCl & MTBST & 9 & 300 & GC-MS & 0.004–707 & \textgreater{}64 & [94] \\  & CAR & & & & & & & & & & & \\  & Soil & HS-SPME & sol-gel M-ß- & 60 & 95 & methanol & - & 12 & 300 & GC-MS & 13.0–78.3 & 78–99 & [384] \\  & & CD-OH-TSO & & & & & & & & & & & \\  & Perfluoro-carboxylic & harbour sediments, PFE & HS-SPME & PDMS & 30 & 30 & saturated & boron & 3 & 300 & GC-MS & 0.5–0.8 ng/g & 99–103 & [95] \\  & & prior to SPME & & & & & & & & & & \\  & & & & & & & & & & & \\ \end{tabular}
\end{table}