## 7 Applications
### Other Applications of TF-SPME
\begin{table}
\begin{tabular}{c c c c c c} \hline \hline
**Extraction Phase Chemistry** & **Sample** & **Targeted Analyses** & **Instrumentation** & **Couting Method** & **Ref.** \\ \hline \multicolumn{6}{c}{**Environmental Analysis**} \\ \hline PDMS & Environmental waters & PAHs & GC-MS & N/A & [12] \\ PDMS & Environmental waters & PAHs & GC-MS & N/A & [16] \\ PDMS & Environmental waters & PAHs & GC-MS & N/A & [49] \\ PDMS & Deionized water & PAHs & GC-MS & N/A & [58] \\ PDMS & Environmental waters & PAHs & GC-MS & N/A & [59] \\ Carbonaceous Nanomaterials & Wastewater & PAHs & GC-MS & Evaporation & [20] \\ Evans and LDFE & Air & PAHs & GC-MS & Dipping & [45] \\ Polyacrylate & Environmental waters & PAHs & GC-MS & Dispersion & [32] \\ PDMS & Soil & PAHs & HPLC-FLD & Dispersion & [46] \\ EVA & Environmental waters & Pesticdes and PCBs & GC-MS & Dip coating & [48] \\ EVA & Air & PCBs & GC-MS & Dispersion & [44] \\ Various monophasic polymers & Soil & Pyrethoids & GC-MS & N/A & [60] \\ PDMS & Human skin & Sebum constituents (qualene/fatty acids) & GC-MS & N/A & [61] \\ PDMS & Plant Tissue & Plant volatiles & GC-MS & N/A & [33] \\ PDMS & Plants/Perfumes & Plant volatiles/perfumes & GC-MS & N/A & [62] \\ DVR/PDMS & Air & Benzene & GC-MS & Bar coating & [36] \\ Polyacrylonitrile & Environmental waters & UV filters/velocides & LC-MS & Spray coating & [54] \\ DVR/PDMS & Environmental waters & Toluene/ylene/pesticdes & GC-MS & Bar coating & [19] \\ DVR/PDMS & Environmental waters & Pesticdes & GC-MS & Bar coating & [55] \\ Car/PDMS & Environmental waters & Crude MCDM constituents & GC-MS & Bar coating & [5] \\ HLB/PDMS & Hot ub water & Chlorination byproducts & GC-MS & Bar coating & [30] \\ Graphene & Various aqueous samples & Trace metals & TXP & Drop-casting & [28] \\ Graphene & Aqueous & Methylcyclopentadhyay manganese tric tricarbonyl? & TXP & Drop-casting & [27] \\ Zeolitic imidazoline framework & Agricultural Wastewater & Ethon (insectic) & IMS & Electrospning & [63] \\ PDMS & Lake water & Organochlorine pesticides & GC-MS & Bar coating & [64] \\ (HLB, CI8, SAX, PS-DVW-WAX, HLB-SAX) & Synthetic Seawater & Fluorinated benzoic acids & LC-MS, GC-MS & Spray coating & [21] \\ PDMS & Fish tissue & Polychlorinated biphenyls & GC-MS & N/A & [65] \\ \hline \multicolumn{6}{c}{**Fluxes and fragrance**} \\ \hline DVR/PDMS & Beverage & Arona and flavor components & GC-MS & Bar coating & [66] \\ DVR/PDMS & Grapes & Linalool/IBMP & DART-MS & Dip coating & [67] \\ PDMS & Perfumes and foodstuffs & Volatile compounds & GC-MS & N/A & [62] \\ DVR/PDMS & Food & Arona and flavor components & GC-MS & Bar coating & [34] \\ PDMS & Grapes & Linalool/IBMP & DART-MS & Dip coating & [38] \\ \hline \hline \end{tabular}
\end{table} 
Table 3: Applications of TF-SPME and closely related devices. \begin{table}
\begin{tabular}{c c c c c c} \hline \hline  & **Other** & & & & \\ \hline PDMS & Human Skin & Volatile organic compounds & GC-MS & N/A & [35] \\ PDMS & Human Skin & Sebium & GC-MS & N/A & [61] \\ PDMS & Human Saliva & Prohibited substances and endogenous steroids & GC-MS, LC-MS & Bar coating & [52] \\ PDMS/DVB & Beverages and biological fluids & Drugs & GC-MS & Dip coating & [39] \\ ZSM-5/PDMS & Human saliva & Volatile metabolites & GC-MS & Deposition & [67] \\ \hline \hline EVA, ethylene-vinyl acetate; LDPE, low-density polyethylene; HLB, hydrophobic lipophilic balance; SAX, strong anion exchange; PAHs, polycyclic aromatic hydrocarbons; PCBs, polychlorinated biphenyl, PS-DVB-WAX, polystyrene divinylbenzene weak anion exchange; TXE, total reflection X-ray fluorescence; MS, ion mobility spectrometry. \\ \hline \hline \end{tabular}
\end{table} 
Table 3: _Cont._