## 9 Application of the TFME Technique in the Analysis of Organic Compounds
\begin{table}
\begin{tabular}{c c c c c c c} \hline \hline
**Analyte** & **Sorption Phase** & **Detection** & **LOD** & **Recovery** [\%]** & **RSD** [\%]** & **Ref.** \\ \hline \multirow{3}{*}{PAHs} & PDMS & GC-MS & - & - & 6–11 & [34] \\ \cline{2-7}  & MWCNTs/CTA & HPLC-UV & 0.02–0.09 ng/mL & 99–101 & 1–8 & [100] \\ \hline Polycyclic aromatic sulfur & MIP & GC-MS & 0.029–0.166 ug L\({}^{-1}\) & - & \(\leq\)6.0 & [59] \\ \hline \multirow{3}{*}{Pesticides/fungicides} & \multirow{3}{*}{DVB/PDMS} & GC-MS & 0.01–0.25 ug L\({}^{-1}\) & 90–130 & 2–20 & [42] \\ \cline{2-7}  & & GC-MS & 1.0–4.0 ng L\({}^{-1}\) & 71–124 & 3–20 & [43] \\ \hline \multirow{3}{*}{Pesticides/fungicides} & PPY/PA & GC-MS & 50 ng L\({}^{-1}\) & 96–98 & 4 & [52] \\ \cline{2-7}  & amino-Zr-MOF/PAN & CD-MS & 0.6 ug L\({}^{-1}\) & - & 11 & [74] \\ \cline{2-7}  & MWCNTs/CTA & GC-MS & 1 ug L\({}^{-1}\) & - & \(\leq\)20 & [96] \\ \cline{2-7}  & MIP & LC-MS/MS & 0.002–0.02 ug L\({}^{-1}\) & 90–110 & \textless{15} & [60] \\ \cline{2-7}  & PAMAM@GO-PVDF & HPLC-UV & 0.12–0.20 ug L\({}^{-1}\) & 98–99 & - & [89] \\ \cline{2-7}  & MOF/PU & GC-MS & 0.005–0.1 ug L\({}^{-1}\) & 72–110 & 4–5 & [128] \\ \cline{2-7}  & DES/CTA & GC-MS & 0.4–1.3 ug L\({}^{-1}\) & 69–103 & 3–14 & [127] \\ \cline{2-7}  & PVA/CA/C)/AV & HPLC-UV & - & 86–97 & 6–7 & [159] \\ \cline{2-7}  & DES & HPLC-UV & - & 72–94 & 3–11 & [160] \\ \cline{2-7}  & DVB/PDMS & GC-TMS & - & - & [40] \\ \hline \multirow{3}{*}{VOCs/SVOCs} & \multirow{3}{*}{DVB/PDMS} & GC-MS & - & - & [24] \\ \cline{2-7}  & & GC-MS & - & - & [24] \\ \hline N-nitrosamines & DVB/PDMS & GC-MS & 3 ng L\({}^{-1}\) & - & 8 & [22] \\ \hline Chlorobenzenes & PANI-N6 & GC-MS & 19–33 ng L\({}^{-1}\) & 93–103 & 5–14 & [54] \\ \hline \multirow{3}{*}{Phenols} & \multirow{3}{*}{MIP} & UHPLC-PDA & 0.1–2 ug L\({}^{-1}\) & 85–100 & 1–14 & [61] \\ \cline{2-7}  & & LC-MS & - & - & [63] \\ \cline{2-7}  & MWCNTs/COOH/PDMS & HPLC-UV & 1–2 ug L\({}^{-1}\) & 64–90 & - & [97] \\ \hline Polychlorinated biphenyls & MWCNTs-COOH-Ch/PP & GC-MS & \textless{}0.60 ng L\({}^{-1}\) & 86–104 & 0.17–5.01 & [99] \\ \hline Bisphenol A & PVA/PVP/PES & FS & 0.3 ng mL\({}^{-1}\) & 84–96 & 5–10 & [136] \\ \hline Phthalates, alkylphenols, bispendals & Polyamide-coated paper & HPLC-DAD & 1.5–7.6 ug L\({}^{-1}\) & - & \(\leq\)24\% & [137] \\ \hline Sulfonamides & p-Poly-(MMA-IL) & HPLC-DAD & 0.14–0.52 ug L\({}^{-1}\) & 90–110 & 10 & [116] \\ \hline Aniline & poly-(MMA-BVImBr) & LC-MS/MS & 0.5 ug L\({}^{-1}\) & 91–96 & 8.3 & [117] \\ \hline Parabens & DES & HPLC-UV & 0.018–0.055 ng L\({}^{-1}\) & 68–94 & 4–7 & [119] \\ \hline Parabens & PDMS/DES & HPLC-UV & 0.023–0.062 ng mL\({}^{-1}\) & 79–88 & 3–6 & [121] \\ \cline{2-7}  & CA-MIL-101(Cr)@CNFs & HPLC-DAD & 11 ng L\({}^{-1}\) & 92–100 & \textless{5} & [141] \\ \hline Formaldehyde & DES & HPLC-UV-Vis & 0.15 ng mL\({}^{-1}\) & 78–99 & 3–5 & [122] \\ \hline Personal care products &
\begin{tabular}{c} MIL- \\ 100(Fe)/PS/cellulose \\ \end{tabular} & HPLC-PDA & 7.5 ug L\({}^{-1}\) & 78–128 & 11 & [75] \\ \hline \hline \end{tabular}
\end{table} 
Table 13: Applicability of TF-SPME technique for quantitative analysis of different analytes in water matrix.