## 3 Experimental Section
### Volatile Profiling Method
\begin{table}
\begin{tabular}{l c c c c c} \hline \hline
**Code** & **Compound** & **Detection a** & **RI b** & **Min** & **Max** & **LSD** \\  & & & **(mg/L)** & **(mg/L)** & **(mg/L)** \\ \hline C1 & sulfur dioxide c & _m/z_ 64 & 510 & n.d. d & 1005 & 156 \\ C2 & acetaldehyde & SIM & 516 & n.d. d & 5.70 & 0.820 \\ C3 & 1-propanol & SIM & 572 & n.d. d & 5.33 & 0.713 \\ C4 & 2,3-butandione & SIM & 591 & n.d. d & 22.6 & 0.653 \\ C5 & acetic acid & _m/z_ 60 & 593 & 533 & 3720 & 726 \\ C6 & ethyl acetate & SIM & 611 & 309 & 903 & 113 \\ C7 & 2-methyl-1-propanol & SIM & 621 & 17.2 & 55.7 & 6.37 \\ C8 & 1-butanol & SIM & 653 & 708 & 2055 & 308 \\ C9 & acetoin & SIM & 695 & n.d. d & 1427 & 214 \\ C10 & ethyl propanoate & SIM & 700 & 3.13 & 8.57 & 0.628 \\ C11 & _n_-propyl acetate & SIM & 703 & 0.470 & 2.00 & 0.166 \\ C12 & 3-methyl-1-butanol & SIM & 725 & 195 & 447 & 51.0 \\ C13 & 2-methyl-1-butanol & SIM & 729 & 75.40 & 241 & 25.0 \\ C14 & ethyl 2-methylpropanoate & SIM & 753 & 3.77 & 32.1 & 1.52 \\ C15 & 2-methylpropyl acetate & SIM & 769 & 1.57 & 6.30 & 0.379 \\ C16 & 2,3-butandiol & SIM & 772 & n.d. d & 1732 & 726 \\ C17 & ethyl butanoate & SIM & 800 & 12.10 & 27.30 & 1.72 \\ C18 & ethyl lactate & _m/z_ 45 & 813 & 2974 & 16158 & 2019 \\ C19 & 3-methylbutanoic acid & _m/z_ 60 & 830 & n.d. d & 184 & 24.2 \\ C20 & furfural & _m/z_ 95 & 832 & n.d. d & 1079 & 45.7 \\ C21 & ethyl (E)-2-butenoate & SIM & 843 & 333 & 1234 & 72.6 \\ C22 & ethyl 2-methylbutanoate & SIM & 850 & 1.83 & 32.8 & 1.01 \\ C23 & ethyl 3-methylbutanoate & SIM & 853 & 3.13 & 37.7 & 1.36 \\ C24 & 1-hexanol & SIM & 867 & 10.0 & 62.5 & 6.19 \\ C25 & 3-methylbutyl acetate & SIM & 875 & 14.4 & 49.7 & 3.40 \\ C26 & 2-methylbutyl acetate & SIM & 878 & 1.87 & 5.50 & 0.335 \\ C27 & ethyl pentanoate & SIM & 899 & 254 & 1381 & 65.2 \\ \hline \hline \end{tabular}
\end{table} 
Table 7: Volatile compounds detected and quantified in this study. Shown are the mode of detection, as well as the calculated linear retention indices (RI) measured on a HP-5 ms column, the concentration ranges (minimum and maximum) expressed as μg internal standard equivalents (ISE) per liter wine, and the Fisher’s least significant different (LSD) concentrations (FDR \(<\) 0.05). _Molecules_**2015**, _20_  
\begin{table}
\begin{tabular}{l c c c c c c} \hline
**Code** & **Compound** & **Detection a ** & **RI b ** & _m/z_ 81 & 901 & n.d. d  & 4485 & 294 \\ C29 & diffurfuryl Ether c  & SIM & 901 & n.d. d  & 824 & 54.6 \\ C30 & butylolactone & SIM & 911 & n.d. d  & 361 & 115 \\ C31 & methyl hexanoate & SIM & 924 & n.d. d  & 592 & 226 \\ C32 & unidentified terpenenc  & SIM & 942 & n.d. d  & 133 & 14.3 \\ C33 & hexanoic Acid & _m/z_ 60 & 966 & 75.4 & 344 & 70.1 \\ C34 & 1-heptanol & SIM & 968 & n.d. d  & 1861 & 295 \\ C35 & ethyl hexanoate & SIM & 997 & 124 & 300 & 16.0 \\ C36 & n-hexyl acetate & SIM & 1010 & 1.47 & 10.4 & 0.403 \\ C37 & 2-ethoxy-2-(2-furyl)ethanol c  & SIM & 1024 & n.d. d  & 347 & 13.7 \\ C38 & _p_-cymene & SIM & 1032 & 0.530 & 2.13 & 0.372 \\ C39 & limonene & SIM & 1037 & n.d. d  & 5.33 & 0.764 \\ C40 & eucalypt & SIM & 1041 & n.d. d  & 632 & 39.9 \\ C41 & ethyl hexanoate & _m/z_ 97 & 1042 & 33.8 & 202 & 11.5 \\ C42 & ethyl 2-hexenoate c  & SIM & 1042 & n.d. d  & 3.67 & 0.246 \\ C43 & phenylacetaldehyde & SIM & 1050 & 0.97 & 2.57 & 0.579 \\ C44 & 2,5-dimethyl-4-methoxy-3(2H)-furanone & SIM & 1061 & n.d. d  & 1357 & 123 \\ C45 & isoamyl lactate c  & SIM & 1070 & 1.03 & 4.17 & 0.662 \\ C46 & (_Z_)-linalool oxide & SIM & 1079 & n.d. d  & 401 & 12.5 \\ C47 & ethyl heptanoate & SIM & 1095 & 1.03 & 6.13 & 0.210 \\ C48 & linalyl acetate & SIM & 1100 & n.d. d  & 854 & 68.8 \\ C49 & nonanal & SIM & 1104 & n.d. d  & 852 & 257 \\ C50 & phenethyl alcohol & SIM & 1121 & 44.6 & 206 & 42.84 \\ C51 & octanoic Acid & _m/z_ 60 & 1159 & n.d. d [FOOTNOTE:d]Footnote d: \(\mathrm{Int}\) \(\mathrm{Int}\