# Establishment of the Volatile Signature of Wine-Based Aromatic Vinegars Subjected to Maceration
## 2 Results and Discussion
### Characterization of Volatile Signature of WBAV by Maceration Using HS-SPME/GC-MS

Table 1: \begin{table}
\begin{tabular}{c c c c c c c c c c c c c c} \hline \hline
**Peak** & **RT \({}^{1}\)** & **K\({}_{\text{Cla }}\)\({}^{2}\)** & **K\({}_{\text{Ilg }}\)\({}^{3}\)** & **Chemical Families** & \multicolumn{6}{c}{**GPC Peak Area \(\times\) 10\({}^{9}\) (RSD)**} \\ \cline{4-13}
**Number** & **(min)** & & & & & & & & & & & \\ \hline
90 & 39.66 & 1970 & 1974 & Methyl jasmonate \({}^{4}\) & 0.98 & (2) & 0.81 & (4) & - & - & 0.26 & (12) & - \\
95 & 43.13 & 2193 & 2189 & Premyethy benoxane \({}^{4}\) & 1.82 & (3) & 3.52 & (13) & 1.81 & (18) & 0.82 & (4) & 2.20 & (11) \\
100 & 48.08 & 2308 & 2301 & Methyl breadacomate \({}^{4}\) & 0.41 & (6) & 1.99 & (12) & 0.45 & (6) & - & 0.53 & (14) \\ \hline \multicolumn{13}{c}{_Alcohals_} \\ \hline
2 & 3.15 & 968 & 972 & Ethanol & 773.10 & (10) & 845.14 & (11) & 1040.94 & (16) & 1099.28 & (12) & 946.25 & (6) \\
3 & 4.66 & 1074 & 1099 & 2-butanol & 12.75 & (6) & 11.75 & (19) & - & 14.45 & (2) \\
6 & 6.12 & 1113 & 1112 & 2-Methyl-1-propanol & 23.13 & (12) & 13.42 & (9) & 9.14 & (12) & 14.55 & (17) & 19.72 & (8) \\
8 & 7.87 & 1165 & 1176 & 2-Hexanol & 2.75 & (7) & 3.25 & (10) & 1.86 & (12) & 2.19 & (15) & - \\
11 & 9.51 & 1206 & 1206 & 3-Methylbutanol & 46.65 & (8) & 20.37 & (13) & 209.63 & (9) & 301.03 & (7) & 399.42 & (2) \\
20 & 13.51 & 1312 & 1332 & 2-Heptanol \({}^{4}\) & 0.23 & (4) & 1.23 & (6) & 1.01 & (3) & 1.61 & (8) & - \\
23 & 15.15 & 1350 & 1360 & 1-Hexanol & 23.03 & (10) & 3.89 & (13) & 69.49 & (3) & 55.64 & (0) & 63.41 & (3) \\
24 & 15.23 & 1352 & 1386 & 3-Hexanol isomer & 0.22 & (18) & 0.47 & (9) & 0.26 & (2) & 0.77 & (19) & 0.41 & (15) \\
27 & 15.81 & 1364 & 1379 & 3-Ethoxyphenyl0 \({}^{4}\) & 0.14 & (10) & 1.82 & (6) & 1.29 & (14) & - & - & - \\
28 & 16.11 & 1371 & 1391 & 3-Hexanol isomer & 5.78 & (9) & 1.83 & (16) & 2.01 & (11) & 8.56 & (13) & 6.49 & (4) \\
33 & 17.69 & 1383 & 1388 & 1-Octanol & 10.25 & (4) & 6.01 & (16) & 10.23 & (1) & 5.63 & (2) & - & \\
42 & 20.48 & 1475 & 1465 & 1-Octanol \({}^{3}\) & 7.12 & (1) & 7.91 & (2) & 9.67 & (9) & 0.32 & (3) & - & \\
46 & 21.71 & 1503 & 1487 & 2-Ethyshenad \({}^{4}\) & 2.56 & (5) & 2.54 & (13) & - & 8.17 & (9) & 10.03 & (1) \\
48 & 22.43 & 1521 & 1546 & 2-3,Buttenediol isomer & 5.06 & (3) & 14.92 & (12) & 1.79 & (4) & 0.29 & (13) & 10.03 & (1) \\
52 & 23.32 & 1540 & 1535 & 2-Nomomated \({}^{4}\) & 0.53 & (9) & 1.91 & (3) & 4.37 & (7) & 3.13 & (8) & - & \\
56 & 23.93 & 1556 & 1583 & 2-3,Buttenediol isomer & 9.44 & (11) & 5.73 & (15) & 1.52 & (8) & 0.27 & (11) & - & \\
72 & 29.65 & 1701 & 1723 & Methinol \({}^{4}\) & 1.21 & (2) & 1.39 & (19) & 1.35 & (5) & 1.66 & (8) & - & \\
73 & 31.28 & 1750 & 1765 & 1-Decanol \({}^{4}\) & 1.60 & (12) & 5.82 & (12) & 1.08 & (17) & 2.22 & (7) & 8.32 & (9) \\
87 & 37.94 & 1898 & 1925 & 2-Phenylethanol & 124.77 & (5) & 78.46 & (12) & 27.58 & (7) & 63.08 & (6) & 68.75 & (6) \\
89 & 39.24 & 1956 & 1952 & Tricodem \({}^{4}\) & 0.67 & (7) & 2.14 & (12) & 6.68 & (10) & 0.99 & (12) & 4.35 & (2) \\ \hline \multicolumn{13}{c}{_Treprequis_} \\ \hline
9 & 8.38 & 1178 & 1182 & Limnenenen & 101.05 & (1) & 82.77 & (6) & 79.66 & (12) & 78.23 & (3) & 104.46 & (8) \\
10 & 8.76 & 1187 & 1214 & Encidyptol & 1.11 & (4) & 4.21 & (21) & 2.13 & (2) & - & 2.15 & (4) \\
113 & 11.18 & 1254 & 1233 & Sabineine & 2.22 & (15) & 6.03 & (2) & 1.19 & (15) & - & - & - \\
19 & 13.38 & 1308 & 1337 & Rose oxide isomer \({}^{4}\) & 8.25 & (3) & 8.31 & (2) & 9.78 & (12) & 9.23 & (1) & 9.77 & (4) \\
32 & 16.74 & 1392 & 1421 & Linaliod oxide isomer & - & - & 1.45 & (12) & 0.33 & (10) & 8.76 & (6) \\
38 & 19.22 & 1443 & 1449 & Dihydrodinolized \({}^{4}\) & 1.32 & (8) & 9.83 & (14) & 1.37 & (20) & 2.61 & (2) & - & \\
39 & 19.44 & 1448 & 1467 & Linaliod oxide isomer & - & 3.32 & (14) & 0.96 & (7) & 0.18 & (6) & - & \\
40 & 19.97 & 1462 & 1474 & Merchone \({}^{4}\) & - & 8.42 & (9) & 4.19 & (2) & - & 14.19 & (14) \\
41 & 20.16 & 1467 & 1467 & Limnenen oxide & - & 12.48 & (15) & 6.40 & (7) & 9.81 & (3) & 7.15 & (3) \\ \hline \hline \end{tabular}
\end{table} 
Table 1: _Cont._