## Appendix C The Identified Compound No. 3 (2-deoxy-5,20,26-trihydroxyecdyson 20,22-acetonide)  
\([R]_{D}^{25}\) +25 (c 0.05 MeOH); UV (MeOH) \(\lambda\)max (log \(\varepsilon\)) **238 (4.08) nm; \({}^{1}\)H NMR (CD3 OD, 500 MHz, Chloroform-d) \(\delta\)** 5.86 (1H, s, br, OH), 4.08 (1H, s, br, CH), 3.70 (1H, m, OH), 3.37 (1H, \(d\), \(J\) 11.0 Hz, CH), 3.36 (1H, \(d\), \(J\) 11.0 Hz, CH), 3.28 (1H, m, CH), 2.32 (1H, \(t\), \(J\) 8.7 Hz,CH), 2.12 (1H, _td, J_ 12.4, 5.7 Hz, CH), 2.04 (1H, m, CH), 2.035 (1H, m, CH), 1.97 (1H, m, CH), 1.96 (1H, m, CH), 1.88 (1H, m, CH), 1.86 (1H, m, CH), 1.84 (1H, m, CH), 1.77 (1H, m, CH), 1.73 (1H, m, CH), 1.72 (1H, m, CH) 1.61 (2H, m, CH), 1.55 (2H, m, CH), 1.53 (1H, m, CH), 1.50 (1H, m, CH), 1.39 (3H, s, CH), 1.32 (3H, s, CH), 1.18 (3H, s, CH), 1.15 (3H, s, CH), 0.89 (3H, s, CH), 0.83 (3H, s, CH); 13C NMR (CD3 OD, 125 MHz) \(\&\) 167.9, 120.7, 108.2, 86.0, 85.4, 83.6, 81.2, 73.6, 70.7, 67.2, 50.6, 48.7, 43.25, 38.1, 37.2, 36.9, 32.6, 31.8, 29.5, 29.3, 27.3, 25.6, 24.05, 23.8, 22.7, 22.5, 22.5, 17.8, 17.3; ESIMS m/z 559 [M + Na]+ (100), 537 [M + H]+ (36), 518 [M - H2O]+ (3), 541 [M + Na - H2O]+ (12), 501 [M + H - 2H2O]+ (2), 445 (10), 385 [M + H - H2O - C603H14]+ (3), 315 (12), 304 (24). HRESIMS m=z 537.3420 (calculated for C30H4908, 537.3414). Appendix D The Identified Compound No. 4 (20,26-dihydroxyocytoson 20,22-acetonide) \([R]_{D}^{25}\) +145 (c 0.005 MeOH); UV (MeOH) \(\uplambda\) (log \(\epsilon\)) 242 (4.01) nm; \({}^{1}\)H NMR (CD3 OD), 500 MHz, Chloroform-d) \(\&\) 5.86 (1H, _d, J_ 2.6 Hz, CH), 3.70 (1H, m, OH), 3.38 (1H, d, J 10.9 Hz, CH), 3.36 (1H, _d, J_ 11.0 Hz, CH), 2.42 (1H, _dd, J_ 12.6, 4.0 Hz, CH), 2.33 (1H, _dd, J_ 9.2, 8.6 Hz, CH), 1.39 (3H, s, CH), 1.32 (3H, s, CH)=, 1.18 (3H, s, CH), 1.15 (3H, s, CH)3, 1.08 (3H, s, CH), 1. * [PERSON] et al. (2001) [PERSON]; [PERSON]; [PERSON]; [PERSON]; [PERSON] Occurrence of cadaverine in hairy roots of _Brugmansia candidia. Phytochemistry_**2001**, _57_, 759-763. [CrossRef]
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