## 2 Results
** & **Compound** & **Experimental Retention** & **Literature Retention** & **BA [\%]** & **SD** & **IAA** [\%]** & **SD** \\ \hline
1 & Hexanal & 807 & 806 & 6.87 \({}^{\ast\ast}\) & \(\pm\)1.13 & 4.53 \({}^{\text{\,at}}\) & \(\pm\)0.45 \\ \hline
2 & 2-Hexenal & 858 & 860 & 22.53 \({}^{\text{\,at}}\) & \(\pm\)3.74 & 25.48 \({}^{\text{\,c}}\) & \(\pm\)2.77 \\ \hline
3 & 1-Hexanol & 862 & 868 & 40.89 \({}^{\ast\ast}\) & \(\pm\)3.58 & 36.44 \({}^{\text{\,at}}\) & \(\pm\)2.02 \\ \hline
4 & 2-Heptenal, (\(Z\))- & 961 & 964 & 1.12 \({}^{\text{\,s}}\) & \(\pm\)0.18 & 0.79 \({}^{\text{\,s}}\) & \(\pm\)0.09 \\ \hline
5 & 2-Hexenoic acid, methyl ester, (\(E\))- & 970 & 966 & 1.94 \({}^{\text{\,t}}\) & \(\pm\)0.84 & 0.99 \({}^{\text{\,s}}\) & \(\pm\)0.49 \\ \hline
6 & 1-Heptenal & 974 & 970 & - & - & 0.24 \({}^{\text{\,s}}\) & \(\pm\)0.25 \\ \hline
7 & 1-Octen-3-ol & 983 & 980 & - & - & 0.35 \({}^{\text{\,s}}\) & \(\pm\)0.32 \\ \hline
8 & 3-Octanone, 2-methyl- & 987 & 985 & 0.59 \({}^{\text{\,s}}\) & \(\pm\)0.44 & 2.67 \({}^{\text{\,s}}\) & \(\pm\)1.72 \\ \hline
9 & Hexanoic acid & 989 & 981 & 0.91 \({}^{\text{\,s}}\) & \(\pm\)0.69 & 1.05 \({}^{\text{\,s}}\) & \(\pm\)0.53 \\ \hline
10 & Furan, 2-pentyl- & 992 & 993 & 0.67 \({}^{\text{\,s}}\) & \(\pm\)0.27 & 0.39 \({}^{\text{\,s}}\) & \(\pm\)0.08 \\ \hline
11 & Octanal & 1004 & 1007 & - & - & 1.04 \({}^{\text{\,s}}\) & \(\pm\)1.01 \\ \hline
12 & \(\circ\)-Cymene & 1029 & 1022 & - & - & 0.82 \({}^{\text{\,s}}\) & \(\pm\)0.64 \\ \hline
13 & Limonene & 1034 & 1031 & 1.26 \({}^{\text{\,s}}\) & \(\pm\)0.31 & 0.95 \({}^{\text{\,s}}\) & \(\pm\)0.22 \\ \hline
14 & Eucalypt & 1036 & 1033 & 1.66 \({}^{\text{\,s}}\) & \(\pm\)0.11 & 0.93 \({}^{\text{\,s}}\) & \(\pm\)0.18 \\ \hline
15 & Pyrazine, 3-methoxy-2-5-dimethyl- & 1057 & 1054 & 0.39 \({}^{\text{\,s}}\) & \(\pm\)0.26 & 0.43 \({}^{\text{\,s}}\) & \(\pm\)0.09 \\ \hline
16 & 1-Octanol & 1074 & 1082 & 0.70 \({}^{\text{\,s}}\) & \(\pm\)0.35 & 0.60 \({}^{\text{\,s}}\) & \(\pm\)0.26 \\ \hline
17 & Heptenaic acid & 1082 & 1078 & 0.45 \({}^{\text{\,s}}\) & \(\pm\)0.30 & - & - \\ \hline
18 & Pyrazine, 2-methoxy-3-(1-methylethyl)- & 1096 & 1093 & 1.27 \({}^{\text{\,s}}\) & \(\pm\)0.09 & 2.07 \({}^{\text{\,s}}\) & \(\pm\)0.36 \\ \hline
19 & Linalool & 1100 & 1103 & 1.49 \({}^{\text{\,s}}\) & \(\pm\)0.24 & 0.57 \({}^{\text{\,s}}\) & \(\pm\)0.07 \\ \hline
20 & Nonanal & 1105 & 1104 & 0.67 \({}^{\text{\,s}}\) & \(\pm\)0.17 & 1.30 \({}^{\text{\,s}}\) & \(\pm\)1.29 \\ \hline
21 & Hexanoic acid, 2-ethyl- & 1126 & 1123 & - & - & 0.85 \({}^{\text{\,s}}\) & \(\pm\)0.64 \\ \hline
22 & Benzene, 1-2-dimethoxy-y & 1149 & 1149 & 1.13 \({}^{\text{\,s}}\) & \(\pm\)0.23 & 0.78 \({}^{\text{\,s}}\) & \(\pm\)0.12 \\ \hline
23 & Pyrazine, 2-methoxy-3-(1-methylpropyl)- & 1175 & 1175 & 2.55 \({}^{\text{\,s}}\) & \(\pm\)0.98 & 2.45 \({}^{\text{\,s}}\) & \(\pm\)0.71 \\ \hline
24 & Octanoic Acid & 1179 & 1182 & 0.66 \({}^{\text{\,s}}\) & \(\pm\)0.35 & 0.98 \({}^{\text{\,s}}\) & \(\pm\)0.40 \\ \hline
25 & Pyrazine, 2-methoxy-3-(2-methylpropyl)- & 1182 & 1192 & 1.03 \({}^{\text{\,s}}\) & \(\pm\)0.22 & 1.31 \({}^{\text{\,s}}\) & \(\pm\)0.07 \\ \hline
26 & Ethanol, 2-(2-butoxyethoxy)- & 1190 & 1196 & - & - & 0.36 \({}^{\text{\,s}}\) & \(\pm\)0.23 \\ \hline
27 & Decanal & 1205 & 1206 & 0.89 \({}^{\text{\,s}}\) & \(\pm\)0.23 & 0.51 \({}^{\text{\,s}}\) & \(\pm\)0.08 \\ \hline
28 & 2-Decanal & 1263 & 1270 & - & - & 0.60 \({}^{\text{\,s}}\) & \(\pm\)0.76 \\ \hline
29 & Nonanoic acid & 1277 & 1280 & 1.24 \({}^{\text{\,s}}\) & \(\pm\)0.32 & 1.06 \({}^{\text{\,s}}\) & \(\pm\)0.90 \\ \hline
30 & Thymol & 1293 & 1291 & 0.67 \({}^{\text{\,s}}\) & \(\pm\)0.11 & 1.60 \({}^{\text{\,s}}\) & \(\pm\)1.18 \\ \hline
31 & Unknown 1 & 1359 & - & 0.74 \({}^{\text{\,s}}\) & \(\pm\)0.37 & 0.65 \({}^{\text{\,s}}\) & \(\pm\)0.20 \\ \hline
32 & Unknown 2 & 1375 & - & 0.55 \({}^{\text{\,s}}\) & \(\pm\)0.22 & 1.49 \({}^{\text{\,s}}\) & \(\pm\)0.69 \\ \hline
33 & Unknown 3 & 1379 & - & 1.07 \({}^{\text{\,s}}\) & \(\pm\)0.61 & 0.63 \({}^{\text{\,s}}\) & \(\pm\)0.59 \\ \hline
34 & Tetradecane & 1399 & 1400 & - & - & 0.59 \({}^{\text{\,s}}\) & \(\pm\)0.51 \\ \hline
35 & Geranyl acetone & 1457 & 1452 & - & - & 0.27 \({}^{\text{\,s}}\) & \(\pm\)0.05 \\ \hline