# 2-Methoxy-4-Vinylphenol as a Biobased Monomer Precursor for Thermoplastics and Thermoset Polymers
## 4 Conclusions
**Supplementary Materials:** The synthetic approaches used for the preparation of MVP-derived monomers and their complete physicochemical characterization, as well as that of their respective homopolymers can be downloaded at [[https://www.mdpi.com/article/10.3390/polym15092168/s1](https://www.mdpi.com/article/10.3390/polym15092168/s1)]([https://www.mdpi.com/article/10.3390/polym15092168/s1](https://www.mdpi.com/article/10.3390/polym15092168/s1)), Figure S1: \({}^{1}\)H-NMR of MVP in DMSO-d\({}_{6}\); Figure S2: \({}^{13}\)C-NMR of MVP in CDCl\({}_{3}\); Figure S3: \({}^{1}\)H-NMR of MVP; Figure S4: \({}^{1}\)H-NMR of MVP-AcOMe in DMSO-d\({}_{6}\); Figure S5: \({}^{13}\)C-NMR of MVP-AcOMe in CDCl\({}_{3}\); Figure S6: \({}^{1}\)H-NMR of MVP-AcOH in DMSO-d\({}_{6}\); Figure S7: \({}^{13}\)C-NMR of MVP-AcOH in DMSO-d\({}_{6}\); Figure S8: \({}^{1}\)H-NMR of MVP-Bz in DMSO-d\({}_{6}\); Figure S9: \({}^{13}\)C-NMR of MVP-Bz in DMSO-d\({}_{6}\); Figure S10: FT-IR of bio-based monomers derived from MVP; Figure S11: \({}^{1}\)H-NMR kinetics of P(MVP-AcOMe) prepared by solution polymerization in DMSO-d\({}_{6}\); Figure S12: \({}^{13}\)H-NMR kinetics of P(MVP-AcOH) prepared by solution polymerization in DMSO-d\({}_{6}\); Figure S13: \({}^{1}\)H-NMR kinetics of P(MVP-Bz) prepared by solution polymerization in DMSO-d\({}_{6}\); Figure S14: Conversion plot of the solution homopolymersizations of the bio-based monomers; Figure S15: FT-IR of bio-based solution homopolymers; Figure S16: FT-IR of emulsion bio-based copolymers; Table S1: Dry content and final conversion of the copolymers prepared via emulsion polymerization; Figure S17: \({}^{1}\)H-NMR spectra of the bio-based emulsion copolymers; Figure S18: Digital images of the bio-based emulsion polymers; (top) liquid dispersion before annealing and (bottom) after annealing; Table S2: DLS results of bio-based emulsions; Figure S19: First derivative from TGA for solution (a) and emulsion (b) polymers; Table S4: Ash content for the solution and emulsion polymers; Figure S20: DSC traces of the MVP-based monomers; Figure S21: DSC traces of the MVP-based polymers obtained via emulsion copolymerization; Figure S22: DSC traces of the MVP-based polymers obtained via emulsion copolymerization with styrene; Table S5: Amounts used for the synthesis of crosslinkers; Table S6: Amounts used for the preparation of thermoset films; Figure S23: \({}^{1}\)H-NMR of 1,3-MVP in CDCl\({}_{3}\); Figure S24: \({}^{13}\)C-NMR of 1,3-MVP in CDCl\({}_{3}\); Figure S25: HSQC of 1,3-MVP in CDCl\({}_{3}\); Figure S26: \({}^{1}\)H-NMR of 1,6-MVP in CDCl\({}_{3}\); Figure S27: \({}^{13}\)C-NMR of 1,6-MVP in CDCl\({}_{3}\); Figure S28. HSQC of 1,6-MVP in CDCl\({}_{3}\); Figure S29: \({}^{1}\)H-NMR of 1,10-MVP in CDCl\({}_{3}\); Figure S30: \({}^{13}\)C-NMR of 1,10-MVP in CDCl\({}_{3}\); Figure S31: HSQC of 1,10-MVP in CDCl\({}_{3}\); Figure S32: FT-IR of bio-based monomers for thermosetting applications; Figure S33: FT-IR of bio-based thermosets based on MVP-derived distyrenic monomers; Figure S34: Digital images of the bio-based thermosets after DMA characterization; Figure S35: TGA thermograms of the thermosets; Table S7: Ash content of the thermosets; Figure S36: DSC traces of the DVB monomers; Figure S37: Thermal curing studied in situ during DSC analysis; Table S8: Maximum curing peak extrapolated from the DSC curves of Figure S37; Figure S38: DSC traces of the thermally crosslinked thermosets; Table S9: Melting temperature and enthalpy of melting of the DVB-like monomers obtained from DSC; Figure S39: Digital images of the chemical stability test of the thermosets; Table S10: Chemical stability of thermosetting films; Table S11: Bio-based characteristics of the synthesized bio-monomers; Table S12: Bio-based characteristics of a selection of lignin-derived monomers containing a functional double bond; Figure S39: Van Kreelen diagram for commercially available fossil-based and bio-based monomers/polymers in comparison with the bio-based monomers presented in this work. Refs.