## 2 Materials and Methods
### Grape Materials and Winemaking
 }} & \multirow{2}{*}{**CAS**} & \multicolumn{2}{c}{**Chemical**} & \multicolumn{2}{c}{**Configure**} & \multicolumn{2}{c}{**Linearly**} \\  & & **Formula** & & **Range** & **Coefficient** \\ \hline \multirow{10}{*}{Aldehydes} & 111-71-7 & C\({}_{7}\)H\({}_{4}\)O & Heptanal & 10–160 \(\mu\)g/L & y = 29.74x + 0.0397 & R\({}^{2}\) = 0.9982 \\  & 124-13-0 & C\({}_{8}\)H\({}_{6}\)O & Octanal & 10–160 \(\mu\)g/L & y = 125.84x \(-\) 2.0365 & R\({}^{2}\) = 0.9934 \\  & 124-19-6 & C\({}_{9}\)H\({}_{8}\)O & Nonanal & 10–160 \(\mu\)g/L & y = 28.958x \(-\) 0.0203 & R\({}^{2}\) = 0.9972 \\  & 100-52-7 & C\({}_{7}\)H\({}_{6}\)O & Benzaldehyde & 10–160 \(\mu\)g/L & y = 12.281x \(-\) 0.1913 & R\({}^{2}\) = 0.9974 \\  & 18829-55-5 & C\({}_{7}\)H\({}_{2}\)O & (E)-2-Heptenal & 10–160 \(\mu\)g/L & y = 23.382x \(+\) 0.1089 & R\({}^{2}\) = 0.9989 \\  & 2548-87-0 & C\({}_{8}\)H\({}_{4}\)O & (E)-2-Octanal & 10–160 \(\mu\)g/L & y = 66.898x \(-\) 1.1385 & R\({}^{2}\) = 0.9975 \\  & 4313-03-5 & C\({}_{7}\)H\({}_{6}\)O & (E, E)-2-4-Heptenal & 10–160 \(\mu\)g/L & y = 19.919x \(-\) 0.1225 & R\({}^{2}\) = 0.9996 \\  & 5910-87-2 & C\({}_{9}\)H\({}_{4}\)O & (E, E)-2,4-Nonadienal & 10–160 \(\mu\)g/L & y = 32.147x \(-\) 0.9573 & R\({}^{2}\) = 0.9921 \\  & 112-31-2 & C\({}_{10}\)H\({}_{20}\)O & Decanal & 10–160 \(\mu\)g/L & y = 259.53x \(-\) 10.679 & R\({}^{2}\) = 0.9923 \\  & 18829-56-6 & C\({}_{9}\)H\({}_{6}\)O & (E)-2-Nonanal & 10–160 \(\mu\)g/L & y = 145.84x \(-\) 5.5835 & R\({}^{2}\) = 0.9927 \\  & 557-48-2 & C\({}_{9}\)H\({}_{4}\)O & (E, Z)-2,6-Nonadienal & 10–160 \(\mu\)g/L & y = 47.523x \(-\) 1.0794 & R\({}^{2}\) = 0.9998 \\ \hline \multirow{10}{*}{Terpenes} & 99-83-2 & C\({}_{10}\)H\({}_{6}\) & \(a\)-Phellandrene & 10–160 \(\mu\)g/L & y = 152.44x \(-\) 3.4687 & R\({}^{2}\) = 0.9985 \\  & 123-35-3 & C\({}_{10}\)H\({}_{6}\) & \(\beta\)-Myrone & 10–160 \(\mu\)g/L & y = 141.09x \(-\) 2.865 & R\({}^{2}\) = 0.9971 \\  & 106-25-2 & C\({}_{10}\)H\({}_{8}\)O & Nerol & 10–160 \(\mu\)g/L & y = 35.863x \(-\) 0.6729 & R\({}^{2}\) = 0.9937 \\  & 16409-43-1 & C\({}_{10}\)H\({}_{8}\)O & (Z)-Rose oxide & 10–160 \(\mu\)g/L & y = 209.19x \(-\) 4.503 & R\({}^{2}\) = 0.9982 \\  & 78-70-6 & C\({}_{10}\)H\({}_{8}\)O & Linalool & 10–160 \(\mu\)g/L & y = 79.016x \(-\) 0.1611 & R\({}^{2}\) = 0.9941 \\  & 562-74-3 & C\({}_{10}\)H\({}_{8}\)O & 4-Terpinenol & 10–160 \(\mu\)g/L & y = 69.579x \(-\) 0.3551 & R\({}^{2}\) = 0.9995 \\  & 985-55 & C\({}_{10}\)H\({}_{8}\)O & \(a\)-Terpinenol & 10–160 \(\mu\)g/L & y = 46.539x \(-\) 0.6597 & R\({}^{2}\) = 0.9996 \\  & 106-22-9 & C\({}_{10}\)H\({}_{20}\)O & Citronellol & 10–160 \(\mu\)g/L & y = 67.36x \(-\) 1.497 & R\({}^{2}\) = 0.9972 \\  & 106-24-1 & C\({}_{10}\)H\({}_{8}\)O & Geraniol & 10–160 \(\mu\)g/L & y = 29.682x \(-\) 0.3935 & R\({}^{2}\) = 0.9939 \\  & 87-44-5 & C\({}_{15}\)H\({}_{24}\) & \(\beta\)-Caryophyllene & 10–160 \(\mu\)g/L & y = 189.71x \(-\) 8.1006 & R\({}^{2}\) = 0.9924 \\  & 536-59-4 & C\({}_{10}\)H\({}_{6}\)O & Dihydrocumi amyloid alcohol & 10–160 \(\mu\)g/L & y = 11.437x \(-\) 0.2996 & R\({}^{2}\) = 0.9951 \\  & 99-49-0 & C\({}_{10}\)H\({}_{4}\)O & Carvone & 10–160 \(\mu\)g/L & y = 63.254x \(-\) 2.057 & R\({}^{2}\) = 0.9951 \\  & 5989-27-5 & C\({}_{10}\)H\({}_{16}\) & D-Limonene & 10–160 \(\mu\)g/L & y = 189.67x \(-\) 1.6892 & R\({}^{2}\) = 0.9928 \\  & 99-87-6 & C\({}_{10}\)H\({}_{4}\) & \(p\)-Cymene & 10–160 \(\mu\)g/L & y = 171.97x \(-\) 1.0382 & R\({}^{2}\) = 0.9967 \\  & 502-61-4 & C\({}_{15}\)H\({}_{24}\) & Farnesene & 10–160 \(\mu\)g/L & y = 69.691x \